{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,7,1]],"date-time":"2026-07-01T04:53:26Z","timestamp":1782881606021,"version":"3.54.5"},"reference-count":48,"publisher":"Royal Society of Chemistry (RSC)","issue":"23","license":[{"start":{"date-parts":[[2027,5,13]],"date-time":"2027-05-13T00:00:00Z","timestamp":1810166400000},"content-version":"am","delay-in-days":497,"URL":"http:\/\/rsc.li\/journals-terms-of-use"}],"funder":[{"DOI":"10.13039\/501100005047","name":"Natural Science Foundation of Liaoning Province","doi-asserted-by":"publisher","award":["2023-MS-072"],"award-info":[{"award-number":["2023-MS-072"]}],"id":[{"id":"10.13039\/501100005047","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100018617","name":"Liaoning Revitalization Talents Program","doi-asserted-by":"publisher","award":["XLYC1907033"],"award-info":[{"award-number":["XLYC1907033"]}],"id":[{"id":"10.13039\/501100018617","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100012226","name":"Fundamental Research Funds for the Central Universities","doi-asserted-by":"publisher","award":["N25LPY025"],"award-info":[{"award-number":["N25LPY025"]}],"id":[{"id":"10.13039\/501100012226","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100015257","name":"Northeastern University","doi-asserted-by":"publisher","id":[{"id":"10.13039\/100015257","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100007765","name":"Shenyang Municipal Bureau of Science and Technology","doi-asserted-by":"publisher","award":["24-202-6-07"],"award-info":[{"award-number":["24-202-6-07"]}],"id":[{"id":"10.13039\/501100007765","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["rsc.org"],"crossmark-restriction":true},"short-container-title":["Phys. Chem. Chem. Phys."],"abstract":"<jats:p>\n                    AFM monolayer Mn\n                    <jats:sub>2<\/jats:sub>\n                    X\n                    <jats:sub>2<\/jats:sub>\n                    exhibits pronounced valley splitting driven by antiferromagnetism and SOC. The valley polarization can be effectively tuned by biaxial strain and Hubbard\n                    <jats:italic>U<\/jats:italic>\n                    , highlighting Mn\n                    <jats:sub>2<\/jats:sub>\n                    X\n                    <jats:sub>2<\/jats:sub>\n                    as a promising AFM valleytronic platform.\n                  <\/jats:p>","DOI":"10.1039\/d6cp00299d","type":"journal-article","created":{"date-parts":[[2026,5,13]],"date-time":"2026-05-13T06:41:48Z","timestamp":1778654508000},"page":"13956-13962","update-policy":"https:\/\/doi.org\/10.1039\/rsc_crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Tunable valley splitting and magnetic anisotropy in two-dimensional buckled honeycomb lattice Mn\n                    <sub>2<\/sub>\n                    X\n                    <sub>2<\/sub>\n                    (X = F, Cl, Br)"],"prefix":"10.1039","volume":"28","author":[{"ORCID":"https:\/\/orcid.org\/0009-0009-4972-2550","authenticated-orcid":false,"given":"Mingyu","family":"L\u00fc","sequence":"first","affiliation":[{"name":"College of Sciences, Northeastern University, Shenyang 110819, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Wendan","family":"Song","sequence":"additional","affiliation":[{"name":"College of Sciences, Northeastern University, Shenyang 110819, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0002-0298-7163","authenticated-orcid":false,"given":"Yuping","family":"Tian","sequence":"additional","affiliation":[{"name":"College of Sciences, Northeastern University, Shenyang 110819, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Chao-Bo","family":"Wang","sequence":"additional","affiliation":[{"name":"College