{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,15]],"date-time":"2026-09-15T01:31:42Z","timestamp":1789435902026,"version":"build-2803163510"},"reference-count":56,"publisher":"Royal Society of Chemistry (RSC)","issue":"28","license":[{"start":{"date-parts":[[2025,6,10]],"date-time":"2025-06-10T00:00:00Z","timestamp":1749513600000},"content-version":"vor","delay-in-days":160,"URL":"http:\/\/creativecommons.org\/licenses\/by-nc\/3.0\/"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22176006"],"award-info":[{"award-number":["22176006"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["rsc.org"],"crossmark-restriction":true},"short-container-title":["Chem. Sci."],"abstract":"<jats:p>The direct transformation of methane into methanol (DMTM) remains a significant challenge of C1 chemistry.<\/jats:p>","DOI":"10.1039\/d5sc02092a","type":"journal-article","created":{"date-parts":[[2025,6,10]],"date-time":"2025-06-10T02:01:17Z","timestamp":1749520877000},"page":"13082-13095","update-policy":"https:\/\/doi.org\/10.1039\/rsc_crossmark_policy","source":"Crossref","is-referenced-by-count":1,"title":["2D spatial structure-favored, tandem catalysis-boosted direct transformation of methane to methanol over Cu-FER"],"prefix":"10.1039","volume":"16","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-4744-7286","authenticated-orcid":false,"given":"Ning","family":"Liu","sequence":"first","affiliation":[{"name":"College of Environmental and Science Engineering, Beijing University of Technology, Beijing, 100124, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Tingting","family":"Zhang","sequence":"additional","affiliation":[{"name":"College of Environmental and Science Engineering, Beijing University of Technology, Beijing, 100124, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-4394-2319","authenticated-orcid":false,"given":"Chengna","family":"Dai","sequence":"additional","affiliation":[{"name":"College of Environmental and Science Engineering, Beijing University of Technology, Beijing, 100124, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-7167-3446","authenticated-orcid":false,"given":"Ruinian","family":"Xu","sequence":"additional","affiliation":[{"name":"College of Environmental and Science Engineering, Beijing University of Technology, Beijing, 100124, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-3595-6972","authenticated-orcid":false,"given":"Gangqiang","family":"Yu","sequence":"additional","affiliation":[{"name":"College of Environmental and Science Engineering, Beijing University of Technology, Beijing, 100124, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-8801-6255","authenticated-orcid":false,"given":"Ning","family":"Wang","sequence":"additional","affiliation":[{"name":"College of Environmental and Science Engineering, Beijing University of Technology, Beijing, 100124, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9871-9560","authenticated-orcid":false,"given":"Biaohua","family":"Chen","sequence":"additional","affiliation":[{"name":"College of Environmental and Science Engineering, Beijing University of Technology, Beijing, 100124, China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"292","published-online":{"date-parts":[[2025]]},"reference":[{"key":"D5SC02092A\/cit1\/1","doi-asserted-by":"crossref","first-page":"6359","DOI":"10.1021\/acs.chemrev.2c00439","volume":"123","author":"Dummer","year":"2023","journal-title":"Chem. Rev."},{"key":"D5SC02092A\/cit2\/1","doi-asserted-by":"crossref","first-page":"523","DOI":"10.1126\/science.aam9035","volume":"356","author":"Sushkevich","year":"2017","journal-title":"Science"},{"key":"D5SC02092A\/cit3\/1","doi-asserted-by":"crossref","first-page":"2785","DOI":"10.1039\/D4SC06281G","volume":"16","author":"Gupta","year":"2025","journal-title":"Chem. Sci."