{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,7,1]],"date-time":"2026-07-01T05:02:20Z","timestamp":1782882140533,"version":"3.54.5"},"reference-count":134,"publisher":"Royal Society of Chemistry (RSC)","issue":"46","license":[{"start":{"date-parts":[[2026,10,29]],"date-time":"2026-10-29T00:00:00Z","timestamp":1793232000000},"content-version":"am","delay-in-days":666,"URL":"http:\/\/rsc.li\/journals-terms-of-use"}],"content-domain":{"domain":["rsc.org"],"crossmark-restriction":true},"short-container-title":["Org. Biomol. Chem."],"abstract":"<jats:p>Chiral phosphoric acid (CPA)-catalyzed Diels\u2013Alder reaction between 2-trifluoroacetamido-1,3-dienes and \u03b1,\u03b2-unsaturated ketones has been theoretically investigated, and the reaction mechanism and origin of the enantioselectivity were uncovered.<\/jats:p>","DOI":"10.1039\/d5ob01404b","type":"journal-article","created":{"date-parts":[[2025,10,29]],"date-time":"2025-10-29T03:01:20Z","timestamp":1761706880000},"page":"10561-10573","update-policy":"https:\/\/doi.org\/10.1039\/rsc_crossmark_policy","source":"Crossref","is-referenced-by-count":2,"title":["Mechanism and origin of enantioselectivity for Diels\u2013Alder reaction catalyzed by chiral phosphoric acids in synthesising 1-trifluoroacetamido cyclohex-1-ene"],"prefix":"10.1039","volume":"23","author":[{"given":"Yu-Hao","family":"Qiao","sequence":"first","affiliation":[{"name":"State Key Laboratory of Natural Product Chemistry, Key Laboratory of Nonferrous Metal Chemistry and Resources Utilization of Gansu Province, College of Chemistry and Chemical Engineering, Lanzhou University, 222 South Tianshui Road, 730000, Lanzhou, P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xiao-Heng","family":"Wang","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Natural Product Chemistry, Key Laboratory of Nonferrous Metal Chemistry and Resources Utilization of Gansu Province, College of Chemistry and Chemical Engineering, Lanzhou University, 222 South Tianshui Road, 730000, Lanzhou, P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Dong","family":"Xie","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Natural Product Chemistry, Key Laboratory of Nonferrous Metal Chemistry and Resources Utilization of Gansu Province, College of Chemistry and Chemical Engineering, Lanzhou University, 222 South Tianshui Road, 730000, Lanzhou, P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xin-Ting","family":"He","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Natural Product Chemistry, Key Laboratory of Nonferrous Metal Chemistry and Resources Utilization of Gansu Province, College of Chemistry and Chemical Engineering, Lanzhou University, 222 South Tianshui Road, 730000, Lanzhou, P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hao","family":"Qiu","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Natural Product Chemistry, Key Laboratory of Nonferrous Metal Chemistry and Resources Utilization of Gansu Province, College of Chemistry and Chemical Engineering, Lanzhou University, 222 South Tianshui Road, 730000, Lanzhou, P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhe-Rui","family":"Zhang","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Natural Product Chemistry, Key Laboratory of Nonferrous Metal Chemistry and Resources Utilization of Gansu Province, College of Chemistry and Chemical Engineering, Lanzhou University, 222 South Tianshui Road, 730000, Lanzhou, P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-8111-8155","authenticated-orcid":false,"given":"Pan-Pan","family":"Zhou","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Natural Product Chemistry, Key Laboratory of Nonferrous Metal Chemistry and Resources Utilization of Gansu Province, College of Chemistry and Chemical Engineering, Lanzhou University, 222 South Tianshui Road, 730000, Lanzhou, P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhaoyong","family":"Yang","sequence":"additional","affiliation":[{"name":"Key Laboratory of Biotechnology of Antibiotics, Ministry of Health, Institute of Medicinal Biotechnology, Chinese Academy of Medical Sciences (CAMS) & Peking Union Medical College(PUMC), Beijing 100050, China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"292","published-online":{"date-parts":[[2025]]},"reference":[{"key":"D5OB01404B\/cit1a\/1","doi-asserted-by":"crossref","first-page":"1566","DOI":"10.1002\/anie.200353240","volume":"43","author":"Akiyama","year":"2004","journal-title":"Angew. Chem., Int. Ed."