{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,7,1]],"date-time":"2026-07-01T23:13:32Z","timestamp":1782947612613,"version":"3.54.5"},"reference-count":30,"publisher":"Royal Society of Chemistry (RSC)","issue":"29","license":[{"start":{"date-parts":[[2026,6,11]],"date-time":"2026-06-11T00:00:00Z","timestamp":1781136000000},"content-version":"am","delay-in-days":526,"URL":"http:\/\/rsc.li\/journals-terms-of-use"}],"funder":[{"DOI":"10.13039\/501100001691","name":"Japan Society for the Promotion of Science","doi-asserted-by":"publisher","award":["23K03346"],"award-info":[{"award-number":["23K03346"]}],"id":[{"id":"10.13039\/501100001691","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["rsc.org"],"crossmark-restriction":true},"short-container-title":["Soft Matter"],"abstract":"<jats:p>\n                    Deviation of kinematic viscosity\n                    <jats:italic>\u03bd<\/jats:italic>\n                    (square) and dielectric time\n                    <jats:italic>\u03c4<\/jats:italic>\n                    <jats:sub>\n                      <jats:italic>\u03b5<\/jats:italic>\n                    <\/jats:sub>\n                    (circle) from respective high-\n                    <jats:italic>T<\/jats:italic>\n                    asymptotes noted for 5CB\/DMT mixtures. Red curves\/asterisks show the deviation of\n                    <jats:italic>\u03c4<\/jats:italic>\n                    <jats:sub>\n                      <jats:italic>\u03b5<\/jats:italic>\n                    <\/jats:sub>\n                    resulting from that of\n                    <jats:italic>\u03bd<\/jats:italic>\n                    deduced from free energy analysis.\n                  <\/jats:p>","DOI":"10.1039\/d5sm00375j","type":"journal-article","created":{"date-parts":[[2025,6,11]],"date-time":"2025-06-11T07:00:42Z","timestamp":1749625242000},"page":"5902-5920","update-policy":"https:\/\/doi.org\/10.1039\/rsc_crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Phase equilibrium and dynamics of 5CB mixed with dimethyl terephthalate: coupling of orientation and composition fluctuations in isotropic phase"],"prefix":"10.1039","volume":"21","author":[{"given":"Ryoko","family":"Shimada","sequence":"first","affiliation":[{"name":"Department of Mathematics, Physics and Computer Science, Japan Women's University, Bunkyo-ku, Tokyo 112-8681, Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5071-208X","authenticated-orcid":false,"given":"Osamu","family":"Urakawa","sequence":"additional","affiliation":[{"name":"Department of Macromolecular Science, Faculty of Science, Osaka University, Toyonaka, Osaka 560-0041, Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9934-1299","authenticated-orcid":false,"given":"Tadashi","family":"Inoue","sequence":"additional","affiliation":[{"name":"Department of Macromolecular Science, Faculty of Science, Osaka University, Toyonaka, Osaka 560-0041, Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0826-2454","authenticated-orcid":false,"given":"Hiroshi","family":"Watanabe","sequence":"additional","affiliation":[{"name":"Institute for Chemical Research, Kyoto University Uji, Kyoto 611-0011, Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"292","published-online":{"date-parts":[[2025]]},"reference":[{"key":"D5SM00375J\/cit1\/1","volume-title":"Physical Properties of Liquid Crystalline Materials","author":"de Jeu","year":"1980","unstructured":"W. H.de Jeu ,  Physical Properties of Liquid Crystalline Materials ,  Gordon and Breach Science Publishers ,  New York ,  1980"},{"key":"D5SM00375J\/cit2\/1","doi-asserted-by":"crossref","DOI":"10.1093\/oso\/9780198520245.001.0001","volume-title":"The Physics of Liquid Crystals","author":"de Gennes","year":"1993","unstructured":"P. G.de Gennes  and  J.Prost ,  The Physics of Liquid Crystals ,  Clarendon Press ,  Oxford , 2nd edn,  1993"},{"key":"D5SM00375J\/cit3\/1","doi-asserted-by":"crossref","first-page":"159","DOI":"10.1007\/0-387-21642-1_6","volume-title":"Chirality in Liquid Crystals","author":"Chilaya","year":"2001","unstructured":"G.Chilaya ,  Cholesteric Liquid Crystals: Optics, Electro-optics, and Photo-optics , in  Chirality in Liquid Crystals , ed.  