{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,4]],"date-time":"2026-09-04T20:38:18Z","timestamp":1788554298369,"version":"build-2803163510"},"reference-count":60,"publisher":"Royal Society of Chemistry (RSC)","issue":"42","license":[{"start":{"date-parts":[[2026,9,27]],"date-time":"2026-09-27T00:00:00Z","timestamp":1790467200000},"content-version":"am","delay-in-days":634,"URL":"http:\/\/rsc.li\/journals-terms-of-use"}],"funder":[{"DOI":"10.13039\/501100008783","name":"National Research Council of Science and Technology","doi-asserted-by":"publisher","award":["GTL24012-000"],"award-info":[{"award-number":["GTL24012-000"]}],"id":[{"id":"10.13039\/501100008783","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100003725","name":"National Research Foundation of Korea","doi-asserted-by":"publisher","award":["RS-2023-00301702"],"award-info":[{"award-number":["RS-2023-00301702"]}],"id":[{"id":"10.13039\/501100003725","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["rsc.org"],"crossmark-restriction":true},"short-container-title":["J. Mater. Chem. A"],"abstract":"<jats:p>\n                    Si-substituted Li\n                    <jats:sub>6<\/jats:sub>\n                    SbS\n                    <jats:sub>5<\/jats:sub>\n                    I (Li\n                    <jats:sub>\n                      6+\n                      <jats:italic>x<\/jats:italic>\n                    <\/jats:sub>\n                    Sb\n                    <jats:sub>\n                      1\u2212\n                      <jats:italic>x<\/jats:italic>\n                    <\/jats:sub>\n                    Si\n                    <jats:sub>\n                      <jats:italic>x<\/jats:italic>\n                    <\/jats:sub>\n                    S\n                    <jats:sub>5<\/jats:sub>\n                    I) achieves a high Li conductivity of 15.4 mS cm\n                    <jats:sup>\u22121<\/jats:sup>\n                    when\n                    <jats:italic>x<\/jats:italic>\n                    = 0.75, because Si changes the charge state of S ions around Li diffusion paths.\n                  <\/jats:p>","DOI":"10.1039\/d5ta06686g","type":"journal-article","created":{"date-parts":[[2025,9,27]],"date-time":"2025-09-27T06:01:16Z","timestamp":1758952876000},"page":"36597-36608","update-policy":"https:\/\/doi.org\/10.1039\/rsc_crossmark_policy","source":"Crossref","is-referenced-by-count":2,"title":["Conductivity enhancement of argyrodite Li\n                    <sub>6<\/sub>\n                    SbS\n                    <sub>5<\/sub>\n                    I solid electrolyte\n                    <i>via<\/i>\n                    charge modulation around Li diffusion paths through Si substitution"],"prefix":"10.1039","volume":"13","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-4118-6185","authenticated-orcid":false,"given":"Seho","family":"Yi","sequence":"first","affiliation":[{"name":"Institute of Sustainable Earth and Environmental Dynamics (SEED), Pukyong National University, Busan 48547, Republic of Korea"},{"name":"Department of Physics, Pukyong National University, Busan 48513, Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5204-1715","authenticated-orcid":false,"given":"Taegon","family":"Jeon","sequence":"additional","affiliation":[{"name":"Department of Physics, Pukyong National