},{"key":"D5OB01404B\/cit1b\/1","doi-asserted-by":"crossref","first-page":"16561","DOI":"10.1021\/jacs.6b11435","volume":"138","author":"Li","year":"2016","journal-title":"J. Am. Chem. Soc."},{"key":"D5OB01404B\/cit1c\/1","doi-asserted-by":"crossref","first-page":"5356","DOI":"10.1021\/ja0491533","volume":"126","author":"Uraguchi","year":"2004","journal-title":"J. Am. Chem. Soc."},{"key":"D5OB01404B\/cit2a\/1","doi-asserted-by":"crossref","first-page":"e202308122","DOI":"10.1002\/anie.202308122","volume":"62","author":"Pan","year":"2023","journal-title":"Angew. Chem., Int. Ed."},{"key":"D5OB01404B\/cit2b\/1","doi-asserted-by":"crossref","first-page":"3683","DOI":"10.1002\/anie.200600191","volume":"45","author":"Rueping","year":"2006","journal-title":"Angew. Chem., Int. Ed."},{"key":"D5OB01404B\/cit2c\/1","doi-asserted-by":"crossref","first-page":"e202202189","DOI":"10.1002\/anie.202202189","volume":"61","author":"Scharinger","year":"2022","journal-title":"Angew. Chem., Int. Ed."},{"key":"D5OB01404B\/cit2d\/1","doi-asserted-by":"crossref","first-page":"e202306864","DOI":"10.1002\/anie.202306864","volume":"62","author":"Wei","year":"2023","journal-title":"Angew. Chem., Int. Ed."},{"key":"D5OB01404B\/cit2e\/1","doi-asserted-by":"crossref","first-page":"8970","DOI":"10.1002\/anie.201603929","volume":"55","author":"Zhou","year":"2016","journal-title":"Angew. Chem., Int. Ed."},{"key":"D5OB01404B\/cit2f\/1","doi-asserted-by":"crossref","first-page":"1426","DOI":"10.1039\/C8SC03587C","volume":"10","author":"Kikuchi","year":"2019","journal-title":"Chem. Sci."},{"key":"D5OB01404B\/cit2g\/1","doi-asserted-by":"crossref","first-page":"1787","DOI":"10.1002\/cjoc.202000751","volume":"39","author":"Da","year":"2021","journal-title":"Chin. J. Chem."},{"key":"D5OB01404B\/cit2h\/1","doi-asserted-by":"crossref","first-page":"592","DOI":"10.1002\/chir.23101","volume":"31","author":"Tang","year":"2019","journal-title":"Chirality"},{"key":"D5OB01404B\/cit2i\/1","doi-asserted-by":"crossref","first-page":"106344","DOI":"10.1016\/j.isci.2023.106344","volume":"26","author":"Jie","year":"2023","journal-title":"iScience"},{"key":"D5OB01404B\/cit2j\/1","doi-asserted-by":"crossref","first-page":"4121","DOI":"10.1021\/acs.joc.0c02956","volume":"86","author":"Qiu","year":"2021","journal-title":"J. Org. Chem."},{"key":"D5OB01404B\/cit2k\/1","doi-asserted-by":"crossref","first-page":"14227","DOI":"10.1021\/jacs.3c05334","volume":"145","author":"Zhang","year":"2023","journal-title":"J. Am. Chem. Soc."},{"key":"D5OB01404B\/cit2l\/1","doi-asserted-by":"crossref","first-page":"504","DOI":"10.1038\/s41929-019-0278-7","volume":"2","author":"Wang","year":"2019","journal-title":"Nat. Catal."},{"key":"D5OB01404B\/cit2m\/1","doi-asserted-by":"crossref","first-page":"4549","DOI":"10.1021\/acs.orglett.9b01437","volume":"21","author":"Bai","year":"2019","journal-title":"Org. Lett."},{"key":"D5OB01404B\/cit2n\/1","doi-asserted-by":"crossref","first-page":"6072","DOI":"10.1021\/acs.orglett.7b02887","volume":"19","author":"Zhang","year":"2017","journal-title":"Org. Lett."},{"key":"D5OB01404B\/cit2o\/1","doi-asserted-by":"crossref","first-page":"6910","DOI":"10.1039\/C7RA13471A","volume":"8","author":"Clot-Almenara","year":"2018","journal-title":"RSC Adv."