{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,7,2]],"date-time":"2026-07-02T05:44:49Z","timestamp":1782971089528,"version":"3.54.5"},"reference-count":70,"publisher":"Royal Society of Chemistry (RSC)","issue":"38","license":[{"start":{"date-parts":[[2026,8,21]],"date-time":"2026-08-21T00:00:00Z","timestamp":1787270400000},"content-version":"am","delay-in-days":597,"URL":"http:\/\/rsc.li\/journals-terms-of-use"}],"funder":[{"DOI":"10.13039\/501100006769","name":"Russian Science Foundation","doi-asserted-by":"publisher","award":["22-72-10034"],"award-info":[{"award-number":["22-72-10034"]}],"id":[{"id":"10.13039\/501100006769","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100012190","name":"Ministry of Science and Higher Education of the Russian Federation","doi-asserted-by":"publisher","award":["124013100858-3"],"award-info":[{"award-number":["124013100858-3"]}],"id":[{"id":"10.13039\/501100012190","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["rsc.org"],"crossmark-restriction":true},"short-container-title":["Dalton Trans."],"abstract":"<jats:p>\n                    The magneto-structural correlations of anhydrous neutral ferric and ferrous complexes based on the pyruvic acid thiosemicarbazone ligand [Fe\n                    <jats:sup>III<\/jats:sup>\n                    (Hthpy)(thpy)] and [Fe\n                    <jats:sup>II<\/jats:sup>\n                    (Hthpy)\n                    <jats:sub>2<\/jats:sub>\n                    ] have been determined for the first time.\n                  <\/jats:p>","DOI":"10.1039\/d5dt01623a","type":"journal-article","created":{"date-parts":[[2025,8,21]],"date-time":"2025-08-21T09:40:46Z","timestamp":1755769246000},"page":"14427-14439","update-policy":"https:\/\/doi.org\/10.1039\/rsc_crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["The magneto-structural correlations of ferric and ferrous neutral complexes with the pyruvic acid thiosemicarbazone ligand"],"prefix":"10.1039","volume":"54","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-7185-3041","authenticated-orcid":false,"given":"Maxim A.","family":"Blagov","sequence":"first","affiliation":[{"name":"Federal Research Center of Problems of Chemical Physics and Medicinal Chemistry, Russian Academy of, Sciences, Chernogolovka, Moscow region 142432, Russia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-3558-0776","authenticated-orcid":false,"given":"Anatoly S.","family":"Lobach","sequence":"additional","affiliation":[{"name":"Federal Research Center of Problems of Chemical Physics and Medicinal Chemistry, Russian Academy of, Sciences, Chernogolovka, Moscow region 142432, Russia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-1024-6461","authenticated-orcid":false,"given":"Leokadiya V.","family":"Zorina","sequence":"additional","affiliation":[{"name":"Osipyan Institute of Solid State Physics, Russian Academy of Sciences, Chernogolovka, Moscow region 142432, Russia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-6366-0255","authenticated-orcid":false,"given":"Sergey V.","family":"Simonov","sequence":"additional","affiliation":[{"name":"Osipyan Institute of Solid State Physics, Russian