{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,7,1]],"date-time":"2026-07-01T06:56:34Z","timestamp":1782888994313,"version":"3.54.5"},"reference-count":29,"publisher":"Royal Society of Chemistry (RSC)","issue":"26","license":[{"start":{"date-parts":[[2026,3,12]],"date-time":"2026-03-12T00:00:00Z","timestamp":1773273600000},"content-version":"vor","delay-in-days":70,"URL":"http:\/\/creativecommons.org\/licenses\/by\/3.0\/"}],"content-domain":{"domain":["rsc.org"],"crossmark-restriction":true},"short-container-title":["Chem. Commun."],"abstract":"<jats:p>A general, copper-catalysed allylic substitution of nitroallyl derivatives with Grignard reagents is reported. The method displays broad scope and functional group tolerance, and is particularly effective with aryl Grignards.<\/jats:p>","DOI":"10.1039\/d6cc00637j","type":"journal-article","created":{"date-parts":[[2026,3,12]],"date-time":"2026-03-12T02:40:56Z","timestamp":1773283256000},"page":"6950-6953","update-policy":"https:\/\/doi.org\/10.1039\/rsc_crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Copper-catalyzed allylic substitution of nitroallyl derivatives with Grignard reagents"],"prefix":"10.1039","volume":"62","author":[{"given":"Louis","family":"Clavier","sequence":"first","affiliation":[{"name":"Laboratoire de Synth\u00e8se Organique (LSO-UMR76523) CNRS, Ecole Polytechnique, ENSTA, Institut Polytechnique de Paris, 828 Bd des Mar\u00e9chaux, 91128 Palaiseau Cedex, France"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Nicolas","family":"Fincias","sequence":"additional","affiliation":[{"name":"Laboratoire de Synth\u00e8se Organique (LSO-UMR76523) CNRS, Ecole Polytechnique, ENSTA, Institut Polytechnique de Paris, 828 Bd des Mar\u00e9chaux, 91128 Palaiseau Cedex, France"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-6831-2631","authenticated-orcid":false,"given":"Stellios","family":"Arseniyadis","sequence":"additional","affiliation":[{"name":"Queen Mary University of London, Department of Chemistry, Mile End Road, E1 4NS, London, UK"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Laurent","family":"El Kaim","sequence":"additional","affiliation":[{"name":"Laboratoire de Synth\u00e8se Organique (LSO-UMR76523) CNRS, Ecole Polytechnique, ENSTA, Institut Polytechnique de Paris, 828 Bd des Mar\u00e9chaux, 91128 Palaiseau Cedex, France"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"292","published-online":{"date-parts":[[2026]]},"reference":[{"key":"D6CC00637J\/cit1a\/1","doi-asserted-by":"crossref","first-page":"2887","DOI":"10.1021\/cr300272t","volume":"113","author":"Noble","year":"2013","journal-title":"Chem. Rev."},{"key":"D6CC00637J\/cit1b\/1","doi-asserted-by":"crossref","first-page":"48022","DOI":"10.1039\/C4RA08828J","volume":"4","author":"Halimehjani","year":"2014","journal-title":"RSC Adv."},{"key":"D6CC00637J\/cit1c\/1","doi-asserted-by":"crossref","first-page":"51794","DOI":"10.1039\/C4RA08830A","volume":"4","author":"Halimehjani","year":"2014","journal-title":"RSC Adv."},{"key":"D6CC00637J\/cit1d\/1","doi-asserted-by":"crossref","first-page":"6191","DOI":"10.1016\/j.tet.2016.07.067","volume":"72","author":"Sukhorukov","year":"2016","journal-title":"Tetrahedron"},{"key":"D6CC00637J\/cit1e\/1","doi-asserted-by":"crossref","first-page":"3680","DOI":"10.3390\/molecules25163680","volume":"25","author":"Nishiwaki","year":"2020","journal-title":"Molecules"},{"key":"D6CC00637J\/cit2a\/1","doi-asserted-by":"crossref","first-page":"2611","DOI":"10.1021\/acs.chemrev.8b00547","volume":"119","author":"Formenti","year":"2019","journal-title":"Chem. Rev."},{"key":"D6CC00637J\/cit2b\/1","doi-asserted-by":"crossref","first-page":"430","DOI":"10.1021\/acs.oprd.6b00205","volume":"22","author":"Orlandi","year":"2018","journal-title":"Org. Process Res. Dev."},{"key":"D6CC00637J\/cit3a\/1","doi-asserted-by":"crossref","first-page":"1285","DOI":"10.1039\/c39860001285","author":"Ono","year":"1986","journal-title":"J. Chem. Soc., Chem. Commun."},{"key":"D6CC00637J\/cit3b\/1","doi-asserted-by":"crossref","first-page":"3055","DOI":"10.1016\/S0040-4039(00)76826-2","volume":"35","author":"Crozet","year":"1994","journal-title":"Tetrahedron. Lett."},{"key":"D6CC00637J\/cit3c\/1","doi-asserted-by":"crossref","first-page":"9844","DOI":"10.1016\/j.tet.2011.09.103","volume":"67","author":"Li","year":"2011","journal-title":"Tetrahedron"},{"key":"D6CC00637J\/cit3d\/1","doi-asserted-by":"crossref","first-page":"3353","DOI":"10.1021\/acs.orglett.2c01038","volume":"24","author":"Lo","year":"2022","journal-title":"Org. Lett."