{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,8,4]],"date-time":"2026-08-04T02:36:28Z","timestamp":1785810988069,"version":"3.56.0"},"reference-count":72,"publisher":"Royal Society of Chemistry (RSC)","issue":"47","license":[{"start":{"date-parts":[[2025,10,17]],"date-time":"2025-10-17T00:00:00Z","timestamp":1760659200000},"content-version":"vor","delay-in-days":289,"URL":"http:\/\/creativecommons.org\/licenses\/by\/3.0\/"}],"funder":[{"DOI":"10.13039\/100012542","name":"Sichuan Province Science and Technology Support Program","doi-asserted-by":"publisher","award":["2025ZNSFSC0124"],"award-info":[{"award-number":["2025ZNSFSC0124"]}],"id":[{"id":"10.13039\/100012542","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["rsc.org"],"crossmark-restriction":true},"short-container-title":["Chem. Sci."],"abstract":"<jats:p>\n                    The palladium-catalysed asymmetric (3 + 2) annulations of Morita\u2013Baylis\u2013Hillman carbonates with allenes and alkenes are reported\n                    <jats:italic>via<\/jats:italic>\n                    a cascade oxidative addition\/migratory insertion\/vinylogous deprotonation\/isomerisation\/allyllation sequence.\n                  <\/jats:p>","DOI":"10.1039\/d5sc06910f","type":"journal-article","created":{"date-parts":[[2025,10,17]],"date-time":"2025-10-17T01:21:24Z","timestamp":1760664084000},"page":"22456-22464","update-policy":"https:\/\/doi.org\/10.1039\/rsc_crossmark_policy","source":"Crossref","is-referenced-by-count":1,"title":["Palladium-catalysed asymmetric annulations of Morita\u2013Baylis\u2013Hillman carbonates with allenes or alkenes\n                    <i>via<\/i>\n                    migratory insertion"],"prefix":"10.1039","volume":"16","author":[{"given":"Jin-Yu","family":"Huang","sequence":"first","affiliation":[{"name":"Key Laboratory of Drug-Targeting and Drug Delivery System of the Education Ministry and Sichuan Province and Sichuan Research Center for Drug Precision Industrial Technology, West China School of Pharmacy, Sichuan University, Chengdu 610041, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xin-Ting","family":"Qin","sequence":"additional","affiliation":[{"name":"Key Laboratory of Drug-Targeting and Drug Delivery System of the Education Ministry and Sichuan Province and Sichuan Research Center for Drug Precision Industrial Technology, West China School of Pharmacy, Sichuan University, Chengdu 610041, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Han-Wen","family":"Rao","sequence":"additional","affiliation":[{"name":"Key Laboratory of Drug-Targeting and Drug Delivery System of the Education Ministry and Sichuan Province and Sichuan Research Center for Drug Precision Industrial Technology, West China School of Pharmacy, Sichuan University, Chengdu 610041, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhi-Chao","family":"Chen","sequence":"additional","affiliation":[{"name":"Key Laboratory of Drug-Targeting and Drug Delivery System of the Education Ministry and Sichuan Province and Sichuan Research Center for Drug Precision Industrial Technology, West China School of Pharmacy, Sichuan University, Chengdu 