{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,8,17]],"date-time":"2026-08-17T22:06:43Z","timestamp":1787004403312,"version":"build-2736575974"},"reference-count":44,"publisher":"Royal Society of Chemistry (RSC)","issue":"11","license":[{"start":{"date-parts":[[2027,2,27]],"date-time":"2027-02-27T00:00:00Z","timestamp":1803686400000},"content-version":"am","delay-in-days":422,"URL":"http:\/\/rsc.li\/journals-terms-of-use"}],"content-domain":{"domain":["rsc.org"],"crossmark-restriction":true},"short-container-title":["Dalton Trans."],"abstract":"<jats:p>A bis(benzene) chromium bridged bidentate organometallic silylene pincer ligand is introduced for zerovalent iron and nickel. The pincer ligand and its Fe complex are accessible by a direct metal-atom route under extremely mild chimie douce conditions.<\/jats:p>","DOI":"10.1039\/d5dt02957k","type":"journal-article","created":{"date-parts":[[2026,2,27]],"date-time":"2026-02-27T16:31:33Z","timestamp":1772209893000},"page":"4657-4663","update-policy":"https:\/\/doi.org\/10.1039\/rsc_crossmark_policy","source":"Crossref","is-referenced-by-count":2,"title":["Zero valent iron and nickel coordination chemistry: metal atoms as direct approach to bis(benzene)chromium bridged N-heterocyclic silylene complexes"],"prefix":"10.1039","volume":"55","author":[{"given":"Johannes M.","family":"Emmert","sequence":"first","affiliation":[{"name":"Eduard-Zintl-Institut f\u00fcr Anorganische und Physikalische Chemie, Technische Universit\u00e4t Darmstadt, Peter-Gr\u00fcnberg-Str. 12, 64287 Darmstadt, Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"J\u00f6rg","family":"Rust","sequence":"additional","affiliation":[{"name":"Max-Planck-Institut f\u00fcr Kohlenforschung, Kaiser-Wilhelm-Platz 1, 42567 M\u00fclheim a. d. Ruhr, Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Christian W.","family":"Lehmann","sequence":"additional","affiliation":[{"name":"Max-Planck-Institut f\u00fcr Kohlenforschung, Kaiser-Wilhelm-Platz 1, 42567 M\u00fclheim a. d. Ruhr, Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-8153-9491","authenticated-orcid":false,"given":"J\u00f6rg J.","family":"Schneider","sequence":"additional","affiliation":[{"name":"Eduard-Zintl-Institut f\u00fcr Anorganische und Physikalische Chemie, Technische Universit\u00e4t Darmstadt, Peter-Gr\u00fcnberg-Str. 12, 64287 Darmstadt, Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"292","published-online":{"date-parts":[[2026]]},"reference":[{"issue":"12","key":"D5DT02957K\/cit1\/1","doi-asserted-by":"crossref","first-page":"3715","DOI":"10.1002\/anie.201811088","volume":"58","author":"Zhou","year":"2019","journal-title":"Angew. Chem., Int. Ed."},{"issue":"1","key":"D5DT02957K\/cit2\/1","doi-asserted-by":"crossref","first-page":"7","DOI":"10.1016\/S0022-328X(01)00672-6","volume":"636","author":"Ostendorf","year":"2001","journal-title":"J. Organomet. Chem."},{"issue":"6","key":"D5DT02957K\/cit3\/1","doi-asserted-by":"crossref","first-page":"2691","DOI":"10.1021\/ja00085a088","volume":"116","author":"Denk","year":"1994","journal-title":"J. Am. Chem. Soc."