{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,15]],"date-time":"2026-09-15T15:41:20Z","timestamp":1789486880655,"version":"build-2803163510"},"reference-count":56,"publisher":"Royal Society of Chemistry (RSC)","license":[{"start":{"date-parts":[[2026,4,29]],"date-time":"2026-04-29T00:00:00Z","timestamp":1777420800000},"content-version":"vor","delay-in-days":118,"URL":"http:\/\/creativecommons.org\/licenses\/by\/3.0\/"}],"funder":[{"DOI":"10.13039\/501100001659","name":"Deutsche Forschungsgemeinschaft","doi-asserted-by":"publisher","award":["388390466 \u2013 TRR 247"],"award-info":[{"award-number":["388390466 \u2013 TRR 247"]}],"id":[{"id":"10.13039\/501100001659","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["rsc.org"],"crossmark-restriction":true},"short-container-title":["Faraday Discuss."],"abstract":"<jats:p>Catalytic activity and selectivity of 2-propanol dissociation is investigated over pristine and vanadium-oxide loaded Co3O4(111), forming acetone at low V loadings while increasing V coverage results in C\u2013O bond scission and the formation of propene.<\/jats:p>","DOI":"10.1039\/d5fd00173k","type":"journal-article","created":{"date-parts":[[2026,4,29]],"date-time":"2026-04-29T10:10:05Z","timestamp":1777457405000},"page":"138-156","update-policy":"https:\/\/doi.org\/10.1039\/rsc_crossmark_policy","source":"Crossref","is-referenced-by-count":1,"title":["Competing reaction pathways in the decomposition of 2-propanol over V-doped Co\n                    <sub>3<\/sub>\n                    O\n                    <sub>4<\/sub>\n                    (111) model catalysts: a mechanistic study"],"prefix":"10.1039","volume":"267","author":[{"ORCID":"https:\/\/orcid.org\/0009-0006-9956-9863","authenticated-orcid":false,"given":"Patrick","family":"Hubert","sequence":"first","affiliation":[{"name":"Institute of Physical Chemistry, Christian-Albrechts-University Kiel, Max-Eyth-Str. 1, 24118 Kiel, Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0008-6093-5859","authenticated-orcid":false,"given":"Jan","family":"Smyczek","sequence":"additional","affiliation":[{"name":"Institute of Physical Chemistry, Christian-Albrechts-University Kiel, Max-Eyth-Str. 1, 24118 Kiel, Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5856-2020","authenticated-orcid":false,"given":"Carsten","family":"Schr\u00f6der","sequence":"additional","affiliation":[{"name":"Institute of Physical Chemistry, Christian-Albrechts-University Kiel, Max-Eyth-Str. 1, 24118 Kiel, Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Maximilian","family":"Galinski","sequence":"additional","affiliation":[{"name":"Institute of Physical Chemistry, Christian-Albrechts-University Kiel, Max-Eyth-Str. 1, 24118 Kiel, Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Lina M.","family":"Marquardt","sequence":"additional","affiliation":[{"name":"Institute of Physical Chemistry, Christian-Albrechts-University Kiel, Max-Eyth-Str. 1, 24118 Kiel, Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Justin","family":"Girschik","sequence":"additional","affiliation":[{"name":"Institute of Physical