{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,8,19]],"date-time":"2026-08-19T16:26:16Z","timestamp":1787156776542,"version":"build-2736575974"},"reference-count":62,"publisher":"Royal Society of Chemistry (RSC)","issue":"32","license":[{"start":{"date-parts":[[2026,8,3]],"date-time":"2026-08-03T00:00:00Z","timestamp":1785715200000},"content-version":"vor","delay-in-days":214,"URL":"http:\/\/creativecommons.org\/licenses\/by-nc\/3.0\/"}],"funder":[{"DOI":"10.13039\/501100008530","name":"European Regional Development Fund","doi-asserted-by":"publisher","award":["PK.1.1.10.0005"],"award-info":[{"award-number":["PK.1.1.10.0005"]}],"id":[{"id":"10.13039\/501100008530","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["rsc.org"],"crossmark-restriction":true},"short-container-title":["Phys. Chem. Chem. Phys."],"abstract":"<jats:p>\n                    We demonstrate how Ag\n                    <jats:sub>3<\/jats:sub>\n                    coordination to natural dyes can be utilized to overcome the inherent limitations of pure natural sensitizers, modulating optical properties through a donor\u2013acceptor architecture.\n                  <\/jats:p>","DOI":"10.1039\/d6cp01426g","type":"journal-article","created":{"date-parts":[[2026,8,3]],"date-time":"2026-08-03T08:03:22Z","timestamp":1785744202000},"page":"19443-19450","update-policy":"https:\/\/doi.org\/10.1039\/rsc_crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Charge-transfer excitations and photoinduced injection in nasunin\u2013Ag\n                    <sub>3<\/sub>\n                    complexes adsorbed on metal-oxide semiconductors"],"prefix":"10.1039","volume":"28","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-0348-7083","authenticated-orcid":false,"given":"Margarita","family":"Bu\u017ean\u010di\u0107 Milosavljevi\u0107","sequence":"first","affiliation":[{"name":"Center of Excellence for Science and Technology-Integration of Mediterranean Region (STIM), Faculty of Science, University of Split, Ru\u0111era Bo\u0161kovi\u0107a 33, 21000 Split, Croatia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-1252-7390","authenticated-orcid":false,"given":"Antonija","family":"Mravak","sequence":"additional","affiliation":[{"name":"Faculty of Chemistry and Technology, University of Split, Ru\u0111era Bo\u0161kovi\u0107a 35, 21 000 Split, Croatia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9134-5500","authenticated-orcid":false,"given":"Martina","family":"Peri\u0107 Bakuli\u0107","sequence":"additional","affiliation":[{"name":"Faculty of Chemistry and Technology, University of Split, Ru\u0111era Bo\u0161kovi\u0107a 35, 21 000 Split, Croatia"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"292","published-online":{"date-parts":[[2026]]},"reference":[{"key":"D6CP01426G\/cit1\/1","doi-asserted-by":"crossref","first-page":"247","DOI":"10.1021\/acs.chemrev.6b00826","volume":"117","author":"Scholes","year":"2017","journal-title":"Chem. Rev."},{"key":"D6CP01426G\/cit2\/1","doi-asserted-by":"crossref","first-page":"365","DOI":"10.1093\/jxb\/eri023","volume":"56","author":"Horton","year":"2005","journal-title":"J. Exp. Bot."},{"key":"D6CP01426G\/cit3\/1","doi-asserted-by":"crossref","first-page":"22299","DOI":"10.1038\/s41598-023-49729-3","volume":"13","author":"Timpmann","year":"2023","journal-title":"Sci. Rep."},{"key":"D6CP01426G\/cit4\/1","first-page":"277","volume":"24","author":"Cardona","year":"2019","journal-title":"J. Biol. Inorg. Chem."