Academy of Sciences, Chernogolovka, Moscow region 142432, Russia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-7099-9599","authenticated-orcid":false,"given":"Konstantin V.","family":"Zakharov","sequence":"additional","affiliation":[{"name":"Lomonosov Moscow State University, Moscow 119991, Russia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-3558-6761","authenticated-orcid":false,"given":"Alexander N.","family":"Vasiliev","sequence":"additional","affiliation":[{"name":"Lomonosov Moscow State University, Moscow 119991, Russia"},{"name":"National University of Science and Technology MISIS, Moscow 119049, Russia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-8342-5474","authenticated-orcid":false,"given":"Nataliya G.","family":"Spitsyna","sequence":"additional","affiliation":[{"name":"Federal Research Center of Problems of Chemical Physics and Medicinal Chemistry, Russian Academy of, Sciences, Chernogolovka, Moscow region 142432, Russia"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"292","published-online":{"date-parts":[[2025]]},"reference":[{"key":"D5DT01623A\/cit1\/1","volume-title":"Spin-Crossover Materials: Properties and Applications","year":"2013","unstructured":"Spin-Crossover Materials: Properties and Applications , ed.  M. A. Halcrow ,  John Wiley & Sons Ltd. ,  Chichester ,  2013"},{"key":"D5DT01623A\/cit2\/1","doi-asserted-by":"crossref","first-page":"1","DOI":"10.1007\/b95410","volume":"234","author":"G\u00fctlich","year":"2004","journal-title":"Top. Curr. Chem."},{"issue":"21\u201324","key":"D5DT01623A\/cit3\/1","doi-asserted-by":"crossref","first-page":"2606","DOI":"10.1016\/j.ccr.2007.08.007","volume":"251","author":"Nihei","year":"2007","journal-title":"Coord. Chem. Rev."},{"issue":"10","key":"D5DT01623A\/cit4\/1","doi-asserted-by":"crossref","first-page":"101296","DOI":"10.1016\/j.jics.2024.101296","volume":"101","author":"Yousef","year":"2024","journal-title":"J. Indian Chem. Soc."},{"issue":"7","key":"D5DT01623A\/cit5\/1","doi-asserted-by":"crossref","first-page":"e22264","DOI":"10.1002\/ddr.22264","volume":"85","author":"Zhao","year":"2024","journal-title":"Drug Dev. Res."},{"key":"D5DT01623A\/cit6\/1","doi-asserted-by":"crossref","first-page":"60","DOI":"10.1016\/j.poly.2014.01.025","volume":"80","author":"Floquet","year":"2014","journal-title":"Polyhedron"},{"key":"D5DT01623A\/cit7\/1","doi-asserted-by":"crossref","first-page":"127","DOI":"10.1016\/0010-8545(85)80022-9","volume":"63","author":"Padhy\u00e9","year":"1985","journal-title":"Coord. Chem. Rev."},{"issue":"2\u20133","key":"D5DT01623A\/cit8\/1","doi-asserted-by":"crossref","first-page":"279","DOI":"10.1016\/S0010-8545(00)80276-3","volume":"15","author":"Campbell","year":"1975","journal-title":"Coord. Chem. Rev."