{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,6,30]],"date-time":"2026-06-30T21:50:07Z","timestamp":1782856207917,"version":"3.54.5"},"reference-count":39,"publisher":"Royal Society of Chemistry (RSC)","issue":"45","license":[{"start":{"date-parts":[[2026,10,21]],"date-time":"2026-10-21T00:00:00Z","timestamp":1792540800000},"content-version":"am","delay-in-days":658,"URL":"http:\/\/rsc.li\/journals-terms-of-use"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22178072"],"award-info":[{"award-number":["22178072"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22308063"],"award-info":[{"award-number":["22308063"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100013091","name":"Science and Technology Major Project of Guangxi","doi-asserted-by":"publisher","award":["AA23062019"],"award-info":[{"award-number":["AA23062019"]}],"id":[{"id":"10.13039\/501100013091","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100013091","name":"Science and Technology Major Project of Guangxi","doi-asserted-by":"publisher","award":["AA23062020"],"award-info":[{"award-number":["AA23062020"]}],"id":[{"id":"10.13039\/501100013091","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100013091","name":"Science and Technology Major Project of Guangxi","doi-asserted-by":"publisher","award":["AA23073019"],"award-info":[{"award-number":["AA23073019"]}],"id":[{"id":"10.13039\/501100013091","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100012298","name":"Guangxi Key Laboratory of Petrochemical Resource Processing and Process Intensification Technology, Guangxi University","doi-asserted-by":"publisher","award":["2023Z007"],"award-info":[{"award-number":["2023Z007"]}],"id":[{"id":"10.13039\/501100012298","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["rsc.org"],"crossmark-restriction":true},"short-container-title":["Nanoscale"],"abstract":"<jats:p>\n                    A novel\n                    <jats:italic>stereo<\/jats:italic>\n                    -Ir(CO)\n                    <jats:sub>2<\/jats:sub>\n                    I\n                    <jats:sub>2<\/jats:sub>\n                    <jats:sup>\u2212<\/jats:sup>\n                    configuration accumulates\n                    <jats:italic>via<\/jats:italic>\n                    solvent-triggered stabilization, causing catalyst deactivation.\n                  <\/jats:p>","DOI":"10.1039\/d5nr04106f","type":"journal-article","created":{"date-parts":[[2025,10,21]],"date-time":"2025-10-21T08:41:30Z","timestamp":1761036090000},"page":"26281-26293","update-policy":"https:\/\/doi.org\/10.1039\/rsc_crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Solvent stabilization mechanisms and deactivation pathways of the inert\n                    <i>stereo<\/i>\n                    -configuration in iridium carbonyl iodide complexes (Ir(CO)\n                    <sub>2<\/sub>\n                    I\n                    <sub>2<\/sub>\n                    <sup>\u2212<\/sup>\n                    )"],"prefix":"10.1039","volume":"17","author":[{"given":"Qiyue","family":"Wei","sequence":"first","affiliation":[{"name":"University Engineering Research Center of Green Chemical New Materials, School of Chemistry and Chemical Engineering, Guangxi University, Nanning, Guangxi 530004, PR China"},{"name":"State Key Laboratory of Featured Metal Materials and Life-Cycle Safety for Composite Structures, Guangxi University, Nanning 530004, China"},{"name":"Guangxi Key Laboratory of Petrochemical Resource Processing and Process Intensification Technology, Guangxi University, Nanning, 