{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,21]],"date-time":"2026-10-21T03:15:35Z","timestamp":1792552535580,"version":"4.5.0"},"reference-count":36,"publisher":"Royal Society of Chemistry (RSC)","issue":"55","license":[{"start":{"date-parts":[[2025,11,28]],"date-time":"2025-11-28T00:00:00Z","timestamp":1764288000000},"content-version":"vor","delay-in-days":331,"URL":"http:\/\/creativecommons.org\/licenses\/by\/3.0\/"}],"funder":[{"DOI":"10.13039\/501100001691","name":"Japan Society for the Promotion of Science","doi-asserted-by":"publisher","award":["JP22H00347"],"award-info":[{"award-number":["JP22H00347"]}],"id":[{"id":"10.13039\/501100001691","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001691","name":"Japan Society for the Promotion of Science","doi-asserted-by":"publisher","award":["JP25H02239"],"award-info":[{"award-number":["JP25H02239"]}],"id":[{"id":"10.13039\/501100001691","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["rsc.org"],"crossmark-restriction":true},"short-container-title":["RSC Adv."],"abstract":"<jats:p>\n                    New reaction mechanisms of the Strecker degradation to form aldehydes are revealed using the theoretical level of density functional theory. Their activation barriers of these reactions are less than 25 kcal mol\n                    <jats:sup>\u22121<\/jats:sup>\n                    .\n                  <\/jats:p>","DOI":"10.1039\/d5ra07604h","type":"journal-article","created":{"date-parts":[[2025,11,28]],"date-time":"2025-11-28T09:30:49Z","timestamp":1764322249000},"page":"46959-46966","update-policy":"https:\/\/doi.org\/10.1039\/rsc_crossmark_policy","source":"Crossref","is-referenced-by-count":4,"title":["Density functional theory insights into the formation mechanisms and reaction rates of Strecker aldehydes"],"prefix":"10.1039","volume":"15","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-3217-9554","authenticated-orcid":false,"given":"Shota","family":"Ishida","sequence":"first","affiliation":[{"name":"Graduate School of Science and Technology, University of Tsukuba, 1-1-1 Tennodai, Tsukuba, Ibaraki 305-8571, Japan"},{"name":"Institute of Livestock and Grassland Science, National Agriculture and Food Research Organization (NARO), 2 Ikenodai, Tsukuba, Ibaraki 305-0901, Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-7409-3727","authenticated-orcid":false,"given":"Koichi","family":"Miyagawa","sequence":"additional","affiliation":[{"name":"Center for Computational Sciences, University of Tsukuba, 1-1-1 Tennodai, Tsukuba, Ibaraki 305-8577, Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-7465-6326","authenticated-orcid":false,"given":"Mitsuo","family":"Shoji","sequence":"additional","affiliation":[{"name":"Center for Computational Sciences, University of Tsukuba, 1-1-1 Tennodai, Tsukuba, Ibaraki 305-8577, Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"292","published-online":{"date-parts":[[2025]]},"reference":[{"key":"D5RA07604H\/cit1\/1","first-page":"66","volume":"154","author":"Maillard","year":"1912","journal-title":"Comptes Rendus Hebd. Seances Acad. Sci."},{"key":"D5RA07604H\/cit2\/1","doi-asserted-by":"crossref","first-page":"13","DOI":"10.1016\/S0924-2244(96)20013-5","volume":"8","author":"Yaylayan","year":"1997","journal-title":"Trends Food Sci. Technol."},{"key":"D5RA07604H\/cit3\/1","doi-asserted-by":"crossref","first-page":"138071","DOI":"10.1016\/j.foodchem.2023.138071","volume":"439","author":"Xing","year":"2024","journal-title":"Food Chem."},{"key":"D5RA07604H\/cit4\/1","doi-asserted-by":"crossref","first-page":"1","DOI":"10.3136\/fstr.9.1","volume":"9","author":"Yaylayan","year":"2003","journal-title":"Food Sci. Technol. Res."