{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,17]],"date-time":"2026-09-17T15:06:21Z","timestamp":1789657581732,"version":"4.0.1"},"reference-count":57,"publisher":"Royal Society of Chemistry (RSC)","issue":"73","license":[{"start":{"date-parts":[[2027,8,14]],"date-time":"2027-08-14T00:00:00Z","timestamp":1818201600000},"content-version":"am","delay-in-days":590,"URL":"http:\/\/rsc.li\/journals-terms-of-use"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22007018"],"award-info":[{"award-number":["22007018"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100010226","name":"Department of Education of Guangdong Province","doi-asserted-by":"publisher","award":["2023ZDZX2028"],"award-info":[{"award-number":["2023ZDZX2028"]}],"id":[{"id":"10.13039\/501100010226","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["rsc.org"],"crossmark-restriction":true},"short-container-title":["Chem. Commun."],"abstract":"<jats:p>\n                    A Rh(\n                    <jats:sc>iii<\/jats:sc>\n                    )-catalyzed regio- and stereoselective \u03b2-C(sp\n                    <jats:sup>2<\/jats:sup>\n                    )\u2013H amidation of enamides with dioxazolones has been developed, which afforded a series of diverse vicinal diamines in moderate to high yields with high\n                    <jats:italic>Z<\/jats:italic>\n                    -selectivity (\n                    <jats:italic>Z<\/jats:italic>\n                    \/\n                    <jats:italic>E<\/jats:italic>\n                    &gt; 20\u2009:\u20091).\n                  <\/jats:p>","DOI":"10.1039\/d6cc03788g","type":"journal-article","created":{"date-parts":[[2026,8,14]],"date-time":"2026-08-14T09:03:06Z","timestamp":1786698186000},"page":"18154-18157","update-policy":"https:\/\/doi.org\/10.1039\/rsc_crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Rhodium-catalyzed regio- and stereoselective \u03b2-C(sp\n                    <sup>2<\/sup>\n                    )\u2013H amidation of enamines with dioxazolones to access vicinal diamines"],"prefix":"10.1039","volume":"62","author":[{"given":"Juan","family":"Chen","sequence":"first","affiliation":[{"name":"School of Pharmacy, Guangdong Pharmaceutical University, Guangzhou, 510006, P. R. China"},{"name":"Center for Drug Research and Development, Guangdong Pharmaceutical University, Guangzhou, 510006, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Huan","family":"Yuan","sequence":"additional","affiliation":[{"name":"School of Pharmacy, Guangdong Pharmaceutical University, Guangzhou, 510006, P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yu-Xuan","family":"Ren","sequence":"additional","affiliation":[{"name":"School of Pharmacy, Guangdong Pharmaceutical University, Guangzhou, 510006, P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xiao-Hui","family":"Cao","sequence":"additional","affiliation":[{"name":"School of Pharmacy, Guangdong Pharmaceutical University, Guangzhou, 510006, P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9247-1373","authenticated-orcid":false,"given":"Shang-Shi","family":"Zhang","sequence":"additional","affiliation":[{"name":"Center for Drug Research and Development, Guangdong Pharmaceutical University, Guangzhou, 510006, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-7321-8682","authenticated-orcid":false,"given":"Bing","family":"Shu","sequence":"additional","affiliation":[{"name":"School of Pharmacy, Guangdong Pharmaceutical University, Guangzhou, 510006, P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Pengju","family":"Feng","sequence":"additional","affiliation":[{"name":"Center for Drug Research and Development, Guangdong Pharmaceutical University, Guangzhou, 510006, China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"292","published-online":{"date-parts":[[2026]]},"reference":[{"key":"D6CC03788G\/cit1a\/1","doi-asserted-by":"crossref","first-page":"20263","DOI":"10.1021\/jacs.4c05581","volume":"146","author":"Liu","year":"2024","journal-title":"J. Am. Chem. Soc."