},{"key":"D5OB01404B\/cit2p\/1","doi-asserted-by":"crossref","first-page":"1501","DOI":"10.1126\/science.aaq0445","volume":"359","author":"Tsuji","year":"2018","journal-title":"Science"},{"key":"D5OB01404B\/cit2q\/1","doi-asserted-by":"crossref","first-page":"1019","DOI":"10.1021\/acs.accounts.6b00053","volume":"49","author":"Sunoj","year":"2016","journal-title":"Acc. Chem. Res."},{"key":"D5OB01404B\/cit2r\/1","doi-asserted-by":"crossref","first-page":"10540","DOI":"10.1002\/anie.202000039","volume":"59","author":"Gao","year":"2020","journal-title":"Angew. Chem., Int. Ed."},{"key":"D5OB01404B\/cit2s\/1","doi-asserted-by":"crossref","first-page":"9684","DOI":"10.1002\/anie.201205383","volume":"51","author":"Honjo","year":"2012","journal-title":"Angew. Chem., Int. Ed."},{"key":"D5OB01404B\/cit3a\/1","doi-asserted-by":"crossref","first-page":"399","DOI":"10.1002\/adsc.200700521","volume":"350","author":"Akiyama","year":"2008","journal-title":"Adv. Synth. Catal."},{"key":"D5OB01404B\/cit3b\/1","doi-asserted-by":"crossref","first-page":"3790","DOI":"10.1021\/ja068236b","volume":"129","author":"Guo","year":"2007","journal-title":"J. Am. Chem. Soc."},{"key":"D5OB01404B\/cit3c\/1","doi-asserted-by":"crossref","first-page":"6756","DOI":"10.1021\/ja0684803","volume":"129","author":"Yamanaka","year":"2007","journal-title":"J. Am. Chem. Soc."},{"key":"D5OB01404B\/cit3d\/1","doi-asserted-by":"crossref","first-page":"6551","DOI":"10.1021\/acs.orglett.4c01958","volume":"26","author":"Jia","year":"2024","journal-title":"Org. Lett."},{"key":"D5OB01404B\/cit3e\/1","doi-asserted-by":"crossref","first-page":"2521","DOI":"10.1021\/acs.orglett.6b00857","volume":"18","author":"Kikuchi","year":"2016","journal-title":"Org. Lett."},{"key":"D5OB01404B\/cit4a\/1","doi-asserted-by":"crossref","first-page":"13489","DOI":"10.1002\/anie.201807010","volume":"57","author":"Rajkumar","year":"2018","journal-title":"Angew. Chem., Int. Ed."},{"key":"D5OB01404B\/cit4b\/1","doi-asserted-by":"crossref","first-page":"2499","DOI":"10.1039\/C9CC09637J","volume":"56","author":"Deng","year":"2020","journal-title":"Chem. Commun."},{"key":"D5OB01404B\/cit4c\/1","doi-asserted-by":"crossref","first-page":"655","DOI":"10.1039\/D4QO01856G","volume":"12","author":"Yang","year":"2025","journal-title":"Org. Chem. Front."},{"key":"D5OB01404B\/cit4d\/1","doi-asserted-by":"crossref","first-page":"1437","DOI":"10.1039\/D3QO01909H","volume":"11","author":"Zhang","year":"2024","journal-title":"Org. Chem. Front."},{"key":"D5OB01404B\/cit4e\/1","doi-asserted-by":"crossref","first-page":"3538","DOI":"10.1021\/acs.orglett.9b00821","volume":"21","author":"Cai","year":"2019","journal-title":"Org. Lett."},{"key":"D5OB01404B\/cit4f\/1","doi-asserted-by":"crossref","first-page":"3569","DOI":"10.1021\/acs.orglett.4c01000","volume":"26","author":"Guo","year":"2024","journal-title":"Org. Lett."},{"key":"D5OB01404B\/cit4g\/1","doi-asserted-by":"crossref","first-page":"477","DOI":"10.1021\/acs.orglett.2c04109","volume":"25","author":"Han","year":"2023","journal-title":"Org. Lett."},{"key":"D5OB01404B\/cit4h\/1","doi-asserted-by":"crossref","first-page":"2393","DOI":"10.1021\/acs.orglett.0c04002","volume":"23","author":"Huang","year":"2021","journal-title":"Org. Lett."},{"key":"D5OB01404B\/cit4i\/1","doi-asserted-by":"crossref","first-page":"3563","DOI":"10.1021\/acs.orglett.9b00963","volume":"21","author":"Liu","year":"2019","journal-title":"Org. Lett."},{"key":"D5OB01404B\/cit4j\/1","doi-asserted-by":"crossref","first-page":"3682","DOI":"10.1021\/acs.orglett.9b01127","volume":"21","author":"Xie","year":"2019","journal-title":"Org. Lett."},{"key":"D5OB01404B\/cit4k\/1","doi-asserted-by":"crossref","first-page":"1625","DOI":"10.1016\/j.tetlet.2019.05.003","volume":"60","author":"Kim","year":"2019","journal-title":"Tetrahedron Lett."},{"key":"D5OB01404B\/cit5a\/1","doi-asserted-by":"crossref","first-page":"4545","DOI":"10.1021\/acscatal.2c00397","volume":"12","author":"Huang","year":"2022","journal-title":"ACS Catal."},{"key":"D5OB01404B\/cit5b\/1","doi-asserted-by":"crossref","first-page":"e2305101","DOI":"10.1002\/advs.202305101","volume":"10","author":"Gao","year":"2023","journal-title":"Adv. Sci."