{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,21]],"date-time":"2026-09-21T10:59:52Z","timestamp":1789988392489,"version":"4.0.1"},"reference-count":65,"publisher":"Royal Society of Chemistry (RSC)","issue":"44","license":[{"start":{"date-parts":[[2025,10,20]],"date-time":"2025-10-20T00:00:00Z","timestamp":1760918400000},"content-version":"vor","delay-in-days":292,"URL":"http:\/\/creativecommons.org\/licenses\/by\/3.0\/"}],"funder":[{"DOI":"10.13039\/501100001659","name":"Deutsche Forschungsgemeinschaft","doi-asserted-by":"publisher","award":["FOR 5215"],"award-info":[{"award-number":["FOR 5215"]}],"id":[{"id":"10.13039\/501100001659","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["rsc.org"],"crossmark-restriction":true},"short-container-title":["Dalton Trans."],"abstract":"<jats:p>\n                    In bispidine-iron(\n                    <jats:sc>iv<\/jats:sc>\n                    )\u2013tosylimido complexes, axial\n                    <jats:italic>vs.<\/jats:italic>\n                    equatorial NTs coordination dictates the decay: axial gives a low-spin Fe(\n                    <jats:sc>iii<\/jats:sc>\n                    )\u2013NHTs, whereas equatorial yields a high-spin Fe(\n                    <jats:sc>iii<\/jats:sc>\n                    ) species\n                    <jats:italic>via<\/jats:italic>\n                    self-decay resulting in N-centered demethylation.\n                  <\/jats:p>","DOI":"10.1039\/d5dt02063h","type":"journal-article","created":{"date-parts":[[2025,10,20]],"date-time":"2025-10-20T13:35:17Z","timestamp":1760967317000},"page":"16420-16431","update-policy":"https:\/\/doi.org\/10.1039\/rsc_crossmark_policy","source":"Crossref","is-referenced-by-count":1,"title":["Elucidating decay pathways of bispidine\u2013iron(\n                    <scp>iv<\/scp>\n                    )\u2013tosylimido complexes: insights gained from decay products"],"prefix":"10.1039","volume":"54","author":[{"given":"Thomas","family":"Josephy","sequence":"first","affiliation":[{"name":"Universit\u00e4t Heidelberg, Anorganisch-Chemisches Institut, INF 270, D-69120 Heidelberg, Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Fridolin","family":"R\u00f6hs","sequence":"additional","affiliation":[{"name":"Universit\u00e4t Bielefeld, Lehrstuhl f\u00fcr Anorganische Chemie I, Fakult\u00e4t f\u00fcr Chemie, Universit\u00e4tsstr. 25, D-33615 Bielefeld, Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Thorsten","family":"Glaser","sequence":"additional","affiliation":[{"name":"Universit\u00e4t Bielefeld, Lehrstuhl f\u00fcr Anorganische Chemie I, Fakult\u00e4t f\u00fcr Chemie, Universit\u00e4tsstr. 25, D-33615 Bielefeld, Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-7796-3532","authenticated-orcid":false,"given":"Peter","family":"Comba","sequence":"additional","affiliation":[{"name":"Universit\u00e4t Heidelberg, Anorganisch-Chemisches Institut, INF 270, D-69120 Heidelberg, Germany"},{"name":"Universit\u00e4t Heidelberg, Interdisziplin\u00e4res Zentrum f\u00fcr Wissenschaftliches Rechnen (IWR), Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0002-0589-9601","authenticated-orcid":false,"given":"Katharina","family":"Bleher","sequence":"additional","affiliation":[{"name":"Universit\u00e4t Heidelberg, Anorganisch-Chemisches Institut, INF 270, D-69120 Heidelberg, Germany"},{"name":"Institute of Functional Interfaces, Karlsruhe Institute of Technology, Hermann-von-Helmholtz-Platz 1, 76344, Eggenstein-Leopoldshafen, Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"292","published-online":{"date-parts":[[2025]]},"reference":[{"key":"D5DT02063H\/cit1\/1","doi-asserted-by":"crossref","first-page":"111613","DOI":"10.1016\/j.jinorgbio.2021.111613","volume":"225","author":"Coin","year":"2021","journal-title":"J. Inorg. Biochem."