{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,7,30]],"date-time":"2026-07-30T03:21:13Z","timestamp":1785381673474,"version":"3.55.0"},"reference-count":65,"publisher":"Royal Society of Chemistry (RSC)","issue":"26","license":[{"start":{"date-parts":[[2027,5,22]],"date-time":"2027-05-22T00:00:00Z","timestamp":1810944000000},"content-version":"am","delay-in-days":506,"URL":"http:\/\/rsc.li\/journals-terms-of-use"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22422302"],"award-info":[{"award-number":["22422302"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["52303148"],"award-info":[{"award-number":["52303148"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["rsc.org"],"crossmark-restriction":true},"short-container-title":["Phys. Chem. Chem. Phys."],"abstract":"<jats:p>CB[8]\u2013spiropyran binding reveals size-dependent gating: small guests are retained, while bulky isomers escape rapidly, providing a confinement mechanism for supramolecular delivery design.<\/jats:p>","DOI":"10.1039\/d6cp00611f","type":"journal-article","created":{"date-parts":[[2026,5,22]],"date-time":"2026-05-22T15:23:16Z","timestamp":1779463396000},"page":"15898-15909","update-policy":"https:\/\/doi.org\/10.1039\/rsc_crossmark_policy","source":"Crossref","is-referenced-by-count":1,"title":["Thermodynamic selectivity and kinetic control in the encapsulation of spiropyran derivatives by cucurbit[8]uril"],"prefix":"10.1039","volume":"28","author":[{"given":"Yinghui","family":"Niu","sequence":"first","affiliation":[{"name":"State Key Laboratory of Advanced Fiber Materials, College of Materials Science and Engineering, Donghua University, Shanghai 201620, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Fengbiao","family":"Chen","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Advanced Fiber Materials, College of Materials Science and Engineering, Donghua University, Shanghai 201620, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xinru","family":"Guo","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Advanced Fiber Materials, College of Materials Science and Engineering, Donghua University, Shanghai 201620, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yinjun","family":"Chen","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Advanced Fiber Materials, College of Materials Science and Engineering, Donghua University, Shanghai 201620, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-6136-8771","authenticated-orcid":false,"given":"Jin","family":"Wen","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Advanced Fiber Materials, College of Materials Science and Engineering, Donghua University, Shanghai 201620, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5228-8216","authenticated-orcid":false,"given":"Meifang","family":"Zhu","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Advanced Fiber Materials, College of Materials Science and Engineering, Donghua University, Shanghai 201620, China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"292","published-online":{"date-parts":[[2026]]},"reference":[{"key":"D6CP00611F\/cit1\/1","doi-asserted-by":"crossref","first-page":"1741","DOI":"10.1021\/cr9800715","volume":"100","author":"Berkovic","year":"2000","journal-title":"Chem. Rev."