},{"key":"D6CC00637J\/cit3e\/1","doi-asserted-by":"crossref","first-page":"1557","DOI":"10.1021\/ja00396a044","volume":"103","author":"Tanner","year":"1981","journal-title":"J. Am. Chem. Soc."},{"key":"D6CC00637J\/cit3f\/1","doi-asserted-by":"crossref","first-page":"4332","DOI":"10.1021\/ja00300a043","volume":"107","author":"DuPuis","year":"1985","journal-title":"J. Am. Chem. Soc."},{"key":"D6CC00637J\/cit3g\/1","doi-asserted-by":"crossref","first-page":"5027","DOI":"10.1021\/jo0605546","volume":"71","author":"Luzzio","year":"2006","journal-title":"J. Org. Chem."},{"key":"D6CC00637J\/cit4a\/1","doi-asserted-by":"crossref","first-page":"3727","DOI":"10.1021\/ja00377a034","volume":"104","author":"Tamura","year":"1982","journal-title":"J. Am. Chem. Soc."},{"key":"D6CC00637J\/cit4b\/1","doi-asserted-by":"crossref","first-page":"4375","DOI":"10.1021\/jo00373a008","volume":"51","author":"Tamura","year":"1986","journal-title":"J. Org. Chem"},{"key":"D6CC00637J\/cit4c\/1","doi-asserted-by":"crossref","first-page":"1439","DOI":"10.1039\/p19860001439","author":"Ono","year":"1986","journal-title":"J. Chem. Soc. Perkin Trans. 1"},{"key":"D6CC00637J\/cit4d\/1","doi-asserted-by":"crossref","first-page":"3966","DOI":"10.1021\/ol401747u","volume":"15","author":"Padilla-Salinas","year":"2013","journal-title":"Org. Lett"},{"key":"D6CC00637J\/cit4e\/1","doi-asserted-by":"crossref","first-page":"8103","DOI":"10.1021\/jo5013042","volume":"79","author":"Nakano","year":"2014","journal-title":"J. Org. Chem"},{"key":"D6CC00637J\/cit4f\/1","doi-asserted-by":"crossref","first-page":"10917","DOI":"10.1039\/C8CC06536E","volume":"54","author":"Dol\u00e9 Kerim","year":"2018","journal-title":"Chem. Commun."},{"key":"D6CC00637J\/cit5\/1","doi-asserted-by":"crossref","first-page":"99","DOI":"10.1021\/jacsau.4c00809","volume":"5","author":"Fincias","year":"2025","journal-title":"JACS Au"},{"key":"D6CC00637J\/cit6a\/1","doi-asserted-by":"crossref","first-page":"1517","DOI":"10.1016\/0040-4020(79)80038-1","volume":"35","author":"Gendreau","year":"1979","journal-title":"Tetrahedron"},{"key":"D6CC00637J\/cit6b\/1","doi-asserted-by":"crossref","first-page":"2884","DOI":"10.1021\/jo00365a006","volume":"51","author":"Tseng","year":"1986","journal-title":"J. Org. Chem."},{"key":"D6CC00637J\/cit6c\/1","doi-asserted-by":"crossref","first-page":"6615","DOI":"10.1021\/ja00174a024","volume":"112","author":"B\u00e4ckvall","year":"1990","journal-title":"J. Am. Chem. Soc."},{"key":"D6CC00637J\/cit6d\/1","doi-asserted-by":"crossref","first-page":"2892","DOI":"10.1021\/jo00365a600","volume":"51","author":"Tseng","year":"1986","journal-title":"J. Org. Chem."},{"key":"D6CC00637J\/cit6e\/1","doi-asserted-by":"crossref","first-page":"1981","DOI":"10.1002\/1521-3765(20010504)7:9<1981::AID-CHEM1981>3.0.CO;2-C","volume":"7","author":"Karlstr\u00f6m","year":"2001","journal-title":"Chem. \u2013 Eur. J."},{"key":"D6CC00637J\/cit7\/1","doi-asserted-by":"crossref","first-page":"9390","DOI":"10.1021\/ja026718r","volume":"124","author":"Sapountzis","year":"2002","journal-title":"J. Am. Chem. Soc."},{"key":"D6CC00637J\/cit7\/2","doi-asserted-by":"crossref","first-page":"3718","DOI":"10.1021\/acs.orglett.3c01167","volume":"25","author":"Meng","year":"2023","journal-title":"Org. Lett."},{"key":"D6CC00637J\/cit8\/1","doi-asserted-by":"crossref","first-page":"274","DOI":"10.1039\/C39840000274","author":"Ono","year":"1984","journal-title":"J. Chem. Soc., Chem. Commun."}],"container-title":["Chemical Communications"],"original-title":[],"language":"en","link":[{"URL":"http:\/\/pubs.rsc.org\/en\/content\/articlepdf\/2026\/CC\/D6CC00637J","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,7,1]],"date-time":"2026-07-01T05:20:57Z","timestamp":1782883257000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.rsc.org\/cc\/article\/62\/26\/6950-6953\/1236699"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026]]},"references-count":29,"journal-issue":{"issue":"26","published-print":{"date-parts":[[2026,4,2]]}},"URL":"https:\/\/doi.org\/10.1039\/d6cc00637j","relation":{},"ISSN":["1359-7345","1364-548X"],"issn-type":[{"value":"1359-7345","type":"print"},{"value":"1364-548X","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026]]}}}