},{"key":"D5DT02957K\/cit4\/1","doi-asserted-by":"crossref","first-page":"33","DOI":"10.1039\/C39940000033","volume":"1","author":"Denk","year":"1994","journal-title":"J. Chem. Soc., Chem. Commun."},{"issue":"38","key":"D5DT02957K\/cit5\/1","doi-asserted-by":"crossref","first-page":"13499","DOI":"10.1021\/jacs.7b07167","volume":"139","author":"Wang","year":"2017","journal-title":"J. Am. Chem. Soc."},{"issue":"26","key":"D5DT02957K\/cit6\/1","doi-asserted-by":"crossref","first-page":"5599","DOI":"10.1021\/om980818h","volume":"17","author":"Gehrhus","year":"1998","journal-title":"Organometallics"},{"issue":"18","key":"D5DT02957K\/cit7\/1","doi-asserted-by":"crossref","first-page":"6733","DOI":"10.1039\/D0CS00815J","volume":"49","author":"Shan","year":"2020","journal-title":"Chem. Soc. Rev."},{"issue":"7","key":"D5DT02957K\/cit8\/1","doi-asserted-by":"crossref","first-page":"1748","DOI":"10.1021\/om200017h","volume":"30","author":"Yao","year":"2011","journal-title":"Organometallics"},{"issue":"71","key":"D5DT02957K\/cit9\/1","doi-asserted-by":"crossref","first-page":"9483","DOI":"10.1039\/D4CC01930J","volume":"60","author":"Hendi","year":"2024","journal-title":"Chem. Commun."},{"issue":"32","key":"D5DT02957K\/cit10\/1","doi-asserted-by":"crossref","first-page":"14518","DOI":"10.1039\/D5SC00879D","volume":"16","author":"Gosh","year":"2025","journal-title":"Chem. Sci."},{"issue":"47","key":"D5DT02957K\/cit11a\/1","doi-asserted-by":"crossref","first-page":"16412","DOI":"10.1039\/C7DT03301J","volume":"46","author":"Luecke","year":"2017","journal-title":"Dalton Trans."},{"issue":"41","key":"D5DT02957K\/cit11b\/1","doi-asserted-by":"crossref","first-page":"12868","DOI":"10.1002\/anie.201606979","volume":"55","author":"Zhou","year":"2016","journal-title":"Angew. Chem., Int. Ed."},{"issue":"30","key":"D5DT02957K\/cit12\/1","doi-asserted-by":"crossref","first-page":"11725","DOI":"10.1021\/acs.inorgchem.2c01369","volume":"61","author":"He","year":"2022","journal-title":"Inorg. Chem."},{"issue":"46","key":"D5DT02957K\/cit13\/1","doi-asserted-by":"crossref","first-page":"11645","DOI":"10.1002\/ange.201205570","volume":"124","author":"Br\u00fcck","year":"2012","journal-title":"Angew. Chem."},{"issue":"17","key":"D5DT02957K\/cit14a\/1","doi-asserted-by":"crossref","first-page":"e202200084","DOI":"10.1002\/zaac.202200084","volume":"648","author":"Fan","year":"2022","journal-title":"Z. Anorg. Allg. Chem."},{"issue":"2","key":"D5DT02957K\/cit14b\/1","doi-asserted-by":"crossref","first-page":"268","DOI":"10.1021\/acs.organomet.8b00700","volume":"38","author":"Qi","year":"2019","journal-title":"Organometallics"},{"issue":"18","key":"D5DT02957K\/cit14c\/1","doi-asserted-by":"crossref","first-page":"3024","DOI":"10.1021\/acs.organomet.8b00399","volume":"37","author":"Witteman","year":"2018","journal-title":"Organometallics"},{"issue":"28","key":"D5DT02957K\/cit14d\/1","doi-asserted-by":"crossref","first-page":"11301","DOI":"10.1039\/C6DT02486F","volume":"45","author":"H\u00e4nninen","year":"2016","journal-title":"Dalton Trans."