},{"key":"D6CP00611F\/cit2\/1","doi-asserted-by":"crossref","first-page":"1789","DOI":"10.1021\/cr9900228","volume":"100","author":"Feringa","year":"2000","journal-title":"Chem. Rev."},{"key":"D6CP00611F\/cit3\/1","doi-asserted-by":"crossref","first-page":"1875","DOI":"10.1021\/cr9800816","volume":"100","author":"Tamai","year":"2000","journal-title":"Chem. Rev."},{"key":"D6CP00611F\/cit4\/1","doi-asserted-by":"crossref","first-page":"639","DOI":"10.1351\/pac200173040639","volume":"73","author":"Bouas-Laurent","year":"2001","journal-title":"Pure Appl. Chem."},{"key":"D6CP00611F\/cit5\/1","doi-asserted-by":"crossref","first-page":"148","DOI":"10.1039\/C3CS60181A","volume":"43","author":"Klajn","year":"2014","journal-title":"Chem. Soc. Rev."},{"key":"D6CP00611F\/cit6\/1","doi-asserted-by":"crossref","first-page":"297","DOI":"10.1039\/jr9540000297","author":"Hirshberg","year":"1954","journal-title":"J. Chem. Soc."},{"key":"D6CP00611F\/cit7\/1","doi-asserted-by":"crossref","first-page":"287","DOI":"10.1039\/B818050D","author":"Stafforst","year":"2009","journal-title":"Chem. Commun."},{"key":"D6CP00611F\/cit8\/1","doi-asserted-by":"crossref","first-page":"1517","DOI":"10.1021\/acs.orglett.5b00397","volume":"17","author":"\u00d6z\u00e7oban","year":"2015","journal-title":"Org. Lett."},{"key":"D6CP00611F\/cit9\/1","doi-asserted-by":"crossref","first-page":"720087","DOI":"10.3389\/fchem.2021.720087","volume":"9","author":"Fagan","year":"2021","journal-title":"Front. Chem."},{"key":"D6CP00611F\/cit10\/1","doi-asserted-by":"crossref","first-page":"8447","DOI":"10.1021\/jacs.0c02201","volume":"142","author":"Li","year":"2020","journal-title":"J. Am. Chem. Soc."},{"key":"D6CP00611F\/cit11\/1","doi-asserted-by":"crossref","first-page":"136963","DOI":"10.1016\/j.molstruc.2023.136963","volume":"1298","author":"Felicio","year":"2024","journal-title":"J. Mol. Struct."},{"key":"D6CP00611F\/cit12\/1","doi-asserted-by":"crossref","first-page":"12577","DOI":"10.1021\/jp207708x","volume":"115","author":"Miskolczy","year":"2011","journal-title":"J. Phys. Chem. B"},{"key":"D6CP00611F\/cit13\/1","doi-asserted-by":"crossref","first-page":"151","DOI":"10.1016\/j.matchemphys.2012.06.045","volume":"136","author":"Wang","year":"2012","journal-title":"Mater. Chem. Phys."},{"key":"D6CP00611F\/cit14\/1","doi-asserted-by":"crossref","first-page":"7794","DOI":"10.1021\/cr500392w","volume":"115","author":"Ma","year":"2015","journal-title":"Chem. Rev."},{"key":"D6CP00611F\/cit15\/1","doi-asserted-by":"crossref","first-page":"1875","DOI":"10.1021\/cr970015o","volume":"98","author":"Rekharsky","year":"1998","journal-title":"Chem. Rev."},{"key":"D6CP00611F\/cit16\/1","doi-asserted-by":"crossref","first-page":"25994","DOI":"10.1039\/D4CP01497A","volume":"26","author":"Xu","year":"2024","journal-title":"Phys. Chem. Chem. Phys."},{"key":"D6CP00611F\/cit17\/1","doi-asserted-by":"crossref","first-page":"3406","DOI":"10.1039\/C9CS00203K","volume":"48","author":"Kortekaas","year":"2019","journal-title":"Chem. Soc. Rev."},{"key":"D6CP00611F\/cit18\/1","doi-asserted-by":"crossref","first-page":"2260","DOI":"10.3390\/molecules13092260","volume":"13","author":"Maafi","year":"2008","journal-title":"Molecules"},{"key":"D6CP00611F\/cit19\/1","doi-asserted-by":"crossref","first-page":"15479","DOI":"10.1021\/acs.inorgchem.9b02547","volume":"58","author":"Feuerstein","year":"2019","journal-title":"Inorg. Chem."