{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,23]],"date-time":"2026-09-23T09:59:58Z","timestamp":1790157598807,"version":"4.1.0"},"reference-count":43,"publisher":"Royal Society of Chemistry (RSC)","license":[{"start":{"date-parts":[[2026,9,17]],"date-time":"2026-09-17T00:00:00Z","timestamp":1789603200000},"content-version":"vor","delay-in-days":259,"URL":"http:\/\/creativecommons.org\/licenses\/by\/3.0\/"}],"funder":[{"DOI":"10.13039\/501100000038","name":"Natural Sciences and Engineering Research Council of Canada","doi-asserted-by":"publisher","award":["RGPIN-2025-06404"],"award-info":[{"award-number":["RGPIN-2025-06404"]}],"id":[{"id":"10.13039\/501100000038","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["rsc.org"],"crossmark-restriction":true},"short-container-title":["Chem. Commun."],"abstract":"<jats:p>\n                    Hydrosilane\u2013Lewis base combinations generate silyl radicals, radical anions, H-atom donors and strongly basic species\n                    <jats:italic>in situ<\/jats:italic>\n                    . This review highlights their use in defunctionalization, silylation, hydrosilylation and C\u2013C bond formation.\n                  <\/jats:p>","DOI":"10.1039\/d6cc05112j","type":"journal-article","created":{"date-parts":[[2026,9,17]],"date-time":"2026-09-17T00:03:05Z","timestamp":1789603385000},"update-policy":"https:\/\/doi.org\/10.1039\/rsc_crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["The unconventional reactivity of hydrosilanes and Lewis base combinations: beyond hydride donation"],"prefix":"10.1039","author":[{"given":"Piers","family":"St. Onge","sequence":"first","affiliation":[{"name":"Centre for Catalysis Research and Innovation, Department of Chemistry and Biomolecular Sciences, University of Ottawa, 10 Marie Curie, Ottawa, Ontario K1N 6N5, Canada"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-6929-3767","authenticated-orcid":false,"given":"Mario D.","family":"Mart\u00ednez","sequence":"additional","affiliation":[{"name":"Centre for Catalysis Research and Innovation, Department of Chemistry and Biomolecular Sciences, University of Ottawa, 10 Marie Curie, Ottawa, Ontario K1N 6N5, Canada"},{"name":"Consejo Nacional de Investigaciones Cient\u00edficas y T\u00e9cnicas (CONICET)\u2013Universidad de Buenos Aires, Unidad de Microan\u00e1lisis y M\u00e9todos F\u00edsicos en Qu\u00edmica Org\u00e1nica (UMYMFOR), Intendente G\u00fciraldes 2160, Piso 3, Ciudad Universitaria, Buenos Aires, C1428EGA, Argentina"},{"name":"Universidad de Buenos Aires, Facultad de Ciencias Exactas y Naturales, Departamento de Qu\u00edmica Org\u00e1nica, Intendente G\u00fciraldes 2160, Piso 3, Ciudad Universitaria, Buenos Aires, C1428EGA, Argentina"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-1949-5069","authenticated-orcid":false,"given":"Stephen G.","family":"Newman","sequence":"additional","affiliation":[{"name":"Centre for Catalysis Research and Innovation, Department of Chemistry and Biomolecular Sciences, University of Ottawa, 10 Marie Curie, Ottawa, Ontario K1N 6N5, Canada"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"292","published-online":{"date-parts":[[2026]]},"reference":[{"key":"D6CC05112J\/cit1\/1","doi-asserted-by":"crossref","first-page":"240","DOI":"10.1016\/j.ccr.2019.02.003","volume":"386","author":"Iglesias","year":"2019","journal-title":"Coord. Chem. Rev."},{"key":"D6CC05112J\/cit2\/1","doi-asserted-by":"crossref","first-page":"8084","DOI":"10.1021\/jacs.6b04818","volume":"138","author":"Zhang","year":"2016","journal-title":"J. Am. Chem. Soc."},{"key":"D6CC05112J\/cit3\/1","doi-asserted-by":"crossref","first-page":"7392","DOI":"10.1039\/D2SC02324E","volume":"13","author":"R\u00edos","year":"2022","journal-title":"Chem. Sci."},{"key":"D6CC05112J\/cit4\/1","doi-asserted-by":"crossref","first-page":"7741","DOI":"10.1021\/jo0158534","volume":"66","author":"Yasuda","year":"2001","journal-title":"J. Org. Chem."