{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,14]],"date-time":"2026-10-14T16:44:29Z","timestamp":1791996269619,"version":"4.4.0"},"reference-count":46,"publisher":"Royal Society of Chemistry (RSC)","issue":"30","license":[{"start":{"date-parts":[[2025,6,27]],"date-time":"2025-06-27T00:00:00Z","timestamp":1750982400000},"content-version":"vor","delay-in-days":177,"URL":"http:\/\/creativecommons.org\/licenses\/by\/3.0\/"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22025502"],"award-info":[{"award-number":["22025502"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22379026"],"award-info":[{"award-number":["22379026"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["U23A20552"],"award-info":[{"award-number":["U23A20552"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100012166","name":"National Key Research and Development Program of China","doi-asserted-by":"publisher","award":["2024YFB4106400"],"award-info":[{"award-number":["2024YFB4106400"]}],"id":[{"id":"10.13039\/501100012166","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100012166","name":"National Key Research and Development Program of China","doi-asserted-by":"publisher","award":["2024YFB4106401"],"award-info":[{"award-number":["2024YFB4106401"]}],"id":[{"id":"10.13039\/501100012166","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100007219","name":"Natural Science Foundation of Shanghai Municipality","doi-asserted-by":"publisher","award":["23ZR1407000"],"award-info":[{"award-number":["23ZR1407000"]}],"id":[{"id":"10.13039\/100007219","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["rsc.org"],"crossmark-restriction":true},"short-container-title":["Chem. Sci."],"abstract":"<jats:p>\n                    We demonstrate a selectivity descriptor to evaluate the competition between the CH\n                    <jats:sub>3<\/jats:sub>\n                    CHO* protonation and the coupling of CH\n                    <jats:sub>3<\/jats:sub>\n                    CHO* and CO*, which are the selectivity-determining steps for the ethanol pathway\n                    <jats:italic>versus<\/jats:italic>\n                    the\n                    <jats:italic>n<\/jats:italic>\n                    -propanol pathway, respectively.\n                  <\/jats:p>","DOI":"10.1039\/d5sc02562a","type":"journal-article","created":{"date-parts":[[2025,6,27]],"date-time":"2025-06-27T04:20:41Z","timestamp":1750998041000},"page":"13944-13950","update-policy":"https:\/\/doi.org\/10.1039\/rsc_crossmark_policy","source":"Crossref","is-referenced-by-count":16,"title":["Promoting electrocatalytic CO\n                    <sub>2<\/sub>\n                    reduction to\n                    <i>n<\/i>\n                    -propanol over ethanol at Cu step sites"],"prefix":"10.1039","volume":"16","author":[{"given":"Yuanyuan","family":"Xue","sequence":"first","affiliation":[{"name":"Laboratory of Advanced Materials, State Key Laboratory of Porous Materials for Separation and Conversion, Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Fudan University, Shanghai, 200438, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-0482-2349","authenticated-orcid":false,"given":"Ximeng","family":"Lv","sequence":"additional","affiliation":[{"name":"Laboratory of Advanced Materials, State Key Laboratory of Porous Materials for Separation and Conversion, Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Fudan University, Shanghai, 200438, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Chao","family":"Yang","sequence":"additional","affiliation":[{"name":"Laboratory of Advanced