H.-S. Kitzerow  and  C. Bahr ,  Springer ,  New York ,  2001 , ch. 6,  pp. 159\u2013185"},{"key":"D5SM00375J\/cit4\/1","volume-title":"Ekisho no Butsuri (Physics of Liquid Crystals)","author":"Orihara","year":"2004","unstructured":"H.Orihara ,  Ekisho no Butsuri (Physics of Liquid Crystals) ,  Uchida Roukaku Ho ,  Tokyo ,  2004"},{"key":"D5SM00375J\/cit5\/1","doi-asserted-by":"crossref","first-page":"48","DOI":"10.1002\/adma.200501355","volume":"18","author":"Yokoyama","year":"2006","journal-title":"Adv. Mater."},{"key":"D5SM00375J\/cit6\/1","volume-title":"The Structure and Rheology of Complex Fluids","author":"Larson","year":"1999","unstructured":"R. G.Larson ,  The Structure and Rheology of Complex Fluids ,  Oxford University Press ,  New York ,  1999"},{"key":"D5SM00375J\/cit7\/1","doi-asserted-by":"crossref","first-page":"010701","DOI":"10.1103\/PhysRevE.64.010701","volume":"64","author":"Matsuyama","year":"2001","journal-title":"Phys. Rev. E"},{"key":"D5SM00375J\/cit8\/1","doi-asserted-by":"crossref","first-page":"959","DOI":"10.1122\/1.550151","volume":"34","author":"Burghardt","year":"1990","journal-title":"J. Rheol."},{"key":"D5SM00375J\/cit9\/1","doi-asserted-by":"crossref","first-page":"527","DOI":"10.1080\/02678299608031139","volume":"20","author":"Mather","year":"1996","journal-title":"Liq. Cryst."},{"key":"D5SM00375J\/cit10\/1","doi-asserted-by":"crossref","first-page":"485","DOI":"10.1007\/BF00368126","volume":"36","author":"Mather","year":"1997","journal-title":"Rheol. Acta"},{"key":"D5SM00375J\/cit11\/1","doi-asserted-by":"crossref","first-page":"1447","DOI":"10.1039\/f29767201447","volume":"72","author":"Davies","year":"1976","journal-title":"J. Chem. Soc., Faraday Trans. 2"},{"key":"D5SM00375J\/cit12\/1","doi-asserted-by":"crossref","first-page":"1465","DOI":"10.1051\/jphys:0197700380110146500","volume":"38","author":"Lippens","year":"1977","journal-title":"J. Phys."},{"key":"D5SM00375J\/cit13\/1","doi-asserted-by":"crossref","first-page":"519","DOI":"10.1007\/s003970050139","volume":"37","author":"Watanabe","year":"1998","journal-title":"Rheol. Acta"},{"key":"D5SM00375J\/cit14\/1","doi-asserted-by":"crossref","first-page":"100","DOI":"10.1007\/s003970050160","volume":"38","author":"Watanabe","year":"1999","journal-title":"Rheol. Acta"},{"key":"D5SM00375J\/cit15\/1","doi-asserted-by":"crossref","first-page":"R29","DOI":"10.1103\/PhysRevE.60.R29","volume":"60","author":"Lapena","year":"1999","journal-title":"Phys. Rev. E"},{"key":"D5SM00375J\/cit16\/1","doi-asserted-by":"crossref","first-page":"015702","DOI":"10.1103\/PhysRevLett.93.015702","volume":"93","author":"Araki","year":"2004","journal-title":"Phys. Rev. Lett."},{"key":"D5SM00375J\/cit17\/1","doi-asserted-by":"crossref","first-page":"6044","DOI":"10.1039\/C9SM00921C","volume":"15","author":"Reyes","year":"2019","journal-title":"Soft Matter"},{"key":"D5SM00375J\/cit18\/1","doi-asserted-by":"crossref","first-page":"199","DOI":"10.1678\/rheology.48.199","volume":"48","author":"Shimada","year":"2020","journal-title":"Nihon Reoroji Gakkaishi (J. Soc. Rheol. Japan)"},{"key":"D5SM00375J\/cit19\/1","doi-asserted-by":"crossref","first-page":"6259","DOI":"10.1039\/D1SM00496D","volume":"17","author":"Shimada","year":"2021","journal-title":"Soft Matter"},{"key":"D5SM00375J\/cit20\/1","doi-asserted-by":"crossref","first-page":"1","DOI":"10.1103\/PhysRev.119.1","volume":"119","author":"Helfand","year":"1960","journal-title":"Phys. Rev."