Chemistry, Christian-Albrechts-University Kiel, Max-Eyth-Str. 1, 24118 Kiel, Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-8480-0862","authenticated-orcid":false,"given":"Bernd","family":"Hartke","sequence":"additional","affiliation":[{"name":"Institute of Physical Chemistry, Christian-Albrechts-University Kiel, Max-Eyth-Str. 1, 24118 Kiel, Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0623-3254","authenticated-orcid":false,"given":"Guntram","family":"Rauhut","sequence":"additional","affiliation":[{"name":"Institute of Theoretical Chemistry, University of Stuttgart, Pfaffenwaldring 55, 70569 Stuttgart, Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9390-2024","authenticated-orcid":false,"given":"Swetlana","family":"Schauermann","sequence":"additional","affiliation":[{"name":"Institute of Physical Chemistry, Christian-Albrechts-University Kiel, Max-Eyth-Str. 1, 24118 Kiel, Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"292","published-online":{"date-parts":[[2026]]},"reference":[{"key":"D5FD00173K\/cit1\/1","doi-asserted-by":"crossref","first-page":"191","DOI":"10.1016\/j.cattod.2007.06.072","volume":"128","author":"Cozzolino","year":"2007","journal-title":"Catal. Today"},{"key":"D5FD00173K\/cit2\/1","doi-asserted-by":"crossref","first-page":"16809","DOI":"10.1002\/chem.202102868","volume":"27","author":"Najafishirtari","year":"2021","journal-title":"Chem. \u2013 Eur. J."},{"key":"D5FD00173K\/cit3\/1","doi-asserted-by":"crossref","first-page":"3986","DOI":"10.1021\/cr300312n","volume":"113","author":"Kuhlenbeck","year":"2013","journal-title":"Chem. Rev."},{"key":"D5FD00173K\/cit4\/1","doi-asserted-by":"crossref","first-page":"1374878","DOI":"10.3389\/fchem.2024.1374878","volume":"12","author":"Sahoo","year":"2024","journal-title":"Front. Chem."},{"key":"D5FD00173K\/cit5\/1","doi-asserted-by":"crossref","first-page":"1391","DOI":"10.1021\/cr950224d","volume":"96","author":"Weldon","year":"1996","journal-title":"Chem. Rev."},{"key":"D5FD00173K\/cit6\/1","doi-asserted-by":"crossref","first-page":"5974","DOI":"10.1021\/acscatal.9b01048","volume":"9","author":"Anke","year":"2019","journal-title":"ACS Catal."},{"key":"D5FD00173K\/cit7\/1","doi-asserted-by":"crossref","first-page":"25","DOI":"10.1016\/S0920-5861(02)00323-1","volume":"78","author":"Weckhuysen","year":"2003","journal-title":"Catal. Today"},{"key":"D5FD00173K\/cit8\/1","doi-asserted-by":"crossref","first-page":"196","DOI":"10.1007\/s42452-023-05416-6","volume":"5","author":"Mabate","year":"2023","journal-title":"SN Appl. Sci."},{"key":"D5FD00173K\/cit9\/1","doi-asserted-by":"crossref","first-page":"e202401587","DOI":"10.1002\/cctc.202401587","volume":"17","author":"Reindl","year":"2024","journal-title":"ChemCatChem"},{"key":"D5FD00173K\/cit10\/1","doi-asserted-by":"crossref","first-page":"171","DOI":"10.1016\/j.jcat.2021.04.005","volume":"398","author":"Hohner","year":"2021","journal-title":"J. Catal."},{"key":"D5FD00173K\/cit11\/1","doi-asserted-by":"crossref","first-page":"4353","DOI":"10.1021\/acs.chemrev.2c00546","volume":"123","author":"Hu","year":"2023","journal-title":"Chem. Rev."