},{"issue":"1","key":"D5DT01623A\/cit9\/1","doi-asserted-by":"crossref","first-page":"13","DOI":"10.1016\/S0020-1693(00)83039-X","volume":"184","author":"Gupta","year":"1991","journal-title":"Inorg. Chim. Acta"},{"issue":"1","key":"D5DT01623A\/cit10\/1","doi-asserted-by":"crossref","first-page":"56","DOI":"10.1016\/j.ica.2008.02.057","volume":"362","author":"Floquet","year":"2009","journal-title":"Inorg. Chim. Acta"},{"issue":"19","key":"D5DT01623A\/cit11\/1","doi-asserted-by":"crossref","first-page":"16547","DOI":"10.1021\/acsomega.2c00705","volume":"7","author":"Fuior","year":"2022","journal-title":"ACS Omega"},{"issue":"1","key":"D5DT01623A\/cit12\/1","doi-asserted-by":"crossref","first-page":"96","DOI":"10.1021\/ic00300a022","volume":"28","author":"Mohan","year":"1989","journal-title":"Inorg. Chem."},{"issue":"21","key":"D5DT01623A\/cit13\/1","doi-asserted-by":"crossref","first-page":"7020","DOI":"10.1039\/C7DT00947J","volume":"46","author":"Phonsri","year":"2017","journal-title":"Dalton Trans."},{"issue":"3","key":"D5DT01623A\/cit14\/1","doi-asserted-by":"crossref","first-page":"51","DOI":"10.3390\/inorganics5030051","volume":"5","author":"Phonsri","year":"2017","journal-title":"Inorganics"},{"issue":"4","key":"D5DT01623A\/cit15\/1","doi-asserted-by":"crossref","first-page":"1322","DOI":"10.1002\/chem.201504266","volume":"22","author":"Phonsri","year":"2016","journal-title":"Chem. \u2013 Eur. J."},{"key":"D5DT01623A\/cit16\/1","doi-asserted-by":"crossref","first-page":"3450","DOI":"10.1021\/ic00215a030","volume":"24","author":"Timken","year":"1985","journal-title":"Inorg. Chem."},{"issue":"1","key":"D5DT01623A\/cit17\/1","doi-asserted-by":"crossref","first-page":"N1","DOI":"10.14494\/jnrs2000.5.N1","volume":"5","author":"Hayami","year":"2004","journal-title":"J. Nucl. Radiochem. Sci."},{"key":"D5DT01623A\/cit18\/1","doi-asserted-by":"crossref","first-page":"143","DOI":"10.1021\/ic701695b","volume":"47","author":"Tido","year":"2008","journal-title":"Inorg. Chem."},{"key":"D5DT01623A\/cit19\/1","doi-asserted-by":"crossref","first-page":"1643","DOI":"10.1039\/B911114J","volume":"39","author":"Tido","year":"2010","journal-title":"Dalton Trans."},{"key":"D5DT01623A\/cit20\/1","doi-asserted-by":"crossref","first-page":"346","DOI":"10.1039\/D4DT02901A","volume":"54","author":"Blagov","year":"2025","journal-title":"Dalton Trans."},{"key":"D5DT01623A\/cit21\/1","doi-asserted-by":"crossref","first-page":"1806","DOI":"10.1039\/D2DT03630D","volume":"52","author":"Blagov","year":"2023","journal-title":"Dalton Trans."},{"issue":"7","key":"D5DT01623A\/cit22\/1","first-page":"1854","volume":"15","author":"Ablov","year":"1970","journal-title":"Russ. J. Inorg. Chem."},{"issue":"1","key":"D5DT01623A\/cit23\/1","doi-asserted-by":"crossref","first-page":"78","DOI":"10.1134\/S1070328424600980","volume":"51","author":"Spitsyna","year":"2025","journal-title":"Russ. J. Coord. Chem."},{"key":"D5DT01623A\/cit24\/1","doi-asserted-by":"crossref","first-page":"350","DOI":"10.1002\/asia.201402954","volume":"10","author":"Ghosh","year":"2015","journal-title":"Chem. \u2013 Asian J."},{"issue":"A","key":"D5DT01623A\/cit25\/1","doi-asserted-by":"crossref","first-page":"407","DOI":"10.1016\/0584-8539(85)80145-8","volume":"41","author":"Jain","year":"1985","journal-title":"Spectrochim. Acta"},{"key":"D5DT01623A\/cit26\/1","doi-asserted-by":"crossref","first-page":"1110","DOI":"10.1515\/znb-2006-0909","volume":"61b","author":"Dodoff","year":"2006","journal-title":"Z. Naturforsch."