{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,8,17]],"date-time":"2026-08-17T22:07:57Z","timestamp":1787004477641,"version":"build-2736575974"},"reference-count":62,"publisher":"Royal Society of Chemistry (RSC)","issue":"17","license":[{"start":{"date-parts":[[2025,3,19]],"date-time":"2025-03-19T00:00:00Z","timestamp":1742342400000},"content-version":"vor","delay-in-days":77,"URL":"http:\/\/creativecommons.org\/licenses\/by-nc\/3.0\/"}],"funder":[{"DOI":"10.13039\/501100020636","name":"Ministerio de Educaci\u00f3n y Formaci\u00f3n Profesional","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100020636","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100007515","name":"Universidad de Valladolid","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100007515","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100016592","name":"Universit\u00e9 du Littoral C\u00f4te d'Opale","doi-asserted-by":"publisher","id":[{"id":"10.13039\/100016592","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100004794","name":"Centre National de la Recherche Scientifique","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100004794","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100003768","name":"Universit\u00e9 de Strasbourg","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100003768","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["rsc.org"],"crossmark-restriction":true},"short-container-title":["J. Mater. Chem. C"],"abstract":"<jats:p>\n                    An uncommon approach to the synthesis of ambipolar semiconductors based on di- and tri-nuclear gold isocyano\u2013triphenylene complexes of the formula [(AuX)\n                    <jats:sub>\n                      <jats:italic>n<\/jats:italic>\n                    <\/jats:sub>\n                    (CN\u2013C\n                    <jats:sub>6<\/jats:sub>\n                    H\n                    <jats:sub>4<\/jats:sub>\n                    \u2013O\u2013(CH\n                    <jats:sub>2<\/jats:sub>\n                    )\n                    <jats:sub>6<\/jats:sub>\n                    )\n                    <jats:sub>\n                      <jats:italic>n<\/jats:italic>\n                    <\/jats:sub>\n                    \u2013TriPh] (\n                    <jats:italic>n<\/jats:italic>\n                    = 2, 3; X = Cl, C\ue002C\u2013Ph) is described.\n                  <\/jats:p>","DOI":"10.1039\/d5tc00575b","type":"journal-article","created":{"date-parts":[[2025,3,19]],"date-time":"2025-03-19T08:01:10Z","timestamp":1742371270000},"page":"8563-8570","update-policy":"https:\/\/doi.org\/10.1039\/rsc_crossmark_policy","source":"Crossref","is-referenced-by-count":4,"title":["Self-assembly and ambipolar charge transport in columnar phases of polynuclear gold isocyano\u2013triphenylene complexes"],"prefix":"10.1039","volume":"13","author":[{"given":"Estela","family":"de Domingo","sequence":"first","affiliation":[{"name":"IU CINQUIMA\/Qu\u00edmica Inorg\u00e1nica, Facultad de Ciencias, Universidad de Valladolid, 47071 Valladolid, Castilla y Le\u00f3n, Spain"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-3200-3153","authenticated-orcid":false,"given":"Gregorio","family":"Garc\u00eda","sequence":"additional","affiliation":[{"name":"IU CINQUIMA\/Qu\u00edmica Inorg\u00e1nica, Facultad de Ciencias, Universidad de Valladolid, 47071 Valladolid, Castilla y Le\u00f3n, Spain"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Emiliano","family":"Tritto","sequence":"additional","affiliation":[{"name":"IU CINQUIMA\/Qu\u00edmica Inorg\u00e1nica, Facultad de