{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,10]],"date-time":"2026-10-10T18:17:10Z","timestamp":1791656230905,"version":"4.3.4"},"reference-count":47,"publisher":"Royal Society of Chemistry (RSC)","issue":"38","license":[{"start":{"date-parts":[[2025,8,28]],"date-time":"2025-08-28T00:00:00Z","timestamp":1756339200000},"content-version":"vor","delay-in-days":239,"URL":"http:\/\/creativecommons.org\/licenses\/by-nc\/3.0\/"}],"funder":[{"DOI":"10.13039\/100000001","name":"National Science Foundation","doi-asserted-by":"publisher","award":["2304777"],"award-info":[{"award-number":["2304777"]}],"id":[{"id":"10.13039\/100000001","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["rsc.org"],"crossmark-restriction":true},"short-container-title":["Chem. Sci."],"abstract":"<jats:p>Solvent attenuation of dispersion interactions was quantified using a new class of rigid intramolecular CH\u2013\u03c0 molecular balances.<\/jats:p>","DOI":"10.1039\/d5sc02852c","type":"journal-article","created":{"date-parts":[[2025,8,28]],"date-time":"2025-08-28T15:00:51Z","timestamp":1756393251000},"page":"17772-17778","update-policy":"https:\/\/doi.org\/10.1039\/rsc_crossmark_policy","source":"Crossref","is-referenced-by-count":10,"title":["Solvent attenuation of dispersion interactions quantified in polar and nonpolar media using rigid CH\u2013\u03c0 balances"],"prefix":"10.1039","volume":"16","author":[{"ORCID":"https:\/\/orcid.org\/0009-0000-7543-5146","authenticated-orcid":false,"given":"Hao","family":"Liu","sequence":"first","affiliation":[{"name":"Department of Chemistry and Biochemistry, University of South Carolina, Columbia, SC 29208, USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Harrison M.","family":"Scott","sequence":"additional","affiliation":[{"name":"Department of Chemistry and Biochemistry, University of South Carolina, Columbia, SC 29208, USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Binzhou","family":"Lin","sequence":"additional","affiliation":[{"name":"Department of Chemistry and Biochemistry, University of South Carolina, Columbia, SC 29208, USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xiaolong","family":"Huang","sequence":"additional","affiliation":[{"name":"Department of Chemistry and Biochemistry, University of South Carolina, Columbia, SC 29208, USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-6977-7131","authenticated-orcid":false,"given":"Mark D.","family":"Smith","sequence":"additional","affiliation":[{"name":"Department of Chemistry and Biochemistry, University of South Carolina, Columbia, SC 29208, USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-0229-6541","authenticated-orcid":false,"given":"Ken D.","family":"Shimizu","sequence":"additional","affiliation":[{"name":"Department of Chemistry and Biochemistry, University of South Carolina, Columbia, SC 29208, USA"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"292","published-online":{"date-parts":[[2025]]},"reference":[{"key":"D5SC02852C\/cit1\/1","doi-asserted-by":"crossref","first-page":"12274","DOI":"10.1002\/anie.201503476","volume":"54","author":"Wagner","year":"2015","journal-title":"Angew. Chem., Int. Ed."},{"key":"D5SC02852C\/cit2\/1","doi-asserted-by":"crossref","first-page":"1815","DOI":"10.1021\/acs.accounts.5b00111","volume":"48","author":"Schneider","year":"2015","journal-title":"Acc. Chem. Res."