},{"issue":"23","key":"D5DT02957K\/cit14e\/1","doi-asserted-by":"crossref","first-page":"6885","DOI":"10.1021\/om500966t","volume":"33","author":"Gallego","year":"2014","journal-title":"Organometallics"},{"issue":"17","key":"D5DT02957K\/cit14f\/1","doi-asserted-by":"crossref","first-page":"6703","DOI":"10.1021\/ja402480v","volume":"135","author":"Blom","year":"2013","journal-title":"J. Am. Chem. Soc."},{"issue":"20","key":"D5DT02957K\/cit15\/1","doi-asserted-by":"crossref","first-page":"6766","DOI":"10.1039\/D1DT00523E","volume":"50","author":"Yang","year":"2021","journal-title":"Dalton Trans."},{"issue":"17","key":"D5DT02957K\/cit16\/1","doi-asserted-by":"crossref","first-page":"3263","DOI":"10.1021\/om000110e","volume":"19","author":"Schmedake","year":"2000","journal-title":"Organometallics"},{"issue":"39","key":"D5DT02957K\/cit17\/1","doi-asserted-by":"crossref","first-page":"14846","DOI":"10.1039\/D5DT01887K","volume":"54","author":"Glok","year":"2025","journal-title":"Dalton Trans."},{"issue":"11","key":"D5DT02957K\/cit18\/1","doi-asserted-by":"crossref","first-page":"3227","DOI":"10.1021\/om400047j","volume":"32","author":"Wu","year":"2013","journal-title":"Organometallics"},{"issue":"49","key":"D5DT02957K\/cit19\/1","doi-asserted-by":"crossref","first-page":"11276","DOI":"10.1002\/chem.202001062","volume":"26","author":"Krahfu\u00df","year":"2020","journal-title":"Chem. \u2013 Eur. J."},{"issue":"15","key":"D5DT02957K\/cit20\/1","doi-asserted-by":"crossref","first-page":"10976","DOI":"10.1021\/acs.inorgchem.0c01462","volume":"59","author":"Krahfu\u00df","year":"2020","journal-title":"Inorg. Chem."},{"issue":"28","key":"D5DT02957K\/cit21\/1","doi-asserted-by":"crossref","first-page":"10277","DOI":"10.1039\/c3dt50939g","volume":"42","author":"Azhakar","year":"2013","journal-title":"Dalton Trans."},{"issue":"3","key":"D5DT02957K\/cit22\/1","doi-asserted-by":"crossref","first-page":"468","DOI":"10.1002\/(SICI)1521-3765(20000204)6:3<468::AID-CHEM468>3.0.CO;2-6","volume":"6","author":"Schneider","year":"2000","journal-title":"Chem. \u2013 Eur. J."},{"issue":"3","key":"D5DT02957K\/cit23\/1","doi-asserted-by":"crossref","first-page":"1123","DOI":"10.1021\/ja9091374","volume":"132","author":"Sen","year":"2010","journal-title":"J. Am. Chem. Soc."},{"issue":"13","key":"D5DT02957K\/cit24\/1","doi-asserted-by":"crossref","first-page":"3699","DOI":"10.1002\/anie.201700625","volume":"56","author":"Mo","year":"2017","journal-title":"Angew. Chem., Int. Ed."},{"issue":"1","key":"D5DT02957K\/cit25\/1","doi-asserted-by":"crossref","first-page":"57","DOI":"10.1016\/0304-5102(93)80111-7","volume":"21","author":"Klabunde","year":"1983","journal-title":"J. Mol. Catal."},{"key":"D5DT02957K\/cit26\/1","doi-asserted-by":"crossref","first-page":"59","DOI":"10.1002\/9780470132500.ch11","volume-title":"Inorganic Syntheses","author":"Klabunde","year":"1979","unstructured":"K.Klabunde ,  P.Timms ,  P. S.Skell  and  S. D.Ittel ,  Inorganic Syntheses ,  John Wiley & Sons, Ltd ,  1979 , pp.  59\u201369"},{"issue":"4","key":"D5DT02957K\/cit27\/1","doi-asserted-by":"crossref","first-page":"889","DOI":"10.1021\/om00118a001","volume":"9","author":"Elschenbroich","year":"1990","journal-title":"Organometallics"},{"issue":"25","key":"D5DT02957K\/cit28\/1","doi-asserted-by":"crossref","first-page":"6271","DOI":"10.1002\/ange.201202175","volume":"124","author":"Wang","year":"2012","journal-title":"Angew. Chem."