},{"key":"D5FD00173K\/cit12\/1","doi-asserted-by":"crossref","first-page":"223","DOI":"10.1007\/s11244-007-0332-6","volume":"46","author":"Bandara","year":"2007","journal-title":"Top. Catal."},{"key":"D5FD00173K\/cit13\/1","doi-asserted-by":"crossref","first-page":"303","DOI":"10.1016\/S0920-5861(03)00396-1","volume":"85","author":"Vohs","year":"2003","journal-title":"Catal. Today"},{"key":"D5FD00173K\/cit14\/1","doi-asserted-by":"crossref","first-page":"120","DOI":"10.1016\/j.jcat.2012.09.008","volume":"296","author":"Beck","year":"2012","journal-title":"J. Catal."},{"key":"D5FD00173K\/cit15\/1","doi-asserted-by":"crossref","first-page":"14874","DOI":"10.1021\/jacs.2c06303","volume":"144","author":"Schumacher","year":"2022","journal-title":"J. Am. Chem. Soc."},{"key":"D5FD00173K\/cit16\/1","doi-asserted-by":"crossref","first-page":"82","DOI":"10.1016\/j.jcat.2010.03.009","volume":"272","author":"Abbott","year":"2010","journal-title":"J. Catal."},{"key":"D5FD00173K\/cit17\/1","doi-asserted-by":"crossref","first-page":"106","DOI":"10.1016\/j.ccr.2014.12.015","volume":"301\u2013302","author":"Artiglia","year":"2015","journal-title":"Coord. Chem. Rev."},{"key":"D5FD00173K\/cit18\/1","doi-asserted-by":"crossref","first-page":"619","DOI":"10.1016\/j.jcat.2003.10.002","volume":"221","author":"Feng","year":"2004","journal-title":"J. Catal."},{"key":"D5FD00173K\/cit19\/1","doi-asserted-by":"crossref","first-page":"150","DOI":"10.1016\/j.susc.2004.05.118","volume":"562","author":"Agnoli","year":"2004","journal-title":"Surf. Sci."},{"key":"D5FD00173K\/cit20\/1","doi-asserted-by":"crossref","first-page":"205","DOI":"10.1006\/jcat.1998.2295","volume":"181","author":"Khodakov","year":"1999","journal-title":"J. Catal."},{"key":"D5FD00173K\/cit21\/1","doi-asserted-by":"crossref","first-page":"28","DOI":"10.1016\/j.molcata.2008.04.007","volume":"289","author":"Dinse","year":"2008","journal-title":"J. Mol. Catal. A: Chem."},{"key":"D5FD00173K\/cit22\/1","doi-asserted-by":"crossref","first-page":"19268","DOI":"10.1021\/acscatal.5c05269","volume":"15","author":"Smyczek","year":"2025","journal-title":"ACS Catal."},{"key":"D5FD00173K\/cit23\/1","author":"Smyczek","unstructured":"J.Smyczek ,  P.Hubert ,  H.Scheele ,  C.Schr\u00f6der et al. , Submitted"},{"key":"D5FD00173K\/cit24\/1","doi-asserted-by":"crossref","first-page":"13945","DOI":"10.1103\/PhysRevB.61.13945","volume":"61","author":"Surnev","year":"2000","journal-title":"Phys.Rev.B:Condens. Matter Mater. Phys."},{"key":"D5FD00173K\/cit25\/1","doi-asserted-by":"crossref","first-page":"16688","DOI":"10.1021\/acs.jpcc.5b04145","volume":"119","author":"Ferstl","year":"2015","journal-title":"J. Phys. Chem. C"},{"key":"D5FD00173K\/cit26\/1","doi-asserted-by":"crossref","first-page":"26785","DOI":"10.1021\/acs.jpcc.1c07393","volume":"125","author":"Fickenscher","year":"2021","journal-title":"J. Phys. Chem. C"},{"key":"D5FD00173K\/cit27\/1","first-page":"173001","volume":"25","author":"Heinz","year":"2013","journal-title":"J. Phys.:Condens. Matter"},{"key":"D5FD00173K\/cit28\/1","doi-asserted-by":"crossref","first-page":"125429","DOI":"10.1103\/PhysRevB.74.125429","volume":"74","author":"Giovanardi","year":"2006","journal-title":"Phys. Rev. B:Condens. Matter Mater. Phys."