},{"key":"D5OB01404B\/cit5c\/1","doi-asserted-by":"crossref","first-page":"5449","DOI":"10.1002\/adsc.201901035","volume":"361","author":"Zhang","year":"2019","journal-title":"Adv. Synth. Catal."},{"key":"D5OB01404B\/cit5d\/1","doi-asserted-by":"crossref","first-page":"642","DOI":"10.1002\/anie.201911420","volume":"59","author":"Yang","year":"2020","journal-title":"Angew. Chem., Int. Ed."},{"key":"D5OB01404B\/cit5e\/1","first-page":"386","volume":"2","author":"Mei","year":"2022","journal-title":"Chem. Catal."},{"key":"D5OB01404B\/cit5f\/1","doi-asserted-by":"crossref","first-page":"9393","DOI":"10.1039\/D2CC02811E","volume":"58","author":"Gao","year":"2022","journal-title":"Chem. Commun."},{"key":"D5OB01404B\/cit5g\/1","doi-asserted-by":"crossref","first-page":"671","DOI":"10.1039\/C9SC05320D","volume":"11","author":"Liu","year":"2019","journal-title":"Chem. Sci."},{"key":"D5OB01404B\/cit5h\/1","doi-asserted-by":"crossref","first-page":"107647","DOI":"10.1016\/j.cclet.2022.06.070","volume":"34","author":"Zhang","year":"2023","journal-title":"Chin. Chem. Lett."},{"key":"D5OB01404B\/cit5i\/1","doi-asserted-by":"crossref","first-page":"15553","DOI":"10.1021\/acs.joc.4c01617","volume":"89","author":"Zhang","year":"2024","journal-title":"J. Org. Chem."},{"key":"D5OB01404B\/cit5j\/1","doi-asserted-by":"crossref","first-page":"11745","DOI":"10.1021\/jacs.3c02773","volume":"145","author":"Huang","year":"2023","journal-title":"J. Am. Chem. Soc."},{"key":"D5OB01404B\/cit5k\/1","doi-asserted-by":"crossref","first-page":"1093","DOI":"10.1038\/s41557-021-00778-z","volume":"13","author":"Zhang","year":"2021","journal-title":"Nat. Chem."},{"key":"D5OB01404B\/cit5l\/1","doi-asserted-by":"crossref","first-page":"5189","DOI":"10.1038\/s41467-023-40891-w","volume":"14","author":"Gao","year":"2023","journal-title":"Nat. Commun."},{"key":"D5OB01404B\/cit5m\/1","doi-asserted-by":"crossref","first-page":"3150","DOI":"10.1038\/s41467-019-11109-9","volume":"10","author":"Xia","year":"2019","journal-title":"Nat. Commun."},{"key":"D5OB01404B\/cit5n\/1","doi-asserted-by":"crossref","first-page":"4740","DOI":"10.1021\/acs.orglett.3c01746","volume":"25","author":"Chen","year":"2023","journal-title":"Org. Lett."},{"key":"D5OB01404B\/cit5o\/1","doi-asserted-by":"crossref","first-page":"6606","DOI":"10.1021\/acs.orglett.1c01849","volume":"23","author":"Woldegiorgis","year":"2021","journal-title":"Org. Lett."},{"key":"D5OB01404B\/cit5p\/1","doi-asserted-by":"crossref","first-page":"330","DOI":"10.1021\/acs.orglett.8b03934","volume":"21","author":"Yang","year":"2019","journal-title":"Org. Lett."},{"key":"D5OB01404B\/cit6a\/1","doi-asserted-by":"crossref","first-page":"4539","DOI":"10.1021\/acs.inorgchem.0c03472","volume":"60","author":"Gogoi","year":"2021","journal-title":"Inorg. Chem."},{"key":"D5OB01404B\/cit6b\/1","doi-asserted-by":"crossref","first-page":"408","DOI":"10.1038\/s41557-023-01384-x","volume":"16","author":"Chen","year":"2024","journal-title":"Nat. Chem."},{"key":"D5OB01404B\/cit6c\/1","doi-asserted-by":"crossref","first-page":"332","DOI":"10.1016\/j.talanta.2013.01.048","volume":"107","author":"Duan","year":"2013","journal-title":"Talanta"},{"key":"D5OB01404B\/cit7a\/1","doi-asserted-by":"crossref","first-page":"1053","DOI":"10.1002\/adsc.201400881","volume":"357","author":"Cacchi","year":"2015","journal-title":"Adv. Synth. Catal."},{"key":"D5OB01404B\/cit7b\/1","doi-asserted-by":"crossref","first-page":"401","DOI":"10.1021\/jo401456x","volume":"79","author":"Cacchi","year":"2014","journal-title":"J. Org. Chem."},{"key":"D5OB01404B\/cit7c\/1","doi-asserted-by":"crossref","first-page":"4490","DOI":"10.1039\/D1QO00790D","volume":"8","author":"Zhang","year":"2021","journal-title":"Org. Chem. Front."},{"key":"D5OB01404B\/cit7d\/1","doi-asserted-by":"crossref","first-page":"2083","DOI":"10.1021\/ol060499n","volume":"8","author":"Ambrogio","year":"2006","journal-title":"Org. Lett."