{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,6,30]],"date-time":"2026-06-30T20:49:22Z","timestamp":1782852562509,"version":"3.54.5"},"reference-count":42,"publisher":"Royal Society of Chemistry (RSC)","issue":"25","license":[{"start":{"date-parts":[[2025,6,25]],"date-time":"2025-06-25T00:00:00Z","timestamp":1750809600000},"content-version":"vor","delay-in-days":175,"URL":"http:\/\/creativecommons.org\/licenses\/by-nc\/3.0\/"}],"funder":[{"DOI":"10.13039\/501100001691","name":"Japan Society for the Promotion of Science","doi-asserted-by":"publisher","award":["23K17920"],"award-info":[{"award-number":["23K17920"]}],"id":[{"id":"10.13039\/501100001691","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["rsc.org"],"crossmark-restriction":true},"short-container-title":["RSC Adv."],"abstract":"<jats:p>The selective hydrogenation of ketones without any reaction at the azide moiety is disclosed. A key factor in the success of the reaction is the formation of phosphazides and catalyst poisoning.<\/jats:p>","DOI":"10.1039\/d5ra02070k","type":"journal-article","created":{"date-parts":[[2025,6,25]],"date-time":"2025-06-25T03:35:19Z","timestamp":1750822519000},"page":"20350-20354","update-policy":"https:\/\/doi.org\/10.1039\/rsc_crossmark_policy","source":"Crossref","is-referenced-by-count":2,"title":["Selective hydrogenation through phosphazide formation"],"prefix":"10.1039","volume":"15","author":[{"given":"Takahiro","family":"Yasuda","sequence":"first","affiliation":[{"name":"Department of Biological Science and Technology, Faculty of Advanced Engineering, Tokyo University of Science, 6-3-1 Niijuku, Katsushika-ku, Tokyo 125-8585, Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5888-9330","authenticated-orcid":false,"given":"Suguru","family":"Yoshida","sequence":"additional","affiliation":[{"name":"Department of Biological Science and Technology, Faculty of Advanced Engineering, Tokyo University of Science, 6-3-1 Niijuku, Katsushika-ku, Tokyo 125-8585, Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"292","published-online":{"date-parts":[[2025]]},"reference":[{"key":"D5RA02070K\/cit1a\/1","doi-asserted-by":"crossref","first-page":"260","DOI":"10.1039\/C3CY00650F","volume":"4","author":"Yabe","year":"2014","journal-title":"Catal. Sci. Technol."},{"key":"D5RA02070K\/cit1b\/1","volume-title":"Handbook of Organopalladium Chemistry for Organic Synthesis","author":"King","year":"2002","unstructured":"A. O.King ,  R. D.Larsen  and  E.Negishi ,  Palladiu-Catalyzed Heterogeneous Hydrogenation , in  Handbook of Organopalladium Chemistry for Organic Synthesis , ed.  E. Negishi ,  John Wiley & Sons, Inc. ,  New York ,  2002"},{"key":"D5RA02070K\/cit2a\/1","doi-asserted-by":"crossref","first-page":"5188","DOI":"10.1002\/anie.200400657","volume":"44","author":"Br\u00e4se","year":"2005","journal-title":"Angew. Chem., Int. Ed."},{"key":"D5RA02070K\/cit2b\/1","volume-title":"Organic Azides: Syntheses and Applications","author":"Br\u00e4se","year":"2010","unstructured":"S.Br\u00e4se  and  K.Banert ,  Organic Azides: Syntheses and Applications ,  John Wiley & Sons, Ltd ,  Chichester ,  2010"},{"key":"D5RA02070K\/cit2c\/1","first-page":"1021","volume":"8","author":"Tanimoto","year":"2013","journal-title":"Nat. Prod. Commun."},{"key":"D5RA02070K\/cit2d\/1","doi-asserted-by":"crossref","first-page":"2361","DOI":"10.1055\/s-0035-1561454","volume":"48","author":"Banert","year":"2016","journal-title":"Synthesis"},{"key":"D5RA02070K\/cit2e\/1","doi-asserted-by":"crossref","first-page":"1600","DOI":"10.1002\/adsc.201700103","volume":"359","author":"Huang","year":"2017","journal-title":"Adv. Synth. Catal."