},{"key":"D5DT02063H\/cit2\/1","doi-asserted-by":"crossref","first-page":"13942","DOI":"10.1021\/ja507807v","volume":"136","author":"Ray","year":"2014","journal-title":"J. Am. Chem. Soc."},{"key":"D5DT02063H\/cit3\/1","doi-asserted-by":"crossref","first-page":"7632","DOI":"10.1002\/anie.201600507","volume":"55","author":"Engelmann","year":"2016","journal-title":"Angew. Chem., Int. Ed."},{"key":"D5DT02063H\/cit4\/1","doi-asserted-by":"crossref","first-page":"424","DOI":"10.1038\/s41570-023-00482-1","volume":"7","author":"Cosio","year":"2023","journal-title":"Nat. Rev. Chem."},{"key":"D5DT02063H\/cit5\/1","doi-asserted-by":"crossref","first-page":"13","DOI":"10.1021\/acscentsci.8b00698","volume":"5","author":"Guo","year":"2019","journal-title":"ACS Cent. Sci."},{"key":"D5DT02063H\/cit6\/1","doi-asserted-by":"crossref","first-page":"720","DOI":"10.1038\/ncomms1718","volume":"3","author":"Hohenberger","year":"2012","journal-title":"Nat. Commun."},{"key":"D5DT02063H\/cit7\/1","doi-asserted-by":"crossref","first-page":"484","DOI":"10.1021\/ar700066p","author":"Krebs","year":"2007","journal-title":"Acc. Chem. Res."},{"key":"D5DT02063H\/cit8\/1","doi-asserted-by":"crossref","first-page":"2227","DOI":"10.1021\/cr040653o","volume":"105","author":"Abu-Omar","year":"2005","journal-title":"Chem. Rev."},{"key":"D5DT02063H\/cit9\/1","doi-asserted-by":"crossref","first-page":"414","DOI":"10.1016\/j.ccr.2012.08.002","volume":"257","author":"McDonald","year":"2013","journal-title":"Coord. Chem. Rev."},{"key":"D5DT02063H\/cit10\/1","doi-asserted-by":"crossref","first-page":"2415","DOI":"10.1021\/acs.accounts.5b00218","volume":"48","author":"Nam","year":"2015","journal-title":"Acc. Chem. Res."},{"key":"D5DT02063H\/cit11\/1","doi-asserted-by":"crossref","first-page":"2725","DOI":"10.1021\/ar400149m","volume":"46","author":"Solomon","year":"2013","journal-title":"Acc. Chem. Res."},{"key":"D5DT02063H\/cit12\/1","doi-asserted-by":"crossref","first-page":"1146","DOI":"10.1021\/ar400258p","volume":"47","author":"Nam","year":"2014","journal-title":"Acc. Chem. Res."},{"key":"D5DT02063H\/cit13\/1","doi-asserted-by":"crossref","first-page":"1544","DOI":"10.1039\/b404561k","volume":"4","author":"Avenier","year":"2004","journal-title":"Chem. Commun."},{"key":"D5DT02063H\/cit14\/1","doi-asserted-by":"crossref","first-page":"4357","DOI":"10.1002\/anie.200351605","volume":"42","author":"Jensen","year":"2003","journal-title":"Angew. Chem., Int. Ed."},{"key":"D5DT02063H\/cit15\/1","doi-asserted-by":"crossref","first-page":"5306","DOI":"10.1021\/ic0005238","volume":"39","author":"Grapperhaus","year":"2000","journal-title":"Inorg. Chem."},{"key":"D5DT02063H\/cit16\/1","doi-asserted-by":"crossref","first-page":"1622","DOI":"10.1021\/acs.inorgchem.9b02216","volume":"59","author":"Li","year":"2020","journal-title":"Inorg. Chem."},{"key":"D5DT02063H\/cit17\/1","doi-asserted-by":"crossref","first-page":"19585","DOI":"10.1021\/jacs.9b11608","volume":"141","author":"Goldberg","year":"2019","journal-title":"J. Am. Chem. Soc."