{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,7,1]],"date-time":"2026-07-01T19:35:15Z","timestamp":1782934515448,"version":"3.54.5"},"reference-count":42,"publisher":"Royal Society of Chemistry (RSC)","issue":"41","license":[{"start":{"date-parts":[[2025,9,17]],"date-time":"2025-09-17T00:00:00Z","timestamp":1758067200000},"content-version":"vor","delay-in-days":259,"URL":"http:\/\/creativecommons.org\/licenses\/by-nc\/3.0\/"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22301291"],"award-info":[{"award-number":["22301291"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22471254"],"award-info":[{"award-number":["22471254"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100011245","name":"State Key Laboratory of Coordination Chemistry","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100011245","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100008048","name":"Nanjing University","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100008048","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["rsc.org"],"crossmark-restriction":true},"short-container-title":["Chem. Sci."],"abstract":"<jats:p>\n                    We developed a dirhodium(\n                    <jats:sc>ii<\/jats:sc>\n                    )\/bisphosphine-catalyzed desymmetrization reaction of benzobicyclo[2.2.1]heptane-2,3-diones with various arylboronic acids. The corresponding products could be transformed into several types of chiral bridged molecules.\n                  <\/jats:p>","DOI":"10.1039\/d5sc03779d","type":"journal-article","created":{"date-parts":[[2025,9,17]],"date-time":"2025-09-17T09:41:03Z","timestamp":1758102063000},"page":"19397-19402","update-policy":"https:\/\/doi.org\/10.1039\/rsc_crossmark_policy","source":"Crossref","is-referenced-by-count":1,"title":["Chiral benzo[2.2.1] \u03b1-hydroxyketones from a dirhodium(\n                    <scp>ii<\/scp>\n                    )\/bisphosphine-catalyzed desymmetrization addition reaction"],"prefix":"10.1039","volume":"16","author":[{"given":"Shuming","family":"Zhan","sequence":"first","affiliation":[{"name":"Department of Chemistry, University of Science and Technology of China, 96 Jinzhai Road, Hefei, Anhui 230026, P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Chengyu","family":"Wang","sequence":"additional","affiliation":[{"name":"Department of Chemistry, University of Science and Technology of China, 96 Jinzhai Road, Hefei, Anhui 230026, P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Longhui","family":"Duan","sequence":"additional","affiliation":[{"name":"Department of Chemistry, University of Science and Technology of China, 96 Jinzhai Road, Hefei, Anhui 230026, P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-8168-2012","authenticated-orcid":false,"given":"Zhenhua","family":"Gu","sequence":"additional","affiliation":[{"name":"Department of Chemistry, University of Science and Technology of China, 96 Jinzhai Road, Hefei, Anhui 230026, P. R. China"},{"name":"State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093, P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"292","published-online":{"date-parts":[[2025]]},"reference":[{"key":"D5SC03779D\/cit1a\/1","doi-asserted-by":"crossref","first-page":"1627","DOI":"10.1039\/C9NP00037B","volume":"37","author":"Liu","year":"2020","journal-title":"Nat. Prod. Rep."},{"key":"D5SC03779D\/cit1b\/1","first-page":"1368","volume":"41","author":"Zhou","year":"2024","journal-title":"Nat. Prod. Rep."},{"key":"D5SC03779D\/cit2a\/1","doi-asserted-by":"crossref","first-page":"7737","DOI":"10.1039\/C4CS00477A","volume":"44","author":"Stockdale","year":"2015","journal-title":"Chem. Soc. Rev."},{"key":"D5SC03779D\/cit2b\/1","doi-asserted-by":"crossref","first-page":"2030","DOI":"10.1039\/D2NP00039C","volume":"39","author":"Chang","year":"2022","journal-title":"Nat. Prod. 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