},{"key":"D6CP01426G\/cit5\/1","doi-asserted-by":"crossref","first-page":"338","DOI":"10.1038\/35104607","volume":"414","author":"Gr\u00e4tzel","year":"2001","journal-title":"Nature"},{"key":"D6CP01426G\/cit6\/1","doi-asserted-by":"crossref","first-page":"13846","DOI":"10.1021\/jacs.3c02825","volume":"145","author":"Muniz","year":"2023","journal-title":"J. Am. Chem. Soc."},{"key":"D6CP01426G\/cit7\/1","doi-asserted-by":"crossref","first-page":"e18393","DOI":"10.1002\/adma.202518393","author":"Qin","year":"2026","journal-title":"Adv. Mater."},{"key":"D6CP01426G\/cit8\/1","doi-asserted-by":"crossref","first-page":"110658","DOI":"10.1016\/j.optmat.2020.110658","volume":"111","author":"Richhariya","year":"2021","journal-title":"Opt. Mater."},{"key":"D6CP01426G\/cit9\/1","doi-asserted-by":"crossref","first-page":"112096","DOI":"10.1016\/j.dyepig.2024.112096","volume":"225","author":"Badawy","year":"2024","journal-title":"Dyes Pigm."},{"key":"D6CP01426G\/cit10\/1","doi-asserted-by":"crossref","first-page":"5814","DOI":"10.1039\/D1QM00580D","volume":"5","author":"Li","year":"2021","journal-title":"Mater. Chem. Front."},{"key":"D6CP01426G\/cit11\/1","doi-asserted-by":"crossref","first-page":"e202400800","DOI":"10.1002\/cphc.202400800","volume":"26","author":"Singh","year":"2025","journal-title":"ChemPhysChem"},{"key":"D6CP01426G\/cit12\/1","doi-asserted-by":"crossref","first-page":"7141","DOI":"10.1039\/D5MA00901D","volume":"6","author":"Mravak","year":"2025","journal-title":"Mater. Adv."},{"key":"D6CP01426G\/cit13\/1","doi-asserted-by":"crossref","first-page":"10346","DOI":"10.1021\/acs.chemrev.5b00703","volume":"116","author":"Jin","year":"2016","journal-title":"Chem. Rev."},{"key":"D6CP01426G\/cit14\/1","doi-asserted-by":"crossref","first-page":"2584","DOI":"10.1021\/acs.jpclett.8b00819","volume":"9","author":"Bona\u010di\u0107-Koutecky","year":"2018","journal-title":"J. Phys. Chem. Lett."},{"key":"D6CP01426G\/cit15\/1","doi-asserted-by":"crossref","first-page":"12436","DOI":"10.1039\/C9NR01826C","volume":"11","author":"Bona\u010di\u0107-Koutecky","year":"2019","journal-title":"Nanoscale"},{"key":"D6CP01426G\/cit16\/1","volume-title":"Atomically precise metal nanoclusters","author":"Pradeep","year":"2022","unstructured":"T.Pradeep ,  Atomically precise metal nanoclusters ,  Elsevier ,  2022"},{"key":"D6CP01426G\/cit17\/1","doi-asserted-by":"crossref","first-page":"13061","DOI":"10.1021\/jp953720e","volume":"100","author":"Nozik","year":"1996","journal-title":"J. Phys. Chem."},{"key":"D6CP01426G\/cit18\/1","doi-asserted-by":"crossref","first-page":"6010","DOI":"10.1039\/D3RA00165B","volume":"13","author":"Milosavljevi\u0107","year":"2023","journal-title":"RSC Adv."},{"key":"D6CP01426G\/cit19\/1","doi-asserted-by":"crossref","first-page":"5088","DOI":"10.1021\/jp507679f","volume":"119","author":"Muniz-Miranda","year":"2015","journal-title":"J. Phys. Chem. A"},{"key":"D6CP01426G\/cit20\/1","doi-asserted-by":"crossref","first-page":"7169","DOI":"10.1039\/C9CP06869D","volume":"22","author":"Pracht","year":"2020","journal-title":"Phys. Chem. Chem. Phys."},{"key":"D6CP01426G\/cit21\/1","doi-asserted-by":"crossref","first-page":"2847","DOI":"10.1021\/acs.jctc.9b00143","volume":"15","author":"Grimme","year":"2019","journal-title":"J. Chem. Theory Comput."},{"key":"D6CP01426G\/cit22\/1","doi-asserted-by":"crossref","first-page":"1652","DOI":"10.1021\/acs.jctc.8b01176","volume":"15","author":"Bannwarth","year":"2019","journal-title":"J. Chem. Theory Comput."