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Commun."],"abstract":"<jats:p>\n                    We report a chromium-catalyzed allylic difluoromethylation of \u03b1-trifluoromethyl alkenes, allowing one-step access to polyfluorinated compounds characterised by both\n                    <jats:italic>gem<\/jats:italic>\n                    -difluoroalkene and difluoromethyl groups.\n                  <\/jats:p>","DOI":"10.1039\/d6cc00019c","type":"journal-article","created":{"date-parts":[[2026,3,19]],"date-time":"2026-03-19T11:41:08Z","timestamp":1773920468000},"page":"7791-7795","update-policy":"https:\/\/doi.org\/10.1039\/rsc_crossmark_policy","source":"Crossref","is-referenced-by-count":1,"title":["Cr-catalyzed difluoromethylation of \u03b1-trifluoromethyl alkenes for modular synthesis of polyfluorinated compounds"],"prefix":"10.1039","volume":"62","author":[{"given":"Jiaran","family":"Yang","sequence":"first","affiliation":[{"name":"Key Laboratory of Green Chemistry & Technology, Ministry of Education, College of Chemistry, Sichuan University, Chengdu 610064, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hongxiang","family":"Li","sequence":"additional","affiliation":[{"name":"Key Laboratory of Green Chemistry & Technology, Ministry of Education, College of Chemistry, Sichuan University, Chengdu 610064, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-1766-9010","authenticated-orcid":false,"given":"Meiming","family":"Luo","sequence":"additional","affiliation":[{"name":"Key Laboratory of Green Chemistry & Technology, Ministry of Education, College of Chemistry, Sichuan University, Chengdu 610064, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0509-1848","authenticated-orcid":false,"given":"Xiaoming","family":"Zeng","sequence":"additional","affiliation":[{"name":"Key Laboratory of Green Chemistry & Technology, Ministry of Education, College of Chemistry, Sichuan University, Chengdu 610064, China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"292","published-online":{"date-parts":[[2026]]},"reference":[{"key":"D6CC00019C\/cit1a\/1","doi-asserted-by":"crossref","first-page":"443","DOI":"10.1146\/annurev.pharmtox.41.1.443","volume":"41","author":"Park","year":"2001","journal-title":"Annu. 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