610041, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-7870-8469","authenticated-orcid":false,"given":"Lei","family":"Zhu","sequence":"additional","affiliation":[{"name":"College of Pharmacy, Third Military Medical University, Shapingba, Chongqing 400038, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-1161-5102","authenticated-orcid":false,"given":"Qin","family":"Ouyang","sequence":"additional","affiliation":[{"name":"College of Pharmacy, Third Military Medical University, Shapingba, Chongqing 400038, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4162-1471","authenticated-orcid":false,"given":"Wei","family":"Du","sequence":"additional","affiliation":[{"name":"Key Laboratory of Drug-Targeting and Drug Delivery System of the Education Ministry and Sichuan Province and Sichuan Research Center for Drug Precision Industrial Technology, West China School of Pharmacy, Sichuan University, Chengdu 610041, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-1902-0979","authenticated-orcid":false,"given":"Ying-Chun","family":"Chen","sequence":"additional","affiliation":[{"name":"Key Laboratory of Drug-Targeting and Drug Delivery System of the Education Ministry and Sichuan Province and Sichuan Research Center for Drug Precision Industrial Technology, West China School of Pharmacy, Sichuan University, Chengdu 610041, China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"292","published-online":{"date-parts":[[2025]]},"reference":[{"key":"D5SC06910F\/cit1a\/1","doi-asserted-by":"crossref","first-page":"1","DOI":"10.1248\/cpb.50.1","volume":"50","author":"Trost","year":"2002","journal-title":"Chem. Pharm. Bull."},{"key":"D5SC06910F\/cit1b\/1","doi-asserted-by":"crossref","first-page":"1892","DOI":"10.1055\/s-0037-1611745","volume":"51","author":"Parisotto","year":"2019","journal-title":"Synthesis"},{"key":"D5SC06910F\/cit1c\/1","doi-asserted-by":"crossref","first-page":"4373","DOI":"10.1021\/acs.chemrev.0c00736","volume":"121","author":"P\u00e0mies","year":"2021","journal-title":"Chem. Rev."},{"key":"D5SC06910F\/cit1d\/1","doi-asserted-by":"crossref","first-page":"29","DOI":"10.1002\/tcr.202000086","volume":"21","author":"Mohammadkhani","year":"2021","journal-title":"Chem. Rec."},{"key":"D5SC06910F\/cit1e\/1","doi-asserted-by":"crossref","first-page":"3475","DOI":"10.1039\/D1QO00273B","volume":"8","author":"Niu","year":"2021","journal-title":"Org. Chem. Front."},{"key":"D5SC06910F\/cit1f\/1","doi-asserted-by":"crossref","first-page":"883","DOI":"10.1039\/D3CS00489A","volume":"53","author":"Xu","year":"2024","journal-title":"Chem. Soc. Rev."},{"key":"D5SC06910F\/cit2a\/1","doi-asserted-by":"crossref","first-page":"7929","DOI":"10.1039\/C5CS00144G","volume":"44","author":"Butt","year":"2015","journal-title":"Chem. Soc. Rev."},{"key":"D5SC06910F\/cit2b\/1","doi-asserted-by":"crossref","first-page":"25","DOI":"10.2174\/2211544705666161117163521","volume":"6","author":"Qian","year":"2017","journal-title":"Curr. Catal."},{"key":"D5SC06910F\/cit2c\/1","doi-asserted-by":"crossref","first-page":"3638","DOI":"10.1039\/D0OB00458H","volume":"18","author":"Li","year":"2020","journal-title":"Org. Biomol. Chem."