},{"key":"D5FD00173K\/cit29\/1","first-page":"265011","volume":"20","author":"Meyer","year":"2008","journal-title":"J. Phys.: Condens. Matter"},{"key":"D5FD00173K\/cit30\/1","doi-asserted-by":"crossref","first-page":"122451","DOI":"10.1016\/j.susc.2024.122451","volume":"742","author":"Schmidt","year":"2024","journal-title":"Surf. Sci."},{"key":"D5FD00173K\/cit31\/1","doi-asserted-by":"crossref","first-page":"4791","DOI":"10.1038\/s41467-023-40461-0","volume":"14","author":"Davis","year":"2023","journal-title":"Nat. Commun."},{"key":"D5FD00173K\/cit32\/1","doi-asserted-by":"crossref","first-page":"1497","DOI":"10.1016\/j.susc.2006.02.003","volume":"600","author":"Haija","year":"2006","journal-title":"Surf. Sci."},{"key":"D5FD00173K\/cit33\/1","doi-asserted-by":"crossref","first-page":"216101","DOI":"10.1103\/PhysRevLett.114.216101","volume":"114","author":"Feiten","year":"2015","journal-title":"Phys. Rev. Lett."},{"key":"D5FD00173K\/cit34\/1","doi-asserted-by":"crossref","first-page":"22961","DOI":"10.1021\/acs.jpcc.5b06943","volume":"119","author":"Feiten","year":"2015","journal-title":"J. Phys. Chem. C"},{"key":"D5FD00173K\/cit35\/1","doi-asserted-by":"crossref","first-page":"1040","DOI":"10.1016\/j.susc.2005.12.035","volume":"600","author":"Abu Haija","year":"2006","journal-title":"Surf. Sci."},{"key":"D5FD00173K\/cit36\/1","doi-asserted-by":"crossref","first-page":"99","DOI":"10.1016\/S0039-6028(03)00752-0","volume":"539","author":"Dupuis","year":"2003","journal-title":"Surf. Sci."},{"key":"D5FD00173K\/cit37\/1","doi-asserted-by":"crossref","first-page":"5394","DOI":"10.1016\/j.susc.2007.09.033","volume":"601","author":"Kolczewski","year":"2007","journal-title":"Surf. Sci."},{"key":"D5FD00173K\/cit38\/1","doi-asserted-by":"crossref","first-page":"074703","DOI":"10.1063\/1.2336770","volume":"125","author":"Kratzer","year":"2006","journal-title":"J. Chem. Phys."},{"key":"D5FD00173K\/cit39\/1","doi-asserted-by":"crossref","first-page":"1743","DOI":"10.1116\/1.581884","volume":"17","author":"Leisenberger","year":"1999","journal-title":"J. Vac. Sci. Technol., A"},{"key":"D5FD00173K\/cit40\/1","doi-asserted-by":"crossref","first-page":"086102","DOI":"10.1103\/PhysRevLett.87.086102","volume":"87","author":"Surnev","year":"2001","journal-title":"Phys. Rev. Lett."},{"key":"D5FD00173K\/cit41\/1","doi-asserted-by":"crossref","first-page":"91","DOI":"10.1016\/S0039-6028(01)01503-5","volume":"495","author":"Surnev","year":"2001","journal-title":"Surf. Sci."},{"key":"D5FD00173K\/cit42\/1","doi-asserted-by":"crossref","first-page":"118","DOI":"10.1016\/j.susc.2004.02.009","volume":"555","author":"Kresse","year":"2004","journal-title":"Surf. Sci."},{"key":"D5FD00173K\/cit43\/1","doi-asserted-by":"crossref","first-page":"101","DOI":"10.1016\/j.susc.2003.12.053","volume":"555","author":"Schoiswohl","year":"2004","journal-title":"Surf. Sci."},{"key":"D5FD00173K\/cit44\/1","doi-asserted-by":"crossref","first-page":"12124","DOI":"10.1039\/c3cp50712b","volume":"15","author":"Tang","year":"2013","journal-title":"Phys. Chem. Chem. Phys."