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Sci."],"abstract":"<jats:p>\n                    The isolation and characterization of the first series of homoleptic bismuth phosphanides aBi(PRR\u2019)\n                    <jats:sub>3<\/jats:sub>\n                    is presented (R, R\u2019 = alkyl). Radical pathways enable phosphorus inversion and the (reversible) activation of \u03b1-olefins, including ethylene.\n                  <\/jats:p>","DOI":"10.1039\/d5sc07240a","type":"journal-article","created":{"date-parts":[[2026,1,8]],"date-time":"2026-01-08T10:40:46Z","timestamp":1767868846000},"page":"5183-5191","update-policy":"https:\/\/doi.org\/10.1039\/rsc_crossmark_policy","source":"Crossref","is-referenced-by-count":2,"title":["The bismuth phosphanides Bi(PR\n                    <sub>2<\/sub>\n                    )\n                    <sub>3<\/sub>\n                    : sources of phosphanyl radicals, P-inversion, and reversible olefin insertion"],"prefix":"10.1039","volume":"17","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-2747-0809","authenticated-orcid":false,"given":"Sascha","family":"Reith","sequence":"first","affiliation":[{"name":"Department of Chemistry, Philipps-University Marburg, Hans-Meerwein-Str. 4, D-35032 Marburg (D), Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Kai","family":"Oberdorf","sequence":"additional","affiliation":[{"name":"Department of Chemistry, Philipps-University Marburg, Hans-Meerwein-Str. 4, D-35032 Marburg (D), Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Sebsti\u00e1n","family":"Mart\u00ednez","sequence":"additional","affiliation":[{"name":"Department of Chemistry, Philipps-University Marburg, Hans-Meerwein-Str. 4, D-35032 Marburg (D), Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0004-5783-9461","authenticated-orcid":false,"given":"Jann B.","family":"Landgraf","sequence":"additional","affiliation":[{"name":"Department of Inorganic Chemistry, Julius-Maximilians-Universit\u00e4t W\u00fcrzburg, Am Hubland, D-97074 W\u00fcrzburg (D), Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Alena","family":"Ahrens","sequence":"additional","affiliation":[{"name":"Department of Chemistry, Philipps-University Marburg, Hans-Meerwein-Str. 4, D-35032 Marburg (D), Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Felix","family":"Jakobi","sequence":"additional","affiliation":[{"name":"Department of Chemistry, Philipps-University Marburg, Hans-Meerwein-Str. 4, D-35032 Marburg (D), Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xiulan","family":"Xie","sequence":"additional","affiliation":[{"name":"Department of Chemistry, Philipps-University Marburg, Hans-Meerwein-Str. 4, D-35032 Marburg (D), Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-0176-0939","authenticated-orcid":false,"given":"Crispin","family":"Lichtenberg","sequence":"additional","affiliation":[{"name":"Department of Chemistry, Philipps-University Marburg, Hans-Meerwein-Str. 4, D-35032 Marburg (D), Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"292","published-online":{"date-parts":[[2026]]},"reference":[{"key":"D5SC07240A\/cit1\/1","doi-asserted-by":"crossref","first-page":"412","DOI":"10.1039\/C6CC07864H","volume":"53","author":"Hickey","year":"2016","journal-title":"Chem. 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