},{"key":"D5SC02852C\/cit3\/1","doi-asserted-by":"crossref","first-page":"e202316364","DOI":"10.1002\/anie.202316364","volume":"63","author":"Rummel","year":"2024","journal-title":"Angew. Chem., Int. Ed."},{"key":"D5SC02852C\/cit4\/1","doi-asserted-by":"crossref","first-page":"3535","DOI":"10.1021\/acs.accounts.3c00625","volume":"56","author":"Gravillier","year":"2023","journal-title":"Acc. Chem. Res."},{"key":"D5SC02852C\/cit5\/1","doi-asserted-by":"crossref","first-page":"3572","DOI":"10.1021\/acs.accounts.3c00539","volume":"56","author":"Liu","year":"2023","journal-title":"Acc. Chem. Res."},{"key":"D5SC02852C\/cit6\/1","doi-asserted-by":"crossref","first-page":"1479","DOI":"10.1039\/C0CC03025B","volume":"47","author":"Aikawa","year":"2011","journal-title":"Chem. Commun."},{"key":"D5SC02852C\/cit7\/1","doi-asserted-by":"crossref","first-page":"19861","DOI":"10.1021\/jacs.2c07563","volume":"144","author":"Gram\u00fcller","year":"2022","journal-title":"J. Am. Chem. Soc."},{"key":"D5SC02852C\/cit8\/1","doi-asserted-by":"crossref","first-page":"383","DOI":"10.1039\/cs9932200383","volume":"22","author":"Webb","year":"1993","journal-title":"Chem. Soc. Rev."},{"key":"D5SC02852C\/cit9\/1","doi-asserted-by":"crossref","first-page":"e202400767","DOI":"10.1002\/anie.202400767","volume":"63","author":"Formen","year":"2024","journal-title":"Angew. Chem., Int. Ed."},{"key":"D5SC02852C\/cit10\/1","doi-asserted-by":"crossref","first-page":"8b","DOI":"10.1039\/tf937330008b","volume":"33","author":"London","year":"1937","journal-title":"Trans. Faraday Soc."},{"key":"D5SC02852C\/cit11\/1","doi-asserted-by":"crossref","first-page":"245","DOI":"10.1007\/BF01421741","volume":"63","author":"London","year":"1930","journal-title":"Z. Phys."},{"key":"D5SC02852C\/cit12\/1","doi-asserted-by":"crossref","first-page":"1","DOI":"10.1038\/s41570-016-0004","volume":"1","author":"Liptrot","year":"2017","journal-title":"Nat. Rev. Chem."},{"key":"D5SC02852C\/cit13\/1","doi-asserted-by":"crossref","first-page":"258","DOI":"10.1021\/acs.accounts.8b00505","volume":"52","author":"Bursch","year":"2019","journal-title":"Acc. Chem. Res."},{"key":"D5SC02852C\/cit14\/1","doi-asserted-by":"crossref","first-page":"211","DOI":"10.1002\/wcms.30","volume":"1","author":"Grimme","year":"2011","journal-title":"WIRES Comput. Mol. Sci."},{"key":"D5SC02852C\/cit15\/1","doi-asserted-by":"crossref","first-page":"13126","DOI":"10.1021\/jacs.7b06997","volume":"139","author":"Pollice","year":"2017","journal-title":"J. Am. Chem. Soc."},{"key":"D5SC02852C\/cit16\/1","doi-asserted-by":"crossref","first-page":"4358","DOI":"10.1039\/C5SC01370D","volume":"6","author":"Hwang","year":"2015","journal-title":"Chem. Sci."},{"key":"D5SC02852C\/cit17\/1","doi-asserted-by":"crossref","first-page":"3451","DOI":"10.1021\/acs.accounts.3c00523","volume":"56","author":"Assaf","year":"2023","journal-title":"Acc. Chem. Res."},{"key":"D5SC02852C\/cit18\/1","doi-asserted-by":"crossref","first-page":"912","DOI":"10.1002\/anie.201508056","volume":"55","author":"Yang","year":"2016","journal-title":"Angew. Chem., Int. Ed."},{"key":"D5SC02852C\/cit19\/1","doi-asserted-by":"crossref","first-page":"1024","DOI":"10.1021\/acs.joc.2c02444","volume":"88","author":"Wilming","year":"2023","journal-title":"J. Org. Chem."},{"key":"D5SC02852C\/cit20\/1","doi-asserted-by":"crossref","first-page":"e202412056","DOI":"10.1002\/anie.202412056","volume":"63","author":"Elmi","year":"2024","journal-title":"Angew. Chem., Int. Ed."