},{"key":"D5FD00173K\/cit45\/1","doi-asserted-by":"crossref","first-page":"117","DOI":"10.1007\/s11244-006-0076-8","volume":"38","author":"Guimond","year":"2006","journal-title":"Top. Catal."},{"key":"D5FD00173K\/cit46\/1","doi-asserted-by":"crossref","first-page":"155403","DOI":"10.1103\/PhysRevB.69.155403","volume":"69","author":"Schoiswohl","year":"2004","journal-title":"Phys. Rev. B:Condens. Matter Mater. Phys."},{"key":"D5FD00173K\/cit48\/1","doi-asserted-by":"crossref","first-page":"2574","DOI":"10.1021\/jp010918s","volume":"106","author":"Concepci\u00f3n","year":"2002","journal-title":"J. Phys. Chem. B"},{"key":"D5FD00173K\/cit49\/1","doi-asserted-by":"crossref","first-page":"3616","DOI":"10.1021\/ja039278s","volume":"126","author":"Magg","year":"2004","journal-title":"J. Am. Chem. Soc."},{"key":"D5FD00173K\/cit50\/1","doi-asserted-by":"crossref","first-page":"9003","DOI":"10.1021\/jp030091x","volume":"107","author":"Magg","year":"2003","journal-title":"J. Phys. Chem. B"},{"key":"D5FD00173K\/cit51\/1","doi-asserted-by":"crossref","first-page":"8309","DOI":"10.1021\/jp5011378","volume":"118","author":"Price","year":"2014","journal-title":"J. Phys. Chem. A"},{"key":"D5FD00173K\/cit52\/1","doi-asserted-by":"crossref","first-page":"134","DOI":"10.1016\/j.jcat.2021.12.025","volume":"406","author":"Kr\u00e4uter","year":"2022","journal-title":"J. Catal."},{"key":"D5FD00173K\/cit53\/1","doi-asserted-by":"crossref","first-page":"399","DOI":"10.1016\/S0039-6028(02)01810-1","volume":"513","author":"Huang","year":"2002","journal-title":"Surf. Sci."},{"key":"D5FD00173K\/cit54\/1","doi-asserted-by":"crossref","first-page":"1389","DOI":"10.1021\/jp962598w","volume":"101","author":"Street","year":"1997","journal-title":"J. Phys. Chem. B"},{"key":"D5FD00173K\/cit55\/1","doi-asserted-by":"crossref","first-page":"8557","DOI":"10.1021\/jp001699y","volume":"104","author":"Davis","year":"2000","journal-title":"J. Phys. Chem. B"},{"key":"D5FD00173K\/cit56\/1","doi-asserted-by":"crossref","first-page":"263","DOI":"10.1016\/0584-8539(73)80070-4","volume":"29","author":"Silvi","year":"1973","journal-title":"Spectrochim. Acta, Part A"},{"key":"D5FD00173K\/cit57\/1","doi-asserted-by":"crossref","first-page":"559","DOI":"10.1016\/j.jqsrt.2013.09.019","volume":"133","author":"Es-sebbar","year":"2014","journal-title":"J. Quant. Spectrosc. Radiat. Transfer"}],"container-title":["Faraday Discussions"],"original-title":[],"language":"en","link":[{"URL":"http:\/\/pubs.rsc.org\/FD\/article-pdf\/doi\/10.1039\/D5FD00173K\/0\/D5FD00173K.pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,9,15]],"date-time":"2026-09-15T13:29:12Z","timestamp":1789478952000},"score":1,"resource":{"primary":{"URL":"http:\/\/pubs.rsc.org\/FD\/article-lookup\/doi\/10.1039\/D5FD00173K"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026]]},"references-count":56,"URL":"https:\/\/doi.org\/10.1039\/d5fd00173k","relation":{},"ISSN":["1359-6640","1364-5498"],"issn-type":[{"value":"1359-6640","type":"print"},{"value":"1364-5498","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026]]}}}