Materials, State Key Laboratory of Porous Materials for Separation and Conversion, Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Fudan University, Shanghai, 200438, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Lu","family":"Song","sequence":"additional","affiliation":[{"name":"Laboratory of Advanced Materials, State Key Laboratory of Porous Materials for Separation and Conversion, Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Fudan University, Shanghai, 200438, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Lijuan","family":"Zhang","sequence":"additional","affiliation":[{"name":"Laboratory of Advanced Materials, State Key Laboratory of Porous Materials for Separation and Conversion, Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Fudan University, Shanghai, 200438, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-1803-6955","authenticated-orcid":false,"given":"Gengfeng","family":"Zheng","sequence":"additional","affiliation":[{"name":"Laboratory of Advanced Materials, State Key Laboratory of Porous Materials for Separation and Conversion, Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Fudan University, Shanghai, 200438, China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"292","published-online":{"date-parts":[[2025]]},"reference":[{"key":"D5SC02562A\/cit1\/1","doi-asserted-by":"crossref","first-page":"75","DOI":"10.1038\/s44160-024-00662-x","volume":"4","author":"Shayesteh Zeraati","year":"2025","journal-title":"Nat. Synth."},{"key":"D5SC02562A\/cit2\/1","doi-asserted-by":"crossref","first-page":"251","DOI":"10.1038\/s41929-022-00757-8","volume":"5","author":"Ji","year":"2022","journal-title":"Nat. Catal."},{"key":"D5SC02562A\/cit3\/1","doi-asserted-by":"crossref","first-page":"319","DOI":"10.1038\/s41929-023-00938-z","volume":"6","author":"Qi","year":"2023","journal-title":"Nat. Catal."},{"key":"D5SC02562A\/cit4\/1","doi-asserted-by":"crossref","first-page":"9923","DOI":"10.1038\/s41467-024-54282-2","volume":"15","author":"He","year":"2024","journal-title":"Nat. Commun."},{"key":"D5SC02562A\/cit5\/1","doi-asserted-by":"crossref","first-page":"1925","DOI":"10.1016\/j.joule.2018.08.016","volume":"2","author":"Shih","year":"2018","journal-title":"Joule"},{"key":"D5SC02562A\/cit6\/1","doi-asserted-by":"crossref","first-page":"1536","DOI":"10.1039\/C8EE00097B","volume":"11","author":"Spurgeon","year":"2018","journal-title":"Energy Environ. Sci."},{"key":"D5SC02562A\/cit7\/1","doi-asserted-by":"crossref","first-page":"6","DOI":"10.1038\/s41929-022-00887-z","volume":"6","author":"Kong","year":"2023","journal-title":"Nat. Catal."},{"key":"D5SC02562A\/cit8\/1","doi-asserted-by":"crossref","first-page":"7170","DOI":"10.1021\/acscatal.3c00972","volume":"13","author":"Zhang","year":"2023","journal-title":"ACS Catal."},{"key":"D5SC02562A\/cit9\/1","doi-asserted-by":"crossref","first-page":"202420286","DOI":"10.1002\/anie.202420286","volume":"64","author":"Xin","year":"2025","journal-title":"Angew. Chem., Int. Ed."},{"key":"D5SC02562A\/cit10\/1","doi-asserted-by":"crossref","first-page":"14260","DOI":"10.1021\/jacs.4c03830","volume":"146","author":"Liu","year":"2024","journal-title":"J. Am. Chem. Soc."},{"key":"D5SC02562A\/cit11\/1","doi-asserted-by":"crossref","first-page":"202316907","DOI":"10.1002\/anie.202316907","volume":"63","author":"Peng","year":"2024","journal-title":"Angew. Chem., Int. Ed."},{"key":"D5SC02562A\/cit12\/1","doi-asserted-by":"crossref","first-page":"2207374","DOI":"10.1002\/smll.202207374","volume":"19","author":"Peng","year":"2023","journal-title":"Small"},{"key":"D5SC02562A\/cit13\/1","doi-asserted-by":"crossref","first-page":"2400152","DOI":"10.1002\/aenm.202400152","volume":"14","author":"Sun","year":"2024","journal-title":"Adv. Energy Mater."