530004, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yue","family":"Li","sequence":"additional","affiliation":[{"name":"University Engineering Research Center of Green Chemical New Materials, School of Chemistry and Chemical Engineering, Guangxi University, Nanning, Guangxi 530004, PR China"},{"name":"State Key Laboratory of Featured Metal Materials and Life-Cycle Safety for Composite Structures, Guangxi University, Nanning 530004, China"},{"name":"Guangxi Key Laboratory of Petrochemical Resource Processing and Process Intensification Technology, Guangxi University, Nanning, 530004, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jinhui","family":"Xie","sequence":"additional","affiliation":[{"name":"University Engineering Research Center of Green Chemical New Materials, School of Chemistry and Chemical Engineering, Guangxi University, Nanning, Guangxi 530004, PR China"},{"name":"State Key Laboratory of Featured Metal Materials and Life-Cycle Safety for Composite Structures, Guangxi University, Nanning 530004, China"},{"name":"Guangxi Key Laboratory of Petrochemical Resource Processing and Process Intensification Technology, Guangxi University, Nanning, 530004, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yanxun","family":"Wu","sequence":"additional","affiliation":[{"name":"University Engineering Research Center of Green Chemical New Materials, School of Chemistry and Chemical Engineering, Guangxi University, Nanning, Guangxi 530004, PR China"},{"name":"State Key Laboratory of Featured Metal Materials and Life-Cycle Safety for Composite Structures, Guangxi University, Nanning 530004, China"},{"name":"Guangxi Key Laboratory of Petrochemical Resource Processing and Process Intensification Technology, Guangxi University, Nanning, 530004, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xiaokun","family":"Zhou","sequence":"additional","affiliation":[{"name":"University Engineering Research Center of Green Chemical New Materials, School of Chemistry and Chemical Engineering, Guangxi University, Nanning, Guangxi 530004, PR China"},{"name":"State Key Laboratory of Featured Metal Materials and Life-Cycle Safety for Composite Structures, Guangxi University, Nanning 530004, China"},{"name":"Guangxi Key Laboratory of Petrochemical Resource Processing and Process Intensification Technology, Guangxi University, Nanning, 530004, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shiyu","family":"Lv","sequence":"additional","affiliation":[{"name":"University Engineering Research Center of Green Chemical New Materials, School of Chemistry and Chemical Engineering, Guangxi University, Nanning, Guangxi 530004, PR China"},{"name":"State Key Laboratory of Featured Metal Materials and Life-Cycle Safety for Composite Structures, Guangxi University, Nanning 530004, China"},{"name":"Guangxi Key Laboratory of Petrochemical Resource Processing and Process Intensification Technology, Guangxi University, Nanning, 530004, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ruifeng","family":"Wang","sequence":"additional","affiliation":[{"name":"University Engineering Research Center of Green Chemical New Materials, School of Chemistry and Chemical Engineering, Guangxi University, Nanning, Guangxi 530004, PR China"},{"name":"State Key Laboratory of Featured Metal Materials and Life-Cycle Safety for Composite Structures, Guangxi University, Nanning 530004, China"},{"name":"Guangxi Key Laboratory of Petrochemical Resource Processing and Process Intensification Technology, Guangxi University, Nanning, 530004, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-7513-6680","authenticated-orcid":false,"given":"Zengxi","family":"Wei","sequence":"additional","affiliation":[{"name":"University