},{"key":"D6CP00611F\/cit20\/1","doi-asserted-by":"crossref","first-page":"2408484","DOI":"10.1002\/adma.202408484","volume":"36","author":"Du","year":"2024","journal-title":"Adv. Mater."},{"key":"D6CP00611F\/cit21\/1","doi-asserted-by":"crossref","first-page":"1075670","DOI":"10.3389\/fbioe.2022.1075670","volume":"10","author":"Xing","year":"2022","journal-title":"Front. Bioeng. Biotechnol."},{"key":"D6CP00611F\/cit22\/1","doi-asserted-by":"crossref","first-page":"121654","DOI":"10.1016\/j.ijpharm.2022.121654","volume":"618","author":"Jansook","year":"2022","journal-title":"Int. J. Pharm."},{"key":"D6CP00611F\/cit23\/1","doi-asserted-by":"crossref","first-page":"2037","DOI":"10.1039\/b925555a","volume":"8","author":"Uzunova","year":"2010","journal-title":"Org. Biomol. Chem."},{"key":"D6CP00611F\/cit24\/1","doi-asserted-by":"crossref","first-page":"3918","DOI":"10.1038\/s41467-023-39610-2","volume":"14","author":"Wu","year":"2023","journal-title":"Nat. Commun."},{"key":"D6CP00611F\/cit25\/1","doi-asserted-by":"crossref","first-page":"9955","DOI":"10.1002\/chem.201200497","volume":"18","author":"Grimme","year":"2012","journal-title":"Chem. \u2013 Eur. J."},{"key":"D6CP00611F\/cit26\/1","doi-asserted-by":"crossref","first-page":"154104","DOI":"10.1063\/1.3382344","volume":"132","author":"Grimme","year":"2010","journal-title":"J. Chem. Phys."},{"key":"D6CP00611F\/cit27\/1","doi-asserted-by":"crossref","first-page":"6615","DOI":"10.1039\/b810189b","volume":"10","author":"Chai","year":"2008","journal-title":"Phys. Chem. Chem. Phys."},{"key":"D6CP00611F\/cit28\/1","doi-asserted-by":"crossref","first-page":"2105","DOI":"10.3390\/molecules27072105","volume":"27","author":"Filipe","year":"2022","journal-title":"Molecules"},{"key":"D6CP00611F\/cit29\/1","doi-asserted-by":"crossref","first-page":"120","DOI":"10.1016\/j.sbi.2009.03.004","volume":"19","author":"Klepeis","year":"2009","journal-title":"Curr. Opin. Struct. Biol."},{"key":"D6CP00611F\/cit30\/1","doi-asserted-by":"crossref","first-page":"899805","DOI":"10.3389\/fmolb.2022.899805","volume":"9","author":"Ahmad","year":"2022","journal-title":"Front. Mol. Biosci."},{"key":"D6CP00611F\/cit31\/1","doi-asserted-by":"crossref","first-page":"187","DOI":"10.1016\/0021-9991(77)90121-8","volume":"23","author":"Torrie","year":"1977","journal-title":"J. Comput. Phys."},{"key":"D6CP00611F\/cit32\/1","doi-asserted-by":"crossref","first-page":"1011","DOI":"10.1002\/jcc.540130812","volume":"13","author":"Kumar","year":"1992","journal-title":"J. Comput. Chem."},{"key":"D6CP00611F\/cit33\/1","doi-asserted-by":"crossref","first-page":"275","DOI":"10.1016\/0010-4655(95)00053-I","volume":"91","author":"Roux","year":"1995","journal-title":"Comput. Phys. Commun."},{"key":"D6CP00611F\/cit34\/1","doi-asserted-by":"crossref","first-page":"9169","DOI":"10.1063\/1.1410978","volume":"115","author":"Darve","year":"2001","journal-title":"J. Chem. Phys."},{"key":"D6CP00611F\/cit35\/1","doi-asserted-by":"crossref","first-page":"1129","DOI":"10.1021\/jp506633n","volume":"119","author":"Comer","year":"2015","journal-title":"J. Phys. Chem. B"},{"key":"D6CP00611F\/cit36\/1","doi-asserted-by":"crossref","first-page":"12562","DOI":"10.1073\/pnas.202427399","volume":"99","author":"Laio","year":"2002","journal-title":"Proc. Natl. Acad. Sci. U. S. A."