University, Busan 48513, Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-0755-161X","authenticated-orcid":false,"given":"Jae-Ho","family":"Lee","sequence":"additional","affiliation":[{"name":"Department of Energy and Materials Engineering and Advanced Energy and Electronic Materials Research Center, Dongguk University-Seoul, Seoul 04620, Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-3274-9545","authenticated-orcid":false,"given":"Young-Kyu","family":"Han","sequence":"additional","affiliation":[{"name":"Department of Energy and Materials Engineering and Advanced Energy and Electronic Materials Research Center, Dongguk University-Seoul, Seoul 04620, Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-6906-4182","authenticated-orcid":false,"given":"Sung Chul","family":"Jung","sequence":"additional","affiliation":[{"name":"Department of Physics, Pukyong National University, Busan 48513, Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"292","published-online":{"date-parts":[[2025]]},"reference":[{"key":"D5TA06686G\/cit1\/1","doi-asserted-by":"crossref","first-page":"16141","DOI":"10.1038\/nenergy.2016.141","volume":"1","author":"Janek","year":"2016","journal-title":"Nat. Energy"},{"key":"D5TA06686G\/cit2\/1","doi-asserted-by":"crossref","first-page":"230","DOI":"10.1038\/s41560-023-01208-9","volume":"8","author":"Janek","year":"2023","journal-title":"Nat. Energy"},{"key":"D5TA06686G\/cit3\/1","doi-asserted-by":"crossref","first-page":"1310","DOI":"10.1038\/s41560-024-01634-3","volume":"9","author":"Puls","year":"2024","journal-title":"Nat. Energy"},{"key":"D5TA06686G\/cit4\/1","doi-asserted-by":"crossref","first-page":"123","DOI":"10.1038\/s41560-020-00748-8","volume":"6","author":"Duffner","year":"2021","journal-title":"Nat. Energy"},{"key":"D5TA06686G\/cit5\/1","doi-asserted-by":"crossref","first-page":"1003","DOI":"10.1038\/s41578-021-00320-0","volume":"6","author":"Fan","year":"2021","journal-title":"Nat. Rev. Mater."},{"key":"D5TA06686G\/cit6\/1","doi-asserted-by":"crossref","first-page":"93","DOI":"10.1016\/j.nanoen.2018.10.035","volume":"55","author":"Wang","year":"2019","journal-title":"Nano Energy"},{"key":"D5TA06686G\/cit7\/1","doi-asserted-by":"crossref","first-page":"1278","DOI":"10.1038\/s41563-019-0431-3","volume":"18","author":"Famprikis","year":"2019","journal-title":"Nat. Mater."},{"key":"D5TA06686G\/cit8\/1","doi-asserted-by":"crossref","first-page":"2000049","DOI":"10.1002\/aenm.202000049","volume":"10","author":"Chen","year":"2020","journal-title":"Adv. Energy Mater."},{"key":"D5TA06686G\/cit9\/1","doi-asserted-by":"crossref","first-page":"4447","DOI":"10.1021\/acs.nanolett.1c01137","volume":"21","author":"Han","year":"2021","journal-title":"Nano Lett."},{"key":"D5TA06686G\/cit10\/1","doi-asserted-by":"crossref","first-page":"25663","DOI":"10.1039\/D0TA08472G","volume":"8","author":"Bai","year":"2020","journal-title":"J. Mater. Chem. A"},{"key":"D5TA06686G\/cit11\/1","doi-asserted-by":"crossref","first-page":"16103","DOI":"10.1038\/natrevmats.2016.103","volume":"2","author":"Manthiram","year":"2017","journal-title":"Nat. Rev. Mater."},{"key":"D5TA06686G\/cit12\/1","doi-asserted-by":"crossref","first-page":"218","DOI":"10.1038\/s41586-021-03486-3","volume":"593","author":"Ye","year":"2021","journal-title":"Nature"},{"key":"D5TA06686G\/cit13\/1","doi-asserted-by":"crossref","first-page":"1902783","DOI":"10.1002\/aenm.201902783","volume":"10","author":"Kaup","year":"2020","journal-title":"Adv. Energy Mater."