},{"key":"D5OB01404B\/cit7e\/1","doi-asserted-by":"crossref","first-page":"3125","DOI":"10.1021\/ol801184x","volume":"10","author":"Okamoto","year":"2008","journal-title":"Org. Lett."},{"key":"D5OB01404B\/cit7f\/1","doi-asserted-by":"crossref","first-page":"3207","DOI":"10.1021\/ol061047d","volume":"8","author":"Xu","year":"2006","journal-title":"Org. Lett."},{"key":"D5OB01404B\/cit8\/1","doi-asserted-by":"crossref","first-page":"98","DOI":"10.1002\/jlac.19284600106","volume":"460","author":"Diels","year":"1927","journal-title":"Justus Liebigs Ann. Chem."},{"key":"D5OB01404B\/cit9a\/1","doi-asserted-by":"crossref","first-page":"101999","DOI":"10.1039\/C5RA17488K","volume":"5","author":"Heravi","year":"2015","journal-title":"RSC Adv."},{"key":"D5OB01404B\/cit9b\/1","doi-asserted-by":"crossref","first-page":"1658","DOI":"10.1021\/acs.accounts.6b00188","volume":"49","author":"Bhojgude","year":"2016","journal-title":"Acc. Chem. Res."},{"key":"D5OB01404B\/cit9c\/1","doi-asserted-by":"crossref","first-page":"11055","DOI":"10.1039\/D0CS01382J","volume":"50","author":"Briou","year":"2021","journal-title":"Chem. Soc. Rev."},{"key":"D5OB01404B\/cit9d\/1","doi-asserted-by":"crossref","first-page":"3822","DOI":"10.1002\/anie.201201636","volume":"52","author":"Funel","year":"2013","journal-title":"Angew. Chem., Int. Ed."},{"key":"D5OB01404B\/cit9e\/1","doi-asserted-by":"crossref","first-page":"2056","DOI":"10.1002\/anie.201305908","volume":"53","author":"Nawrat","year":"2014","journal-title":"Angew. Chem., Int. Ed."},{"key":"D5OB01404B\/cit9f\/1","doi-asserted-by":"crossref","first-page":"4895","DOI":"10.1039\/C7CS00184C","volume":"46","author":"Oliveira","year":"2017","journal-title":"Chem. Soc. Rev."},{"key":"D5OB01404B\/cit9g\/1","doi-asserted-by":"crossref","first-page":"4496","DOI":"10.1039\/D4RA07989B","volume":"15","author":"Rana","year":"2025","journal-title":"RSC Adv."},{"key":"D5OB01404B\/cit9h\/1","doi-asserted-by":"crossref","first-page":"101001","DOI":"10.1016\/j.pmatsci.2022.101001","volume":"131","author":"Ratwani","year":"2023","journal-title":"Prog. Mater. Sci."},{"key":"D5OB01404B\/cit9i\/1","first-page":"100451","volume":"3","author":"Wang","year":"2023","journal-title":"Chem. Catal."},{"key":"D5OB01404B\/cit9j\/1","doi-asserted-by":"crossref","first-page":"e202212016","DOI":"10.1002\/anie.202212016","volume":"61","author":"Sim","year":"2022","journal-title":"Angew. Chem., Int. Ed."},{"key":"D5OB01404B\/cit10\/1","doi-asserted-by":"crossref","first-page":"1650","DOI":"10.1002\/1521-3773(20020517)41:10<1650::AID-ANIE1650>3.0.CO;2-B","volume":"41","author":"Corey","year":"2002","journal-title":"Angew. Chem., Int. Ed."},{"key":"D5OB01404B\/cit11\/1","doi-asserted-by":"crossref","first-page":"6388","DOI":"10.1021\/ja035393r","volume":"125","author":"Ryu","year":"2003","journal-title":"J. Am. Chem. Soc."},{"key":"D5OB01404B\/cit12\/1","doi-asserted-by":"crossref","first-page":"9992","DOI":"10.1021\/ja027468h","volume":"124","author":"Ryu","year":"2002","journal-title":"J. Am. Chem. Soc."},{"key":"D5OB01404B\/cit13\/1","doi-asserted-by":"crossref","first-page":"3979","DOI":"10.1021\/ol035542a","volume":"5","author":"Zhou","year":"2003","journal-title":"Org. Lett."},{"key":"D5OB01404B\/cit14\/1","doi-asserted-by":"crossref","first-page":"4800","DOI":"10.1021\/ja049323b","volume":"126","author":"Ryu","year":"2004","journal-title":"J. Am. Chem. Soc."},{"key":"D5OB01404B\/cit15\/1","doi-asserted-by":"crossref","first-page":"3808","DOI":"10.1021\/ja025848x","volume":"124","author":"Corey","year":"2002","journal-title":"J. Am. Chem. Soc."},{"key":"D5OB01404B\/cit16\/1","doi-asserted-by":"crossref","first-page":"3271","DOI":"10.1021\/ol8011502","volume":"10","author":"Canales","year":"2008","journal-title":"Org. Lett."},{"key":"D5OB01404B\/cit17\/1","doi-asserted-by":"crossref","first-page":"3611","DOI":"10.1021\/ja00087a062","volume":"116","author":"Corey","year":"1994","journal-title":"J. Am. Chem. Soc."