{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,8,17]],"date-time":"2026-08-17T22:07:08Z","timestamp":1787004428412,"version":"build-2736575974"},"reference-count":40,"publisher":"Royal Society of Chemistry (RSC)","issue":"34","license":[{"start":{"date-parts":[[2025,7,21]],"date-time":"2025-07-21T00:00:00Z","timestamp":1753056000000},"content-version":"vor","delay-in-days":201,"URL":"http:\/\/creativecommons.org\/licenses\/by-nc\/3.0\/"}],"funder":[{"DOI":"10.13039\/100004341","name":"Dow Chemical Company","doi-asserted-by":"publisher","award":["UPI 226772AR"],"award-info":[{"award-number":["UPI 226772AR"]}],"id":[{"id":"10.13039\/100004341","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["rsc.org"],"crossmark-restriction":true},"short-container-title":["Chem. Sci."],"abstract":"<jats:p>\n                    This study reveals the mechanism by which Pd(acac)\n                    <jats:sub>2<\/jats:sub>\n                    and PPh\n                    <jats:sub>3<\/jats:sub>\n                    can generate Pd\n                    <jats:sup>0<\/jats:sup>\n                    or \u03c0-octadienyl Pd\n                    <jats:sup>II<\/jats:sup>\n                    species in methanol, which are active catalysts for butadiene telomerization.\n                  <\/jats:p>","DOI":"10.1039\/d5sc02171e","type":"journal-article","created":{"date-parts":[[2025,7,21]],"date-time":"2025-07-21T12:21:07Z","timestamp":1753100467000},"page":"15486-15498","update-policy":"https:\/\/doi.org\/10.1039\/rsc_crossmark_policy","source":"Crossref","is-referenced-by-count":3,"title":["Insights into the mechanism of active catalyst generation for the Pd\n                    <sup>II<\/sup>\n                    (acac)\n                    <sub>2<\/sub>\n                    \/PPh\n                    <sub>3<\/sub>\n                    system in the context of telomerization of 1,3-butadiene"],"prefix":"10.1039","volume":"16","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-9529-2653","authenticated-orcid":false,"given":"Bailey S.","family":"Bouley","sequence":"first","affiliation":[{"name":"Department of Chemistry, University of Illinois at Urbana-Champaign, Urbana, IL 61801, USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0593-3064","authenticated-orcid":false,"given":"Dae Young","family":"Bae","sequence":"additional","affiliation":[{"name":"Department of Chemistry, University of Illinois at Urbana-Champaign, Urbana, IL 61801, USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-0757-1127","authenticated-orcid":false,"given":"Sagnik","family":"Chakrabarti","sequence":"additional","affiliation":[{"name":"Department of Chemistry, University of Illinois at Urbana-Champaign, Urbana, IL 61801, USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Mari","family":"Rosen","sequence":"additional","affiliation":[{"name":"Core R&D, The Dow Chemical Company, Midland, Michigan, 48667, USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Robert D.","family":"Kennedy","sequence":"additional","affiliation":[{"name":"Core R&D, The Dow Chemical Company, Midland, Michigan, 48667, USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0584-9508","authenticated-orcid":false,"given":"Liviu M.","family":"Mirica","sequence":"additional","affiliation":[{"name":"Department of Chemistry, University of Illinois at Urbana-Champaign, Urbana, IL 61801, USA"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"292","published-online":{"date-parts":[[2025]]},"reference":[{"key":"D5SC02171E\/cit1\/1","doi-asserted-by":"crossref","first-page":"5094","DOI":"10.1002\/anie.200806273","volume":"48","author":"Chen","year":"2009","journal-title":"Angew. Chem., Int. Ed."},{"key":"D5SC02171E\/cit2\/1","doi-asserted-by":"crossref","first-page":"2457","DOI":"10.1021\/cr00039a007","volume":"95","author":"Miyaura","year":"1995","journal-title":"Chem. Rev."},{"key":"D5SC02171E\/cit3\/1","doi-asserted-by":"crossref","first-page":"5062","DOI":"10.1002\/anie.201107017","volume":"51","author":"Johansson Seechurn","year":"2012","journal-title":"Angew. Chem., Int. Ed."},{"key":"D5SC02171E\/cit4\/1","doi-asserted-by":"crossref","first-page":"1811","DOI":"10.1007\/s00216-010-4555-1","volume":"399","author":"Astruc","year":"2011","journal-title":"Anal. Bioanal. Chem."