},{"key":"D5SC02852C\/cit21\/1","doi-asserted-by":"crossref","first-page":"1006","DOI":"10.1038\/nchem.1779","volume":"5","author":"Yang","year":"2013","journal-title":"Nat. Chem."},{"key":"D5SC02852C\/cit22\/1","doi-asserted-by":"crossref","first-page":"779","DOI":"10.1002\/anie.202012094","volume":"60","author":"Strauss","year":"2021","journal-title":"Angew. Chem., Int. Ed."},{"key":"D5SC02852C\/cit23\/1","doi-asserted-by":"crossref","first-page":"14281","DOI":"10.1002\/anie.201905436","volume":"58","author":"Pollice","year":"2019","journal-title":"Angew. Chem., Int. Ed."},{"key":"D5SC02852C\/cit24\/1","doi-asserted-by":"crossref","first-page":"1164","DOI":"10.1002\/anie.201408982","volume":"54","author":"Adam","year":"2015","journal-title":"Angew. Chem., Int. Ed."},{"key":"D5SC02852C\/cit25\/1","doi-asserted-by":"crossref","first-page":"2584","DOI":"10.1039\/b718656h","volume":"10","author":"Tsuzuki","year":"2008","journal-title":"Phys. Chem. Chem. Phys."},{"key":"D5SC02852C\/cit26\/1","doi-asserted-by":"crossref","first-page":"3547","DOI":"10.1021\/ol801286k","volume":"10","author":"Carroll","year":"2008","journal-title":"Org. Lett."},{"key":"D5SC02852C\/cit27\/1","doi-asserted-by":"crossref","first-page":"4320","DOI":"10.1021\/ol201657p","volume":"13","author":"Carroll","year":"2011","journal-title":"Org. Lett."},{"key":"D5SC02852C\/cit28\/1","doi-asserted-by":"crossref","first-page":"7209","DOI":"10.1002\/anie.201702950","volume":"56","author":"Li","year":"2017","journal-title":"Angew. Chem., Int. Ed."},{"key":"D5SC02852C\/cit29\/1","doi-asserted-by":"crossref","first-page":"13301","DOI":"10.1021\/jacs.8b07617","volume":"140","author":"Hwang","year":"2018","journal-title":"J. Am. Chem. Soc."},{"key":"D5SC02852C\/cit30\/1","doi-asserted-by":"crossref","first-page":"14060","DOI":"10.1021\/ja504378p","volume":"136","author":"Hwang","year":"2014","journal-title":"J. Am. Chem. Soc."},{"key":"D5SC02852C\/cit31\/1","doi-asserted-by":"crossref","first-page":"e202314962","DOI":"10.1002\/anie.202314962","volume":"63","author":"Manzewitsch","year":"2024","journal-title":"Angew. Chem., Int. Ed."},{"key":"D5SC02852C\/cit32\/1","doi-asserted-by":"crossref","first-page":"10084","DOI":"10.1021\/jacs.5b05736","volume":"137","author":"Yang","year":"2015","journal-title":"J. Am. Chem. Soc."},{"key":"D5SC02852C\/cit33\/1","doi-asserted-by":"crossref","first-page":"3520","DOI":"10.1021\/ol5014729","volume":"16","author":"Zhao","year":"2014","journal-title":"Org. Lett."},{"key":"D5SC02852C\/cit34\/1","doi-asserted-by":"crossref","first-page":"4529","DOI":"10.1039\/D4QO00779D","volume":"11","author":"Yuan","year":"2024","journal-title":"Org. Chem. Front."},{"key":"D5SC02852C\/cit35\/1","doi-asserted-by":"crossref","first-page":"1757","DOI":"10.1039\/b902318f","volume":"11","author":"Nishio","year":"2009","journal-title":"CrystEngComm"},{"key":"D5SC02852C\/cit36\/1","doi-asserted-by":"crossref","first-page":"6185","DOI":"10.1016\/S0040-4020(00)00575-5","volume":"56","author":"Takahashi","year":"2000","journal-title":"Tetrahedron"},{"key":"D5SC02852C\/cit37\/1","doi-asserted-by":"crossref","first-page":"13873","DOI":"10.1039\/c1cp20404a","volume":"13","author":"Nishio","year":"2011","journal-title":"Phys. Chem. Chem. Phys."},{"key":"D5SC02852C\/cit38\/1","doi-asserted-by":"crossref","first-page":"2021","DOI":"10.1016\/S0968-0896(99)00123-6","volume":"7","author":"Umezawa","year":"1999","journal-title":"Bioorg. Med. Chem."