},{"key":"D5DT02063H\/cit18\/1","doi-asserted-by":"crossref","first-page":"8800","DOI":"10.1021\/jacs.7b04695","volume":"139","author":"Hong","year":"2017","journal-title":"J. Am. Chem. Soc."},{"key":"D5DT02063H\/cit19\/1","doi-asserted-by":"crossref","first-page":"2905","DOI":"10.1021\/cr020043t","volume":"103","author":"M\u00fcller","year":"2003","journal-title":"Chem. Rev."},{"key":"D5DT02063H\/cit20\/1","doi-asserted-by":"crossref","first-page":"13819","DOI":"10.1002\/chem.201702537","volume":"23","author":"Kuijpers","year":"2017","journal-title":"Chem. \u2013 Eur. J."},{"key":"D5DT02063H\/cit21\/1","doi-asserted-by":"crossref","first-page":"7384","DOI":"10.1002\/anie.201201945","volume":"51","author":"Dequirez","year":"2012","journal-title":"Angew. Chem., Int. Ed."},{"key":"D5DT02063H\/cit22\/1","doi-asserted-by":"crossref","first-page":"10257","DOI":"10.1021\/jm501100b","volume":"57","author":"Vitaku","year":"2014","journal-title":"J. Med. Chem."},{"key":"D5DT02063H\/cit23\/1","doi-asserted-by":"crossref","first-page":"3451","DOI":"10.1021\/jm200187y","volume":"54","author":"Roughley","year":"2011","journal-title":"J. Med. Chem."},{"key":"D5DT02063H\/cit24\/1","doi-asserted-by":"crossref","first-page":"1","DOI":"10.1002\/adma.202406203","volume":"36","author":"Castro","year":"2024","journal-title":"Adv. Mater."},{"key":"D5DT02063H\/cit25\/1","doi-asserted-by":"crossref","first-page":"6444","DOI":"10.1039\/D1DT00832C","volume":"50","author":"Thomas","year":"2021","journal-title":"Dalton Trans."},{"issue":"3","key":"D5DT02063H\/cit26\/1","doi-asserted-by":"crossref","first-page":"100955","DOI":"10.1016\/j.isci.2020.100955","volume":"23","author":"Ren","year":"2020","journal-title":"iScience"},{"key":"D5DT02063H\/cit27\/1","doi-asserted-by":"crossref","first-page":"120752","DOI":"10.1016\/j.ica.2021.120752","volume":"532","author":"Bleher","year":"2022","journal-title":"Inorg. Chim. Acta"},{"key":"D5DT02063H\/cit28\/1","doi-asserted-by":"crossref","first-page":"1711","DOI":"10.1002\/ejic.200200618","author":"Comba","year":"2003","journal-title":"Eur. J. Inorg. Chem."},{"key":"D5DT02063H\/cit29\/1","doi-asserted-by":"crossref","first-page":"5313","DOI":"10.1002\/chem.200701910","volume":"14","author":"Comba","year":"2008","journal-title":"Chem. \u2013 Eur. J."},{"key":"D5DT02063H\/cit30\/1","doi-asserted-by":"crossref","first-page":"4913","DOI":"10.1021\/ic000664+","volume":"39","author":"Halfen","year":"2000","journal-title":"Inorg. Chem."},{"key":"D5DT02063H\/cit31\/1","doi-asserted-by":"crossref","first-page":"122587","DOI":"10.1016\/j.ica.2025.122587","author":"Josephy","year":"2025","journal-title":"Inorg. Chim. Acta"},{"key":"D5DT02063H\/cit32\/1","doi-asserted-by":"crossref","first-page":"9183","DOI":"10.1021\/acscatal.8b01941","volume":"8","author":"Bagchi","year":"2018","journal-title":"ACS Catal."},{"key":"D5DT02063H\/cit33\/1","doi-asserted-by":"crossref","first-page":"13937","DOI":"10.1016\/S0040-4020(99)00853-4","volume":"55","author":"Nishikori","year":"1999","journal-title":"Tetrahedron"},{"key":"D5DT02063H\/cit34\/1","doi-asserted-by":"crossref","first-page":"9513","DOI":"10.1039\/C9SC02526J","volume":"10","author":"Sabenya","year":"2019","journal-title":"Chem. Sci."