},{"key":"D6CC03788G\/cit1b\/1","doi-asserted-by":"crossref","first-page":"101","DOI":"10.1111\/j.1747-0285.2006.00347.x","volume":"67","author":"Saibabu Kotti","year":"2006","journal-title":"Chem. Biol. Drug Des."},{"key":"D6CC03788G\/cit1c\/1","doi-asserted-by":"crossref","first-page":"3167","DOI":"10.1021\/cr0406561","volume":"105","author":"Viso","year":"2005","journal-title":"Chem. Rev."},{"key":"D6CC03788G\/cit1d\/1","doi-asserted-by":"crossref","first-page":"1","DOI":"10.1021\/cr100127y","volume":"111","author":"Viso","year":"2011","journal-title":"Chem. Rev."},{"key":"D6CC03788G\/cit1e\/1","doi-asserted-by":"crossref","first-page":"4156","DOI":"10.1021\/ol101747n","volume":"12","author":"Zhu","year":"2010","journal-title":"Org. Lett."},{"key":"D6CC03788G\/cit2a\/1","doi-asserted-by":"crossref","first-page":"582","DOI":"10.1126\/science.1142696","volume":"316","author":"Beeson","year":"2007","journal-title":"Science"},{"key":"D6CC03788G\/cit2b\/1","doi-asserted-by":"crossref","first-page":"140","DOI":"10.1021\/cr040107v","volume":"108","author":"Kizirian","year":"2008","journal-title":"Chem. Rev."},{"key":"D6CC03788G\/cit2c\/1","doi-asserted-by":"crossref","first-page":"219","DOI":"10.1038\/s41929-019-0230-x","volume":"2","author":"Park","year":"2019","journal-title":"Nat. Catal."},{"key":"D6CC03788G\/cit2d\/1","doi-asserted-by":"crossref","first-page":"986","DOI":"10.1021\/acs.accounts.5b00028","volume":"48","author":"Zhang","year":"2015","journal-title":"Acc. Chem. Res."},{"key":"D6CC03788G\/cit3a\/1","doi-asserted-by":"crossref","first-page":"11799","DOI":"10.1021\/ja407277a","volume":"135","author":"Bandar","year":"2013","journal-title":"J. Am. Chem. Soc."},{"key":"D6CC03788G\/cit3b\/1","doi-asserted-by":"crossref","first-page":"1438","DOI":"10.1126\/science.aat4210","volume":"360","author":"Chen","year":"2018","journal-title":"Science"},{"key":"D6CC03788G\/cit3c\/1","doi-asserted-by":"crossref","first-page":"4473","DOI":"10.1038\/s41467-020-18235-9","volume":"11","author":"Gan","year":"2020","journal-title":"Nat. Commun."},{"key":"D6CC03788G\/cit3d\/1","doi-asserted-by":"crossref","first-page":"8471","DOI":"10.1002\/anie.201502215","volume":"54","author":"Kano","year":"2015","journal-title":"Angew. Chem., Int. Ed."},{"key":"D6CC03788G\/cit3e\/1","doi-asserted-by":"crossref","first-page":"14362","DOI":"10.1021\/ja804527r","volume":"130","author":"Yan","year":"2008","journal-title":"J. Am. Chem. Soc."},{"key":"D6CC03788G\/cit4a\/1","doi-asserted-by":"crossref","first-page":"21548","DOI":"10.1021\/jacs.0c11025","volume":"142","author":"Makai","year":"2020","journal-title":"J. Am. Chem. Soc."},{"key":"D6CC03788G\/cit4b\/1","doi-asserted-by":"crossref","first-page":"1120","DOI":"10.1038\/s41929-022-00883-3","volume":"5","author":"Tan","year":"2022","journal-title":"Nat. Catal."},{"key":"D6CC03788G\/cit4c\/1","doi-asserted-by":"crossref","first-page":"3665","DOI":"10.1021\/ar500344t","volume":"47","author":"Zhu","year":"2014","journal-title":"Acc. Chem. Res."},{"key":"D6CC03788G\/cit5a\/1","doi-asserted-by":"crossref","first-page":"2597","DOI":"10.1002\/chem.201203462","volume":"19","author":"MacDonald","year":"2013","journal-title":"Chem. \u2013 Eur. J."},{"key":"D6CC03788G\/cit5b\/1","doi-asserted-by":"crossref","first-page":"202303078","DOI":"10.1002\/chem.202303078","volume":"30","author":"Mohiti","year":"2024","journal-title":"Chem. \u2013 Eur. J."},{"key":"D6CC03788G\/cit5c\/1","doi-asserted-by":"crossref","first-page":"8551","DOI":"10.1002\/anie.201902642","volume":"58","author":"Yu","year":"2019","journal-title":"Angew. Chem., Int. Ed."