},{"key":"D5SC02562A\/cit14\/1","doi-asserted-by":"crossref","first-page":"10530","DOI":"10.1021\/acs.chemrev.2c00514","volume":"123","author":"Yan","year":"2023","journal-title":"Chem. Rev."},{"key":"D5SC02562A\/cit15\/1","doi-asserted-by":"crossref","first-page":"4508","DOI":"10.1021\/jacs.3c11013","volume":"146","author":"Jeong","year":"2024","journal-title":"J. Am. Chem. Soc."},{"key":"D5SC02562A\/cit16\/1","doi-asserted-by":"crossref","first-page":"574","DOI":"10.1038\/s41929-024-01147-y","volume":"7","author":"Sakamoto","year":"2024","journal-title":"Nat. Catal."},{"key":"D5SC02562A\/cit17\/1","doi-asserted-by":"crossref","first-page":"1580","DOI":"10.1038\/s41467-021-21901-1","volume":"12","author":"Peng","year":"2021","journal-title":"Nat. Commun."},{"key":"D5SC02562A\/cit18\/1","doi-asserted-by":"crossref","first-page":"5122","DOI":"10.1038\/s41467-022-32740-z","volume":"13","author":"Yang","year":"2022","journal-title":"Nat. Commun."},{"key":"D5SC02562A\/cit19\/1","doi-asserted-by":"crossref","first-page":"170","DOI":"10.1038\/s41560-021-00967-7","volume":"7","author":"Wang","year":"2022","journal-title":"Nat. Energy"},{"key":"D5SC02562A\/cit20\/1","doi-asserted-by":"crossref","first-page":"4882","DOI":"10.1038\/s41467-023-40689-w","volume":"14","author":"Niu","year":"2023","journal-title":"Nat. Commun."},{"key":"D5SC02562A\/cit21\/1","doi-asserted-by":"crossref","first-page":"4614","DOI":"10.1038\/s41467-018-07032-0","volume":"9","author":"Li","year":"2018","journal-title":"Nat. Commun."},{"key":"D5SC02562A\/cit22\/1","doi-asserted-by":"crossref","first-page":"251","DOI":"10.1038\/s41929-019-0225-7","volume":"2","author":"Pang","year":"2019","journal-title":"Nat. Catal."},{"key":"D5SC02562A\/cit23\/1","doi-asserted-by":"crossref","first-page":"26374","DOI":"10.1021\/jacs.3c10202","volume":"145","author":"Yan","year":"2023","journal-title":"J. Am. Chem. Soc."},{"key":"D5SC02562A\/cit24\/1","doi-asserted-by":"crossref","first-page":"202309319","DOI":"10.1002\/anie.202309319","volume":"62","author":"Liu","year":"2023","journal-title":"Angew. Chem., Int. Ed."},{"key":"D5SC02562A\/cit25\/1","first-page":"100565","volume":"3","author":"Kuang","year":"2023","journal-title":"Chem Catal."},{"key":"D5SC02562A\/cit26\/1","doi-asserted-by":"crossref","first-page":"1905","DOI":"10.1021\/acscentsci.3c00826","volume":"9","author":"Yang","year":"2023","journal-title":"ACS Cent. Sci."},{"key":"D5SC02562A\/cit27\/1","doi-asserted-by":"crossref","first-page":"11375","DOI":"10.1021\/acsami.4c21239","volume":"17","author":"Xue","year":"2025","journal-title":"ACS Appl. Mater."},{"key":"D5SC02562A\/cit28\/1","doi-asserted-by":"crossref","first-page":"2025","DOI":"10.1039\/D4EE05715E","volume":"18","author":"Jiang","year":"2025","journal-title":"Energy Environ. Sci."},{"key":"D5SC02562A\/cit29\/1","doi-asserted-by":"crossref","first-page":"16119","DOI":"10.1021\/jacs.4c03515","volume":"146","author":"Zhang","year":"2024","journal-title":"J. Am. Chem. Soc."},{"key":"D5SC02562A\/cit30\/1","doi-asserted-by":"crossref","first-page":"12607","DOI":"10.1021\/acscatal.0c03865","volume":"10","author":"Exner","year":"2020","journal-title":"ACS Catal."},{"key":"D5SC02562A\/cit31\/1","doi-asserted-by":"crossref","first-page":"1021","DOI":"10.1038\/s41929-024-01218-0","volume":"7","author":"Lucky","year":"2024","journal-title":"Nat. Catal."