},{"key":"D5RA02070K\/cit2f\/1","doi-asserted-by":"crossref","first-page":"1550","DOI":"10.1039\/C9OB02698C","volume":"18","author":"Yoshida","year":"2020","journal-title":"Org. Biomol. Chem."},{"key":"D5RA02070K\/cit2g\/1","doi-asserted-by":"crossref","first-page":"411","DOI":"10.1002\/adsc.202001168","volume":"363","author":"Liu","year":"2020","journal-title":"Adv. Synth. Catal."},{"key":"D5RA02070K\/cit2h\/1","doi-asserted-by":"crossref","first-page":"12062","DOI":"10.1039\/D4CC03359K","volume":"60","author":"Tanimoto","year":"2024","journal-title":"Chem. Commun."},{"key":"D5RA02070K\/cit3a\/1","doi-asserted-by":"crossref","first-page":"4327","DOI":"10.1021\/jo00143a031","volume":"47","author":"Rolla","year":"1982","journal-title":"J. Org. Chem."},{"key":"D5RA02070K\/cit3b\/1","doi-asserted-by":"crossref","first-page":"1201","DOI":"10.1080\/00397918808060911","volume":"18","author":"Maiti","year":"1988","journal-title":"Synth. Commun."},{"key":"D5RA02070K\/cit3c\/1","doi-asserted-by":"crossref","first-page":"3937","DOI":"10.1016\/S0040-4039(99)00614-0","volume":"40","author":"Reddy","year":"1999","journal-title":"Tetrahedron Lett."},{"key":"D5RA02070K\/cit3d\/1","doi-asserted-by":"crossref","first-page":"10059","DOI":"10.1016\/S0040-4020(02)01322-4","volume":"58","author":"Salunkhe","year":"2002","journal-title":"Tetrahedron"},{"key":"D5RA02070K\/cit3e\/1","doi-asserted-by":"crossref","first-page":"1297","DOI":"10.1055\/s-2008-1072742","author":"Kamal","year":"2008","journal-title":"Synlett"},{"key":"D5RA02070K\/cit3f\/1","doi-asserted-by":"crossref","first-page":"7215","DOI":"10.1002\/chem.200900853","volume":"15","author":"Kamal","year":"2009","journal-title":"Chem.\u2013Eur. J."},{"key":"D5RA02070K\/cit3g\/1","doi-asserted-by":"crossref","first-page":"2091","DOI":"10.1002\/adsc.200900316","volume":"351","author":"Maegawa","year":"2009","journal-title":"Adv. Synth. Catal."},{"key":"D5RA02070K\/cit4a\/1","doi-asserted-by":"crossref","first-page":"4126","DOI":"10.1021\/acs.orglett.8b01692","volume":"20","author":"Meguro","year":"2018","journal-title":"Org. Lett."},{"key":"D5RA02070K\/cit4b\/1","doi-asserted-by":"crossref","first-page":"6062","DOI":"10.1039\/D1CC01143J","volume":"57","author":"Aimi","year":"2021","journal-title":"Chem. Commun."},{"key":"D5RA02070K\/cit4c\/1","doi-asserted-by":"crossref","first-page":"1237878","DOI":"10.3389\/fchem.2023.1237878","volume":"11","author":"Namioka","year":"2023","journal-title":"Front. Chem."},{"key":"D5RA02070K\/cit5\/1","doi-asserted-by":"crossref","first-page":"1272","DOI":"10.1039\/b901970g","volume":"39","author":"Jewett","year":"2010","journal-title":"Chem. Soc. Rev."},{"key":"D5RA02070K\/cit6a\/1","doi-asserted-by":"crossref","first-page":"7990","DOI":"10.1021\/jo9814694","volume":"63","author":"Sajiki","year":"1998","journal-title":"J. Org. Chem."},{"key":"D5RA02070K\/cit6b\/1","doi-asserted-by":"crossref","first-page":"4146","DOI":"10.1016\/j.bmcl.2008.05.075","volume":"18","author":"Phillips","year":"2008","journal-title":"Bioorg. Med. Chem. Lett."},{"key":"D5RA02070K\/cit6c\/1","doi-asserted-by":"crossref","first-page":"e202300002","DOI":"10.1002\/cctc.202300002","volume":"15","author":"Li","year":"2023","journal-title":"ChemCatChem"},{"key":"D5RA02070K\/cit7a\/1","doi-asserted-by":"crossref","first-page":"4926","DOI":"10.1021\/jo01312a021","volume":"45","author":"Weir","year":"1980","journal-title":"J. Org. Chem."},{"key":"D5RA02070K\/cit7b\/1","doi-asserted-by":"crossref","first-page":"3279","DOI":"10.1021\/ol061147j","volume":"8","author":"Mori","year":"2006","journal-title":"Org. Lett."},{"key":"D5RA02070K\/cit7c\/1","doi-asserted-by":"crossref","first-page":"853","DOI":"10.1038\/nmat2849","volume":"9","author":"Marshall","year":"2010","journal-title":"Nat. Mag."