Ciencias, Universidad de Valladolid, 47071 Valladolid, Castilla y Le\u00f3n, Spain"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5907-7705","authenticated-orcid":false,"given":"Bertrand","family":"Donnio","sequence":"additional","affiliation":[{"name":"Institut de Physique et Chimie des Mat\u00e9riaux de Strasbourg (IPCMS), UMR 7504 (CNRS-Universit\u00e9 de Strasbourg), F-67034 Strasbourg Cedex 2, France"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-2047-0750","authenticated-orcid":false,"given":"Asmita","family":"Shah","sequence":"additional","affiliation":[{"name":"Unit\u00e9 de Dynamique et Structure des Mat\u00e9riaux Mol\u00e9culaires (UDSMM), Universit\u00e9 du Littoral C\u00f4te d\u2019Opale (ULCO), 62228 Calais cedex, France"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-6949-6110","authenticated-orcid":false,"given":"Dharmendra Pratap","family":"Singh","sequence":"additional","affiliation":[{"name":"Unit\u00e9 de Dynamique et Structure des Mat\u00e9riaux Mol\u00e9culaires (UDSMM), Universit\u00e9 du Littoral C\u00f4te d\u2019Opale (ULCO), 62228 Calais cedex, France"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-8959-1075","authenticated-orcid":false,"given":"Silverio","family":"Coco","sequence":"additional","affiliation":[{"name":"IU CINQUIMA\/Qu\u00edmica Inorg\u00e1nica, Facultad de Ciencias, Universidad de Valladolid, 47071 Valladolid, Castilla y Le\u00f3n, Spain"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"292","published-online":{"date-parts":[[2025]]},"reference":[{"key":"D5TC00575B\/cit1\/1","doi-asserted-by":"crossref","first-page":"378","DOI":"10.1021\/cm102117c","volume":"23","author":"Kaafarani","year":"2011","journal-title":"Chem. Mater."},{"key":"D5TC00575B\/cit2\/1","doi-asserted-by":"crossref","first-page":"1179","DOI":"10.1002\/marc.200900251","volume":"30","author":"Pisula","year":"2009","journal-title":"Macromol. Rapid Commun."},{"key":"D5TC00575B\/cit3\/1","doi-asserted-by":"crossref","first-page":"729","DOI":"10.1039\/b816624b","author":"Kato","year":"2009","journal-title":"Chem. Commun."},{"key":"D5TC00575B\/cit4\/1","doi-asserted-by":"crossref","first-page":"1902","DOI":"10.1039\/b417320c","volume":"36","author":"Sergeyev","year":"2007","journal-title":"Chem. Soc. Rev."},{"key":"D5TC00575B\/cit5\/1","doi-asserted-by":"crossref","first-page":"4832","DOI":"10.1002\/anie.200604203","volume":"46","author":"Laschat","year":"2007","journal-title":"Angew. Chem., Int. Ed."},{"key":"D5TC00575B\/cit6\/1","doi-asserted-by":"crossref","first-page":"6689","DOI":"10.1021\/cr9002984","volume":"110","author":"Hains","year":"2010","journal-title":"Chem. Rev."},{"key":"D5TC00575B\/cit7\/1","doi-asserted-by":"crossref","first-page":"535","DOI":"10.1016\/j.solmat.2004.05.012","volume":"85","author":"Oukachmih","year":"2005","journal-title":"Sol. Energy Mater. Sol. Cells"},{"key":"D5TC00575B\/cit8\/1","doi-asserted-by":"crossref","first-page":"1119","DOI":"10.1126\/science.293.5532.1119","volume":"293","author":"Schmidt-Mende","year":"2001","journal-title":"Science"},{"key":"D5TC00575B\/cit9\/1","doi-asserted-by":"crossref","first-page":"7993","DOI":"10.1039\/C5TC01565K","volume":"3","author":"Wang","year":"2015","journal-title":"J. Mater. Chem. C"},{"key":"D5TC00575B\/cit10\/1","doi-asserted-by":"crossref","DOI":"10.1007\/978-90-481-2873-0","volume-title":"Liquid crystalline semiconductors: materials, properties and applications","author":"Bushby","year":"2013","unstructured":"R. J.Bushby ,  S. M.Kelly  and  M.O\u2019Neill ,  Liquid crystalline semiconductors: materials, properties and applications ,  Springer ,  Dordrecht, Netherlands ,  2013"},{"key":"D5TC00575B\/cit11\/1","doi-asserted-by":"crossref","first-page":"1139","DOI":"10.1021\/acs.chemrev.5b00190","volume":"116","author":"Wohrle","year":"2016","journal-title":"Chem. Rev."