},{"key":"D6CP00611F\/cit37\/1","doi-asserted-by":"crossref","first-page":"020603","DOI":"10.1103\/PhysRevLett.100.020603","volume":"100","author":"Barducci","year":"2008","journal-title":"Phys. Rev. Lett."},{"key":"D6CP00611F\/cit38\/1","doi-asserted-by":"crossref","first-page":"3506","DOI":"10.1021\/acs.jctc.6b00447","volume":"12","author":"Fu","year":"2016","journal-title":"J. Chem. Theory Comput."},{"key":"D6CP00611F\/cit39\/1","doi-asserted-by":"crossref","first-page":"3676","DOI":"10.1021\/acs.jpcb.6b10055","volume":"121","author":"Lesage","year":"2017","journal-title":"J. Phys. Chem. B"},{"key":"D6CP00611F\/cit40\/1","doi-asserted-by":"crossref","first-page":"4738","DOI":"10.1021\/acs.jpclett.8b01994","volume":"9","author":"Fu","year":"2018","journal-title":"J. Phys. Chem. Lett."},{"key":"D6CP00611F\/cit41\/1","doi-asserted-by":"crossref","first-page":"3254","DOI":"10.1021\/acs.accounts.9b00473","volume":"52","author":"Fu","year":"2019","journal-title":"Acc. Chem. Res."},{"key":"D6CP00611F\/cit42\/1","first-page":"041034","volume":"10","author":"Invernizzi","year":"2020","journal-title":"Phys. Rev. X"},{"key":"D6CP00611F\/cit43\/1","doi-asserted-by":"crossref","first-page":"5731","DOI":"10.1021\/acs.jctc.3c00254","volume":"19","author":"Rizzi","year":"2023","journal-title":"J. Chem. Theory Comput."},{"key":"D6CP00611F\/cit44\/1","first-page":"e1521","volume":"11","author":"Wang","year":"2021","journal-title":"Wiley Interdiscip. Rev.: Comput. Mol. Sci."},{"key":"D6CP00611F\/cit45\/1","first-page":"e70055","volume":"15","author":"Chong","year":"2025","journal-title":"Wiley Interdiscip. Rev.: Comput. Mol. Sci."},{"key":"D6CP00611F\/cit46\/1","volume-title":"Gaussian 16(Revision C.02)","author":"Frisch","year":"2016","unstructured":"M. J.Frisch ,  et al. ,  Gaussian 16(Revision C.02) ,  Gaussian Inc. ,  Wallingford, CT ,  2016"},{"key":"D6CP00611F\/cit47\/1","doi-asserted-by":"crossref","first-page":"5648","DOI":"10.1063\/1.464913","volume":"98","author":"Becke","year":"1993","journal-title":"J. Chem. Phys."},{"key":"D6CP00611F\/cit48\/1","doi-asserted-by":"crossref","first-page":"1456","DOI":"10.1002\/jcc.21759","volume":"32","author":"Grimme","year":"2011","journal-title":"J. Comput. Chem."},{"key":"D6CP00611F\/cit49\/1","first-page":"73","volume":"2","author":"Neese","year":"2012","journal-title":"Wiley Interdiscip. Rev.: Comput. Mol. Sci."},{"key":"D6CP00611F\/cit50\/1","doi-asserted-by":"crossref","first-page":"084106","DOI":"10.1063\/1.2834918","volume":"128","author":"Chai","year":"2008","journal-title":"J. Chem. Phys."},{"key":"D6CP00611F\/cit51\/1","doi-asserted-by":"crossref","first-page":"2531","DOI":"10.1021\/jp500405s","volume":"118","author":"Su","year":"2014","journal-title":"J. Phys. Chem. A"},{"key":"D6CP00611F\/cit52\/1","doi-asserted-by":"crossref","first-page":"2341","DOI":"10.1002\/jcc.26765","volume":"42","author":"Tang","year":"2021","journal-title":"J. Comput. Chem."},{"key":"D6CP00611F\/cit53\/1","first-page":"e1460","volume":"10","author":"Su","year":"2020","journal-title":"Wiley Interdiscip. Rev.: Comput. Mol. Sci."},{"key":"D6CP00611F\/cit54\/1","doi-asserted-by":"crossref","first-page":"472","DOI":"10.1002\/jcc.10382","volume":"25","author":"Song","year":"2004","journal-title":"J. Comput. Chem."},{"key":"D6CP00611F\/cit55\/1","doi-asserted-by":"crossref","first-page":"090902","DOI":"10.1063\/5.0019480","volume":"153","author":"Chen","year":"2020","journal-title":"J. Chem. Phys."