},{"key":"D5SM00375J\/cit21\/1","volume-title":"Ekitai no Kouzou to Seishitsu (Structures and Properties of Liquids)","author":"Toda","year":"1976","unstructured":"M.Toda ,  H.Matsuda ,  Y.Hiwatari  and  M.Wadachi ,  Ekitai no Kouzou to Seishitsu (Structures and Properties of Liquids) ,  Iwanami ,  Tokyo ,  1976"},{"key":"D5SM00375J\/cit22\/1","doi-asserted-by":"crossref","first-page":"385","DOI":"10.1007\/978-3-642-56120-7_10","volume-title":"Broadband Dielectric Spectroscopy","author":"Kremer","year":"2003","unstructured":"F.Kremer  and  A.Sch\u00f6nhals ,  Molecular and Collective Dynamics of (Polymeric) Liquid Crystals , in  Broadband Dielectric Spectroscopy , ed.  F. Kremer  and  A. Sch\u00f6nhals ,  Springer ,  New York ,  2003 , ch. 10,  pp. 385\u2013432"},{"key":"D5SM00375J\/cit23\/1","doi-asserted-by":"crossref","DOI":"10.1093\/oso\/9780198520597.001.0001","volume-title":"Polymer Physics","author":"Rubinstein","year":"2003","unstructured":"M.Rubinstein  and  R. H.Colby ,  Polymer Physics ,  Oxford University Press ,  New York ,  2003"},{"key":"D5SM00375J\/cit24\/1","volume-title":"Physical Chemistry","author":"Atkins","year":"2014","unstructured":"P.Atkins  and  J.de Paula ,  Physical Chemistry ,  Oxford University Press ,  Oxford , 10th edn,  2014"},{"key":"D5SM00375J\/cit25\/1","doi-asserted-by":"crossref","first-page":"475","DOI":"10.1021\/je60039a005","volume":"13","author":"Elliott","year":"1968","journal-title":"J. Chem. Eng. Data"},{"key":"D5SM00375J\/cit27\/1","volume-title":"The Theory of Polymer Dynamics","author":"Doi","year":"1986","unstructured":"M.Doi  and  S. F.Edwards ,  The Theory of Polymer Dynamics ,  Clarendon Press ,  Oxford ,  1986"},{"key":"D5SM00375J\/cit28\/1","doi-asserted-by":"crossref","DOI":"10.1093\/acprof:oso\/9780199652952.001.0001","volume-title":"Soft Matter Physics","author":"Doi","year":"2013","unstructured":"M.Doi ,  Soft Matter Physics ,  Oxford University Press ,  Oxford ,  2013"},{"key":"D5SM00375J\/cit29\/1","doi-asserted-by":"crossref","first-page":"127","DOI":"10.1002\/1521-3927(200102)22:3<127::AID-MARC127>3.0.CO;2-S","volume":"22","author":"Watanabe","year":"2001","journal-title":"Macromol. Rapid Commun."},{"key":"D5SM00375J\/cit31\/1","doi-asserted-by":"crossref","first-page":"1","DOI":"10.1007\/BFb0031037","volume":"16","author":"Graessley","year":"1974","journal-title":"Adv. Polym. Sci."},{"key":"D5SM00375J\/cit32\/1","doi-asserted-by":"crossref","first-page":"67","DOI":"10.1007\/BFb0038532","volume":"47","author":"Graessley","year":"1982","journal-title":"Adv. Polym. Sci."}],"container-title":["Soft Matter"],"original-title":[],"language":"en","link":[{"URL":"http:\/\/pubs.rsc.org\/en\/content\/articlepdf\/2025\/SM\/D5SM00375J","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,7,1]],"date-time":"2026-07-01T22:04:41Z","timestamp":1782943481000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.rsc.org\/sm\/article\/21\/29\/5902-5920\/912645"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2025]]},"references-count":30,"journal-issue":{"issue":"29","published-print":{"date-parts":[[2025,7,23]]}},"URL":"https:\/\/doi.org\/10.1039\/d5sm00375j","relation":{},"ISSN":["1744-683X","1744-6848"],"issn-type":[{"value":"1744-683X","type":"print"},{"value":"1744-6848","type":"electronic"}],"subject":[],"published":{"date-parts":[[2025]]}}}