},{"key":"D5DT02063H\/cit35\/1","doi-asserted-by":"crossref","first-page":"7394","DOI":"10.1002\/anie.200602799","volume":"45","author":"Klinker","year":"2006","journal-title":"Angew. Chem., Int. Ed."},{"key":"D5DT02063H\/cit36\/1","doi-asserted-by":"crossref","first-page":"17102","DOI":"10.1021\/ja508403w","volume":"136","author":"Kumar","year":"2014","journal-title":"J. Am. Chem. Soc."},{"key":"D5DT02063H\/cit37\/1","doi-asserted-by":"crossref","first-page":"12288","DOI":"10.1002\/anie.201305370","volume":"52","author":"Vardhaman","year":"2013","journal-title":"Angew. Chem., Int. Ed."},{"key":"D5DT02063H\/cit38\/1","doi-asserted-by":"crossref","first-page":"5921","DOI":"10.1039\/D0DT00018C","volume":"49","author":"Mukherjee","year":"2020","journal-title":"Dalton Trans."},{"key":"D5DT02063H\/cit39\/1","doi-asserted-by":"crossref","first-page":"4405","DOI":"10.1039\/D5DT00050E","volume":"54","author":"Bleher","year":"2025","journal-title":"Dalton Trans."},{"key":"D5DT02063H\/cit40\/1","doi-asserted-by":"crossref","first-page":"12109","DOI":"10.1021\/acs.inorgchem.4c01237","volume":"63","author":"Josephy","year":"2024","journal-title":"Inorg. Chem."},{"key":"D5DT02063H\/cit41\/1","doi-asserted-by":"crossref","first-page":"11377","DOI":"10.1002\/chem.202101045","volume":"27","author":"Abu-Odeh","year":"2021","journal-title":"Chem. \u2013 Eur. J."},{"key":"D5DT02063H\/cit42\/1","doi-asserted-by":"crossref","first-page":"8635","DOI":"10.1021\/ja100366c","volume":"132","author":"England","year":"2010","journal-title":"J. Am. Chem. Soc."},{"key":"D5DT02063H\/cit43\/1","doi-asserted-by":"crossref","first-page":"1602","DOI":"10.1002\/anie.200502656","volume":"45","author":"Nielsen","year":"2006","journal-title":"Angew. Chem., Int. Ed."},{"key":"D5DT02063H\/cit44\/1","doi-asserted-by":"crossref","first-page":"3891","DOI":"10.1021\/jacs.9b11682","volume":"142","author":"Lu","year":"2020","journal-title":"J. Am. Chem. Soc."},{"key":"D5DT02063H\/cit45\/1","doi-asserted-by":"crossref","first-page":"7194","DOI":"10.1021\/ja3122526","volume":"135","author":"Liu","year":"2013","journal-title":"J. Am. Chem. Soc."},{"key":"D5DT02063H\/cit46\/1","doi-asserted-by":"crossref","first-page":"5378","DOI":"10.1021\/ja0498033","volume":"126","author":"Decker","year":"2004","journal-title":"J. Am. Chem. Soc."},{"key":"D5DT02063H\/cit47\/1","doi-asserted-by":"crossref","first-page":"4305","DOI":"10.1002\/anie.201612472","volume":"56","author":"Gour\u00e9","year":"2017","journal-title":"Angew. Chem., Int. Ed."},{"key":"D5DT02063H\/cit48\/1","doi-asserted-by":"crossref","first-page":"17495","DOI":"10.1002\/chem.202103295","volume":"27","author":"Li","year":"2021","journal-title":"Chem. \u2013 Eur. J."},{"key":"D5DT02063H\/cit49\/1","doi-asserted-by":"crossref","first-page":"80","DOI":"10.1021\/jacs.8b11045","volume":"141","author":"Lu","year":"2019","journal-title":"J. Am. Chem. Soc."},{"key":"D5DT02063H\/cit50\/1","doi-asserted-by":"crossref","first-page":"576","DOI":"10.1071\/CH16674","volume":"70","author":"Comba","year":"2017","journal-title":"Aust. J. Chem."},{"key":"D5DT02063H\/cit51\/1","doi-asserted-by":"crossref","first-page":"8625","DOI":"10.1039\/D2DT00809B","volume":"51","author":"Bleher","year":"2022","journal-title":"Dalton Trans."},{"key":"D5DT02063H\/cit52\/1","doi-asserted-by":"crossref","first-page":"11596","DOI":"10.1021\/ja052952g","volume":"127","author":"Lucas","year":"2005","journal-title":"J. Am. Chem. Soc."