},{"key":"D6CC05112J\/cit5\/1","doi-asserted-by":"crossref","first-page":"e202201149","DOI":"10.1002\/celc.202201149","volume":"10","author":"Beck","year":"2023","journal-title":"ChemElectroChem"},{"key":"D6CC05112J\/cit6\/1","volume-title":"Silicon in Organic, Organometallic, and Polymer Chemistry","author":"Brook","year":"1999","unstructured":"M. A.Brook ,  Silicon in Organic, Organometallic, and Polymer Chemistry ,  Wiley-Interscience ,  New York ,  1999"},{"key":"D6CC05112J\/cit7\/1","doi-asserted-by":"crossref","first-page":"1371","DOI":"10.1021\/cr00020a003","volume":"93","author":"Chuit","year":"1993","journal-title":"Chem. Rev."},{"key":"D6CC05112J\/cit8\/1","doi-asserted-by":"crossref","first-page":"7053","DOI":"10.1021\/acsomega.0c00366","volume":"5","author":"Jenkins","year":"2020","journal-title":"ACS Omega"},{"key":"D6CC05112J\/cit9\/1","doi-asserted-by":"crossref","first-page":"2297","DOI":"10.1021\/om00053a035","volume":"10","author":"Corriu","year":"1991","journal-title":"Organometallics"},{"key":"D6CC05112J\/cit10\/1","doi-asserted-by":"crossref","first-page":"C25","DOI":"10.1016\/0022-328X(89)85321-5","volume":"368","author":"Becker","year":"1989","journal-title":"J. Organomet. Chem."},{"key":"D6CC05112J\/cit11\/1","doi-asserted-by":"crossref","first-page":"3574","DOI":"10.1021\/om00056a030","volume":"10","author":"Corriu","year":"1991","journal-title":"Organometallics"},{"key":"D6CC05112J\/cit12\/1","doi-asserted-by":"crossref","first-page":"839","DOI":"10.1002\/chem.201302728","volume":"20","author":"Revunova","year":"2014","journal-title":"Chem. \u2013 Eur. J."},{"key":"D6CC05112J\/cit13\/1","doi-asserted-by":"crossref","first-page":"2267","DOI":"10.1021\/jo00362a019","volume":"51","author":"Yang","year":"1986","journal-title":"J. Org. Chem."},{"key":"D6CC05112J\/cit14\/1","doi-asserted-by":"crossref","first-page":"C7","DOI":"10.1016\/0022-328X(89)87040-8","volume":"365","author":"Corriu","year":"1989","journal-title":"J. Organomet. Chem."},{"key":"D6CC05112J\/cit15\/1","doi-asserted-by":"crossref","first-page":"1640","DOI":"10.1039\/c3sc22256j","volume":"4","author":"Fedorov","year":"2013","journal-title":"Chem. Sci."},{"key":"D6CC05112J\/cit16\/1","doi-asserted-by":"crossref","first-page":"80","DOI":"10.1038\/nature14126","volume":"518","author":"Toutov","year":"2015","journal-title":"Nature"},{"key":"D6CC05112J\/cit17\/1","doi-asserted-by":"crossref","first-page":"510","DOI":"10.1016\/j.ccr.2015.02.004","volume":"306","author":"Deuss","year":"2016","journal-title":"Coord. Chem. Rev."},{"key":"D6CC05112J\/cit18\/1","doi-asserted-by":"crossref","first-page":"17008","DOI":"10.1038\/nenergy.2017.8","volume":"2","author":"Toutov","year":"2017","journal-title":"Nat. Energy"},{"key":"D6CC05112J\/cit19\/1","doi-asserted-by":"crossref","first-page":"3","DOI":"10.1016\/j.cattod.2004.07.048","volume":"98","author":"Ho","year":"2004","journal-title":"Catal. Today"},{"key":"D6CC05112J\/cit20\/1","doi-asserted-by":"crossref","first-page":"84","DOI":"10.1016\/j.cattod.2005.10.008","volume":"111","author":"Prins","year":"2006","journal-title":"Catal. Today"},{"key":"D6CC05112J\/cit21\/1","doi-asserted-by":"crossref","first-page":"4277","DOI":"10.1016\/j.jorganchem.2004.05.027","volume":"689","author":"Bianchini","year":"2004","journal-title":"J. Organomet. Chem."},{"key":"D6CC05112J\/cit22\/1","doi-asserted-by":"crossref","first-page":"13747","DOI":"10.1002\/anie.201707914","volume":"56","author":"Smith","year":"2017","journal-title":"Angew. Chem., Int. Ed."},{"key":"D6CC05112J\/cit23\/1","doi-asserted-by":"crossref","first-page":"4925","DOI":"10.1021\/jo971751v","volume":"63","author":"Talukdar","year":"1998","journal-title":"J. Org. Chem."},{"key":"D6CC05112J\/cit24\/1","doi-asserted-by":"crossref","first-page":"7177","DOI":"10.1021\/ja00362a030","volume":"105","author":"Fujiwara","year":"1983","journal-title":"J. Am. Chem. Soc."},{"key":"D6CC05112J\/cit25\/1","doi-asserted-by":"crossref","first-page":"1030","DOI":"10.1021\/acs.orglett.3c00258","volume":"25","author":"St. Onge","year":"2023","journal-title":"Org. Lett."