},{"issue":"7\u20138","key":"D5DT01623A\/cit27\/1","doi-asserted-by":"crossref","first-page":"1011","DOI":"10.2298\/JSC240417050B","volume":"89","author":"Belo\u0161evi\u0107","year":"2024","journal-title":"J. Serb. Chem. Soc."},{"issue":"16","key":"D5DT01623A\/cit28\/1","doi-asserted-by":"crossref","first-page":"2719","DOI":"10.1080\/00958970902902705","volume":"62","author":"Han","year":"2009","journal-title":"J. Coord. Chem."},{"key":"D5DT01623A\/cit29\/1","doi-asserted-by":"crossref","first-page":"1454","DOI":"10.1039\/D4DT02774D","volume":"54","author":"Altiparmak","year":"2025","journal-title":"Dalton Trans."},{"key":"D5DT01623A\/cit30\/1","doi-asserted-by":"crossref","first-page":"361","DOI":"10.1039\/dt9890000361","volume":"2","author":"Ferrari","year":"1989","journal-title":"J. Chem. Soc., Dalton Trans."},{"key":"D5DT01623A\/cit31\/1","doi-asserted-by":"crossref","first-page":"2262","DOI":"10.1002\/cctc.201600967","volume":"9","author":"Straistari","year":"2017","journal-title":"ChemCatChem"},{"key":"D5DT01623A\/cit32\/1","doi-asserted-by":"crossref","first-page":"25","DOI":"10.1016\/j.jksus.2010.08.006","volume":"24","author":"Al-Karawi","year":"2012","journal-title":"J. King Saud Univ., Sci."},{"key":"D5DT01623A\/cit33\/1","doi-asserted-by":"crossref","first-page":"1621","DOI":"10.1039\/B605326B","volume":"30","author":"Floquet","year":"2006","journal-title":"New J. Chem."},{"issue":"3","key":"D5DT01623A\/cit34\/1","doi-asserted-by":"crossref","first-page":"1086","DOI":"10.1039\/D0DT03988H","volume":"50","author":"Ketkaew","year":"2021","journal-title":"Dalton Trans."},{"key":"D5DT01623A\/cit35\/1","doi-asserted-by":"crossref","first-page":"451","DOI":"10.1098\/rspa.1952.0181","volume":"214","author":"Bleaney","year":"1952","journal-title":"Proc. R. Soc. London, Ser. A"},{"key":"D5DT01623A\/cit36\/1","doi-asserted-by":"crossref","first-page":"29","DOI":"10.3390\/magnetochemistry6030029","volume":"6","author":"Ishikawa","year":"2020","journal-title":"Magnetochemistry"},{"key":"D5DT01623A\/cit37\/1","doi-asserted-by":"crossref","first-page":"382","DOI":"10.3390\/cryst8100382","volume":"8","author":"Spitsyna","year":"2018","journal-title":"Crystals"},{"key":"D5DT01623A\/cit38\/1","doi-asserted-by":"crossref","first-page":"7858","DOI":"10.1039\/C5TC00859J","volume":"3","author":"Okai","year":"2015","journal-title":"J. Mater. Chem. C"},{"key":"D5DT01623A\/cit39\/1","doi-asserted-by":"crossref","first-page":"7015","DOI":"10.1039\/c2ce25862e","volume":"14","author":"Nemec","year":"2012","journal-title":"CrystEngComm"},{"key":"D5DT01623A\/cit40\/1","doi-asserted-by":"crossref","first-page":"1634","DOI":"10.1021\/ja066426g","volume":"129","author":"Huang","year":"2007","journal-title":"J. Am. Chem. Soc."},{"key":"D5DT01623A\/cit41\/1","doi-asserted-by":"crossref","first-page":"149","DOI":"10.1039\/B913234A","volume":"39","author":"Ross","year":"2010","journal-title":"Dalton Trans."},{"key":"D5DT01623A\/cit42\/1","doi-asserted-by":"crossref","first-page":"1178","DOI":"10.1246\/cl.140464","volume":"43","author":"Halcrow","year":"2014","journal-title":"Chem. Lett."},{"key":"D5DT01623A\/cit43\/1","doi-asserted-by":"crossref","first-page":"4119","DOI":"10.1039\/c1cs15046d","volume":"40","author":"Halcrow","year":"2011","journal-title":"Chem. Soc. Rev."