Engineering Research Center of Green Chemical New Materials, School of Chemistry and Chemical Engineering, Guangxi University, Nanning, Guangxi 530004, PR China"},{"name":"State Key Laboratory of Featured Metal Materials and Life-Cycle Safety for Composite Structures, Guangxi University, Nanning 530004, China"},{"name":"Guangxi Key Laboratory of Petrochemical Resource Processing and Process Intensification Technology, Guangxi University, Nanning, 530004, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shuangliang","family":"Zhao","sequence":"additional","affiliation":[{"name":"University Engineering Research Center of Green Chemical New Materials, School of Chemistry and Chemical Engineering, Guangxi University, Nanning, Guangxi 530004, PR China"},{"name":"State Key Laboratory of Featured Metal Materials and Life-Cycle Safety for Composite Structures, Guangxi University, Nanning 530004, China"},{"name":"Guangxi Key Laboratory of Petrochemical Resource Processing and Process Intensification Technology, Guangxi University, Nanning, 530004, China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"292","published-online":{"date-parts":[[2025]]},"reference":[{"key":"D5NR04106F\/cit1\/1","doi-asserted-by":"publisher","first-page":"1","DOI":"10.1002\/0471238961.0103052023010714.a01.pub3","volume-title":"Kirk\u2013Othmer Encyclopedia of Chemical Technology","author":"Wagner","year":"2000","unstructured":"F. S.Wagner  and  U.Staff ,  Kirk\u2013Othmer Encyclopedia of Chemical Technology ,  2000 , pp.  1\u201321 ,  10.1002\/0471238961.0103052023010714.a01.pub3"},{"issue":"1","key":"D5NR04106F\/cit2\/1","doi-asserted-by":"publisher","first-page":"253","DOI":"10.1016\/S0926-860X(01)00800-6","volume":"221","author":"Yoneda","year":"2001","journal-title":"Appl. Catal., A"},{"issue":"4","key":"D5NR04106F\/cit3\/1","doi-asserted-by":"publisher","first-page":"325","DOI":"10.1016\/0920-5861(93)80060-E","volume":"18","author":"Howard","year":"1993","journal-title":"Catal. Today"},{"issue":"9","key":"D5NR04106F\/cit4\/1","doi-asserted-by":"publisher","first-page":"2847","DOI":"10.1021\/ja039464y","volume":"126","author":"Haynes","year":"2004","journal-title":"J. Am. Chem. Soc."},{"key":"D5NR04106F\/cit5\/1","doi-asserted-by":"publisher","first-page":"721","DOI":"10.1039\/TF9514700721","volume":"47","author":"Bawn","year":"1951","journal-title":"Trans. Faraday Soc."},{"issue":"2","key":"D5NR04106F\/cit6\/1","doi-asserted-by":"publisher","first-page":"213","DOI":"10.1016\/0166-3615(92)90115-4","volume":"18","author":"Shuqing","year":"1992","journal-title":"Comput. Ind."},{"issue":"11","key":"D5NR04106F\/cit7\/1","doi-asserted-by":"publisher","first-page":"23","DOI":"10.3390\/pr10112355","volume":"10","author":"Sitnov","year":"2022","journal-title":"Processes"},{"key":"D5NR04106F\/cit8\/1","doi-asserted-by":"publisher","first-page":"1","DOI":"10.1016\/j.cherd.2020.04.013","volume":"159","author":"Dimian","year":"2020","journal-title":"Chem. Eng. Res. Des."},{"key":"D5NR04106F\/cit9\/1","doi-asserted-by":"publisher","first-page":"179","DOI":"10.1007\/3418_021","volume-title":"Catalytic carbonylation reactions","author":"Haynes","year":"2006","unstructured":"A.Haynes ,  Catalytic carbonylation reactions ,  2006 , pp.  179\u2013205 ,  10.1007\/3418_021"},{"key":"D5NR04106F\/cit10\/1","doi-asserted-by":"publisher","first-page":"213078","DOI":"10.1016\/j.ccr.2019.213078","volume":"402","author":"Kalck","year":"2020","journal-title":"Coord. Chem. Rev."},{"issue":"9","key":"D5NR04106F\/cit11\/1","doi-asserted-by":"publisher","first-page":"3044","DOI":"10.1021\/ie950755s","volume":"35","author":"Nguyen","year":"1996","journal-title":"Ind. Eng. Chem. Res."