},{"key":"D6CP00611F\/cit56\/1","doi-asserted-by":"crossref","first-page":"2157","DOI":"10.1002\/jcc.21224","volume":"30","author":"Mart\u00ednez","year":"2009","journal-title":"J. Comput. Chem."},{"key":"D6CP00611F\/cit57\/1","doi-asserted-by":"crossref","first-page":"2978","DOI":"10.1021\/ja00086a030","volume":"116","author":"Sun","year":"1994","journal-title":"J. Am. Chem. Soc."},{"key":"D6CP00611F\/cit58\/1","doi-asserted-by":"crossref","first-page":"6774","DOI":"10.1039\/D5MH00353A","volume":"12","author":"Raza","year":"2025","journal-title":"Mater. Horiz."},{"key":"D6CP00611F\/cit59\/1","doi-asserted-by":"crossref","first-page":"4069","DOI":"10.1063\/1.449071","volume":"83","author":"Evans","year":"1985","journal-title":"J. Chem. Phys."},{"key":"D6CP00611F\/cit60\/1","doi-asserted-by":"crossref","first-page":"108171","DOI":"10.1016\/j.cpc.2021.108171","volume":"271","author":"Thompson","year":"2022","journal-title":"Comput. Phys. Commun."},{"key":"D6CP00611F\/cit61\/1","doi-asserted-by":"crossref","first-page":"3345","DOI":"10.1080\/00268976.2013.813594","volume":"111","author":"Fiorin","year":"2013","journal-title":"Mol. Phys."},{"key":"D6CP00611F\/cit62\/1","doi-asserted-by":"crossref","first-page":"129201","DOI":"10.1016\/j.polymer.2025.129201","volume":"340","author":"Lin","year":"2025","journal-title":"Polymer"},{"key":"D6CP00611F\/cit63\/1","doi-asserted-by":"crossref","first-page":"15969","DOI":"10.1021\/jacs.8b10376","volume":"140","author":"Lin","year":"2018","journal-title":"J. Am. Chem. Soc."},{"key":"D6CP00611F\/cit64\/1","doi-asserted-by":"crossref","first-page":"2310","DOI":"10.1021\/acs.macromol.1c02242","volume":"55","author":"Chen","year":"2022","journal-title":"Macromolecules"},{"key":"D6CP00611F\/cit65\/1","doi-asserted-by":"crossref","first-page":"335","DOI":"10.1002\/poc.610080503","volume":"8","author":"Sueishi","year":"1995","journal-title":"J. Phys. Org. Chem."}],"container-title":["Physical Chemistry Chemical Physics"],"original-title":[],"language":"en","link":[{"URL":"http:\/\/pubs.rsc.org\/en\/content\/articlepdf\/2026\/CP\/D6CP00611F","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,7,8]],"date-time":"2026-07-08T12:21:56Z","timestamp":1783513316000},"score":1,"resource":{"primary":{"URL":"https:\/\/xlink.rsc.org\/?DOI=D6CP00611F"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026]]},"references-count":65,"journal-issue":{"issue":"26","published-print":{"date-parts":[[2026,7,8]]}},"URL":"https:\/\/doi.org\/10.1039\/d6cp00611f","relation":{"has-review":[{"id-type":"doi","id":"10.1039\/D6CP00611F\/v1\/review3","asserted-by":"object"},{"id-type":"doi","id":"10.1039\/D6CP00611F\/v2\/review1","asserted-by":"object"},{"id-type":"doi","id":"10.1039\/D6CP00611F\/v2\/response1","asserted-by":"object"},{"id-type":"doi","id":"10.1039\/D6CP00611F\/v1\/decision1","asserted-by":"object"},{"id-type":"doi","id":"10.1039\/D6CP00611F\/v1\/review1","asserted-by":"object"},{"id-type":"doi","id":"10.1039\/D6CP00611F\/v1\/review2","asserted-by":"object"},{"id-type":"doi","id":"10.1039\/D6CP00611F\/v2\/decision1","asserted-by":"object"}]},"ISSN":["1463-9076","1463-9084"],"issn-type":[{"value":"1463-9076","type":"print"},{"value":"1463-9084","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026]]}}}