{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,8,4]],"date-time":"2026-08-04T21:45:04Z","timestamp":1785879904697,"version":"3.56.0"},"reference-count":73,"publisher":"Royal Society of Chemistry (RSC)","issue":"60","license":[{"start":{"date-parts":[[2026,6,30]],"date-time":"2026-06-30T00:00:00Z","timestamp":1782777600000},"content-version":"vor","delay-in-days":180,"URL":"http:\/\/creativecommons.org\/licenses\/by-nc\/3.0\/"}],"funder":[{"DOI":"10.13039\/100000879","name":"Alfred P. 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Commun."],"abstract":"<jats:p>\n                    Here we report the first Np\n                    <jats:sup>4+<\/jats:sup>\n                    \u03c3-benzyl complex, [NpBn(NP*)\n                    <jats:sub>3<\/jats:sub>\n                    ] (NP* = [NP(1,2-bis-\n                    <jats:sup>\n                      <jats:italic>t<\/jats:italic>\n                    <\/jats:sup>\n                    Bu-diamidoethane)(NEt\n                    <jats:sub>2<\/jats:sub>\n                    )]\n                    <jats:sup>1\u2212<\/jats:sup>\n                    ; Bn = CH\n                    <jats:sub>2<\/jats:sub>\n                    (C\n                    <jats:sub>6<\/jats:sub>\n                    H\n                    <jats:sub>5<\/jats:sub>\n                    )), providing a rare example of a stable Np\n                    <jats:sup>4+<\/jats:sup>\n                    \u2013C \u03c3-bond and new insight into transuranic organometallic chemistry.\n                  <\/jats:p>","DOI":"10.1039\/d6cc03345h","type":"journal-article","created":{"date-parts":[[2026,6,30]],"date-time":"2026-06-30T06:04:19Z","timestamp":1782799459000},"page":"15058-15062","update-policy":"https:\/\/doi.org\/10.1039\/rsc_crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Isolation of an Np\n                    <sup>4+<\/sup>\n                    \u03c3-benzyl complex"],"prefix":"10.1039","volume":"62","author":[{"ORCID":"https:\/\/orcid.org\/0009-0000-2951-6615","authenticated-orcid":false,"given":"Tyler-Rayne","family":"Nero","sequence":"first","affiliation":[{"name":"School of Chemistry and Biochemistry, Georgia Institute of Technology, Atlanta, GA 30332-0400, USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-4225-9163","authenticated-orcid":false,"given":"Matilda I.","family":"Duffy","sequence":"additional","affiliation":[{"name":"School of Chemistry and Biochemistry, Georgia Institute of Technology, Atlanta, GA 30332-0400, USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-8413-0635","authenticated-orcid":false,"given":"Kaitlyn S.","family":"Engle","sequence":"additional","affiliation":[{"name":"School of Chemistry and Biochemistry, Georgia Institute of Technology, Atlanta, GA 30332-0400, USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0000-6498-7586","authenticated-orcid":false,"given":"Cara","family":"O\u2019Leary","sequence":"additional","affiliation":[{"name":"Department of Chemistry, University of Iowa, Iowa City, Iowa 52242, USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-4132-3733","authenticated-orcid":false,"given":"Julie E.","family":"Niklas","sequence":"additional","affiliation":[{"name":"School of Chemistry and Biochemistry, Georgia Institute of Technology, Atlanta, GA 30332-0400, USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Florian","family":"Kleemiss","sequence":"additional","affiliation":[{"name":"Institut f\u00fcr Anorganische Chemie, RWTH Aachen University, Aachen, Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-6065-0732","authenticated-orcid":false,"given":"Bess","family":"Vlaisavljevich","sequence":"additional","affiliation":[{"name":"Department of Chemistry, University of Iowa, Iowa City, Iowa 52242, USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-0895-0655","authenticated-orcid":false,"given":"Henry S.","family":"La Pierre","sequence":"additional","affiliation":[{"name":"School of Chemistry and Biochemistry, Georgia Institute of Technology, Atlanta, GA 30332-0400, USA"},{"name":"Nuclear and Radiological Engineering Program, Georgia Institute of Technology, Atlanta, GA 30332, USA"},{"name":"Physical Sciences Division, Pacific Northwest National Laboratory, Richland, WA 99532, USA"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"292","published-online":{"date-parts":[[2026]]},"reference":[{"key":"D6CC03345H\/cit1\/1","doi-asserted-by":"crossref","first-page":"3556","DOI":"10.1021\/ic300867m","volume":"52","author":"Seaman","year":"2013","journal-title":"Inorg. 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