},{"key":"D5TA06686G\/cit14\/1","doi-asserted-by":"crossref","first-page":"731","DOI":"10.1039\/D3TA05012B","volume":"12","author":"Hasegawa","year":"2024","journal-title":"J. Mater. Chem. A"},{"key":"D5TA06686G\/cit15\/1","doi-asserted-by":"crossref","first-page":"22458","DOI":"10.1039\/D4TA03257H","volume":"12","author":"Dong","year":"2024","journal-title":"J. Mater. Chem. A"},{"key":"D5TA06686G\/cit16\/1","doi-asserted-by":"crossref","first-page":"3061","DOI":"10.1039\/D3TA05122F","volume":"12","author":"Chen","year":"2024","journal-title":"J. Mater. Chem. A"},{"key":"D5TA06686G\/cit17\/1","doi-asserted-by":"crossref","first-page":"5181","DOI":"10.1039\/D3TA07036K","volume":"12","author":"Cort\u00e9s","year":"2024","journal-title":"J. Mater. Chem. A"},{"key":"D5TA06686G\/cit18\/1","doi-asserted-by":"crossref","first-page":"105858","DOI":"10.1016\/j.nanoen.2021.105858","volume":"83","author":"Yu","year":"2021","journal-title":"Nano Energy"},{"key":"D5TA06686G\/cit19\/1","doi-asserted-by":"crossref","first-page":"9451","DOI":"10.1021\/acsaem.4c02036","volume":"7","author":"Hwang","year":"2024","journal-title":"ACS Appl. Energy Mater."},{"key":"D5TA06686G\/cit20\/1","doi-asserted-by":"crossref","first-page":"33296","DOI":"10.1021\/acsami.8b07476","volume":"10","author":"Yu","year":"2018","journal-title":"ACS Appl. Mater. Interfaces"},{"key":"D5TA06686G\/cit21\/1","doi-asserted-by":"crossref","first-page":"67","DOI":"10.1016\/j.ensm.2020.04.042","volume":"30","author":"Feng","year":"2020","journal-title":"Energy Storage Mater."},{"key":"D5TA06686G\/cit22\/1","doi-asserted-by":"crossref","first-page":"1435","DOI":"10.1021\/acs.chemmater.0c04650","volume":"33","author":"Patel","year":"2021","journal-title":"Chem. Mater."},{"key":"D5TA06686G\/cit23\/1","doi-asserted-by":"crossref","first-page":"230849","DOI":"10.1016\/j.jpowsour.2021.230849","volume":"520","author":"Subramanian","year":"2022","journal-title":"J. Power Sources"},{"key":"D5TA06686G\/cit24\/1","doi-asserted-by":"crossref","first-page":"755","DOI":"10.1002\/anie.200703900","volume":"47","author":"Deiseroth","year":"2008","journal-title":"Angew. Chem., Int. Ed."},{"key":"D5TA06686G\/cit25\/1","doi-asserted-by":"crossref","first-page":"1807","DOI":"10.1007\/s10008-011-1572-8","volume":"16","author":"Rayavarapu","year":"2012","journal-title":"J. Solid State Electrochem."},{"key":"D5TA06686G\/cit26\/1","doi-asserted-by":"crossref","first-page":"10909","DOI":"10.1021\/jacs.7b06327","volume":"139","author":"Kraft","year":"2017","journal-title":"J. Am. Chem. Soc."},{"key":"D5TA06686G\/cit27\/1","doi-asserted-by":"crossref","first-page":"10787","DOI":"10.1039\/D1CC03083C","volume":"57","author":"Zhao","year":"2021","journal-title":"Chem. Commun."},{"key":"D5TA06686G\/cit28\/1","doi-asserted-by":"crossref","first-page":"993","DOI":"10.1039\/D3TA06069A","volume":"12","author":"Jeon","year":"2024","journal-title":"J. Mater. Chem. A"},{"key":"D5TA06686G\/cit29\/1","doi-asserted-by":"crossref","first-page":"2307954","DOI":"10.1002\/adfm.202307954","volume":"33","author":"Wang","year":"2023","journal-title":"Adv. Funct. Mater."},{"key":"D5TA06686G\/cit30\/1","doi-asserted-by":"crossref","first-page":"16330","DOI":"10.1021\/jacs.8b10282","volume":"140","author":"Kraft","year":"2018","journal-title":"J. Am. Chem. Soc."