},{"key":"D5OB01404B\/cit18\/1","doi-asserted-by":"crossref","first-page":"3679","DOI":"10.1002\/1521-3773(20011001)40:19<3679::AID-ANIE3679>3.0.CO;2-T","volume":"40","author":"Nicolaou","year":"2001","journal-title":"Angew. Chem., Int. Ed."},{"key":"D5OB01404B\/cit19\/1","doi-asserted-by":"crossref","first-page":"1668","DOI":"10.1002\/1521-3773(20020517)41:10<1668::AID-ANIE1668>3.0.CO;2-Z","volume":"41","author":"Nicolaou","year":"2002","journal-title":"Angew. Chem., Int. Ed."},{"key":"D5OB01404B\/cit20\/1","doi-asserted-by":"crossref","first-page":"613","DOI":"10.1021\/ja030498f","volume":"126","author":"Nicolaou","year":"2003","journal-title":"J. Am. Chem. Soc."},{"key":"D5OB01404B\/cit21a\/1","doi-asserted-by":"crossref","first-page":"9589","DOI":"10.1021\/acscatal.2c02479","volume":"12","author":"Sarkar","year":"2022","journal-title":"ACS Catal."},{"key":"D5OB01404B\/cit21b\/1","doi-asserted-by":"crossref","first-page":"1911","DOI":"10.3390\/sym13101911","volume":"13","author":"Jasi\u0144ski","year":"2021","journal-title":"Symmetry"},{"key":"D5OB01404B\/cit21c\/1","doi-asserted-by":"crossref","first-page":"12303","DOI":"10.1021\/ja982050y","volume":"120","author":"Jenny","year":"1998","journal-title":"J. Am. Chem. Soc."},{"key":"D5OB01404B\/cit21d\/1","doi-asserted-by":"crossref","first-page":"12860","DOI":"10.1073\/pnas.1209316109","volume":"109","author":"Black","year":"2012","journal-title":"Proc. Natl. Acad. Sci. U. S. A."},{"key":"D5OB01404B\/cit21e\/1","doi-asserted-by":"crossref","first-page":"473","DOI":"10.1021\/mz200137m","volume":"1","author":"Imbesi","year":"2012","journal-title":"ACS Macro Lett."},{"key":"D5OB01404B\/cit21f\/1","doi-asserted-by":"crossref","first-page":"6582","DOI":"10.1021\/jo400900x","volume":"78","author":"James","year":"2013","journal-title":"J. Org. Chem."},{"key":"D5OB01404B\/cit21g\/1","doi-asserted-by":"crossref","first-page":"5330","DOI":"10.1039\/C4PY00644E","volume":"5","author":"Langer","year":"2014","journal-title":"Polym. Chem."},{"key":"D5OB01404B\/cit21h\/1","doi-asserted-by":"crossref","first-page":"7871","DOI":"10.1039\/C8OB01944D","volume":"16","author":"Li","year":"2018","journal-title":"Org. Biomol. Chem."},{"key":"D5OB01404B\/cit21i\/1","doi-asserted-by":"crossref","first-page":"1197","DOI":"10.1021\/jacs.4c15004","volume":"147","author":"Li","year":"2025","journal-title":"J. Am. Chem. Soc."},{"key":"D5OB01404B\/cit21j\/1","doi-asserted-by":"crossref","first-page":"8968","DOI":"10.1021\/jo502041f","volume":"79","author":"Pham","year":"2014","journal-title":"J. Org. Chem."},{"key":"D5OB01404B\/cit21k\/1","doi-asserted-by":"crossref","first-page":"8709","DOI":"10.1016\/j.tet.2008.06.103","volume":"64","author":"Oliveira","year":"2008","journal-title":"Tetrahedron"},{"key":"D5OB01404B\/cit22a\/1","doi-asserted-by":"crossref","first-page":"12285","DOI":"10.1021\/ja204856a","volume":"133","author":"Anderson","year":"2011","journal-title":"J. Am. Chem. Soc."},{"key":"D5OB01404B\/cit22b\/1","doi-asserted-by":"crossref","first-page":"7823","DOI":"10.1002\/anie.201503483","volume":"54","author":"Burford","year":"2015","journal-title":"Angew. Chem., Int. Ed."},{"key":"D5OB01404B\/cit22c\/1","doi-asserted-by":"crossref","first-page":"2134","DOI":"10.1002\/anie.201309022","volume":"53","author":"Eschenbrenner-Lux","year":"2014","journal-title":"Angew. Chem., Int. Ed."},{"key":"D5OB01404B\/cit22d\/1","doi-asserted-by":"crossref","first-page":"5131","DOI":"10.1039\/c3cs60049a","volume":"42","author":"Knall","year":"2013","journal-title":"Chem. Soc. Rev."},{"key":"D5OB01404B\/cit22e\/1","doi-asserted-by":"crossref","first-page":"526","DOI":"10.1038\/s41557-022-01117-6","volume":"15","author":"Liu","year":"2023","journal-title":"Nat. Chem."},{"key":"D5OB01404B\/cit22f\/1","doi-asserted-by":"crossref","first-page":"6131","DOI":"10.1002\/anie.201402934","volume":"53","author":"Matsumura","year":"2014","journal-title":"Angew. Chem., Int. Ed."