},{"key":"D5RA07604H\/cit5\/1","doi-asserted-by":"crossref","first-page":"261","DOI":"10.1021\/cr60156a002","volume":"50","author":"Sch\u00f6nberg","year":"1952","journal-title":"Chem. Rev."},{"key":"D5RA07604H\/cit6\/1","doi-asserted-by":"crossref","first-page":"335","DOI":"10.1007\/978-1-4615-4693-1_28","volume-title":"Flavor Chemistry: Thirty Years of Progress","author":"Rizzi","year":"1999","unstructured":"G. P.Rizzi ,  Flavor Chemistry: Thirty Years of Progress ,  Springer ,  Boston ,  1999 ,  pp. 335\u2013343"},{"key":"D5RA07604H\/cit7\/1","doi-asserted-by":"crossref","first-page":"268","DOI":"10.1590\/1678-457X.02415","volume":"36","author":"Zhou","year":"2016","journal-title":"Food Sci. Technol. Res."},{"key":"D5RA07604H\/cit8\/1","doi-asserted-by":"crossref","first-page":"247","DOI":"10.3390\/molecules23020247","volume":"23","author":"Chen","year":"2018","journal-title":"Molecules"},{"key":"D5RA07604H\/cit9\/1","doi-asserted-by":"crossref","first-page":"1072261","DOI":"10.3389\/fnut.2023.1072261","volume":"10","author":"Zhao","year":"2023","journal-title":"Front. Nutr."},{"key":"D5RA07604H\/cit10\/1","doi-asserted-by":"crossref","first-page":"1881","DOI":"10.3390\/foods14111881","volume":"14","author":"El Hosry","year":"2025","journal-title":"Foods"},{"key":"D5RA07604H\/cit11\/1","doi-asserted-by":"crossref","first-page":"2002","DOI":"10.1021\/jo01258a117","volume":"34","author":"Rizzi","year":"1969","journal-title":"J. Org. Chem."},{"key":"D5RA07604H\/cit12\/1","doi-asserted-by":"crossref","first-page":"926","DOI":"10.1021\/ci000399a","volume":"41","author":"Patel","year":"2001","journal-title":"J. Chem. Inf. Comput. Sci."},{"key":"D5RA07604H\/cit13\/1","doi-asserted-by":"crossref","first-page":"45","DOI":"10.1016\/j.theochem.2004.07.035","volume":"710","author":"Shipar","year":"2004","journal-title":"J. Mol. Struct.: THEOCHEM"},{"key":"D5RA07604H\/cit14\/1","doi-asserted-by":"crossref","first-page":"123","DOI":"10.1016\/j.foodchem.2005.03.041","volume":"97","author":"Shipar","year":"2006","journal-title":"Food Chem."},{"key":"D5RA07604H\/cit15\/1","doi-asserted-by":"crossref","first-page":"231","DOI":"10.1016\/j.foodchem.2005.03.041","volume":"98","author":"Shipar","year":"2006","journal-title":"Food Chem."},{"key":"D5RA07604H\/cit16\/1","first-page":"274","volume":"98","author":"Shipar","year":"2006","journal-title":"Food Chem."},{"key":"D5RA07604H\/cit17\/1","doi-asserted-by":"crossref","first-page":"359","DOI":"10.1016\/j.foodchem.2006.07.061","volume":"103","author":"Jalbout","year":"2007","journal-title":"Food Chem."},{"key":"D5RA07604H\/cit18\/1","doi-asserted-by":"crossref","first-page":"1208","DOI":"10.1016\/j.foodchem.2006.10.025","volume":"103","author":"Jalbout","year":"2007","journal-title":"Food Chem."},{"key":"D5RA07604H\/cit19\/1","doi-asserted-by":"crossref","first-page":"1342","DOI":"10.1016\/j.foodchem.2007.04.061","volume":"105","author":"Jalbout","year":"2007","journal-title":"Food Chem."},{"key":"D5RA07604H\/cit20\/1","doi-asserted-by":"crossref","first-page":"1587","DOI":"10.1080\/00268970902980060","volume":"107","author":"Flores-Morales","year":"2009","journal-title":"Mol. Phys."},{"key":"D5RA07604H\/cit21\/1","doi-asserted-by":"crossref","first-page":"433","DOI":"10.1007\/BF03249077","volume":"8","author":"Shipar","year":"2011","journal-title":"J. Iran. Chem. Soc."},{"key":"D5RA07604H\/cit22\/1","doi-asserted-by":"crossref","first-page":"132","DOI":"10.1007\/s00894-015-2674-5","volume":"21","author":"Ren","year":"2015","journal-title":"J. Mol. Model."