},{"key":"D6CC03788G\/cit6a\/1","doi-asserted-by":"crossref","first-page":"650","DOI":"10.1002\/anie.201610693","volume":"56","author":"Chai","year":"2017","journal-title":"Angew. Chem., Int. Ed."},{"key":"D6CC03788G\/cit6b\/1","first-page":"1247","author":"Lee","year":"2020","journal-title":"Synthesis"},{"key":"D6CC03788G\/cit6c\/1","doi-asserted-by":"crossref","first-page":"1102","DOI":"10.1039\/C3SC52929K","volume":"5","author":"Wu","year":"2014","journal-title":"Chem. Sci."},{"key":"D6CC03788G\/cit7a\/1","doi-asserted-by":"crossref","first-page":"4599","DOI":"10.1021\/cr100031f","volume":"111","author":"Gopalaiah","year":"2011","journal-title":"Chem. Rev."},{"key":"D6CC03788G\/cit7b\/1","doi-asserted-by":"crossref","first-page":"13573","DOI":"10.1002\/anie.201908089","volume":"58","author":"Li","year":"2019","journal-title":"Angew. Chem., Int. Ed."},{"key":"D6CC03788G\/cit7c\/1","doi-asserted-by":"crossref","first-page":"1713","DOI":"10.1021\/cr100218m","volume":"111","author":"Xie","year":"2011","journal-title":"Chem. Rev."},{"key":"D6CC03788G\/cit7d\/1","doi-asserted-by":"crossref","first-page":"11505","DOI":"10.1002\/anie.201905263","volume":"58","author":"Zhang","year":"2019","journal-title":"Angew. Chem., Int. Ed."},{"key":"D6CC03788G\/cit8a\/1","doi-asserted-by":"crossref","first-page":"2762","DOI":"10.1021\/acs.orglett.6b01255","volume":"18","author":"Bartoccini","year":"2016","journal-title":"Org. Lett."},{"key":"D6CC03788G\/cit8b\/1","doi-asserted-by":"crossref","first-page":"9865","DOI":"10.1039\/C4CC04072D","volume":"50","author":"Feng","year":"2014","journal-title":"Chem. Commun."},{"key":"D6CC03788G\/cit8c\/1","doi-asserted-by":"crossref","first-page":"3304","DOI":"10.1021\/ol301249n","volume":"14","author":"Gigant","year":"2012","journal-title":"Org. Lett."},{"key":"D6CC03788G\/cit8d\/1","doi-asserted-by":"crossref","first-page":"6524","DOI":"10.1039\/D2GC01978G","volume":"24","author":"Guan","year":"2022","journal-title":"Green Chem."},{"key":"D6CC03788G\/cit8e\/1","doi-asserted-by":"crossref","first-page":"6540","DOI":"10.1039\/D2QO01304E","volume":"9","author":"Tao","year":"2022","journal-title":"Org. Chem. Front."},{"key":"D6CC03788G\/cit8f\/1","doi-asserted-by":"crossref","first-page":"5497","DOI":"10.1039\/D0GC01947J","volume":"22","author":"Zhao","year":"2020","journal-title":"Green Chem."},{"key":"D6CC03788G\/cit9\/1","doi-asserted-by":"crossref","first-page":"2235","DOI":"10.1002\/cjoc.202400350","volume":"42","author":"Qin","year":"2024","journal-title":"Chin. J. Chem."},{"key":"D6CC03788G\/cit10a\/1","doi-asserted-by":"crossref","first-page":"70158","DOI":"10.1002\/adsc.70158","volume":"367","author":"Gong","year":"2025","journal-title":"Adv. Synth. Catal."},{"key":"D6CC03788G\/cit10b\/1","doi-asserted-by":"crossref","first-page":"6557","DOI":"10.1021\/acs.orglett.6c01350","volume":"28","author":"Metya","year":"2026","journal-title":"Org. Lett."},{"key":"D6CC03788G\/cit10c\/1","doi-asserted-by":"crossref","first-page":"9695","DOI":"10.1039\/D5SC09742H","volume":"17","author":"Ren","year":"2026","journal-title":"Chem. Sci."},{"key":"D6CC03788G\/cit10d\/1","doi-asserted-by":"crossref","first-page":"7905","DOI":"10.1021\/jacs.5c22538","volume":"148","author":"Li","year":"2026","journal-title":"J. Am. Chem. Soc."},{"key":"D6CC03788G\/cit10e\/1","doi-asserted-by":"crossref","first-page":"13983","DOI":"10.1021\/jacs.5c03484","volume":"147","author":"Liu","year":"2025","journal-title":"J. Am. Chem. Soc."},{"key":"D6CC03788G\/cit10f\/1","doi-asserted-by":"crossref","first-page":"6555","DOI":"10.1021\/acscatal.5c00001","volume":"15","author":"Song","year":"2025","journal-title":"ACS Catal."},{"key":"D6CC03788G\/cit11a\/1","doi-asserted-by":"crossref","first-page":"14103","DOI":"10.1002\/anie.201505820","volume":"54","author":"Park","year":"2015","journal-title":"Angew. Chem., Int. Ed."