},{"key":"D5SC02092A\/cit4\/1","doi-asserted-by":"crossref","first-page":"12928","DOI":"10.1021\/jacs.3c04260","volume":"145","author":"Wang","year":"2023","journal-title":"J. Am. Chem. Soc."},{"key":"D5SC02092A\/cit5\/1","doi-asserted-by":"crossref","first-page":"3152","DOI":"10.1039\/D0SC06067D","volume":"12","author":"Yu","year":"2021","journal-title":"Chem. Sci."},{"key":"D5SC02092A\/cit6\/1","doi-asserted-by":"crossref","first-page":"302","DOI":"10.1016\/j.jcat.2022.09.001","volume":"414","author":"Liu","year":"2022","journal-title":"J. Catal."},{"key":"D5SC02092A\/cit7\/1","doi-asserted-by":"crossref","first-page":"889","DOI":"10.1038\/s41929-018-0170-x","volume":"1","author":"Xie","year":"2018","journal-title":"Nat. Catal."},{"key":"D5SC02092A\/cit8\/1","doi-asserted-by":"crossref","first-page":"10014","DOI":"10.1021\/jacs.4c00646","volume":"146","author":"Xiao","year":"2024","journal-title":"J. Am. Chem. Soc."},{"key":"D5SC02092A\/cit9\/1","doi-asserted-by":"crossref","first-page":"140","DOI":"10.1016\/j.jcat.2022.11.030","volume":"417","author":"Zhao","year":"2023","journal-title":"J. Catal."},{"key":"D5SC02092A\/cit10\/1","doi-asserted-by":"crossref","first-page":"16634","DOI":"10.1002\/anie.202105167","volume":"60","author":"Xu","year":"2021","journal-title":"Angew. Chem., Int. Ed."},{"key":"D5SC02092A\/cit11\/1","doi-asserted-by":"crossref","first-page":"10","DOI":"10.1016\/j.jcat.2021.04.019","volume":"400","author":"Zhao","year":"2021","journal-title":"J. Catal."},{"key":"D5SC02092A\/cit12\/1","doi-asserted-by":"crossref","first-page":"115113","DOI":"10.1016\/j.jcat.2023.115113","volume":"427","author":"Gokce","year":"2023","journal-title":"J. Catal."},{"key":"D5SC02092A\/cit13\/1","doi-asserted-by":"crossref","first-page":"2302143","DOI":"10.1002\/advs.202302143","volume":"10","author":"Yu","year":"2023","journal-title":"Adv. Sci."},{"key":"D5SC02092A\/cit14\/1","doi-asserted-by":"crossref","first-page":"6765","DOI":"10.1039\/C8SC02376J","volume":"9","author":"Sz\u00e9cs\u00e9nyi","year":"2018","journal-title":"Chem. Sci."},{"key":"D5SC02092A\/cit15\/1","doi-asserted-by":"crossref","first-page":"292","DOI":"10.1021\/acscatal.3c04603","volume":"14","author":"Deng","year":"2024","journal-title":"ACS Catal."},{"key":"D5SC02092A\/cit16\/1","doi-asserted-by":"crossref","first-page":"3647","DOI":"10.1021\/acscatal.3c06181","volume":"14","author":"Wilcox","year":"2024","journal-title":"ACS Catal."},{"key":"D5SC02092A\/cit17\/1","doi-asserted-by":"crossref","first-page":"2208504","DOI":"10.1002\/adma.202208504","volume":"35","author":"Tang","year":"2023","journal-title":"Adv. Mater."},{"key":"D5SC02092A\/cit18\/1","doi-asserted-by":"crossref","first-page":"7705","DOI":"10.1038\/s41467-023-43508-4","volume":"14","author":"Zhang","year":"2023","journal-title":"Nat. Commun."},{"key":"D5SC02092A\/cit19\/1","doi-asserted-by":"crossref","first-page":"7546","DOI":"10.1038\/ncomms8546","volume":"6","author":"Grundner","year":"2015","journal-title":"Nat. Commun."},{"key":"D5SC02092A\/cit20\/1","doi-asserted-by":"crossref","first-page":"1412","DOI":"10.1021\/jacsau.1c00196","volume":"1","author":"Lee","year":"2021","journal-title":"JACS Au"},{"key":"D5SC02092A\/cit21\/1","doi-asserted-by":"crossref","first-page":"5854","DOI":"10.1002\/anie.202014030","volume":"60","author":"Knorpp","year":"2021","journal-title":"Angew. Chem., Int. Ed."},{"key":"D5SC02092A\/cit22\/1","doi-asserted-by":"crossref","first-page":"3345","DOI":"10.1021\/acscatal.2c06099","volume":"13","author":"Mlekodaj","year":"2023","journal-title":"ACS Catal."