},{"issue":"2","key":"D5NR04106F\/cit12\/1","doi-asserted-by":"publisher","first-page":"257","DOI":"10.1016\/0022-328X(86)80137-1","volume":"303","author":"Murphy","year":"1986","journal-title":"J. Organomet. Chem."},{"issue":"1","key":"D5NR04106F\/cit13\/1","doi-asserted-by":"publisher","first-page":"115","DOI":"10.1016\/0304-5102(87)80053-6","volume":"39","author":"Smith","year":"1987","journal-title":"J. Mol. Catal."},{"issue":"11","key":"D5NR04106F\/cit14\/1","doi-asserted-by":"publisher","first-page":"1639","DOI":"10.1039\/DT9790001639","volume":"1","author":"Forster","year":"1979","journal-title":"Dalton Trans."},{"issue":"6","key":"D5NR04106F\/cit15\/1","doi-asserted-by":"publisher","first-page":"1161","DOI":"10.1021\/om000761a","volume":"20","author":"Aivanova","year":"2001","journal-title":"Organometallics"},{"issue":"4","key":"D5NR04106F\/cit16\/1","doi-asserted-by":"publisher","first-page":"293","DOI":"10.1016\/S0920-5861(00)00263-7","volume":"58","author":"Sunley","year":"2000","journal-title":"Catal. Today"},{"issue":"12","key":"D5NR04106F\/cit17\/1","doi-asserted-by":"publisher","first-page":"67","DOI":"10.3969\/j.issn.1008-1143.2011.12.014","volume":"19","author":"Lai","year":"2011","journal-title":"Ind. Catal."},{"issue":"1\u20132","key":"D5NR04106F\/cit18\/1","doi-asserted-by":"publisher","first-page":"339","DOI":"10.1016\/S0022-328X(97)00519-6","volume":"551","author":"Haynes","year":"1998","journal-title":"J. Organomet. Chem."},{"issue":"2\u20134","key":"D5NR04106F\/cit19\/1","doi-asserted-by":"publisher","first-page":"122","DOI":"10.1016\/S0927-0256(00)00008-2","volume":"17","author":"Delley","year":"2000","journal-title":"Comput. Mater. Sci."},{"issue":"3","key":"D5NR04106F\/cit20\/1","doi-asserted-by":"publisher","first-page":"036402","DOI":"10.1103\/PhysRevLett.115.036402","volume":"115","author":"Sun","year":"2015","journal-title":"Phys. Rev. Lett."},{"issue":"9","key":"D5NR04106F\/cit21\/1","doi-asserted-by":"publisher","first-page":"831","DOI":"10.1038\/NCHEM.2535","volume":"8","author":"Sun","year":"2016","journal-title":"Nat. Chem."},{"issue":"2","key":"D5NR04106F\/cit22\/1","doi-asserted-by":"publisher","first-page":"250","DOI":"10.1016\/S0927-0256(03)00111-3","volume":"28","author":"Govind","year":"2003","journal-title":"Comput. Mater. Sci."},{"issue":"2","key":"D5NR04106F\/cit23\/1","doi-asserted-by":"publisher","first-page":"225","DOI":"10.1016\/0009-2614(77)80574-5","volume":"49","author":"Halgren","year":"1977","journal-title":"Chem. Phys. Lett."},{"issue":"12","key":"D5NR04106F\/cit24\/1","doi-asserted-by":"publisher","first-page":"786","DOI":"10.1063\/1.1749593","volume":"3","author":"Eyring","year":"1935","journal-title":"J. Chem. Phys."},{"issue":"10","key":"D5NR04106F\/cit25\/1","doi-asserted-by":"publisher","first-page":"1973","DOI":"10.1021\/om9910221","volume":"19","author":"Cheong","year":"2000","journal-title":"Organometallics"},{"issue":"1","key":"D5NR04106F\/cit26\/1","doi-asserted-by":"publisher","first-page":"28","DOI":"10.1021\/ic8017858","volume":"48","author":"Haynes","year":"2009","journal-title":"Inorg. Chem."},{"issue":"13","key":"D5NR04106F\/cit27\/1","doi-asserted-by":"publisher","first-page":"3053","DOI":"10.1021\/om049383q","volume":"24","author":"Cheong","year":"2005","journal-title":"Organometallics"},{"key":"D5NR04106F\/cit28\/1","doi-asserted-by":"publisher","first-page":"355","DOI":"10.1016\/j.ccr.2017.03.002","volume":"344","author":"Kaupp","year":"2017","journal-title":"Coord. Chem. Rev."