},{"key":"D5SC06910F\/cit2d\/1","doi-asserted-by":"crossref","first-page":"e202101887","DOI":"10.1002\/cctc.202101887","volume":"14","author":"You","year":"2022","journal-title":"ChemCatChem"},{"key":"D5SC06910F\/cit3a\/1","doi-asserted-by":"crossref","first-page":"3079","DOI":"10.1055\/s-0035-1560465","volume":"47","author":"Mann","year":"2015","journal-title":"Synthesis"},{"key":"D5SC06910F\/cit3b\/1","doi-asserted-by":"crossref","first-page":"2841","DOI":"10.1021\/acs.accounts.0c00477","volume":"53","author":"Wang","year":"2020","journal-title":"Acc. Chem. Res."},{"key":"D5SC06910F\/cit4a\/1","doi-asserted-by":"crossref","first-page":"2060","DOI":"10.1039\/C9CS00400A","volume":"49","author":"Li","year":"2020","journal-title":"Chem. Soc. Rev."},{"key":"D5SC06910F\/cit4b\/1","doi-asserted-by":"crossref","first-page":"e202200295","DOI":"10.1002\/cctc.202200295","volume":"14","author":"Cera","year":"2022","journal-title":"ChemCatChem"},{"key":"D5SC06910F\/cit4c\/1","first-page":"124","volume":"4","author":"Li","year":"2023","journal-title":"Green Synth. Catal."},{"key":"D5SC06910F\/cit5a\/1","doi-asserted-by":"crossref","first-page":"8647","DOI":"10.1039\/C9OB01725A","volume":"17","author":"Fernandes","year":"2019","journal-title":"Org. Biomol. Chem."},{"key":"D5SC06910F\/cit5b\/1","doi-asserted-by":"crossref","first-page":"27288","DOI":"10.1002\/anie.202112285","volume":"60","author":"Yang","year":"2021","journal-title":"Angew. Chem., Int. Ed."},{"key":"D5SC06910F\/cit5c\/1","doi-asserted-by":"crossref","first-page":"1118","DOI":"10.1038\/s41557-022-01023-x","volume":"14","author":"Jin","year":"2022","journal-title":"Nat. Chem."},{"key":"D5SC06910F\/cit5d\/1","doi-asserted-by":"crossref","first-page":"1295","DOI":"10.1016\/j.chempr.2024.02.006","volume":"10","author":"Liu","year":"2024","journal-title":"Chem"},{"key":"D5SC06910F\/cit5e\/1","doi-asserted-by":"crossref","first-page":"1067","DOI":"10.1126\/science.ado8027","volume":"385","author":"Kaster","year":"2024","journal-title":"Science"},{"key":"D5SC06910F\/cit6a\/1","doi-asserted-by":"crossref","first-page":"1159","DOI":"10.1039\/C7CS00449D","volume":"47","author":"Spielmann","year":"2018","journal-title":"Chem. Soc. Rev."},{"key":"D5SC06910F\/cit6b\/1","doi-asserted-by":"crossref","first-page":"1135","DOI":"10.1039\/c0sc00645a","volume":"2","author":"Zhu","year":"2011","journal-title":"Chem. Sci."},{"key":"D5SC06910F\/cit6c\/1","doi-asserted-by":"crossref","first-page":"16391","DOI":"10.1002\/chem.201503359","volume":"21","author":"Mita","year":"2015","journal-title":"Chem.\u2013Eur. J."},{"key":"D5SC06910F\/cit6d\/1","doi-asserted-by":"crossref","first-page":"5418","DOI":"10.1039\/D1QO00505G","volume":"8","author":"Li","year":"2021","journal-title":"Org. Chem. Front."},{"key":"D5SC06910F\/cit7a\/1","doi-asserted-by":"crossref","first-page":"1562","DOI":"10.1002\/anie.201806088","volume":"58","author":"Ping","year":"2019","journal-title":"Angew. Chem., Int. Ed."},{"key":"D5SC06910F\/cit7b\/1","doi-asserted-by":"crossref","first-page":"734","DOI":"10.1021\/acs.accounts.1c00781","volume":"55","author":"Liang","year":"2022","journal-title":"Acc. Chem. Res."},{"key":"D5SC06910F\/cit7c\/1","doi-asserted-by":"crossref","first-page":"e202400076","DOI":"10.1002\/chem.202400076","volume":"30","author":"Zhao","year":"2024","journal-title":"Chem.