of Sciences, Northeastern University, Shenyang 110819, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xuefeng","family":"Dai","sequence":"additional","affiliation":[{"name":"College of Sciences, Northeastern University, Shenyang 110819, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xudong","family":"Su","sequence":"additional","affiliation":[{"name":"College of Sciences, Northeastern University, Shenyang 110819, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-6143-4038","authenticated-orcid":false,"given":"Xiangru","family":"Kong","sequence":"additional","affiliation":[{"name":"College of Sciences, Northeastern University, Shenyang 110819, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-9100-2885","authenticated-orcid":false,"given":"Wei-Jiang","family":"Gong","sequence":"additional","affiliation":[{"name":"College of Sciences, Northeastern University, Shenyang 110819, China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"292","published-online":{"date-parts":[[2026]]},"reference":[{"key":"D6CP00299D\/cit1\/1","doi-asserted-by":"crossref","first-page":"6","DOI":"10.1038\/s44306-024-00011-w","volume":"2","author":"Zhang","year":"2024","journal-title":"npj Spintron."},{"key":"D6CP00299D\/cit2\/1","doi-asserted-by":"crossref","first-page":"14909","DOI":"10.1021\/acs.nanolett.4c04251","volume":"24","author":"Pan","year":"2024","journal-title":"Nano Lett."},{"key":"D6CP00299D\/cit3\/1","doi-asserted-by":"crossref","first-page":"183","DOI":"10.1016\/j.mattod.2023.11.008","volume":"72","author":"Elahi","year":"2024","journal-title":"Mater. Today"},{"key":"D6CP00299D\/cit4\/1","doi-asserted-by":"crossref","first-page":"895","DOI":"10.1038\/s41565-024-01695-1","volume":"19","author":"Kim","year":"2024","journal-title":"Nat. Nanotechnol."},{"key":"D6CP00299D\/cit5\/1","doi-asserted-by":"crossref","first-page":"187","DOI":"10.1021\/acsnano.4c14733","volume":"19","author":"Zhang","year":"2025","journal-title":"ACS Nano"},{"key":"D6CP00299D\/cit6\/1","doi-asserted-by":"crossref","first-page":"2309046","DOI":"10.1002\/adfm.202309046","volume":"34","author":"Papavasileiou","year":"2024","journal-title":"Adv. Funct. Mater."},{"key":"D6CP00299D\/cit7\/1","doi-asserted-by":"crossref","first-page":"e2206574","DOI":"10.1002\/smll.202206574","volume":"19","author":"Bai","year":"2023","journal-title":"Small"},{"key":"D6CP00299D\/cit8\/1","doi-asserted-by":"crossref","first-page":"8161","DOI":"10.1007\/s12598-025-03413-9","volume":"44","author":"Co\u015fkun","year":"2025","journal-title":"Rare Met."},{"key":"D6CP00299D\/cit9\/1","doi-asserted-by":"crossref","first-page":"3954","DOI":"10.1039\/C8CP07444E","volume":"21","author":"Ma","year":"2019","journal-title":"Phys. Chem. Chem. Phys."},{"key":"D6CP00299D\/cit10\/1","doi-asserted-by":"crossref","first-page":"107584","DOI":"10.1016\/j.isci.2023.107584","volume":"26","author":"Liu","year":"2023","journal-title":"iScience"},{"key":"D6CP00299D\/cit11\/1","doi-asserted-by":"crossref","first-page":"212","DOI":"10.1038\/s41563-023-01735-6","volume":"23","author":"Boix-Constant","year":"2024","journal-title":"Nat. Mater."},{"key":"D6CP00299D\/cit12\/1","first-page":"4826","volume":"24","author":"Chen","year":"2024","journal-title":"Nano Lett."},{"key":"D6CP00299D\/cit13\/1","doi-asserted-by":"crossref","first-page":"91","DOI":"10.1021\/acs.nanolett.2c03680","volume":"23","author":"Li","year":"2023","journal-title":"Nano Lett."},{"key":"D6CP00299D\/cit14\/1","doi-asserted-by":"crossref","first-page":"022006","DOI":"10.1088\/2515-7639\/ad3b6e","volume":"7","author":"Luo","year":"2024","journal-title":"J. Phys. Mater."