},{"key":"D5DT02063H\/cit53\/1","doi-asserted-by":"crossref","DOI":"10.1007\/978-3-319-54398-7","volume-title":"Mass Spectrometry","author":"Gross","year":"2017","unstructured":"J. H.Gross ,  Mass Spectrometry ,  Springer Nature , 3rd edn,  2017"},{"key":"D5DT02063H\/cit54\/1","doi-asserted-by":"crossref","first-page":"1604","DOI":"10.1002\/mas.21751","volume":"42","author":"Conder","year":"2023","journal-title":"Mass Spectrom. Rev."},{"key":"D5DT02063H\/cit55\/1","doi-asserted-by":"crossref","first-page":"4068","DOI":"10.1021\/ja01043a008","volume":"91","author":"Studier","year":"1969","journal-title":"J. Am. Chem. Soc."},{"key":"D5DT02063H\/cit56\/1","doi-asserted-by":"crossref","first-page":"2878","DOI":"10.1021\/j100709a005","volume":"74","author":"Michael","year":"1970","journal-title":"J. Phys. Chem."},{"key":"D5DT02063H\/cit57\/1","doi-asserted-by":"crossref","first-page":"11129","DOI":"10.1002\/anie.201605099","volume":"55","author":"Comba","year":"2016","journal-title":"Angew. Chem., Int. Ed."},{"issue":"18","key":"D5DT02063H\/cit58\/1","doi-asserted-by":"crossref","first-page":"7077","DOI":"10.1021\/ic0602401","volume":"45","author":"Bautz","year":"2006","journal-title":"Inorg. Chem."},{"key":"D5DT02063H\/cit59\/1","doi-asserted-by":"crossref","first-page":"232","DOI":"10.1039\/D1FD00073J","volume":"234","author":"Comba","year":"2021","journal-title":"Faraday Discuss."},{"key":"D5DT02063H\/cit60\/1","doi-asserted-by":"crossref","first-page":"6744","DOI":"10.1021\/jo00024a008","volume":"56","author":"Evans","year":"1991","journal-title":"J. Org. Chem."},{"key":"D5DT02063H\/cit61\/1","doi-asserted-by":"crossref","first-page":"2742","DOI":"10.1021\/ja00086a007","volume":"116","author":"Evans","year":"1994","journal-title":"J. Am. Chem. Soc."},{"key":"D5DT02063H\/cit62\/1","doi-asserted-by":"crossref","first-page":"361","DOI":"10.1246\/cl.1975.361","author":"Yamada","year":"1975","journal-title":"Chem. Lett."},{"key":"D5DT02063H\/cit63\/1","doi-asserted-by":"crossref","first-page":"407","DOI":"10.1016\/S0020-1693(02)01100-3","volume":"337","author":"B\u00f6rzel","year":"2002","journal-title":"Inorg. Chim. Acta"},{"key":"D5DT02063H\/cit64\/1","doi-asserted-by":"crossref","first-page":"608","DOI":"10.1002\/cber.19300630314","volume":"63","author":"Mannich","year":"1930","journal-title":"Ber. Dtsch. Chem. Ges."},{"key":"D5DT02063H\/cit65\/1","doi-asserted-by":"crossref","first-page":"613","DOI":"10.1002\/9780470144428.ch9","volume":"55","author":"Comba","year":"2007","journal-title":"Prog. Inorg. Chem."}],"container-title":["Dalton Transactions"],"original-title":[],"language":"en","link":[{"URL":"http:\/\/pubs.rsc.org\/DT\/article-pdf\/doi\/10.1039\/D5DT02063H\/0\/D5DT02063H.pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,9,21]],"date-time":"2026-09-21T10:02:30Z","timestamp":1789984950000},"score":1,"resource":{"primary":{"URL":"http:\/\/pubs.rsc.org\/DT\/article-lookup\/doi\/10.1039\/D5DT02063H"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2025]]},"references-count":65,"journal-issue":{"issue":"44","published-print":{"date-parts":[[2025,11,11]]}},"URL":"https:\/\/doi.org\/10.1039\/d5dt02063h","relation":{},"ISSN":["1477-9226","1477-9234"],"issn-type":[{"value":"1477-9226","type":"print"},{"value":"1477-9234","type":"electronic"}],"subject":[],"published":{"date-parts":[[2025]]}}}