\u2013Eur. J."},{"key":"D5SC06910F\/cit8\/1","doi-asserted-by":"crossref","first-page":"7723","DOI":"10.1021\/ja00777a600","volume":"94","author":"Hughes","year":"1972","journal-title":"J. Am. Chem. Soc."},{"key":"D5SC06910F\/cit9a\/1","doi-asserted-by":"crossref","first-page":"564","DOI":"10.1126\/science.aau4821","volume":"362","author":"Trost","year":"2018","journal-title":"Science"},{"key":"D5SC06910F\/cit9b\/1","doi-asserted-by":"crossref","first-page":"6396","DOI":"10.1002\/anie.201900693","volume":"58","author":"Trost","year":"2019","journal-title":"Angew. Chem., Int. Ed."},{"key":"D5SC06910F\/cit9c\/1","doi-asserted-by":"crossref","first-page":"3595","DOI":"10.1021\/jacs.0c13412","volume":"143","author":"Chai","year":"2021","journal-title":"J. Am. Chem. Soc."},{"key":"D5SC06910F\/cit9d\/1","doi-asserted-by":"crossref","first-page":"19627","DOI":"10.1021\/jacs.2c09799","volume":"144","author":"Zhang","year":"2022","journal-title":"J. Am. Chem. Soc."},{"key":"D5SC06910F\/cit10\/1","doi-asserted-by":"crossref","first-page":"12382","DOI":"10.1021\/jacs.9b05762","volume":"141","author":"Zou","year":"2019","journal-title":"J. Am. Chem. Soc."},{"key":"D5SC06910F\/cit11a\/1","doi-asserted-by":"crossref","first-page":"10491","DOI":"10.1021\/jacs.3c03102","volume":"145","author":"Witkowski","year":"2023","journal-title":"J. Am. Chem. Soc."},{"key":"D5SC06910F\/cit11b\/1","doi-asserted-by":"crossref","first-page":"e202213676","DOI":"10.1002\/anie.202213676","volume":"62","author":"Xu","year":"2023","journal-title":"Angew. Chem., Int. Ed."},{"key":"D5SC06910F\/cit12\/1","doi-asserted-by":"crossref","first-page":"12824","DOI":"10.1021\/acscatal.4c04038","volume":"14","author":"Yan","year":"2024","journal-title":"ACS Catal."},{"key":"D5SC06910F\/cit13a\/1","doi-asserted-by":"crossref","first-page":"8578","DOI":"10.1039\/C5OB00865D","volume":"13","author":"Xie","year":"2015","journal-title":"Org. Biomol. Chem."},{"key":"D5SC06910F\/cit13b\/1","doi-asserted-by":"crossref","first-page":"541","DOI":"10.1002\/tcr.201900058","volume":"20","author":"Chen","year":"2020","journal-title":"Chem. Rec."},{"key":"D5SC06910F\/cit13c\/1","first-page":"2922","volume":"52","author":"Calcatelli","year":"2020","journal-title":"Synthesis"},{"key":"D5SC06910F\/cit13d\/1","doi-asserted-by":"crossref","first-page":"2076","DOI":"10.1039\/D4QO02212B","volume":"12","author":"Duan","year":"2025","journal-title":"Org. Chem. Front."},{"key":"D5SC06910F\/cit14\/1","doi-asserted-by":"crossref","first-page":"100","DOI":"10.1021\/acs.orglett.1c03689","volume":"24","author":"He","year":"2022","journal-title":"Org. Lett."},{"key":"D5SC06910F\/cit15a\/1","doi-asserted-by":"crossref","first-page":"1","DOI":"10.1021\/cr60053a001","volume":"16","author":"Fuson","year":"1935","journal-title":"Chem. Rev."},{"key":"D5SC06910F\/cit15b\/1","doi-asserted-by":"crossref","first-page":"2448","DOI":"10.1021\/acs.chemrev.9b00481","volume":"120","author":"Curti","year":"2020","journal-title":"Chem. Rev."