},{"key":"D6CC05112J\/cit26\/1","first-page":"2307","volume":"22","author":"Cousins","year":"2020","journal-title":"Environ. Sci.: Processes Impacts"},{"key":"D6CC05112J\/cit27\/1","doi-asserted-by":"crossref","first-page":"3719","DOI":"10.1039\/D0SC00361A","volume":"11","author":"Smith","year":"2020","journal-title":"Chem. Sci."},{"key":"D6CC05112J\/cit28a\/1","doi-asserted-by":"crossref","first-page":"3855","DOI":"10.1021\/acs.orglett.9b01353","volume":"21","author":"Tsuchiya","year":"2019","journal-title":"Org. Lett."},{"key":"D6CC05112J\/cit28b\/1","doi-asserted-by":"crossref","first-page":"1019","DOI":"10.1246\/cl.190393","volume":"48","author":"Saito","year":"2019","journal-title":"Chem. Lett."},{"key":"D6CC05112J\/cit29\/1","doi-asserted-by":"crossref","first-page":"12364","DOI":"10.1039\/D0SC04244G","volume":"11","author":"Smith","year":"2020","journal-title":"Chem. Sci."},{"key":"D6CC05112J\/cit30\/1","doi-asserted-by":"crossref","first-page":"2260","DOI":"10.1002\/adsc.202000356","volume":"362","author":"Arokianathar","year":"2020","journal-title":"Adv. Synth. Catal."},{"key":"D6CC05112J\/cit31\/1","doi-asserted-by":"crossref","first-page":"6879","DOI":"10.3390\/molecules26226879","volume":"26","author":"Kolodziejczak","year":"2021","journal-title":"Molecules"},{"key":"D6CC05112J\/cit32\/1","doi-asserted-by":"crossref","first-page":"6880","DOI":"10.1021\/jacs.6b13032","volume":"139","author":"Banerjee","year":"2017","journal-title":"J. Am. Chem. Soc."},{"key":"D6CC05112J\/cit33\/1","doi-asserted-by":"crossref","first-page":"6867","DOI":"10.1021\/jacs.6b13031","volume":"139","author":"Liu","year":"2017","journal-title":"J. Am. Chem. Soc."},{"key":"D6CC05112J\/cit34\/1","doi-asserted-by":"crossref","first-page":"e202517336","DOI":"10.1002\/anie.202517336","volume":"64","author":"Jenkins","year":"2025","journal-title":"Angew. Chem., Int. Ed."},{"key":"D6CC05112J\/cit35\/1","doi-asserted-by":"crossref","first-page":"1668","DOI":"10.1021\/jacs.6b12114","volume":"139","author":"Toutov","year":"2017","journal-title":"J. Am. Chem. Soc."},{"key":"D6CC05112J\/cit36\/1","doi-asserted-by":"crossref","first-page":"449","DOI":"10.1007\/s11426-017-9163-2","volume":"61","author":"Yu","year":"2018","journal-title":"Sci. China: Chem."},{"key":"D6CC05112J\/cit37\/1","doi-asserted-by":"crossref","first-page":"e1900235","DOI":"10.1002\/hlca.201900235","volume":"102","author":"Palumbo","year":"2019","journal-title":"Helv. Chim. Acta"},{"key":"D6CC05112J\/cit38\/1","doi-asserted-by":"crossref","first-page":"164","DOI":"10.1038\/s41929-018-0217-z","volume":"2","author":"Asgari","year":"2019","journal-title":"Nat. Catal."},{"key":"D6CC05112J\/cit39\/1","doi-asserted-by":"crossref","first-page":"9659","DOI":"10.1021\/jacs.8b05744","volume":"140","author":"Xie","year":"2018","journal-title":"J. Am. Chem. Soc."},{"key":"D6CC05112J\/cit40\/1","doi-asserted-by":"crossref","first-page":"e202421077","DOI":"10.1002\/anie.202421077","volume":"64","author":"Onge","year":"2025","journal-title":"Angew. Chem., Int. Ed."},{"key":"D6CC05112J\/cit41\/1","doi-asserted-by":"crossref","first-page":"9081","DOI":"10.1039\/D5SC10055K","volume":"17","author":"Stewart","year":"2026","journal-title":"Chem. Sci."},{"key":"D6CC05112J\/cit42\/1","doi-asserted-by":"publisher","DOI":"10.26434\/chemrxiv.15004559","volume-title":"ChemRxiv","author":"Onge","year":"2026","unstructured":"P.Onge ,  B.White ,  H.Yao ,  T.Dudding  and  S. G.Newman ,  ChemRxiv ,  2026 , preprint 10.26434\/chemrxiv.15004559"}],"container-title":["Chemical Communications"],"original-title":[],"language":"en","link":[{"URL":"http:\/\/pubs.rsc.org\/CC\/article-pdf\/doi\/10.1039\/D6CC05112J\/0\/D6CC05112J.pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,9,23]],"date-time":"2026-09-23T09:01:08Z","timestamp":1790154068000},"score":1,"resource":{"primary":{"URL":"http:\/\/pubs.rsc.org\/CC\/article-lookup\/doi\/10.1039\/D6CC05112J"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026]]},"references-count":43,"URL":"https:\/\/doi.org\/10.1039\/d6cc05112j","relation":{},"ISSN":["1359-7345","1364-548X"],"issn-type":[{"value":"1359-7345","type":"print"},{"value":"1364-548X","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026]]}}}