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Sci."],"abstract":"<jats:p>We describe the synthesis of an isolable phosphinidene sulfide and phosphinidene selenide (BnArNP\ue001Ch; Ch = S, Se) by reaction of a sterically protected phosphinidene oxide (BnArNP\ue001O) with Lawesson's or Woollins' reagents, respectively.<\/jats:p>","DOI":"10.1039\/d5sc04352b","type":"journal-article","created":{"date-parts":[[2025,7,10]],"date-time":"2025-07-10T09:31:22Z","timestamp":1752139882000},"page":"14690-14697","update-policy":"https:\/\/doi.org\/10.1039\/rsc_crossmark_policy","source":"Crossref","is-referenced-by-count":6,"title":["Isolation of a phosphinidene sulfide and selenide"],"prefix":"10.1039","volume":"16","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-8475-6168","authenticated-orcid":false,"given":"Chenyang","family":"Hu","sequence":"first","affiliation":[{"name":"Department of Chemistry, Indiana University, 800 East Kirkwood Ave., Bloomington, Indiana, 47405, USA"},{"name":"Department of Chemistry, University of Oxford, Chemistry Research Laboratory, 12 Mansfield Rd., Oxford, OX1 3TA, UK"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Maren","family":"Pink","sequence":"additional","affiliation":[{"name":"Department of Chemistry, University of Oxford, Chemistry Research Laboratory, 12 Mansfield Rd., Oxford, OX1 3TA, UK"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-7311-1663","authenticated-orcid":false,"given":"Jose M.","family":"Goicoechea","sequence":"additional","affiliation":[{"name":"Department of Chemistry, Indiana University, 800 East Kirkwood Ave., Bloomington, Indiana, 47405, USA"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"292","published-online":{"date-parts":[[2025]]},"reference":[{"key":"D5SC04352B\/cit1\/1","doi-asserted-by":"crossref","first-page":"315","DOI":"10.1002\/anie.198903151","volume":"28","author":"Fritz","year":"1989","journal-title":"Angew Chem. 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