},{"key":"D5SC02092A\/cit23\/1","doi-asserted-by":"crossref","first-page":"eaaz9776","DOI":"10.1126\/sciadv.aaz9776","volume":"6","author":"Tabor","year":"2020","journal-title":"Sci. Adv."},{"key":"D5SC02092A\/cit24\/1","doi-asserted-by":"crossref","first-page":"2718","DOI":"10.1038\/s41467-024-46924-2","volume":"15","author":"Xiao","year":"2024","journal-title":"Nat. Commun."},{"key":"D5SC02092A\/cit25\/1","doi-asserted-by":"crossref","first-page":"140379","DOI":"10.1016\/j.cej.2022.140379","volume":"455","author":"Wang","year":"2023","journal-title":"Chem. Eng. J."},{"key":"D5SC02092A\/cit26\/1","doi-asserted-by":"crossref","first-page":"2454","DOI":"10.1021\/acscatal.1c05559","volume":"12","author":"Ohyama","year":"2022","journal-title":"ACS Catal."},{"key":"D5SC02092A\/cit27\/1","doi-asserted-by":"crossref","first-page":"3522","DOI":"10.1021\/ja4113808","volume":"136","author":"Tsai","year":"2014","journal-title":"J. Am. Chem. Soc."},{"key":"D5SC02092A\/cit28\/1","doi-asserted-by":"crossref","first-page":"6383","DOI":"10.1021\/jacs.5b02817","volume":"137","author":"Vanelderen","year":"2015","journal-title":"J. Am. Chem. Soc."},{"key":"D5SC02092A\/cit29\/1","doi-asserted-by":"crossref","first-page":"15884","DOI":"10.1021\/jacs.0c06270","volume":"142","author":"Negri","year":"2020","journal-title":"J. Am. Chem. Soc."},{"key":"D5SC02092A\/cit30\/1","doi-asserted-by":"crossref","first-page":"130001","DOI":"10.1016\/j.fuel.2023.130001","volume":"357","author":"Tuo","year":"2024","journal-title":"Fuel"},{"key":"D5SC02092A\/cit31\/1","doi-asserted-by":"crossref","first-page":"4993","DOI":"10.1039\/D2CY01112C","volume":"12","author":"Xiong","year":"2022","journal-title":"Catal. Sci. Technol."},{"key":"D5SC02092A\/cit32\/1","doi-asserted-by":"crossref","first-page":"24894","DOI":"10.1039\/D3CP01906C","volume":"25","author":"Dai","year":"2023","journal-title":"Phys. Chem. Phys. Chem."},{"key":"D5SC02092A\/cit33\/1","doi-asserted-by":"crossref","first-page":"27","DOI":"10.1016\/j.jcat.2008.11.025","volume":"262","author":"J\u00ed\u0161a","year":"2009","journal-title":"J. Catal."},{"key":"D5SC02092A\/cit34\/1","doi-asserted-by":"crossref","first-page":"262","DOI":"10.1016\/j.jcat.2010.04.008","volume":"272","author":"Sklenak","year":"2010","journal-title":"J. Catal."},{"key":"D5SC02092A\/cit35\/1","doi-asserted-by":"crossref","first-page":"7344","DOI":"10.1021\/acs.jpcc.3c00585","volume":"127","author":"Olsz\u00f3wka","year":"2023","journal-title":"J. Phys. Chem. C"},{"key":"D5SC02092A\/cit36\/1","doi-asserted-by":"crossref","first-page":"12177","DOI":"10.1002\/anie.201406823","volume":"53","author":"Jones","year":"2014","journal-title":"Angew. Chem., Int. Ed."},{"key":"D5SC02092A\/cit37\/1","doi-asserted-by":"crossref","first-page":"163","DOI":"10.1021\/acsmaterialsau.1c00057","volume":"2","author":"Marsden","year":"2022","journal-title":"ACS Mater. Au"},{"key":"D5SC02092A\/cit38\/1","doi-asserted-by":"crossref","first-page":"6197","DOI":"10.1021\/acscatal.0c01063","volume":"10","author":"Xu","year":"2020","journal-title":"ACS Catal."},{"key":"D5SC02092A\/cit39\/1","doi-asserted-by":"crossref","first-page":"101","DOI":"10.1016\/j.freeradbiomed.2018.08.006","volume":"126","author":"Jugniot","year":"2018","journal-title":"Free Radical Biol. Med."},{"key":"D5SC02092A\/cit40\/1","doi-asserted-by":"crossref","first-page":"537","DOI":"10.1107\/S0909049505012719","volume":"12","author":"Ravel","year":"2005","journal-title":"J. Synchrotron Radiat."},{"key":"D5SC02092A\/cit41\/1","doi-asserted-by":"crossref","first-page":"11169","DOI":"10.1103\/PhysRevB.54.11169","volume":"54","author":"Kresse","year":"1996","journal-title":"Phys. Rev. B: Condens. Matter Mater. Phys."},{"key":"D5SC02092A\/cit42\/1","doi-asserted-by":"crossref","first-page":"1758","DOI":"10.1103\/PhysRevB.59.1758","volume":"59","author":"Kresse","year":"1999","journal-title":"Phys. Rev. B: Condens. Matter Mater. Phys."