},{"issue":"22","key":"D5DT01623A\/cit44\/1","doi-asserted-by":"crossref","first-page":"7843","DOI":"10.1039\/D1DT01069G","volume":"50","author":"Zenno","year":"2021","journal-title":"Dalton Trans."},{"issue":"10","key":"D5DT01623A\/cit45\/1","doi-asserted-by":"crossref","first-page":"2880","DOI":"10.1039\/C4CS00376D","volume":"44","author":"Brooker","year":"2015","journal-title":"Chem. Soc. Rev."},{"issue":"44","key":"D5DT01623A\/cit46\/1","doi-asserted-by":"crossref","first-page":"16937","DOI":"10.1039\/C4DT02587C","volume":"43","author":"Luo","year":"2014","journal-title":"Dalton Trans."},{"key":"D5DT01623A\/cit47\/1","doi-asserted-by":"crossref","first-page":"7802","DOI":"10.1039\/C5TC00311C","volume":"3","author":"Zhao","year":"2015","journal-title":"J. Mater. Chem. C"},{"issue":"7","key":"D5DT01623A\/cit48\/1","doi-asserted-by":"crossref","first-page":"2536","DOI":"10.1039\/D0DT03986A","volume":"50","author":"Jornet-Moll\u00e1","year":"2021","journal-title":"Dalton Trans."},{"key":"D5DT01623A\/cit49\/1","doi-asserted-by":"crossref","first-page":"181","DOI":"10.12693\/APhysPolA.91.181","volume":"91","author":"Johnston","year":"1997","journal-title":"Act. Phys. Pol. A"},{"key":"D5DT01623A\/cit50\/1","doi-asserted-by":"crossref","first-page":"343","DOI":"10.1119\/1.1970340","volume":"32","author":"Fisher","year":"1964","journal-title":"Am. J. Phys."},{"key":"D5DT01623A\/cit51\/1","doi-asserted-by":"crossref","first-page":"2782","DOI":"10.1021\/ic0521527","volume":"45","author":"Liu","year":"2006","journal-title":"Inorg. Chem."},{"key":"D5DT01623A\/cit52\/1","doi-asserted-by":"crossref","first-page":"035010","DOI":"10.1088\/2515-7639\/ace21a","volume":"6","author":"Dale","year":"2023","journal-title":"J. Phys. Mater."},{"issue":"24","key":"D5DT01623A\/cit53\/1","doi-asserted-by":"crossref","first-page":"6738","DOI":"10.1021\/jp068774a","volume":"111","author":"Grunert","year":"2007","journal-title":"J. Phys. Chem. B"},{"key":"D5DT01623A\/cit54\/1","volume-title":"M\u00f6ssbauer spectroscopy and transition metal chemistry: fundamentals and applications","author":"G\u00fctlich","year":"2010","unstructured":"P.G\u00fctlich ,  E.Bill  and  A. X.Trautwein ,  M\u00f6ssbauer spectroscopy and transition metal chemistry: fundamentals and applications ,  Springer Science & Business Media ,  2010"},{"key":"D5DT01623A\/cit55\/1","first-page":"6","volume":"7","author":"\u010cern\u00e1","year":"2000","journal-title":"Mater. Struct."},{"key":"D5DT01623A\/cit56\/1","doi-asserted-by":"crossref","first-page":"7192","DOI":"10.1038\/s41467-024-51385-8","volume":"15","author":"Getzner","year":"2024","journal-title":"Nat. Commun."},{"key":"D5DT01623A\/cit57\/1","doi-asserted-by":"crossref","first-page":"5510","DOI":"10.1038\/s41467-019-13279-y","volume":"10","author":"Huang","year":"2019","journal-title":"Nat. Commun."},{"key":"D5DT01623A\/cit58\/1","doi-asserted-by":"crossref","first-page":"123","DOI":"10.1021\/ic50215a028","volume":"20","author":"Haddad","year":"1981","journal-title":"Inorg. Chem."