},{"key":"D5OB01404B\/cit22g\/1","doi-asserted-by":"crossref","first-page":"1184","DOI":"10.1002\/tcr.201700006","volume":"17","author":"Xie","year":"2017","journal-title":"Chem. Rec."},{"key":"D5OB01404B\/cit22h\/1","doi-asserted-by":"crossref","first-page":"5659","DOI":"10.1021\/jacs.9b02204","volume":"141","author":"Zhang","year":"2019","journal-title":"J. Am. Chem. Soc."},{"key":"D5OB01404B\/cit23a\/1","doi-asserted-by":"crossref","first-page":"968","DOI":"10.1039\/D0QO01236J","volume":"8","author":"Koay","year":"2021","journal-title":"Org. Chem. Front."},{"key":"D5OB01404B\/cit23b\/1","doi-asserted-by":"crossref","first-page":"5633","DOI":"10.1021\/acs.orglett.0c01994","volume":"22","author":"He","year":"2020","journal-title":"Org. Lett."},{"key":"D5OB01404B\/cit23c\/1","doi-asserted-by":"crossref","first-page":"1406","DOI":"10.1002\/chem.201904902","volume":"26","author":"Jarrige","year":"2020","journal-title":"Chem. \u2013 Eur. J."},{"key":"D5OB01404B\/cit23d\/1","doi-asserted-by":"crossref","first-page":"6483","DOI":"10.1021\/acs.orglett.2c02747","volume":"24","author":"Matsui","year":"2022","journal-title":"Org. Lett."},{"key":"D5OB01404B\/cit23e\/1","doi-asserted-by":"crossref","first-page":"7175","DOI":"10.1021\/acs.joc.9b00860","volume":"84","author":"Ukis","year":"2019","journal-title":"J. Org. Chem."},{"key":"D5OB01404B\/cit23f\/1","doi-asserted-by":"crossref","first-page":"8491","DOI":"10.1002\/anie.202000838","volume":"59","author":"Varlet","year":"2020","journal-title":"Angew. Chem., Int. Ed."},{"key":"D5OB01404B\/cit24\/1","doi-asserted-by":"crossref","first-page":"e202214925","DOI":"10.1002\/anie.202214925","volume":"62","author":"Zhu","year":"2023","journal-title":"Angew. Chem., Int. Ed."},{"key":"D5OB01404B\/cit25\/1","doi-asserted-by":"crossref","first-page":"215","DOI":"10.1007\/s00214-007-0310-x","volume":"120","author":"Zhao","year":"2007","journal-title":"Theor. Chem. Acc."},{"key":"D5OB01404B\/cit26\/1","doi-asserted-by":"crossref","first-page":"1109","DOI":"10.1002\/jcc.540080807","volume":"8","author":"Spitznagel","year":"2004","journal-title":"J. Comput. Chem."},{"key":"D5OB01404B\/cit27\/1","volume-title":"Gaussian 16 Rev. B.01","author":"Frisch","year":"2016","unstructured":"M. J.Frisch ,  G. W.Trucks ,  H. B.Schlegel ,  G. E.Scuseria ,  M. A.Robb ,  J. R.Cheeseman ,  G.Scalmani ,  V.Barone ,  B.Mennucci ,  G. A.Petersson ,  H.Nakatsuji ,  M.Caricato ,  X.Li ,  H. P.Hratchian ,  A. F.Izmaylov ,  J.Bloino ,  G.Zheng ,  J. L.Sonnenberg ,  M.Hada ,  M.Ehara ,  K.Toyota ,  R.Fukuda ,  J.Hasegawa ,  M.Ishida ,  T.Nakajima ,  Y.Honda ,  O.Kitao ,  H.Nakai ,  T.Vreven ,  J. J. A.Montgomery ,  J. E.Peralta ,  F.Ogliaro ,  M.Bearpark ,  J. J.Heyd ,  E.Brothers ,  K. N.Kudin ,  V. N.Staroverov ,  T.Keith ,  R.Kobayashi ,  J.Normand ,  K.Raghavachari ,  A.Rendell ,  J. C.Burant ,  S. S.Iyengar ,  J.Tomasi ,  M.Cossi ,  N.Rega ,  J. M.Millam ,  M.Klene ,  J. E.Knox ,  J. B.Cross ,  V.Bakken ,  C.Adamo ,  J.Jaramillo ,  R.Gomperts ,  R. E.Stratmann ,  O.Yazyev ,  A. J.Austin ,  R.Cammi ,  C.Pomelli ,  J. W.Ochterski ,  R. L.Martin ,  K.Morokuma ,  V. G.Zakrzewski ,  G. A.Voth ,  P.Salvador ,  J. J.Dannenberg ,  S.Dapprich ,  A. D.Daniels ,  O.Farkas ,  J. B.Foresman ,  J. V.Ortiz ,  J.Cioslowski  and  D. J.Fox ,  Gaussian 16 Rev. B.01 ,  Wallingford, CT ,  2016"},{"key":"D5OB01404B\/cit28\/1","doi-asserted-by":"crossref","first-page":"93","DOI":"10.1016\/j.comptc.2014.08.002","volume":"1046","author":"Jasi\u0144ski","year":"2014","journal-title":"Comput. Theor. Chem."},{"key":"D5OB01404B\/cit29\/1","doi-asserted-by":"crossref","first-page":"5829","DOI":"10.1063\/1.467146","volume":"100","author":"Sch\u00e4fer","year":"1994","journal-title":"J. Chem. Phys."},{"key":"D5OB01404B\/cit30\/1","doi-asserted-by":"crossref","first-page":"4538","DOI":"10.1021\/jp809094y","volume":"113","author":"Marenich","year":"2009","journal-title":"J. Phys. Chem. B"},{"key":"D5OB01404B\/cit31\/1","doi-asserted-by":"crossref","first-page":"6378","DOI":"10.1021\/jp810292n","volume":"113","author":"Marenich","year":"2009","journal-title":"J. Phys. Chem. B"},{"key":"D5OB01404B\/cit32\/1","doi-asserted-by":"crossref","first-page":"1456","DOI":"10.1002\/jcc.21759","volume":"32","author":"Grimme","year":"2011","journal-title":"J. Comput. Chem."