},{"key":"D5RA02070K\/cit7d\/1","doi-asserted-by":"crossref","first-page":"16814","DOI":"10.1021\/acssuschemeng.9b04347","volume":"7","author":"Moore","year":"2019","journal-title":"ACS Sustainable Chem. Eng."},{"key":"D5RA02070K\/cit7e\/1","doi-asserted-by":"crossref","first-page":"31775","DOI":"10.1021\/acsami.1c09682","volume":"13","author":"Luo","year":"2021","journal-title":"ACS Appl. Mater. Interfaces"},{"key":"D5RA02070K\/cit8a\/1","doi-asserted-by":"crossref","first-page":"4043","DOI":"10.1039\/a807486k","author":"Sajiki","year":"1998","journal-title":"J. Chem. Soc., Perkin Trans. 1"},{"key":"D5RA02070K\/cit8b\/1","doi-asserted-by":"crossref","first-page":"10243","DOI":"10.1021\/acsomega.9b00707","volume":"4","author":"Yamada","year":"2019","journal-title":"ACS Omega"},{"key":"D5RA02070K\/cit8c\/1","doi-asserted-by":"crossref","first-page":"14216","DOI":"10.1021\/acssuschemeng.1c04876","volume":"9","author":"Li","year":"2021","journal-title":"ACS Sustainable Chem. Eng."},{"key":"D5RA02070K\/cit9\/1","doi-asserted-by":"crossref","first-page":"1093","DOI":"10.1002\/adsc.200404089","volume":"346","author":"Sarkar","year":"2004","journal-title":"Adv. Synth. Catal."},{"key":"D5RA02070K\/cit10\/1","doi-asserted-by":"crossref","first-page":"2655","DOI":"10.1021\/jo00364a007","volume":"51","author":"Crabtree","year":"1986","journal-title":"J. Org. Chem."},{"key":"D5RA02070K\/cit11a\/1","first-page":"2279","volume":"65","author":"Hu","year":"2000","journal-title":"J. Org. Chem."},{"key":"D5RA02070K\/cit11b\/1","doi-asserted-by":"crossref","first-page":"941","DOI":"10.1016\/j.carres.2008.01.030","volume":"343","author":"Inaba","year":"2008","journal-title":"Carbohydr. Res."},{"key":"D5RA02070K\/cit11c\/1","doi-asserted-by":"crossref","first-page":"576","DOI":"10.1016\/j.bmcl.2007.11.067","volume":"18","author":"Santella III","year":"2008","journal-title":"Bioorg. Med. Chem. Lett."},{"key":"D5RA02070K\/cit12\/1","doi-asserted-by":"crossref","first-page":"14222","DOI":"10.1021\/jacs.0c05446","volume":"142","author":"Mahmoodi","year":"2020","journal-title":"J. Am. Chem. Soc."},{"key":"D5RA02070K\/cit13a\/1","doi-asserted-by":"crossref","first-page":"3057","DOI":"10.1021\/jo011148j","volume":"67","author":"Torn\u00f8e","year":"2002","journal-title":"J. Org. Chem."},{"key":"D5RA02070K\/cit13b\/1","doi-asserted-by":"crossref","first-page":"2596","DOI":"10.1002\/1521-3773(20020715)41:14<2596::AID-ANIE2596>3.0.CO;2-4","volume":"41","author":"Rostovtsev","year":"2002","journal-title":"Angew. Chem., Int. Ed."},{"key":"D5RA02070K\/cit13c\/1","doi-asserted-by":"crossref","first-page":"2952","DOI":"10.1021\/cr0783479","volume":"108","author":"Meldal","year":"2008","journal-title":"Chem. Rev."},{"key":"D5RA02070K\/cit13d\/1","doi-asserted-by":"crossref","first-page":"1174","DOI":"10.3390\/molecules21091174","volume":"21","author":"Mandoli","year":"2016","journal-title":"Molecules"}],"container-title":["RSC Advances"],"original-title":[],"language":"en","link":[{"URL":"http:\/\/pubs.rsc.org\/en\/content\/articlepdf\/2025\/RA\/D5RA02070K","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,6,30]],"date-time":"2026-06-30T19:49:34Z","timestamp":1782848974000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.rsc.org\/ra\/article\/15\/25\/20350-20354\/906637"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2025]]},"references-count":42,"journal-issue":{"issue":"25","published-print":{"date-parts":[[2025,6,10]]}},"URL":"https:\/\/doi.org\/10.1039\/d5ra02070k","relation":{},"ISSN":["2046-2069"],"issn-type":[{"value":"2046-2069","type":"electronic"}],"subject":[],"published":{"date-parts":[[2025]]}}}