},{"key":"D5TC00575B\/cit12\/1","doi-asserted-by":"crossref","first-page":"877","DOI":"10.3390\/ijms22020877","volume":"22","author":"Termine","year":"2021","journal-title":"Int. J. Mol. Sci."},{"key":"D5TC00575B\/cit13\/1","doi-asserted-by":"crossref","first-page":"17001","DOI":"10.1038\/natrevmats.2017.1","volume":"2","author":"Kato","year":"2017","journal-title":"Nat. Rev. Mater."},{"key":"D5TC00575B\/cit14\/1","doi-asserted-by":"crossref","first-page":"523","DOI":"10.1080\/02678292.2021.1983047","volume":"49","author":"Uttam","year":"2021","journal-title":"Liq. Cryst."},{"key":"D5TC00575B\/cit15\/1","doi-asserted-by":"crossref","first-page":"10364","DOI":"10.1021\/acs.jpcb.1c06009","volume":"125","author":"Vadivel","year":"2021","journal-title":"J. Phys. Chem. B"},{"key":"D5TC00575B\/cit16\/1","doi-asserted-by":"crossref","first-page":"1879","DOI":"10.1039\/C9CC08248D","volume":"56","author":"Chen","year":"2020","journal-title":"Chem. Commun."},{"key":"D5TC00575B\/cit17\/1","doi-asserted-by":"crossref","first-page":"1195","DOI":"10.1080\/02678292.2020.1720840","volume":"47","author":"Kumar","year":"2020","journal-title":"Liq. Cryst."},{"key":"D5TC00575B\/cit18\/1","doi-asserted-by":"crossref","first-page":"673","DOI":"10.1080\/02678299508036673","volume":"18","author":"Boden","year":"1995","journal-title":"Liq. Cryst."},{"key":"D5TC00575B\/cit19\/1","doi-asserted-by":"crossref","first-page":"2275","DOI":"10.1039\/jm9950502275","volume":"5","author":"Boden","year":"1995","journal-title":"J. Mater. Chem."},{"key":"D5TC00575B\/cit20\/1","doi-asserted-by":"crossref","first-page":"1455","DOI":"10.1080\/026782999203788","volume":"26","author":"Kumar","year":"1999","journal-title":"Liq. Cryst."},{"key":"D5TC00575B\/cit21\/1","doi-asserted-by":"crossref","first-page":"470","DOI":"10.1039\/b211133k","volume":"13","author":"Bushby","year":"2003","journal-title":"J. Mater. Chem."},{"key":"D5TC00575B\/cit22\/1","doi-asserted-by":"crossref","first-page":"495","DOI":"10.1080\/026782999204930","volume":"26","author":"Boden","year":"1999","journal-title":"Liq. Cryst."},{"key":"D5TC00575B\/cit23\/1","doi-asserted-by":"crossref","first-page":"161","DOI":"10.1080\/02678290010003732","volume":"28","author":"Kumar","year":"2001","journal-title":"Liq. Cryst."},{"key":"D5TC00575B\/cit24\/1","doi-asserted-by":"crossref","first-page":"171","DOI":"10.1016\/S0022-328X(97)00586-X","volume":"552","author":"Schulte","year":"1998","journal-title":"J. Organomet. Chem."},{"key":"D5TC00575B\/cit25\/1","doi-asserted-by":"crossref","first-page":"966","DOI":"10.1039\/b200978a","author":"Cammidge","year":"2002","journal-title":"Chem. Commun."},{"key":"D5TC00575B\/cit26\/1","doi-asserted-by":"crossref","first-page":"995","DOI":"10.1039\/c39950000995","author":"Mohr","year":"1995","journal-title":"Chem. Commun."},{"key":"D5TC00575B\/cit27\/1","doi-asserted-by":"crossref","first-page":"409","DOI":"10.1016\/j.tetlet.2012.11.029","volume":"54","author":"Yang","year":"2013","journal-title":"Tetrahedron Lett."},{"key":"D5TC00575B\/cit28\/1","doi-asserted-by":"crossref","first-page":"463","DOI":"10.1016\/j.tet.2014.11.070","volume":"71","author":"Shi","year":"2015","journal-title":"Tetrahedron"},{"key":"D5TC00575B\/cit29\/1","doi-asserted-by":"crossref","first-page":"6984","DOI":"10.1021\/acs.cgd.6b01206","volume":"16","author":"Chico","year":"2016","journal-title":"Cryst. Growth Des."