},{"key":"D5TA06686G\/cit31\/1","doi-asserted-by":"crossref","first-page":"4077","DOI":"10.1038\/s41467-023-39686-w","volume":"14","author":"Lu","year":"2023","journal-title":"Nat. Commun."},{"key":"D5TA06686G\/cit32\/1","doi-asserted-by":"crossref","first-page":"19002","DOI":"10.1021\/jacs.9b08357","volume":"141","author":"Zhou","year":"2019","journal-title":"J. Am. Chem. Soc."},{"key":"D5TA06686G\/cit33\/1","doi-asserted-by":"crossref","first-page":"120","DOI":"10.1021\/acssuschemeng.0c05549","volume":"9","author":"Lee","year":"2021","journal-title":"ACS Sustain. Chem. Eng."},{"key":"D5TA06686G\/cit34\/1","doi-asserted-by":"crossref","first-page":"171","DOI":"10.1021\/acsenergylett.1c02428","volume":"7","author":"Lee","year":"2022","journal-title":"ACS Energy Lett."},{"key":"D5TA06686G\/cit35\/1","doi-asserted-by":"crossref","first-page":"2107346","DOI":"10.1002\/adma.202107346","volume":"34","author":"Liu","year":"2022","journal-title":"Adv. Mater."},{"key":"D5TA06686G\/cit36\/1","doi-asserted-by":"crossref","first-page":"27011","DOI":"10.1039\/D4TA03873H","volume":"12","author":"Ma","year":"2024","journal-title":"J. Mater. Chem. A"},{"key":"D5TA06686G\/cit37\/1","doi-asserted-by":"crossref","first-page":"645","DOI":"10.1039\/C7TA08581H","volume":"6","author":"Minafra","year":"2018","journal-title":"J. Mater. Chem. A"},{"key":"D5TA06686G\/cit38\/1","doi-asserted-by":"crossref","first-page":"2500532","DOI":"10.1002\/aenm.202500532","volume":"15","author":"Choi","year":"2025","journal-title":"Adv. Energy Mater."},{"key":"D5TA06686G\/cit39\/1","doi-asserted-by":"crossref","first-page":"1952","DOI":"10.1039\/D3MA01042B","volume":"5","author":"Schwietert","year":"2024","journal-title":"Mater. Adv."},{"key":"D5TA06686G\/cit40\/1","doi-asserted-by":"crossref","first-page":"2004","DOI":"10.1021\/acs.chemmater.0c03738","volume":"33","author":"Morgan","year":"2021","journal-title":"Chem. Mater."},{"key":"D5TA06686G\/cit41\/1","doi-asserted-by":"crossref","first-page":"13115","DOI":"10.1103\/PhysRevB.48.13115","volume":"48","author":"Kresse","year":"1993","journal-title":"Phys. Rev. B"},{"key":"D5TA06686G\/cit42\/1","doi-asserted-by":"crossref","first-page":"15","DOI":"10.1016\/0927-0256(96)00008-0","volume":"6","author":"Kresse","year":"1996","journal-title":"Comput. Mater. Sci."},{"key":"D5TA06686G\/cit43\/1","doi-asserted-by":"crossref","first-page":"17953","DOI":"10.1103\/PhysRevB.50.17953","volume":"50","author":"Bl\u00f6chl","year":"1994","journal-title":"Phys. Rev. B"},{"key":"D5TA06686G\/cit44\/1","doi-asserted-by":"crossref","first-page":"3865","DOI":"10.1103\/PhysRevLett.77.3865","volume":"77","author":"Perdew","year":"1996","journal-title":"Phys. Rev. Lett."},{"key":"D5TA06686G\/cit45\/1","doi-asserted-by":"crossref","first-page":"70","DOI":"10.1016\/j.commatsci.2010.04.023","volume":"49","author":"Le Roux","year":"2010","journal-title":"Comput. Mater. Sci."},{"key":"D5TA06686G\/cit46\/1","doi-asserted-by":"crossref","first-page":"314","DOI":"10.1016\/j.commatsci.2012.10.028","volume":"68","author":"Ong","year":"2013","journal-title":"Comput. Mater. Sci."},{"key":"D5TA06686G\/cit47\/1","doi-asserted-by":"crossref","first-page":"281","DOI":"10.1021\/acs.chemmater.6b02648","volume":"29","author":"Deng","year":"2017","journal-title":"Chem. Mater."