},{"key":"D5DT01623A\/cit60\/1","doi-asserted-by":"crossref","first-page":"479","DOI":"10.1107\/S002188989600163X","volume":"29","author":"Brown","year":"1996","journal-title":"J. Appl. Crystallogr."},{"key":"D5DT01623A\/cit61\/1","doi-asserted-by":"crossref","first-page":"9328","DOI":"10.1039\/C9DT01404G","volume":"48","author":"Spitsyna","year":"2019","journal-title":"Dalton Trans."},{"key":"D5DT01623A\/cit62\/1","doi-asserted-by":"crossref","first-page":"5737","DOI":"10.1063\/1.440939","volume":"74","author":"Noodleman","year":"1981","journal-title":"J. Chem. Phys."},{"key":"D5DT01623A\/cit63\/1","doi-asserted-by":"crossref","first-page":"4035","DOI":"10.1063\/1.1286418","volume":"113","author":"Mitani","year":"2000","journal-title":"J. Chem. Phys."},{"key":"D5DT01623A\/cit64\/1","doi-asserted-by":"crossref","first-page":"4556","DOI":"10.1002\/ejic.201800742","volume":"41","author":"Mandal","year":"2018","journal-title":"Eur. J. Inorg. Chem."},{"key":"D5DT01623A\/cit65\/1","doi-asserted-by":"crossref","first-page":"1151","DOI":"10.1007\/s00214-012-1151-9","volume":"131","author":"Meskaldji","year":"2012","journal-title":"Theor. Chem. Acc."},{"key":"D5DT01623A\/cit66\/1","doi-asserted-by":"crossref","first-page":"2837","DOI":"10.1002\/chem.201903924","volume":"26","author":"Rams","year":"2020","journal-title":"Chem. \u2013 Eur. J."},{"issue":"12","key":"D5DT01623A\/cit67\/1","doi-asserted-by":"crossref","first-page":"2298","DOI":"10.1021\/acs.jcim.6b00236","volume":"56","author":"Koebel","year":"2016","journal-title":"J. Chem. Inf. Model."},{"issue":"46","key":"D5DT01623A\/cit68\/1","doi-asserted-by":"crossref","first-page":"17088","DOI":"10.1073\/pnas.0603978103","volume":"103","author":"Howard","year":"2006","journal-title":"Proc. Natl. Acad. Sci. U. S. A."},{"key":"D5DT01623A\/cit69a\/1","doi-asserted-by":"publisher","year":"2025","unstructured":"CCDC 2465360: Experimental Crystal Structure Determination ,  2025 ,  10.5517\/ccdc.csd.cc2nrdrl","DOI":"10.5517\/ccdc.csd.cc2nrdrl"},{"key":"D5DT01623A\/cit69b\/1","doi-asserted-by":"publisher","year":"2025","unstructured":"CCDC 2465361: Experimental Crystal Structure Determination ,  2025 ,  10.5517\/ccdc.csd.cc2nrdsm","DOI":"10.5517\/ccdc.csd.cc2nrdsm"},{"key":"D5DT01623A\/cit69c\/1","doi-asserted-by":"publisher","year":"2025","unstructured":"CCDC 2465362: Experimental Crystal Structure Determination ,  2025 ,  10.5517\/ccdc.csd.cc2nrdtn","DOI":"10.5517\/ccdc.csd.cc2nrdtn"}],"container-title":["Dalton Transactions"],"original-title":[],"language":"en","link":[{"URL":"http:\/\/pubs.rsc.org\/en\/content\/articlepdf\/2025\/DT\/D5DT01623A","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,7,2]],"date-time":"2026-07-02T04:30:47Z","timestamp":1782966647000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.rsc.org\/dt\/article\/54\/38\/14427-14439\/890070"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2025]]},"references-count":70,"journal-issue":{"issue":"38","published-print":{"date-parts":[[2025,9,30]]}},"URL":"https:\/\/doi.org\/10.1039\/d5dt01623a","relation":{},"ISSN":["1477-9226","1477-9234"],"issn-type":[{"value":"1477-9226","type":"print"},{"value":"1477-9234","type":"electronic"}],"subject":[],"published":{"date-parts":[[2025]]}}}