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Commun."],"abstract":"<jats:p>\n                    The Mg(\n                    <jats:sc>i<\/jats:sc>\n                    ) dimer [K(thf)\n                    <jats:sub>3<\/jats:sub>\n                    ]\n                    <jats:sub>2<\/jats:sub>\n                    [LMg\u2013MgL] (L = [(2,6-iPr\n                    <jats:sub>2<\/jats:sub>\n                    C\n                    <jats:sub>6<\/jats:sub>\n                    H\n                    <jats:sub>3<\/jats:sub>\n                    )NC(CH\n                    <jats:sub>3<\/jats:sub>\n                    )]\n                    <jats:sub>2<\/jats:sub>\n                    <jats:sup>2\u2212<\/jats:sup>\n                    ) promotes\n                    <jats:italic>ortho<\/jats:italic>\n                    C\u2013H magnesiation of thiophenes under ambient conditions to afford Mg(\n                    <jats:sc>ii<\/jats:sc>\n                    ) thienyl complexes, which react with aldehyde or ketone substrates to form alcohols.\n                  <\/jats:p>","DOI":"10.1039\/d6cc00381h","type":"journal-article","created":{"date-parts":[[2026,3,12]],"date-time":"2026-03-12T09:21:51Z","timestamp":1773307311000},"page":"7172-7175","update-policy":"https:\/\/doi.org\/10.1039\/rsc_crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Direct C\u2013H magnesiation of thiophenes with an Mg\u2013Mg-bonded compound"],"prefix":"10.1039","volume":"62","author":[{"given":"Li","family":"Yang","sequence":"first","affiliation":[{"name":"Key Laboratory of Medicinal Molecule Science and Pharmaceutics Engineering, Ministry of Industry and Information Technology, School of Chemistry and Chemical Engineering, Beijing Institute of Technology, Beijing 100081, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhenzhou","family":"Sun","sequence":"additional","affiliation":[{"name":"Key Laboratory of Medicinal Molecule Science and Pharmaceutics Engineering, Ministry of Industry and Information Technology, School of Chemistry and Chemical Engineering, Beijing Institute of Technology, Beijing 100081, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Lin","family":"Wang","sequence":"additional","affiliation":[{"name":"Key Laboratory of Medicinal Molecule Science and Pharmaceutics Engineering, Ministry of Industry and Information Technology, School of Chemistry and Chemical Engineering, Beijing Institute of Technology, Beijing 100081, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jianqi","family":"Geng","sequence":"additional","affiliation":[{"name":"Key Laboratory of Medicinal Molecule Science and Pharmaceutics Engineering, Ministry of Industry and Information Technology, School of Chemistry and Chemical Engineering, Beijing Institute of Technology, Beijing 100081, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Biao","family":"Wu","sequence":"additional","affiliation":[{"name":"Key Laboratory of Medicinal Molecule Science and Pharmaceutics Engineering, Ministry of Industry and Information Technology, School of Chemistry and Chemical Engineering, Beijing Institute of Technology, Beijing 100081, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-0869-4460","authenticated-orcid":false,"given":"Xiao-Juan","family":"Yang","sequence":"additional","affiliation":[{"name":"Key Laboratory of Medicinal Molecule Science and Pharmaceutics Engineering, Ministry of Industry and Information Technology, School of Chemistry and Chemical Engineering, Beijing Institute of Technology, Beijing 100081, China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"292","published-online":{"date-parts":[[2026]]},"reference":[{"key":"D6CC00381H\/cit1\/1","doi-asserted-by":"crossref","first-page":"1514","DOI":"10.2174\/1389557523666230206104257","volume":"23","author":"Chawla","year":"2023","journal-title":"Mini-Rev. 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