},{"key":"D5TA06686G\/cit48\/1","doi-asserted-by":"crossref","first-page":"9901","DOI":"10.1063\/1.1329672","volume":"113","author":"Henkelman","year":"2000","journal-title":"J. Chem. Phys."},{"key":"D5TA06686G\/cit49\/1","doi-asserted-by":"crossref","first-page":"134106","DOI":"10.1063\/1.2841941","volume":"128","author":"Sheppard","year":"2008","journal-title":"J. Chem. Phys."},{"key":"D5TA06686G\/cit50\/1","doi-asserted-by":"crossref","first-page":"33088","DOI":"10.1039\/D4TA06120A","volume":"12","author":"Yi","year":"2024","journal-title":"J. Mater. Chem. A"},{"key":"D5TA06686G\/cit51\/1","doi-asserted-by":"crossref","first-page":"354","DOI":"10.1016\/j.commatsci.2005.04.010","volume":"36","author":"Henkelman","year":"2006","journal-title":"Comput. Mater. Sci."},{"key":"D5TA06686G\/cit52\/1","doi-asserted-by":"crossref","first-page":"527","DOI":"10.1039\/C9EE02616A","volume":"13","author":"Bae","year":"2020","journal-title":"Energy Environ. Sci."},{"key":"D5TA06686G\/cit53\/1","doi-asserted-by":"crossref","first-page":"499","DOI":"10.1038\/s41586-023-06509-3","volume":"622","author":"Yang","year":"2023","journal-title":"Nature"},{"key":"D5TA06686G\/cit54\/1","doi-asserted-by":"crossref","first-page":"3340","DOI":"10.1039\/D3TA06291K","volume":"12","author":"Lai","year":"2024","journal-title":"J. Mater. Chem. A"},{"key":"D5TA06686G\/cit55\/1","doi-asserted-by":"crossref","first-page":"282","DOI":"10.1016\/j.jechem.2024.11.045","volume":"103","author":"Hu","year":"2025","journal-title":"J. Energy Chem."},{"key":"D5TA06686G\/cit56\/1","doi-asserted-by":"crossref","first-page":"15287","DOI":"10.1021\/acscatal.5c04857","volume":"15","author":"Teja","year":"2025","journal-title":"ACS Catal."},{"key":"D5TA06686G\/cit57\/1","doi-asserted-by":"crossref","first-page":"2554","DOI":"10.1021\/acsenergylett.4c00915","volume":"9","author":"Jeong","year":"2024","journal-title":"ACS Energy Lett."},{"key":"D5TA06686G\/cit58\/1","doi-asserted-by":"crossref","first-page":"10832","DOI":"10.1021\/acsami.3c14763","volume":"16","author":"Serbessa","year":"2024","journal-title":"ACS Appl. Mater. Interfaces"},{"key":"D5TA06686G\/cit59\/1","doi-asserted-by":"crossref","first-page":"2400135","DOI":"10.1002\/aesr.202400135","volume":"5","author":"Byeon","year":"2024","journal-title":"Adv. Energy Sustainability Res."},{"key":"D5TA06686G\/cit60\/1","doi-asserted-by":"crossref","first-page":"6017","DOI":"10.1021\/acs.chemmater.4c00515","volume":"36","author":"Jin","year":"2024","journal-title":"Chem. Mater."}],"container-title":["Journal of Materials Chemistry A"],"original-title":[],"language":"en","link":[{"URL":"http:\/\/pubs.rsc.org\/en\/content\/articlepdf\/2025\/TA\/D5TA06686G","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,7,1]],"date-time":"2026-07-01T04:20:07Z","timestamp":1782879607000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.rsc.org\/ta\/article\/13\/42\/36597-36608\/915791"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2025]]},"references-count":60,"journal-issue":{"issue":"42","published-print":{"date-parts":[[2025,10,28]]}},"URL":"https:\/\/doi.org\/10.1039\/d5ta06686g","relation":{},"ISSN":["2050-7488","2050-7496"],"issn-type":[{"value":"2050-7488","type":"print"},{"value":"2050-7496","type":"electronic"}],"subject":[],"published":{"date-parts":[[2025]]}}}