},{"key":"D5SC02852C\/cit39\/1","doi-asserted-by":"crossref","first-page":"2705","DOI":"10.1021\/acs.accounts.0c00519","volume":"53","author":"Li","year":"2020","journal-title":"Acc. Chem. Res."},{"key":"D5SC02852C\/cit40\/1","doi-asserted-by":"crossref","first-page":"3746","DOI":"10.1021\/ja993972j","volume":"122","author":"Tsuzuki","year":"2000","journal-title":"J. Am. Chem. Soc."},{"key":"D5SC02852C\/cit41a\/1","doi-asserted-by":"publisher","DOI":"10.5517\/ccdc.csd.cc2n0393","author":"Liu","year":"2025","unstructured":"H.Liu ,  H. M.Scott ,  B.Lin ,  X.Huang ,  M. D.Smith  and  K. D.Shimizu ,  CCDC 2442964: Experimental Crystal Structure Determination ,  2025 ,  10.5517\/ccdc.csd.cc2n0393 ."},{"key":"D5SC02852C\/cit41b\/1","doi-asserted-by":"publisher","DOI":"10.5517\/ccdc.csd.cc2n03b4","author":"Liu","year":"2025","unstructured":"H.Liu ,  H. M.Scott ,  B.Lin ,  X.Huang ,  M. D.Smith  and  K. D.Shimizu ,  CCDC 2442965: Experimental Crystal Structure Determination ,  2025 ,  10.5517\/ccdc.csd.cc2n03b4"},{"key":"D5SC02852C\/cit41c\/1","doi-asserted-by":"publisher","DOI":"10.5517\/ccdc.csd.cc2n03c5","author":"Liu","year":"2025","unstructured":"H.Liu ,  H. M.Scott ,  B.Lin ,  X.Huang ,  M. D.Smith  and  K. D.Shimizu ,  CCDC 2442966: Experimental Crystal Structure Determination ,  2025 ,  10.5517\/ccdc.csd.cc2n03c5"},{"key":"D5SC02852C\/cit41d\/1","doi-asserted-by":"publisher","DOI":"10.5517\/ccdc.csd.cc2n03f7","author":"Liu","year":"2025","unstructured":"H.Liu ,  H. M.Scott ,  B.Lin ,  X.Huang ,  M. D.Smith  and  K. D.Shimizu ,  CCDC 2442968: Experimental Crystal Structure Determination ,  2025 ,  10.5517\/ccdc.csd.cc2n03f7"},{"key":"D5SC02852C\/cit41e\/1","doi-asserted-by":"publisher","DOI":"10.5517\/ccdc.csd.cc2n03g8","author":"Liu","year":"2025","unstructured":"H.Liu ,  H. M.Scott ,  B.Lin ,  X.Huang ,  M. D.Smith  and  K. D.Shimizu ,  CCDC 2442969: Experimental Crystal Structure Determination ,  2025 ,  10.5517\/ccdc.csd.cc2n03g8"},{"key":"D5SC02852C\/cit41f\/1","doi-asserted-by":"publisher","DOI":"10.5517\/ccdc.csd.cc2n03jb","author":"Liu","year":"2025","unstructured":"H.Liu ,  H. M.Scott ,  B.Lin ,  X.Huang ,  M. D.Smith  and  K. D.Shimizu ,  CCDC 2442971: Experimental Crystal Structure Determination ,  2025 ,  10.5517\/ccdc.csd.cc2n03jb"},{"key":"D5SC02852C\/cit41g\/1","doi-asserted-by":"publisher","DOI":"10.5517\/ccdc.csd.cc2n03ld","author":"Liu","year":"2025","unstructured":"H.Liu ,  H. M.Scott ,  B.Lin ,  X.Huang ,  M. D.Smith  and  K. D.Shimizu ,  CCDC 2442973: Experimental Crystal Structure Determination ,  2025 ,  10.5517\/ccdc.csd.cc2n03ld"}],"container-title":["Chemical Science"],"original-title":[],"language":"en","link":[{"URL":"http:\/\/pubs.rsc.org\/en\/content\/articlepdf\/2025\/SC\/D5SC02852C","content-type":"application\/pdf","content-version":"vor","intended-application":"syndication"},{"URL":"http:\/\/pubs.rsc.org\/en\/content\/articlepdf\/2025\/SC\/D5SC02852C","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,7,2]],"date-time":"2026-07-02T03:37:20Z","timestamp":1782963440000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.rsc.org\/sc\/article\/16\/38\/17772-17778\/910410"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2025]]},"references-count":47,"journal-issue":{"issue":"38","published-print":{"date-parts":[[2025,10,1]]}},"URL":"https:\/\/doi.org\/10.1039\/d5sc02852c","relation":{},"ISSN":["2041-6520","2041-6539"],"issn-type":[{"value":"2041-6520","type":"print"},{"value":"2041-6539","type":"electronic"}],"subject":[],"published":{"date-parts":[[2025]]}}}