},{"key":"D5TC00575B\/cit30\/1","doi-asserted-by":"crossref","first-page":"6070","DOI":"10.1002\/slct.201701117","volume":"2","author":"Gupta","year":"2017","journal-title":"ChemistrySelect"},{"key":"D5TC00575B\/cit31\/1","doi-asserted-by":"crossref","first-page":"1811","DOI":"10.1039\/C4CC08602C","volume":"51","author":"Beltr\u00e1n","year":"2015","journal-title":"Chem. Commun."},{"key":"D5TC00575B\/cit32\/1","doi-asserted-by":"crossref","first-page":"12511","DOI":"10.1021\/jacs.6b06792","volume":"138","author":"Fering\u00e1n","year":"2016","journal-title":"J. Am. Chem. Soc."},{"key":"D5TC00575B\/cit33\/1","doi-asserted-by":"crossref","first-page":"10736","DOI":"10.1021\/ja203822q","volume":"133","author":"Hayashi","year":"2011","journal-title":"J. Am. Chem. Soc."},{"key":"D5TC00575B\/cit34\/1","doi-asserted-by":"crossref","first-page":"10379","DOI":"10.1002\/chem.201500889","volume":"21","author":"Zhao","year":"2015","journal-title":"Chem. \u2013 Eur. J."},{"key":"D5TC00575B\/cit35\/1","doi-asserted-by":"crossref","first-page":"4615","DOI":"10.1002\/anie.201007065","volume":"50","author":"Umeyama","year":"2011","journal-title":"Angew. Chem., Int. Ed."},{"key":"D5TC00575B\/cit36\/1","doi-asserted-by":"crossref","first-page":"7587","DOI":"10.1021\/acs.chemmater.7b02922","volume":"29","author":"Chico","year":"2017","journal-title":"Chem. Mater."},{"key":"D5TC00575B\/cit37\/1","doi-asserted-by":"crossref","first-page":"1435","DOI":"10.1039\/D2TC02272A","volume":"11","author":"Conejo-Rodr\u0131guez","year":"2023","journal-title":"J. Mater. Chem. C"},{"key":"D5TC00575B\/cit38\/1","doi-asserted-by":"crossref","first-page":"9222","DOI":"10.1039\/D2TC01100J","volume":"10","author":"Barcenilla","year":"2022","journal-title":"J. Mater. Chem. C"},{"key":"D5TC00575B\/cit39\/1","doi-asserted-by":"crossref","first-page":"10482","DOI":"10.1021\/acs.inorgchem.0c00794","volume":"59","author":"de Domingo","year":"2020","journal-title":"Inorg. Chem."},{"key":"D5TC00575B\/cit40\/1","doi-asserted-by":"crossref","first-page":"3449","DOI":"10.1021\/ic402886t","volume":"53","author":"Tritto","year":"2014","journal-title":"Inorg. Chem."},{"key":"D5TC00575B\/cit41\/1","doi-asserted-by":"crossref","first-page":"9385","DOI":"10.1039\/C5TC01802A","volume":"3","author":"Tritto","year":"2015","journal-title":"J. Mater. Chem. C"},{"key":"D5TC00575B\/cit42\/1","doi-asserted-by":"crossref","first-page":"4359","DOI":"10.1021\/acs.inorgchem.7b03178","volume":"57","author":"Miguel-Coello","year":"2018","journal-title":"Inorg. Chem."},{"key":"D5TC00575B\/cit43\/1","doi-asserted-by":"crossref","first-page":"872","DOI":"10.1016\/j.tetlet.2019.02.033","volume":"60","author":"Sonet","year":"2019","journal-title":"Tetrahedron Lett."},{"key":"D5TC00575B\/cit44\/1","doi-asserted-by":"crossref","first-page":"4722","DOI":"10.1039\/c2cc17802h","volume":"48","author":"Bhalla","year":"2012","journal-title":"Chem. Commun."},{"key":"D5TC00575B\/cit45\/1","doi-asserted-by":"crossref","first-page":"11413","DOI":"10.1039\/c2dt31244a","volume":"41","author":"Bhalla","year":"2012","journal-title":"Dalton Trans."},{"key":"D5TC00575B\/cit46\/1","doi-asserted-by":"crossref","first-page":"7009","DOI":"10.1002\/anie.201302686","volume":"52","author":"Gonell","year":"2013","journal-title":"Angew. Chem., Int. Ed."},{"key":"D5TC00575B\/cit47\/1","doi-asserted-by":"crossref","first-page":"214459","DOI":"10.1016\/j.ccr.2022.214459","volume":"460","author":"Contreras-Pereda","year":"2022","journal-title":"Coord. Chem. Rev."