},{"key":"D5OB01404B\/cit35\/1","doi-asserted-by":"crossref","first-page":"368","DOI":"10.1021\/ar00072a001","volume":"14","author":"Fukui","year":"1981","journal-title":"Acc. Chem. Res."},{"key":"D5OB01404B\/cit36\/1","doi-asserted-by":"crossref","first-page":"2154","DOI":"10.1063\/1.456010","volume":"90","author":"Gonzalez","year":"1989","journal-title":"J. Chem. Phys."},{"key":"D5OB01404B\/cit37\/1","doi-asserted-by":"crossref","first-page":"580","DOI":"10.1002\/jcc.22885","volume":"33","author":"Lu","year":"2012","journal-title":"J. Comput. Chem."},{"key":"D5OB01404B\/cit38\/1","doi-asserted-by":"crossref","first-page":"33","DOI":"10.1016\/0263-7855(96)00018-5","volume":"14","author":"Humphrey","year":"1996","journal-title":"J. Mol. Graphics"},{"key":"D5OB01404B\/cit39a\/1","doi-asserted-by":"crossref","first-page":"6498","DOI":"10.1021\/ja100936w","volume":"132","author":"Johnson","year":"2010","journal-title":"J. Am. Chem. Soc."},{"key":"D5OB01404B\/cit39b\/1","doi-asserted-by":"crossref","first-page":"625","DOI":"10.1021\/ct100641a","volume":"7","author":"Contreras-Garc\u00eda","year":"2011","journal-title":"J. Chem. Theory Comput."},{"key":"D5OB01404B\/cit39c\/1","doi-asserted-by":"crossref","first-page":"12983","DOI":"10.1021\/jp204278k","volume":"115","author":"Contreras-Garc\u00eda","year":"2011","journal-title":"J. Phys. Chem. A"},{"key":"D5OB01404B\/cit40\/1","doi-asserted-by":"crossref","first-page":"893","DOI":"10.1021\/cr00005a013","volume":"91","author":"Bader","year":"1991","journal-title":"Chem. Rev."},{"key":"D5OB01404B\/cit41\/1","doi-asserted-by":"crossref","first-page":"12835","DOI":"10.1021\/ja0025705","volume":"122","author":"Arnold","year":"2000","journal-title":"J. Am. Chem. Soc."},{"key":"D5OB01404B\/cit42\/1","doi-asserted-by":"crossref","first-page":"1793","DOI":"10.1021\/cr990029p","volume":"103","author":"Geerlings","year":"2003","journal-title":"Chem. Rev."},{"key":"D5OB01404B\/cit43a\/1","doi-asserted-by":"crossref","first-page":"10646","DOI":"10.1021\/ja0734086","volume":"129","author":"Ess","year":"2007","journal-title":"J. Am. Chem. Soc."},{"key":"D5OB01404B\/cit43b\/1","doi-asserted-by":"crossref","first-page":"10187","DOI":"10.1021\/ja800009z","volume":"130","author":"Ess","year":"2008","journal-title":"J. Am. Chem. Soc."},{"key":"D5OB01404B\/cit43c\/1","doi-asserted-by":"crossref","first-page":"10070","DOI":"10.1002\/anie.201701486","volume":"56","author":"Bickelhaupt","year":"2017","journal-title":"Angew. Chem., Int. Ed."},{"key":"D5OB01404B\/cit44\/1","doi-asserted-by":"crossref","first-page":"094106","DOI":"10.1063\/1.4867135","volume":"140","author":"Parker","year":"2014","journal-title":"J. Chem. Phys."},{"key":"D5OB01404B\/cit45\/1","doi-asserted-by":"crossref","first-page":"7023","DOI":"10.1021\/acs.jpca.3c04374","volume":"127","author":"Lu","year":"2023","journal-title":"J. Phys. Chem. A"}],"container-title":["Organic &amp; Biomolecular Chemistry"],"original-title":[],"language":"en","link":[{"URL":"http:\/\/pubs.rsc.org\/en\/content\/articlepdf\/2025\/OB\/D5OB01404B","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,7,1]],"date-time":"2026-07-01T03:58:06Z","timestamp":1782878286000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.rsc.org\/ob\/article\/23\/46\/10561-10573\/903231"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2025]]},"references-count":134,"journal-issue":{"issue":"46","published-print":{"date-parts":[[2025,11,27]]}},"URL":"https:\/\/doi.org\/10.1039\/d5ob01404b","relation":{},"ISSN":["1477-0520","1477-0539"],"issn-type":[{"value":"1477-0520","type":"print"},{"value":"1477-0539","type":"electronic"}],"subject":[],"published":{"date-parts":[[2025]]}}}