},{"key":"D5SC06910F\/cit17a\/1","doi-asserted-by":"crossref","first-page":"132","DOI":"10.1021\/om010541c","volume":"21","author":"Trzeciak","year":"2002","journal-title":"Organometallics"},{"key":"D5SC06910F\/cit17b\/1","doi-asserted-by":"crossref","first-page":"2797","DOI":"10.1021\/acs.orglett.1c00716","volume":"23","author":"Bajohr","year":"2021","journal-title":"Org. Lett."},{"key":"D5SC06910F\/cit18a\/1","doi-asserted-by":"crossref","first-page":"4430","DOI":"10.1021\/ja00194a043","volume":"111","author":"Trost","year":"1989","journal-title":"J. Am. Chem. Soc."},{"key":"D5SC06910F\/cit18b\/1","doi-asserted-by":"crossref","first-page":"615","DOI":"10.1016\/S0040-4039(00)94582-9","volume":"31","author":"Trost","year":"1990","journal-title":"Tetrahedron Lett."},{"key":"D5SC06910F\/cit18c\/1","doi-asserted-by":"crossref","first-page":"1173","DOI":"10.1021\/jo00057a033","volume":"58","author":"Ohe","year":"1993","journal-title":"J. Org. Chem."},{"key":"D5SC06910F\/cit18d\/1","doi-asserted-by":"crossref","first-page":"4971","DOI":"10.1021\/jo951425k","volume":"61","author":"Ikeda","year":"1996","journal-title":"J. Org. Chem."},{"key":"D5SC06910F\/cit19a\/1","doi-asserted-by":"crossref","first-page":"26","DOI":"10.1002\/1521-3773(20020104)41:1<26::AID-ANIE26>3.0.CO;2-9","volume":"41","author":"Fagnou","year":"2002","journal-title":"Angew. Chem., Int. Ed."},{"key":"D5SC06910F\/cit19b\/1","doi-asserted-by":"crossref","first-page":"4277","DOI":"10.1002\/ejoc.200500345","author":"Cantat","year":"2005","journal-title":"Eur. J. Org Chem."},{"key":"D5SC06910F\/cit19c\/1","doi-asserted-by":"crossref","first-page":"3744","DOI":"10.1016\/j.tet.2008.02.019","volume":"64","author":"Knight","year":"2008","journal-title":"Tetrahedron"},{"key":"D5SC06910F\/cit19d\/1","doi-asserted-by":"crossref","first-page":"6370","DOI":"10.1002\/anie.201101389","volume":"50","author":"Lowe","year":"2011","journal-title":"Angew. Chem., Int. Ed."},{"key":"D5SC06910F\/cit19e\/1","doi-asserted-by":"crossref","first-page":"13744","DOI":"10.1021\/acs.joc.4c01425","volume":"89","author":"Chao","year":"2024","journal-title":"J. Org. Chem."},{"key":"D5SC06910F\/cit20a\/1","doi-asserted-by":"crossref","first-page":"6973","DOI":"10.1002\/anie.201602075","volume":"55","author":"Tabuchi","year":"2016","journal-title":"Angew. Chem., Int. Ed."},{"key":"D5SC06910F\/cit20b\/1","doi-asserted-by":"crossref","first-page":"12102","DOI":"10.1002\/anie.201806742","volume":"57","author":"Schwarz","year":"2018","journal-title":"Angew. Chem., Int. Ed."},{"key":"D5SC06910F\/cit20c\/1","doi-asserted-by":"crossref","first-page":"12952","DOI":"10.1021\/acscatal.3c03650","volume":"13","author":"Sun","year":"2023","journal-title":"ACS Catal."},{"key":"D5SC06910F\/cit21\/1","doi-asserted-by":"crossref","first-page":"2297","DOI":"10.1016\/j.tet.2010.02.001","volume":"66","author":"Guo","year":"2010","journal-title":"Tetrahedron"},{"key":"D5SC06910F\/cit22a\/1","doi-asserted-by":"crossref","first-page":"37","DOI":"10.1016\/S0022-328X(01)01066-X","volume":"635","author":"Kubas","year":"2001","journal-title":"J. Organomet. Chem."},{"key":"D5SC06910F\/cit22b\/1","doi-asserted-by":"crossref","first-page":"4809","DOI":"10.1021\/jacs.1c01420","volume":"143","author":"Xiao","year":"2021","journal-title":"J. Am. Chem. Soc."