},{"key":"D6CC03788G\/cit11b\/1","doi-asserted-by":"crossref","first-page":"4534","DOI":"10.1021\/jacs.5b01324","volume":"137","author":"Park","year":"2015","journal-title":"J. Am. Chem. Soc."},{"key":"D6CC03788G\/cit12a\/1","doi-asserted-by":"crossref","first-page":"202509056","DOI":"10.1002\/anie.202509056","volume":"64","author":"Chakraborty","year":"2025","journal-title":"Angew. Chem., Int. Ed."},{"key":"D6CC03788G\/cit12b\/1","doi-asserted-by":"crossref","first-page":"18383","DOI":"10.1021\/acscatal.5c06667","volume":"15","author":"Kang","year":"2025","journal-title":"ACS Catal."},{"key":"D6CC03788G\/cit12c\/1","doi-asserted-by":"crossref","first-page":"378","DOI":"10.1038\/s41557-021-00650-0","volume":"13","author":"Wang","year":"2021","journal-title":"Nat. Chem."},{"key":"D6CC03788G\/cit13a\/1","doi-asserted-by":"crossref","first-page":"8585","DOI":"10.1021\/acscatal.1c02406","volume":"11","author":"Lee","year":"2021","journal-title":"ACS Catal."},{"key":"D6CC03788G\/cit13b\/1","doi-asserted-by":"crossref","first-page":"2268","DOI":"10.1021\/jacs.9b00237","volume":"141","author":"Lei","year":"2019","journal-title":"J. Am. Chem. Soc."},{"key":"D6CC03788G\/cit13c\/1","doi-asserted-by":"crossref","first-page":"14103","DOI":"10.1002\/anie.201505820","volume":"54","author":"Park","year":"2015","journal-title":"Angew. Chem., Int. Ed."},{"key":"D6CC03788G\/cit13d\/1","doi-asserted-by":"crossref","first-page":"15041","DOI":"10.1002\/anie.201907269","volume":"58","author":"Pinkert","year":"2019","journal-title":"Angew. Chem., Int. Ed."},{"key":"D6CC03788G\/cit14a\/1","doi-asserted-by":"crossref","first-page":"23434","DOI":"10.1021\/jacs.5c08385","volume":"147","author":"Chen","year":"2025","journal-title":"J. Am. Chem. Soc."},{"key":"D6CC03788G\/cit14b\/1","doi-asserted-by":"crossref","first-page":"19660","DOI":"10.1002\/anie.202105679","volume":"60","author":"Jiu","year":"2021","journal-title":"Angew. Chem., Int. Ed."},{"key":"D6CC03788G\/cit14c\/1","doi-asserted-by":"crossref","first-page":"18579","DOI":"10.1021\/jacs.6c00508","volume":"148","author":"Ruud","year":"2026","journal-title":"J. Am. Chem. Soc."},{"key":"D6CC03788G\/cit14d\/1","doi-asserted-by":"crossref","first-page":"17453","DOI":"10.1021\/acs.joc.4c02105","volume":"89","author":"Wu","year":"2024","journal-title":"J. Org. Chem."},{"key":"D6CC03788G\/cit15a\/1","doi-asserted-by":"crossref","first-page":"635","DOI":"10.1039\/D0QO01353F","volume":"8","author":"Xie","year":"2021","journal-title":"Org. Chem. Front."},{"key":"D6CC03788G\/cit15b\/1","doi-asserted-by":"crossref","first-page":"3302","DOI":"10.1002\/adsc.202200570","volume":"364","author":"Chen","year":"2022","journal-title":"Adv. Synth. Catal."},{"key":"D6CC03788G\/cit15c\/1","doi-asserted-by":"crossref","first-page":"202200710","DOI":"10.1002\/ejoc.202200710","author":"Song","year":"2022","journal-title":"Eur. J. Org. Chem."},{"key":"D6CC03788G\/cit16\/1","doi-asserted-by":"publisher","year":"2026","unstructured":"CCDC 2561567: Experimental Crystal Structure Determination ,  2026 10.5517\/ccdc.csd.cc2rzj6h","DOI":"10.5517\/ccdc.csd.cc2rzj6h"}],"container-title":["Chemical Communications"],"original-title":[],"language":"en","link":[{"URL":"http:\/\/pubs.rsc.org\/CC\/article-pdf\/doi\/10.1039\/D6CC03788G\/0\/D6CC03788G.pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,9,17]],"date-time":"2026-09-17T14:29:52Z","timestamp":1789655392000},"score":1,"resource":{"primary":{"URL":"http:\/\/pubs.rsc.org\/CC\/article-lookup\/doi\/10.1039\/D6CC03788G"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026]]},"references-count":57,"journal-issue":{"issue":"73","published-print":{"date-parts":[[2026,9,17]]}},"URL":"https:\/\/doi.org\/10.1039\/d6cc03788g","relation":{},"ISSN":["1359-7345","1364-548X"],"issn-type":[{"value":"1359-7345","type":"print"},{"value":"1364-548X","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026]]}}}