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Sci."],"abstract":"<jats:p>\n                    Novel Na-ion solid-state electrolytes (MCl\n                    <jats:italic>\n                      <jats:sub>y<\/jats:sub>\n                    <\/jats:italic>\n                    \u2013\n                    <jats:italic>x<\/jats:italic>\n                    Na\n                    <jats:sub>2<\/jats:sub>\n                    CO\n                    <jats:sub>3<\/jats:sub>\n                    , M = Ta, Nb, Hf, Zr, and Al) were synthesized rapidly by ball milling. Conductivity of 1.11 mS cm\n                    <jats:sup>\u22121<\/jats:sup>\n                    was achieved in 10 min for TaCl\n                    <jats:sub>5<\/jats:sub>\n                    \u20131.2Na\n                    <jats:sub>2<\/jats:sub>\n                    CO\n                    <jats:sub>3<\/jats:sub>\n                    , with optimized TaCl\n                    <jats:sub>5<\/jats:sub>\n                    \u20130.5Na\n                    <jats:sub>2<\/jats:sub>\n                    CO\n                    <jats:sub>3<\/jats:sub>\n                    reaching 5.01 mS cm\n                    <jats:sup>\u22121<\/jats:sup>\n                    .\n                  <\/jats:p>","DOI":"10.1039\/d5ee03490f","type":"journal-article","created":{"date-parts":[[2025,10,11]],"date-time":"2025-10-11T02:21:14Z","timestamp":1760149274000},"page":"9927-9938","update-policy":"https:\/\/doi.org\/10.1039\/rsc_crossmark_policy","source":"Crossref","is-referenced-by-count":27,"title":["A new class of carbonate\u2013oxychloride solid electrolytes for high-performance sodium-ion all-solid-state batteries"],"prefix":"10.1039","volume":"18","author":[{"given":"Xinmiao","family":"Wang","sequence":"first","affiliation":[{"name":"Eastern Institute for Advanced Study, Eastern Institute of Technology, Ningbo, Zhejiang, 315200, P. 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