},{"key":"D5RA07604H\/cit23\/1","doi-asserted-by":"crossref","first-page":"81","DOI":"10.1007\/s00894-023-05484-w","volume":"29","author":"Gao","year":"2023","journal-title":"J. Mol. Model."},{"key":"D5RA07604H\/cit24\/1","doi-asserted-by":"crossref","first-page":"6725","DOI":"10.1021\/jf011164h","volume":"50","author":"Brands","year":"2002","journal-title":"J. Agric. Food Chem."},{"key":"D5RA07604H\/cit25\/1","doi-asserted-by":"crossref","first-page":"967","DOI":"10.1016\/j.foodchem.2009.11.033","volume":"120","author":"Lan","year":"2010","journal-title":"Food Chem."},{"key":"D5RA07604H\/cit26\/1","doi-asserted-by":"crossref","first-page":"126458","DOI":"10.1016\/j.foodchem.2020.126458","volume":"317","author":"Yu","year":"2020","journal-title":"Food Chem."},{"key":"D5RA07604H\/cit27\/1","doi-asserted-by":"crossref","first-page":"113343","DOI":"10.1016\/j.lwt.2022.113343","volume":"161","author":"Cao","year":"2022","journal-title":"LWT"},{"key":"D5RA07604H\/cit28\/1","doi-asserted-by":"crossref","first-page":"15023","DOI":"10.1039\/D3CP00278K","volume":"25","author":"Watanabe","year":"2023","journal-title":"Phys. Chem. Chem. Phys."},{"key":"D5RA07604H\/cit29\/1","doi-asserted-by":"crossref","first-page":"340","DOI":"10.1039\/D4CP02579B","volume":"27","author":"Watanabe","year":"2024","journal-title":"Phys. Chem. Chem. Phys."},{"key":"D5RA07604H\/cit32\/1","doi-asserted-by":"crossref","first-page":"385","DOI":"10.1142\/9789812839664_0016","volume-title":"Classical and Quantum Dynamics in Condensed Phase Simulations","author":"Jonsson","year":"1998","unstructured":"H.Jonsson ,  G.Mills , and  K. W.Jacobsen , in  Classical and Quantum Dynamics in Condensed Phase Simulations ,  World Scientific ,  1998 ,  pp. 385\u2013404"},{"key":"D5RA07604H\/cit33\/1","doi-asserted-by":"crossref","first-page":"1477","DOI":"10.1016\/j.cpc.2010.04.018","volume":"181","author":"Valiev","year":"2010","journal-title":"Comput. Phys. Commun."},{"key":"D5RA07604H\/cit34\/1","doi-asserted-by":"crossref","first-page":"65","DOI":"10.1021\/cr60056a006","volume":"17","author":"Eyring","year":"1935","journal-title":"Chem. Rev."},{"key":"D5RA07604H\/cit35\/1","doi-asserted-by":"crossref","first-page":"130952","DOI":"10.1016\/j.foodchem.2021.130952","volume":"369","author":"Hu","year":"2022","journal-title":"Food Chem."},{"key":"D5RA07604H\/cit36\/1","first-page":"131","volume":"35","author":"Ayran\u00e7","year":"1990","journal-title":"J. Chem. Eng. Data"},{"key":"D5RA07604H\/cit37\/1","doi-asserted-by":"crossref","first-page":"8035","DOI":"10.1021\/acs.jafc.6b03502","volume":"64","author":"Wietstock","year":"2016","journal-title":"J. Agric. Food Chem."},{"key":"D5RA07604H\/cit38\/1","doi-asserted-by":"crossref","first-page":"130","DOI":"10.1016\/j.jcs.2018.08.009","volume":"83","author":"Gibson","year":"2018","journal-title":"J. Cereal Sci."}],"container-title":["RSC Advances"],"original-title":[],"language":"en","link":[{"URL":"http:\/\/pubs.rsc.org\/en\/content\/articlepdf\/2025\/RA\/D5RA07604H","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,6,30]],"date-time":"2026-06-30T20:14:48Z","timestamp":1782850488000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.rsc.org\/ra\/article\/15\/55\/46959-46966\/908873"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2025]]},"references-count":36,"journal-issue":{"issue":"55","published-print":{"date-parts":[[2025,11,27]]}},"URL":"https:\/\/doi.org\/10.1039\/d5ra07604h","relation":{},"ISSN":["2046-2069"],"issn-type":[{"value":"2046-2069","type":"electronic"}],"subject":[],"published":{"date-parts":[[2025]]}}}