},{"key":"D5SC02092A\/cit43\/1","doi-asserted-by":"crossref","first-page":"13298","DOI":"10.1103\/PhysRevB.44.13298","volume":"44","author":"Wang","year":"1991","journal-title":"Phys. Rev. B: Condens. Matter Mater. Phys."},{"key":"D5SC02092A\/cit44\/1","doi-asserted-by":"crossref","first-page":"6671","DOI":"10.1103\/PhysRevB.46.6671","volume":"46","author":"Perdew","year":"1992","journal-title":"Phys. Rev. B: Condens. Matter Mater. Phys."},{"key":"D5SC02092A\/cit45\/1","doi-asserted-by":"crossref","first-page":"9901","DOI":"10.1063\/1.1329672","volume":"113","author":"Henkelman","year":"2000","journal-title":"J. Chem. Phys."},{"key":"D5SC02092A\/cit46\/1","doi-asserted-by":"crossref","first-page":"5188","DOI":"10.1103\/PhysRevB.13.5188","volume":"13","author":"Monkhorst","year":"1976","journal-title":"Phys. Rev. B"},{"key":"D5SC02092A\/cit47\/1","doi-asserted-by":"publisher","DOI":"10.48550\/arXiv.1908.08269","volume-title":"arXiv","author":"Wang","year":"2019","unstructured":"V.Wang ,  N.Xu ,  J.Liu ,  G.Tang  and  W.Geng ,  arXiv ,  2019 , preprint, arXiv:1908.08269,  10.48550\/arXiv.1908.08269"},{"key":"D5SC02092A\/cit48\/1","first-page":"15","volume":"4","author":"Hutter","year":"2014","journal-title":"Wiley Interdiscip. Rev.: Comput. Mol. Sci."},{"key":"D5SC02092A\/cit49\/1","doi-asserted-by":"crossref","first-page":"3865","DOI":"10.1103\/PhysRevLett.77.3865","volume":"77","author":"Perdew","year":"1996","journal-title":"Phys. Rev. Lett."},{"key":"D5SC02092A\/cit50\/1","doi-asserted-by":"crossref","first-page":"1703","DOI":"10.1103\/PhysRevB.54.1703","volume":"54","author":"Goedecker","year":"1996","journal-title":"Phys. Rev. B: Condens. Matter Mater. Phys."},{"key":"D5SC02092A\/cit51\/1","doi-asserted-by":"crossref","first-page":"154104","DOI":"10.1063\/1.3382344","volume":"132","author":"Grimme","year":"2010","journal-title":"J. Chem. Phys."},{"key":"D5SC02092A\/cit52\/1","doi-asserted-by":"crossref","first-page":"8291","DOI":"10.1021\/ja909249u","volume":"132","author":"Petersen","year":"2010","journal-title":"J. Am. Chem. Soc."},{"key":"D5SC02092A\/cit53\/1","doi-asserted-by":"crossref","first-page":"604","DOI":"10.1016\/j.cpc.2013.09.018","volume":"185","author":"Tribello","year":"2014","journal-title":"Comput. Phys. Commun."},{"key":"D5SC02092A\/cit54\/1","doi-asserted-by":"crossref","first-page":"241","DOI":"10.1016\/0301-0104(89)80010-2","volume":"129","author":"Ciccotti","year":"1989","journal-title":"Chem. Phys."},{"key":"D5SC02092A\/cit55\/1","doi-asserted-by":"crossref","first-page":"6028","DOI":"10.1021\/jacs.6b02651","volume":"138","author":"Paolucci","year":"2016","journal-title":"J. Am. Chem. Soc."},{"key":"D5SC02092A\/cit56\/1","doi-asserted-by":"crossref","first-page":"1444","DOI":"10.3390\/catal11121444","volume":"11","author":"Li","year":"2021","journal-title":"Catalysts"}],"container-title":["Chemical Science"],"original-title":[],"language":"en","link":[{"URL":"http:\/\/pubs.rsc.org\/en\/content\/articlepdf\/2025\/SC\/D5SC02092A","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,7,1]],"date-time":"2026-07-01T06:23:22Z","timestamp":1782887002000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.rsc.org\/sc\/article\/16\/28\/13082-13095\/910238"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2025]]},"references-count":56,"journal-issue":{"issue":"28","published-print":{"date-parts":[[2025,7,16]]}},"URL":"https:\/\/doi.org\/10.1039\/d5sc02092a","relation":{},"ISSN":["2041-6520","2041-6539"],"issn-type":[{"value":"2041-6520","type":"print"},{"value":"2041-6539","type":"electronic"}],"subject":[],"published":{"date-parts":[[2025]]}}}