},{"key":"D6CP00299D\/cit15\/1","doi-asserted-by":"crossref","first-page":"746","DOI":"10.1038\/s41586-024-07156-y","volume":"628","author":"Tyulnev","year":"2024","journal-title":"Nature"},{"key":"D6CP00299D\/cit16\/1","doi-asserted-by":"crossref","first-page":"5451","DOI":"10.1039\/D4TC00115J","volume":"12","author":"Li","year":"2024","journal-title":"J. Mater. Chem. C"},{"key":"D6CP00299D\/cit17\/1","doi-asserted-by":"crossref","first-page":"047304","DOI":"10.1088\/1674-1056\/ad1c59","volume":"33","author":"Chen","year":"2024","journal-title":"Chin. Phys. B"},{"key":"D6CP00299D\/cit18\/1","doi-asserted-by":"crossref","first-page":"080502","DOI":"10.1063\/5.0250823","volume":"126","author":"Guo","year":"2025","journal-title":"Appl. Phys. Lett."},{"key":"D6CP00299D\/cit19\/1","doi-asserted-by":"crossref","first-page":"13276","DOI":"10.1021\/acs.nanolett.5c03229","volume":"25","author":"Ali","year":"2025","journal-title":"Nano Lett."},{"key":"D6CP00299D\/cit20\/1","doi-asserted-by":"crossref","first-page":"580","DOI":"10.1039\/D5NA00834D","volume":"8","author":"Park","year":"2026","journal-title":"Nanoscale Adv."},{"key":"D6CP00299D\/cit21\/1","doi-asserted-by":"crossref","first-page":"684","DOI":"10.1038\/s41563-023-01492-6","volume":"22","author":"Han","year":"2023","journal-title":"Nat. Mater."},{"key":"D6CP00299D\/cit22\/1","doi-asserted-by":"crossref","first-page":"1045","DOI":"10.1038\/s41586-024-07818-x","volume":"632","author":"Chen","year":"2024","journal-title":"Nature"},{"key":"D6CP00299D\/cit23\/1","doi-asserted-by":"crossref","first-page":"25","DOI":"10.1038\/s44306-024-00029-0","volume":"2","author":"Dal Din","year":"2024","journal-title":"npj Spintron."},{"key":"D6CP00299D\/cit24\/1","doi-asserted-by":"crossref","first-page":"13","DOI":"10.1038\/s44306-024-00014-7","volume":"2","author":"Shao","year":"2024","journal-title":"npj Spintron."},{"key":"D6CP00299D\/cit25\/1","doi-asserted-by":"crossref","first-page":"eadn0479","DOI":"10.1126\/sciadv.adn0479","volume":"10","author":"Han","year":"2024","journal-title":"Sci. Adv."},{"key":"D6CP00299D\/cit26\/1","doi-asserted-by":"crossref","first-page":"125408","DOI":"10.1103\/PhysRevB.107.125408","volume":"107","author":"Xu","year":"2023","journal-title":"Phys. Rev. B"},{"key":"D6CP00299D\/cit27\/1","doi-asserted-by":"crossref","first-page":"L140416","DOI":"10.1103\/PhysRevB.111.L140416","volume":"111","author":"Jiang","year":"2025","journal-title":"Phys. Rev. B"},{"key":"D6CP00299D\/cit28\/1","doi-asserted-by":"crossref","first-page":"134426","DOI":"10.1103\/PhysRevB.109.134426","volume":"109","author":"Guo","year":"2024","journal-title":"Phys. Rev. B"},{"key":"D6CP00299D\/cit29\/1","doi-asserted-by":"crossref","first-page":"024416","DOI":"10.1103\/PhysRevB.110.024416","volume":"110","author":"Guo","year":"2024","journal-title":"Phys. Rev. B"},{"key":"D6CP00299D\/cit30\/1","doi-asserted-by":"crossref","first-page":"269","DOI":"10.1016\/j.jmat.2023.10.008","volume":"10","author":"Zhao","year":"2024","journal-title":"J. Materiomics"},{"key":"D6CP00299D\/cit31\/1","doi-asserted-by":"crossref","first-page":"17953","DOI":"10.1103\/PhysRevB.50.17953","volume":"50","author":"Bl\u00f6chl","year":"1994","journal-title":"Phys. Rev. B:Condens. Matter Mater. Phys."},{"key":"D6CP00299D\/cit32\/1","doi-asserted-by":"crossref","first-page":"11169","DOI":"10.1103\/PhysRevB.54.11169","volume":"54","author":"Kresse","year":"1996","journal-title":"Phys. Rev. B: Condens. Matter Mater. Phys."},{"key":"D6CP00299D\/cit33\/1","doi-asserted-by":"crossref","first-page":"3865","DOI":"10.1103\/PhysRevLett.77.3865","volume":"77","author":"Perdew","year":"1996","journal-title":"Phys. Rev. Lett."