},{"key":"D5SC02562A\/cit32\/1","doi-asserted-by":"crossref","first-page":"7012","DOI":"10.1021\/jacs.8b04058","volume":"140","author":"Clark","year":"2018","journal-title":"J. Am. Chem. Soc."},{"key":"D5SC02562A\/cit33\/1","doi-asserted-by":"crossref","first-page":"4339","DOI":"10.1021\/acscatal.3c00190","volume":"13","author":"da Silva","year":"2023","journal-title":"ACS Catal."},{"key":"D5SC02562A\/cit34\/1","doi-asserted-by":"crossref","first-page":"2975","DOI":"10.1021\/jacs.9b11817","volume":"142","author":"Chang","year":"2020","journal-title":"J. Am. Chem. Soc."},{"key":"D5SC02562A\/cit35\/1","doi-asserted-by":"crossref","first-page":"20495","DOI":"10.1021\/jacs.2c09378","volume":"144","author":"Li","year":"2022","journal-title":"J. Am. Chem. Soc."},{"key":"D5SC02562A\/cit36\/1","doi-asserted-by":"crossref","first-page":"18106","DOI":"10.1039\/D3TA03115B","volume":"11","author":"He","year":"2023","journal-title":"J. Mater. Chem. A"},{"key":"D5SC02562A\/cit37\/1","doi-asserted-by":"crossref","first-page":"6688","DOI":"10.1021\/jacs.4c16129","volume":"147","author":"Li","year":"2025","journal-title":"J. Am. Chem. Soc."},{"key":"D5SC02562A\/cit38\/1","doi-asserted-by":"crossref","first-page":"202405733","DOI":"10.1002\/anie.202405733","volume":"63","author":"Zhang","year":"2024","journal-title":"Angew. Chem., Int. Ed."},{"key":"D5SC02562A\/cit39\/1","doi-asserted-by":"crossref","first-page":"4854","DOI":"10.1021\/acscatal.0c00297","volume":"10","author":"De Gregorio","year":"2020","journal-title":"ACS Catal."},{"key":"D5SC02562A\/cit40\/1","doi-asserted-by":"crossref","first-page":"5062","DOI":"10.1021\/acscatal.3c00228","volume":"13","author":"Kastlunger","year":"2023","journal-title":"ACS Catal."},{"key":"D5SC02562A\/cit41\/1","doi-asserted-by":"crossref","first-page":"6497","DOI":"10.1021\/acscatal.4c07168","volume":"15","author":"Zhang","year":"2025","journal-title":"ACS Catal."},{"key":"D5SC02562A\/cit42\/1","doi-asserted-by":"crossref","first-page":"5186","DOI":"10.1038\/s41467-019-13190-6","volume":"10","author":"Wang","year":"2019","journal-title":"Nat. Commun."},{"key":"D5SC02562A\/cit43\/1","doi-asserted-by":"crossref","first-page":"3748","DOI":"10.1039\/C4CY00335G","volume":"4","author":"Montemore","year":"2014","journal-title":"Catal. Sci. Technol."},{"key":"D5SC02562A\/cit44\/1","doi-asserted-by":"crossref","first-page":"4879","DOI":"10.1002\/anie.202015159","volume":"60","author":"Zhong","year":"2021","journal-title":"Angew. Chem., Int. Ed."},{"key":"D5SC02562A\/cit45\/1","doi-asserted-by":"crossref","first-page":"125053","DOI":"10.1016\/j.apcatb.2025.125053","volume":"366","author":"Harzandi","year":"2025","journal-title":"Appl. Catal., B"},{"key":"D5SC02562A\/cit46\/1","doi-asserted-by":"crossref","first-page":"158187","DOI":"10.1016\/j.cej.2024.158187","volume":"503","author":"Zhang","year":"2025","journal-title":"Chem. Eng. J."}],"container-title":["Chemical Science"],"original-title":[],"language":"en","link":[{"URL":"http:\/\/pubs.rsc.org\/en\/content\/articlepdf\/2025\/SC\/D5SC02562A","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,7,2]],"date-time":"2026-07-02T04:36:31Z","timestamp":1782966991000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.rsc.org\/sc\/article\/16\/30\/13944-13950\/910342"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2025]]},"references-count":46,"journal-issue":{"issue":"30","published-print":{"date-parts":[[2025,7,30]]}},"URL":"https:\/\/doi.org\/10.1039\/d5sc02562a","relation":{},"ISSN":["2041-6520","2041-6539"],"issn-type":[{"value":"2041-6520","type":"print"},{"value":"2041-6539","type":"electronic"}],"subject":[],"published":{"date-parts":[[2025]]}}}