},{"key":"D5SC02171E\/cit5\/1","doi-asserted-by":"crossref","first-page":"3009","DOI":"10.1021\/om00045a012","volume":"11","author":"Amatore","year":"1992","journal-title":"Organometallics"},{"key":"D5SC02171E\/cit6\/1","doi-asserted-by":"crossref","first-page":"314","DOI":"10.1021\/ar980063a","volume":"33","author":"Amatore","year":"2000","journal-title":"Acc. Chem. Res."},{"key":"D5SC02171E\/cit7\/1","doi-asserted-by":"crossref","first-page":"7898","DOI":"10.1039\/C9SC01847F","volume":"10","author":"Scott","year":"2019","journal-title":"Chem. Sci."},{"key":"D5SC02171E\/cit8\/1","doi-asserted-by":"crossref","first-page":"5483","DOI":"10.1016\/S0040-4020(01)87264-1","volume":"49","author":"Mandai","year":"1993","journal-title":"Tetrahedron"},{"key":"D5SC02171E\/cit9\/1","doi-asserted-by":"crossref","first-page":"6090","DOI":"10.1021\/jo00049a004","volume":"57","author":"Mandai","year":"1992","journal-title":"J. Org. Chem."},{"key":"D5SC02171E\/cit10\/1","doi-asserted-by":"crossref","first-page":"4311","DOI":"10.1016\/S0040-4039(00)88328-8","volume":"24","author":"Fabre","year":"1983","journal-title":"Tetrahedron Lett."},{"key":"D5SC02171E\/cit11\/1","doi-asserted-by":"crossref","first-page":"155","DOI":"10.1039\/D3IM00009E","volume":"1","author":"Yang","year":"2023","journal-title":"Ind. Chem. Mater."},{"key":"D5SC02171E\/cit12\/1","volume-title":"Global demand for linear low-density polyethylene (LLDPE) from 1999 to 2019 actual, and forecast for 2020 to 2040, by region","author":"Jaganmohan","unstructured":"M.Jaganmohan ,  Global demand for linear low-density polyethylene (LLDPE) from 1999 to 2019 actual, and forecast for 2020 to 2040, by region ,  https:\/\/www.statista.com\/statistics\/1248064\/worldwide-demand-for-lldpe\/ , accessed 9 February 2024"},{"key":"D5SC02171E\/cit13\/1","doi-asserted-by":"crossref","first-page":"6793","DOI":"10.1021\/ja01001a089","volume":"89","author":"Smutny","year":"1967","journal-title":"J. Am. Chem. Soc."},{"key":"D5SC02171E\/cit14\/1","doi-asserted-by":"crossref","first-page":"2451","DOI":"10.1016\/S0040-4039(00)90830-X","author":"Takahashi","year":"1967","journal-title":"Tetrahedron Lett."},{"key":"D5SC02171E\/cit15\/1","doi-asserted-by":"publisher","DOI":"10.2172\/1616517","volume-title":"Report of the Basic Energy Sciences Roundtable on Chemical Upcycling of Polymers","author":"Britt","year":"2019","unstructured":"P. F.Britt ,  G. W.Coates ,  K. I.Winey ,  J.Byers ,  E.Chen ,  B.Coughlin ,  C.Ellison ,  J.Garcia ,  A.Goldman  and  J.Guzman ,  Report of the Basic Energy Sciences Roundtable on Chemical Upcycling of Polymers ,  USDOE Office of Science, Office of Science and Technical Information ,  2019 ,  10.2172\/1616517"},{"key":"D5SC02171E\/cit16\/1","doi-asserted-by":"crossref","first-page":"1825","DOI":"10.1002\/1099-0682(200008)2000:8<1825::AID-EJIC1825>3.0.CO;2-5","volume":"2000","author":"Vollm\u00fcller","year":"2000","journal-title":"Eur. J. Inorg. Chem."},{"key":"D5SC02171E\/cit17\/1","doi-asserted-by":"crossref","first-page":"431","DOI":"10.1007\/s00894-009-0544-8","volume":"16","author":"Huo","year":"2010","journal-title":"J. Mol. Model."},{"key":"D5SC02171E\/cit18\/1","doi-asserted-by":"crossref","first-page":"3891","DOI":"10.1002\/chem.200400182","volume":"10","author":"Jackstell","year":"2004","journal-title":"Chem.\u2013Eur. J."},{"key":"D5SC02171E\/cit19\/1","doi-asserted-by":"crossref","first-page":"27","DOI":"10.1016\/S1381-1169(98)00349-5","volume":"144","author":"Benvenuti","year":"1999","journal-title":"J. Mol. Catal. A: Chem."},{"key":"D5SC02171E\/cit20\/1","doi-asserted-by":"crossref","first-page":"179","DOI":"10.1016\/S1381-1169(97)00155-6","volume":"129","author":"Patrini","year":"1998","journal-title":"J. Mol. Catal. A: Chem."},{"key":"D5SC02171E\/cit21\/1","doi-asserted-by":"crossref","first-page":"1155","DOI":"10.1039\/b904274a","volume":"11","author":"Palkovits","year":"2009","journal-title":"Green Chem."},{"key":"D5SC02171E\/cit22\/1","doi-asserted-by":"crossref","first-page":"127","DOI":"10.1016\/1381-1169(96)00024-6","volume":"109","author":"Camargo","year":"1996","journal-title":"J. Mol. Catal. A: Chem."