},{"issue":"19","key":"D5DT02957K\/cit29\/1","doi-asserted-by":"crossref","first-page":"4780","DOI":"10.1002\/chem.201705745","volume":"24","author":"Zhou","year":"2018","journal-title":"Chem. \u2013 Eur. J."},{"key":"D5DT02957K\/cit30\/1","doi-asserted-by":"crossref","first-page":"2095","DOI":"10.1039\/b102094n","volume":"14","author":"Bridgeman","year":"2001","journal-title":"J. Chem. Soc., Dalton Trans."},{"issue":"15","key":"D5DT02957K\/cit31\/1","doi-asserted-by":"crossref","first-page":"3534","DOI":"10.1021\/ja00967a013","volume":"88","author":"Cramer","year":"1966","journal-title":"J. Am. Chem. Soc."},{"issue":"40","key":"D5DT02957K\/cit32\/1","doi-asserted-by":"crossref","first-page":"14105","DOI":"10.1039\/D1DT02846D","volume":"50","author":"Kaufmann","year":"2021","journal-title":"Dalton Trans."},{"issue":"22","key":"D5DT02957K\/cit33\/1","doi-asserted-by":"crossref","first-page":"2646","DOI":"10.1021\/acs.organomet.5c00303","volume":"44","author":"Ajithkumar","year":"2025","journal-title":"Organometallics"},{"key":"D5DT02957K\/cit34\/1","doi-asserted-by":"crossref","first-page":"2003","DOI":"10.1039\/jr9590002003","author":"Evans","year":"1959","journal-title":"J. Chem. Soc."},{"issue":"20","key":"D5DT02957K\/cit35\/1","doi-asserted-by":"crossref","first-page":"5560","DOI":"10.1021\/om5000612","volume":"33","author":"Liu","year":"2014","journal-title":"Organometallics"},{"issue":"26","key":"D5DT02957K\/cit36\/1","doi-asserted-by":"crossref","first-page":"24078","DOI":"10.1021\/acsomega.3c03161","volume":"8","author":"Suga","year":"2023","journal-title":"ACS Omega"},{"issue":"2","key":"D5DT02957K\/cit37\/1","doi-asserted-by":"crossref","first-page":"184","DOI":"10.1021\/acs.organomet.0c00683","volume":"40","author":"Feng","year":"2021","journal-title":"Organometallics"},{"key":"D5DT02957K\/cit38\/1","doi-asserted-by":"publisher","year":"2026","unstructured":"CCDC 2500552: Experimental Crystal Structure Determination ,  2026 ,  10.5517\/ccdc.csd.cc2py0zn","DOI":"10.5517\/ccdc.csd.cc2py0zn"}],"container-title":["Dalton Transactions"],"original-title":[],"language":"en","link":[{"URL":"http:\/\/pubs.rsc.org\/en\/content\/articlepdf\/2026\/DT\/D5DT02957K","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,7,2]],"date-time":"2026-07-02T18:08:50Z","timestamp":1783015730000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.rsc.org\/dt\/article\/55\/11\/4657-4663\/1242792"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026]]},"references-count":44,"journal-issue":{"issue":"11","published-print":{"date-parts":[[2026,3,17]]}},"URL":"https:\/\/doi.org\/10.1039\/d5dt02957k","relation":{},"ISSN":["1477-9226","1477-9234"],"issn-type":[{"value":"1477-9226","type":"print"},{"value":"1477-9234","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026]]}}}