},{"key":"D5TC00575B\/cit48\/1","doi-asserted-by":"crossref","first-page":"132102","DOI":"10.1063\/1.2056608","volume":"87","author":"Lino","year":"2005","journal-title":"Appl. Phys. Lett."},{"key":"D5TC00575B\/cit49\/1","doi-asserted-by":"crossref","first-page":"117353","DOI":"10.1016\/j.molliq.2021.117353","volume":"342","author":"Shah","year":"2021","journal-title":"J. Mol. Liq."},{"key":"D5TC00575B\/cit50\/1","doi-asserted-by":"crossref","first-page":"9252","DOI":"10.1039\/D0TC02028A","volume":"8","author":"Mahesh","year":"2020","journal-title":"J. Mater. Chem. C"},{"key":"D5TC00575B\/cit51\/1","doi-asserted-by":"crossref","first-page":"1797","DOI":"10.1063\/1.1334958","volume":"114","author":"Kreouzis","year":"2001","journal-title":"J. Chem. Phys."},{"key":"D5TC00575B\/cit52\/1","doi-asserted-by":"crossref","first-page":"1005","DOI":"10.1021\/j100003a025","volume":"99","author":"Markovitsi","year":"1995","journal-title":"J. Phys. Chem."},{"key":"D5TC00575B\/cit53\/1","doi-asserted-by":"crossref","first-page":"1025","DOI":"10.1021\/cr030063a","volume":"105","author":"Burda","year":"2005","journal-title":"Chem. Rev."},{"key":"D5TC00575B\/cit54\/1","doi-asserted-by":"crossref","first-page":"8654","DOI":"10.1021\/ic201210p","volume":"50","author":"Chico","year":"2011","journal-title":"Inorg. Chem."},{"key":"D5TC00575B\/cit55\/1","doi-asserted-by":"crossref","first-page":"15258","DOI":"10.1021\/ja0471673","volume":"126","author":"Donnio","year":"2004","journal-title":"J. Am. Chem. Soc."},{"key":"D5TC00575B\/cit56\/1","doi-asserted-by":"crossref","first-page":"5724","DOI":"10.1039\/C9TC01178A","volume":"7","author":"Bala","year":"2019","journal-title":"J. Mater. Chem. C"},{"key":"D5TC00575B\/cit57\/1","doi-asserted-by":"crossref","first-page":"14872","DOI":"10.1039\/D0NJ03290E","volume":"44","author":"Shah","year":"2020","journal-title":"New J. Chem."},{"key":"D5TC00575B\/cit58\/1","doi-asserted-by":"crossref","first-page":"2922","DOI":"10.1039\/D3CC05707K","volume":"60","author":"Dhingra","year":"2024","journal-title":"Chem. Commun."},{"key":"D5TC00575B\/cit59\/1","doi-asserted-by":"crossref","first-page":"123535","DOI":"10.1016\/j.molliq.2023.123535","volume":"393","author":"Shah","year":"2024","journal-title":"J. Mol. Liq."},{"key":"D5TC00575B\/cit60\/1","doi-asserted-by":"crossref","first-page":"10652","DOI":"10.1039\/D3CC02440G","volume":"59","author":"Gupta","year":"2023","journal-title":"Chem. Commun."},{"key":"D5TC00575B\/cit61\/1","doi-asserted-by":"crossref","first-page":"3271","DOI":"10.1021\/ja0390956","volume":"126","author":"Lemaur","year":"2004","journal-title":"J. Am. Chem. Soc."},{"key":"D5TC00575B\/cit62\/1","doi-asserted-by":"crossref","first-page":"421","DOI":"10.1038\/nmat2427","volume":"8","author":"Feng","year":"2009","journal-title":"Nat. Mater."}],"container-title":["Journal of Materials Chemistry C"],"original-title":[],"language":"en","link":[{"URL":"http:\/\/pubs.rsc.org\/en\/content\/articlepdf\/2025\/TC\/D5TC00575B","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,7,1]],"date-time":"2026-07-01T05:43:10Z","timestamp":1782884590000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.rsc.org\/tc\/article\/13\/17\/8563-8570\/917995"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2025]]},"references-count":62,"journal-issue":{"issue":"17","published-print":{"date-parts":[[2025,5,1]]}},"URL":"https:\/\/doi.org\/10.1039\/d5tc00575b","relation":{},"ISSN":["2050-7526","2050-7534"],"issn-type":[{"value":"2050-7526","type":"print"},{"value":"2050-7534","type":"electronic"}],"subject":[],"published":{"date-parts":[[2025]]}}}