},{"key":"D6CP01426G\/cit23\/1","unstructured":"TURBOMOLE V7.5 2020, a development of University of Karlsruhe and Forschungszentrum Karlsruhe GmbH, 1989-2007, TURBOMOLE GmbH, since 2007; available from,  https:\/\/www.turbomole.com"},{"key":"D6CP01426G\/cit24\/1","doi-asserted-by":"crossref","first-page":"3865","DOI":"10.1103\/PhysRevLett.77.3865","volume":"77","author":"Perdew","year":"1996","journal-title":"Phys. Rev. Lett."},{"key":"D6CP01426G\/cit25\/1","doi-asserted-by":"crossref","first-page":"1396","DOI":"10.1103\/PhysRevLett.78.1396","volume":"78","author":"Perdew","year":"1997","journal-title":"Phys. Rev. Lett."},{"key":"D6CP01426G\/cit26\/1","doi-asserted-by":"crossref","first-page":"1057","DOI":"10.1039\/b515623h","volume":"8","author":"Weigend","year":"2006","journal-title":"Phys. Chem. Chem. Phys."},{"key":"D6CP01426G\/cit27\/1","doi-asserted-by":"crossref","first-page":"123","DOI":"10.1007\/BF01114537","volume":"77","author":"Andrae","year":"1990","journal-title":"Theor. Chim. Acta"},{"key":"D6CP01426G\/cit29\/1","doi-asserted-by":"crossref","first-page":"51","DOI":"10.1016\/j.cplett.2004.06.011","volume":"393","author":"Yanai","year":"2004","journal-title":"Chem. Phys. Lett."},{"key":"D6CP01426G\/cit30\/1","doi-asserted-by":"crossref","first-page":"5648","DOI":"10.1063\/1.464913","volume":"98","author":"Becke","year":"1993","journal-title":"J. Chem. Phys."},{"key":"D6CP01426G\/cit31\/1","doi-asserted-by":"crossref","first-page":"6158","DOI":"10.1063\/1.478522","volume":"110","author":"Adamo","year":"1999","journal-title":"J. Chem. Phys."},{"key":"D6CP01426G\/cit32\/1","doi-asserted-by":"crossref","first-page":"5029","DOI":"10.1063\/1.478401","volume":"110","author":"Ernzerhof","year":"1999","journal-title":"J. Chem. Phys."},{"key":"D6CP01426G\/cit33\/1","doi-asserted-by":"crossref","first-page":"6615","DOI":"10.1039\/b810189b","volume":"10","author":"Chai","year":"2008","journal-title":"Phys. Chem. Chem. Phys."},{"key":"D6CP01426G\/cit34\/1","doi-asserted-by":"crossref","first-page":"4267","DOI":"10.1021\/jp3124154","volume":"117","author":"Rabilloud","year":"2013","journal-title":"J. Phys. Chem. A"},{"key":"D6CP01426G\/cit35\/1","doi-asserted-by":"crossref","first-page":"13001","DOI":"10.1039\/c3ra47244b","volume":"4","author":"Anak","year":"2014","journal-title":"RSC Adv."},{"key":"D6CP01426G\/cit36\/1","doi-asserted-by":"crossref","first-page":"1174","DOI":"10.1063\/1.463245","volume":"97","author":"Hettema","year":"1992","journal-title":"J. Chem. Phys."},{"key":"D6CP01426G\/cit37\/1","doi-asserted-by":"crossref","first-page":"8331","DOI":"10.1063\/1.476261","volume":"108","author":"H\u00e4ttig","year":"1998","journal-title":"J. Chem. Phys."},{"key":"D6CP01426G\/cit38\/1","first-page":"269","volume":"4","author":"Aidas","year":"2014","journal-title":"Wiley Interdiscip. Rev.: Comput. Mol. Sci."},{"key":"D6CP01426G\/cit39\/1","doi-asserted-by":"crossref","first-page":"2409","DOI":"10.3390\/nano11092409","volume":"11","author":"Muniz-Miranda","year":"2021","journal-title":"Nanomaterials"},{"key":"D6CP01426G\/cit40\/1","doi-asserted-by":"crossref","first-page":"11","DOI":"10.1016\/j.cplett.2017.01.074","volume":"673","author":"Maksimov","year":"2017","journal-title":"Chem. Phys. Lett."},{"key":"D6CP01426G\/cit41\/1","doi-asserted-by":"crossref","first-page":"5863","DOI":"10.1021\/acs.jpcc.6c01227","volume":"130","author":"Elhajj","year":"2026","journal-title":"J. Phys. Chem. C"},{"key":"D6CP01426G\/cit42\/1","doi-asserted-by":"crossref","first-page":"3879","DOI":"10.1021\/acs.jctc.4c00133","volume":"20","author":"Elayan","year":"2024","journal-title":"J. Chem. Theory Comput."