},{"key":"D5SC02171E\/cit23\/1","doi-asserted-by":"crossref","first-page":"349","DOI":"10.1021\/op800278g","volume":"13","author":"Jackstell","year":"2009","journal-title":"Org. Process Res. Dev."},{"key":"D5SC02171E\/cit25\/1","doi-asserted-by":"crossref","first-page":"1677","DOI":"10.1016\/j.jorganchem.2011.02.007","volume":"696","author":"Briggs","year":"2011","journal-title":"J. Organomet. Chem."},{"key":"D5SC02171E\/cit26\/1","doi-asserted-by":"publisher","first-page":"199","DOI":"10.1246\/cl.1976.199","author":"Kanda","year":"1976","journal-title":"Chem. Lett."},{"key":"D5SC02171E\/cit27\/1","doi-asserted-by":"crossref","first-page":"121413","DOI":"10.1016\/j.jorganchem.2020.121413","volume":"923","author":"Suslov","year":"2020","journal-title":"J. Organomet. Chem."},{"key":"D5SC02171E\/cit28\/1","doi-asserted-by":"crossref","first-page":"1654","DOI":"10.1021\/acs.oprd.9b00018","volume":"23","author":"Klinkenberg","year":"2019","journal-title":"Org. Process Res. Dev."},{"key":"D5SC02171E\/cit29\/1","doi-asserted-by":"crossref","first-page":"2384","DOI":"10.1021\/acs.organomet.1c00288","volume":"40","author":"Bigler","year":"2021","journal-title":"Organometallics"},{"key":"D5SC02171E\/cit30\/1","doi-asserted-by":"crossref","first-page":"5596","DOI":"10.1021\/acscatal.5b01291","volume":"5","author":"Melvin","year":"2015","journal-title":"ACS Catal."},{"key":"D5SC02171E\/cit31\/1","doi-asserted-by":"crossref","first-page":"2871","DOI":"10.1039\/C5CS00537J","volume":"45","author":"Hazari","year":"2016","journal-title":"Chem. Soc. Rev."},{"key":"D5SC02171E\/cit32\/1","doi-asserted-by":"crossref","first-page":"51","DOI":"10.1016\/0010-8545(86)80035-2","volume":"70","author":"Kawaguchi","year":"1986","journal-title":"Coord. Chem. Rev."},{"key":"D5SC02171E\/cit33\/1","doi-asserted-by":"crossref","first-page":"665","DOI":"10.1246\/bcsj.47.665","volume":"47","author":"Baba","year":"2006","journal-title":"Bull. Chem. Soc. Jpn."},{"key":"D5SC02171E\/cit34\/1","doi-asserted-by":"crossref","first-page":"5605","DOI":"10.1021\/om00012a029","volume":"14","author":"Amatore","year":"1995","journal-title":"Organometallics"},{"key":"D5SC02171E\/cit35\/1","doi-asserted-by":"crossref","first-page":"1475","DOI":"10.1016\/S0277-5387(00)83509-3","volume":"5","author":"Hursthouse","year":"1986","journal-title":"Polyhedron"},{"key":"D5SC02171E\/cit36\/1","doi-asserted-by":"crossref","first-page":"1136","DOI":"10.1021\/om00125a034","volume":"4","author":"Benn","year":"1985","journal-title":"Organometallics"},{"key":"D5SC02171E\/cit37\/1","doi-asserted-by":"crossref","first-page":"1945","DOI":"10.1021\/om00130a005","volume":"4","author":"Benn","year":"1985","journal-title":"Organometallics"},{"key":"D5SC02171E\/cit38\/1","doi-asserted-by":"crossref","first-page":"473","DOI":"10.1021\/om00134a014","volume":"5","author":"Jolly","year":"1986","journal-title":"Organometallics"},{"key":"D5SC02171E\/cit39\/1","doi-asserted-by":"crossref","first-page":"443","DOI":"10.1016\/0022-328X(85)80374-0","volume":"296","author":"Benn","year":"1985","journal-title":"J. Organomet. Chem."},{"key":"D5SC02171E\/cit40\/1","doi-asserted-by":"crossref","first-page":"7972","DOI":"10.1002\/anie.201003090","volume":"49","author":"Hausoul","year":"2010","journal-title":"Angew. Chem., Int. Ed."},{"key":"D5SC02171E\/cit41\/1","doi-asserted-by":"crossref","first-page":"5047","DOI":"10.1021\/om400246a","volume":"32","author":"Hausoul","year":"2013","journal-title":"Organometallics"}],"container-title":["Chemical Science"],"original-title":[],"language":"en","link":[{"URL":"http:\/\/pubs.rsc.org\/en\/content\/articlepdf\/2025\/SC\/D5SC02171E","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,7,1]],"date-time":"2026-07-01T04:52:13Z","timestamp":1782881533000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.rsc.org\/sc\/article\/16\/34\/15486-15498\/910256"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2025]]},"references-count":40,"journal-issue":{"issue":"34","published-print":{"date-parts":[[2025,8,27]]}},"URL":"https:\/\/doi.org\/10.1039\/d5sc02171e","relation":{},"ISSN":["2041-6520","2041-6539"],"issn-type":[{"value":"2041-6520","type":"print"},{"value":"2041-6539","type":"electronic"}],"subject":[],"published":{"date-parts":[[2025]]}}}