},{"key":"D5SC06910F\/cit22c\/1","doi-asserted-by":"crossref","first-page":"17989","DOI":"10.1021\/jacs.1c09877","volume":"143","author":"He","year":"2021","journal-title":"J. Am. Chem. Soc."},{"key":"D5SC06910F\/cit22d\/1","doi-asserted-by":"crossref","first-page":"6422","DOI":"10.1021\/jacs.3c14674","volume":"146","author":"Chen","year":"2024","journal-title":"J. Am. Chem. Soc."},{"key":"D5SC06910F\/cit23a\/1","doi-asserted-by":"crossref","first-page":"8060","DOI":"10.1002\/chem.200701643","volume":"14","author":"Steinreiber","year":"2008","journal-title":"Chem.\u2013Eur. J."},{"key":"D5SC06910F\/cit23b\/1","doi-asserted-by":"crossref","first-page":"4528","DOI":"10.1021\/acs.chemrev.6b00731","volume":"117","author":"Bhat","year":"2017","journal-title":"Chem. Rev."},{"key":"D5SC06910F\/cit23c\/1","doi-asserted-by":"crossref","first-page":"5987","DOI":"10.1002\/anie.200352857","volume":"42","author":"Trost","year":"2003","journal-title":"Angew. Chem., Int. Ed."},{"key":"D5SC06910F\/cit23d\/1","doi-asserted-by":"crossref","first-page":"7014","DOI":"10.1021\/ja050340q","volume":"127","author":"Trost","year":"2005","journal-title":"J. Am. Chem. Soc."},{"key":"D5SC06910F\/cit23e\/1","doi-asserted-by":"crossref","first-page":"12622","DOI":"10.1021\/jacs.1c05087","volume":"143","author":"Zhang","year":"2021","journal-title":"J. Am. Chem. Soc."},{"key":"D5SC06910F\/cit24a\/1","doi-asserted-by":"publisher","year":"2025","unstructured":"CCDC 2473163: Experimental Crystal Structure Determination ,  2025 ,  10.5517\/ccdc.csd.cc2p0jgq","DOI":"10.5517\/ccdc.csd.cc2p0jgq"},{"key":"D5SC06910F\/cit24b\/1","doi-asserted-by":"publisher","year":"2025","unstructured":"CCDC 2476164: Experimental Crystal Structure Determination ,  2025 ,  10.5517\/ccdc.csd.cc2p3n8r","DOI":"10.5517\/ccdc.csd.cc2p3n8r"},{"key":"D5SC06910F\/cit24c\/1","doi-asserted-by":"publisher","year":"2025","unstructured":"CCDC 2476165: Experimental Crystal Structure Determination ,  2025 ,  10.5517\/ccdc.csd.cc2p3n9s","DOI":"10.5517\/ccdc.csd.cc2p3n9s"},{"key":"D5SC06910F\/cit24d\/1","doi-asserted-by":"publisher","year":"2025","unstructured":"CCDC 2476166: Experimental Crystal Structure Determination ,  2025 ,  10.5517\/ccdc.csd.cc2p3nbt","DOI":"10.5517\/ccdc.csd.cc2p3nbt"},{"key":"D5SC06910F\/cit24e\/1","doi-asserted-by":"publisher","year":"2025","unstructured":"CCDC 2476167: Experimental Crystal Structure Determination ,  2025 ,  10.5517\/ccdc.csd.cc2p3ncv","DOI":"10.5517\/ccdc.csd.cc2p3ncv"}],"container-title":["Chemical Science"],"original-title":[],"language":"en","link":[{"URL":"http:\/\/pubs.rsc.org\/en\/content\/articlepdf\/2025\/SC\/D5SC06910F","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,6,30]],"date-time":"2026-06-30T20:41:34Z","timestamp":1782852094000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.rsc.org\/sc\/article\/16\/47\/22456-22464\/911257"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2025]]},"references-count":72,"journal-issue":{"issue":"47","published-print":{"date-parts":[[2025,12,3]]}},"URL":"https:\/\/doi.org\/10.1039\/d5sc06910f","relation":{},"ISSN":["2041-6520","2041-6539"],"issn-type":[{"value":"2041-6520","type":"print"},{"value":"2041-6539","type":"electronic"}],"subject":[],"published":{"date-parts":[[2025]]}}}