},{"key":"D6CP00299D\/cit34\/1","doi-asserted-by":"crossref","first-page":"12705","DOI":"10.1021\/acs.jpcc.0c01308","volume":"124","author":"Li","year":"2020","journal-title":"J. Phys. Chem. C"},{"key":"D6CP00299D\/cit35\/1","doi-asserted-by":"crossref","first-page":"19673","DOI":"10.1039\/D1CP02000E","volume":"23","author":"Li","year":"2021","journal-title":"Phys. Chem. Chem. Phys."},{"key":"D6CP00299D\/cit36\/1","doi-asserted-by":"crossref","first-page":"085432","DOI":"10.1103\/PhysRevB.111.085432","volume":"111","author":"Wang","year":"2025","journal-title":"Phys. Rev. B"},{"key":"D6CP00299D\/cit37\/1","doi-asserted-by":"crossref","first-page":"1","DOI":"10.1016\/j.scriptamat.2015.07.021","volume":"108","author":"Togo","year":"2015","journal-title":"Scr. Mater."},{"key":"D6CP00299D\/cit38\/1","doi-asserted-by":"crossref","first-page":"511","DOI":"10.1063\/1.447334","volume":"81","author":"Nos\u00e9","year":"1984","journal-title":"J. Chem. Phys."},{"key":"D6CP00299D\/cit39\/1","doi-asserted-by":"crossref","first-page":"100625","DOI":"10.1016\/j.patter.2022.100625","volume":"3","author":"Kabiraj","year":"2022","journal-title":"Patterns"},{"key":"D6CP00299D\/cit40\/1","doi-asserted-by":"crossref","first-page":"685","DOI":"10.1016\/j.cpc.2007.11.016","volume":"178","author":"Mostofi","year":"2008","journal-title":"Comput. Phys. Commun."},{"key":"D6CP00299D\/cit41\/1","doi-asserted-by":"crossref","first-page":"2309","DOI":"10.1016\/j.cpc.2014.05.003","volume":"185","author":"Mostofi","year":"2014","journal-title":"Comput. Phys. Commun."},{"key":"D6CP00299D\/cit42\/1","doi-asserted-by":"crossref","first-page":"024203","DOI":"10.15302\/frontphys.2025.024203","volume":"20","author":"Huang","year":"2025","journal-title":"Front. Phys."},{"key":"D6CP00299D\/cit43\/1","doi-asserted-by":"crossref","first-page":"2108847","DOI":"10.1002\/adma.202108847","volume":"34","author":"Zeng","year":"2022","journal-title":"Adv. Mater."},{"key":"D6CP00299D\/cit44\/1","doi-asserted-by":"crossref","first-page":"7433","DOI":"10.1021\/acs.nanolett.6b03052","volume":"16","author":"Lee","year":"2016","journal-title":"Nano Lett."},{"key":"D6CP00299D\/cit45\/1","doi-asserted-by":"crossref","first-page":"6195","DOI":"10.1021\/acs.nanolett.7b02855","volume":"17","author":"Li","year":"2017","journal-title":"Nano Lett."},{"key":"D6CP00299D\/cit46\/1","doi-asserted-by":"crossref","first-page":"2200816","DOI":"10.1002\/advs.202200816","volume":"9","author":"Liu","year":"2022","journal-title":"Adv. Sci."},{"key":"D6CP00299D\/cit47\/1","doi-asserted-by":"crossref","first-page":"1650","DOI":"10.1038\/s41467-022-29281-w","volume":"13","author":"Lu","year":"2022","journal-title":"Nat. Commun."},{"key":"D6CP00299D\/cit48\/1","doi-asserted-by":"crossref","first-page":"405","DOI":"10.1103\/PhysRevLett.49.405","volume":"49","author":"Thouless","year":"1982","journal-title":"Phys. Rev. Lett."}],"container-title":["Physical Chemistry Chemical Physics"],"original-title":[],"language":"en","link":[{"URL":"http:\/\/pubs.rsc.org\/en\/content\/articlepdf\/2026\/CP\/D6CP00299D","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,7,1]],"date-time":"2026-07-01T03:50:21Z","timestamp":1782877821000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.rsc.org\/cp\/article\/28\/23\/13956-13962\/1222849"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026]]},"references-count":48,"journal-issue":{"issue":"23","published-print":{"date-parts":[[2026,6,17]]}},"URL":"https:\/\/doi.org\/10.1039\/d6cp00299d","relation":{},"ISSN":["1463-9076","1463-9084"],"issn-type":[{"value":"1463-9076","type":"print"},{"value":"1463-9084","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026]]}}}