},{"issue":"1","key":"D5NR04106F\/cit29\/1","doi-asserted-by":"publisher","first-page":"49","DOI":"10.1103\/PhysRev.41.49","volume":"41","author":"Mulliken","year":"1932","journal-title":"Phys. Rev."},{"issue":"2","key":"D5NR04106F\/cit30\/1","doi-asserted-by":"publisher","first-page":"153","DOI":"10.1002\/wcms.19","volume":"1","author":"Murray","year":"2011","journal-title":"Wiley Interdiscip. Rev.:Comput. Mol. Sci."},{"key":"D5NR04106F\/cit31\/1","doi-asserted-by":"publisher","first-page":"4814","DOI":"10.1039\/C2RA20222K","volume":"2","author":"Zhang","year":"2012","journal-title":"RSC Adv."},{"issue":"11","key":"D5NR04106F\/cit32\/1","doi-asserted-by":"publisher","first-page":"6561","DOI":"10.1021\/acs.chemrev.8b00588","volume":"119","author":"Durand","year":"2019","journal-title":"Chem. Rev."},{"issue":"11","key":"D5NR04106F\/cit33\/1","doi-asserted-by":"publisher","first-page":"4422","DOI":"10.1021\/j100348a011","volume":"93","author":"Lendvay","year":"1989","journal-title":"J. Phys. Chem."},{"key":"D5NR04106F\/cit35\/1","doi-asserted-by":"publisher","first-page":"e202513213","DOI":"10.1002\/anie.202513213","author":"Deng","year":"2025","journal-title":"Angew. Chem., Int. Ed."},{"issue":"1","key":"D5NR04106F\/cit36\/1","doi-asserted-by":"publisher","first-page":"490","DOI":"10.1021\/acsenergylett.1c02425","volume":"7","author":"Cheng","year":"2022","journal-title":"ACS Energy Lett."},{"key":"D5NR04106F\/cit37\/1","doi-asserted-by":"publisher","first-page":"580","DOI":"10.1002\/jcc.22885","volume":"33","author":"Lu","year":"2012","journal-title":"J. Comput. Chem."},{"key":"D5NR04106F\/cit38\/1","doi-asserted-by":"publisher","first-page":"082503","DOI":"10.1063\/5.0216272","volume":"161","author":"Lu","year":"2024","journal-title":"J. Chem. Phys."},{"key":"D5NR04106F\/cit39\/1","doi-asserted-by":"publisher","first-page":"231","DOI":"10.1002\/cmtd.202100007","volume":"1","author":"Lu","year":"2021","journal-title":"Chem. Methods"},{"key":"D5NR04106F\/cit40\/1","doi-asserted-by":"publisher","first-page":"e202504895","DOI":"10.1002\/anie.202504895","volume":"64","author":"Lu","year":"2025","journal-title":"Angew. Chem., Int. Ed."}],"container-title":["Nanoscale"],"original-title":[],"language":"en","link":[{"URL":"http:\/\/pubs.rsc.org\/en\/content\/articlepdf\/2025\/NR\/D5NR04106F","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,6,30]],"date-time":"2026-06-30T20:41:05Z","timestamp":1782852065000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.rsc.org\/nr\/article\/17\/45\/26281-26293\/902044"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2025]]},"references-count":39,"journal-issue":{"issue":"45","published-print":{"date-parts":[[2025,11,20]]}},"URL":"https:\/\/doi.org\/10.1039\/d5nr04106f","relation":{"has-review":[{"id-type":"doi","id":"10.1039\/D5NR04106F\/v2\/decision1","asserted-by":"object"},{"id-type":"doi","id":"10.1039\/D5NR04106F\/v2\/review1","asserted-by":"object"},{"id-type":"doi","id":"10.1039\/D5NR04106F\/v2\/response1","asserted-by":"object"},{"id-type":"doi","id":"10.1039\/D5NR04106F\/v1\/review2","asserted-by":"object"},{"id-type":"doi","id":"10.1039\/D5NR04106F\/v3\/decision1","asserted-by":"object"},{"id-type":"doi","id":"10.1039\/D5NR04106F\/v2\/review2","asserted-by":"object"},{"id-type":"doi","id":"10.1039\/D5NR04106F\/v1\/review1","asserted-by":"object"},{"id-type":"doi","id":"10.1039\/D5NR04106F\/v3\/response1","asserted-by":"object"},{"id-type":"doi","id":"10.1039\/D5NR04106F\/v1\/decision1","asserted-by":"object"}]},"ISSN":["2040-3364","2040-3372"],"issn-type":[{"value":"2040-3364","type":"print"},{"value":"2040-3372","type":"electronic"}],"subject":[],"published":{"date-parts":[[2025]]}}}