},{"key":"D6CP01426G\/cit43\/1","doi-asserted-by":"crossref","first-page":"1467","DOI":"10.1007\/s00894-010-0853-y","volume":"17","author":"Koch","year":"2011","journal-title":"J. Mol. Model."},{"key":"D6CP01426G\/cit44\/1","first-page":"253202","volume":"22","author":"Enkovaara","year":"2010","journal-title":"J. Phys.: Condens. Matter"},{"key":"D6CP01426G\/cit45\/1","doi-asserted-by":"crossref","first-page":"092503","DOI":"10.1063\/5.0182685","volume":"160","author":"Mortensen","year":"2024","journal-title":"J. Chem. Phys."},{"key":"D6CP01426G\/cit46\/1","doi-asserted-by":"crossref","first-page":"17953","DOI":"10.1103\/PhysRevB.50.17953","volume":"50","author":"Bl\u00f6chl","year":"1994","journal-title":"Phys. Rev. B: Condens. Matter Mater. Phys."},{"key":"D6CP01426G\/cit47\/1","doi-asserted-by":"crossref","first-page":"33","DOI":"10.1007\/BF02712785","volume":"26","author":"Bl\u00f6chl","year":"2003","journal-title":"Bull. Mater. Sci."},{"key":"D6CP01426G\/cit48\/1","doi-asserted-by":"crossref","first-page":"3214","DOI":"10.1002\/qua.21088","volume":"106","author":"Lundqvist","year":"2006","journal-title":"Int. J. Quantum Chem."},{"key":"D6CP01426G\/cit49\/1","doi-asserted-by":"crossref","first-page":"29","DOI":"10.1515\/ehs-2018-0008","volume":"5","author":"Marcano","year":"2018","journal-title":"Energy Harvest. Syst."},{"key":"D6CP01426G\/cit50\/1","doi-asserted-by":"crossref","first-page":"1034","DOI":"10.3390\/nano14121034","volume":"14","author":"Bu\u017ean\u010di\u0107 Milosavljevi\u0107","year":"2024","journal-title":"Nanomaterials"},{"key":"D6CP01426G\/cit51\/1","doi-asserted-by":"crossref","first-page":"10154","DOI":"10.1021\/jf801322m","volume":"56","author":"Azuma","year":"2008","journal-title":"J. Agric. Food Chem."},{"key":"D6CP01426G\/cit52\/1","doi-asserted-by":"crossref","first-page":"24","DOI":"10.1016\/j.optmat.2018.11.005","volume":"88","author":"Calogero","year":"2019","journal-title":"Opt. Mater."},{"key":"D6CP01426G\/cit53\/1","doi-asserted-by":"crossref","first-page":"123","DOI":"10.1021\/ct700187z","volume":"4","author":"Jacquemin","year":"2008","journal-title":"J. Chem. Theory Comput."},{"key":"D6CP01426G\/cit54\/1","first-page":"4003","volume":"13","author":"Fan","year":"2012","journal-title":"ChemPhysChem"},{"key":"D6CP01426G\/cit55\/1","doi-asserted-by":"crossref","first-page":"381","DOI":"10.1186\/s11671-018-2760-6","volume":"13","author":"Sharma","year":"2018","journal-title":"Nanoscale Res. Lett."},{"key":"D6CP01426G\/cit56\/1","doi-asserted-by":"crossref","first-page":"591","DOI":"10.1038\/srep00591","volume":"2","author":"Kim","year":"2012","journal-title":"Sci. Rep."},{"key":"D6CP01426G\/cit57\/1","doi-asserted-by":"crossref","first-page":"23","DOI":"10.1016\/j.cplett.2017.07.031","volume":"685","author":"Fujisawa","year":"2017","journal-title":"Chem. Phys. Lett."},{"key":"D6CP01426G\/cit58\/1","first-page":"9935","volume":"31","author":"Parashar","year":"2020","journal-title":"J. Mater. Sci.: Mater. Electron."},{"key":"D6CP01426G\/cit59\/1","doi-asserted-by":"crossref","first-page":"1162","DOI":"10.1038\/ncomms1655","volume":"3","author":"Yum","year":"2012","journal-title":"Nat. Commun."},{"key":"D6CP01426G\/cit60\/1","doi-asserted-by":"crossref","first-page":"1229","DOI":"10.1039\/D0MA01023E","volume":"2","author":"Srivishnu","year":"2021","journal-title":"Mater. Adv."},{"key":"D6CP01426G\/cit61\/1","doi-asserted-by":"crossref","first-page":"92","DOI":"10.1039\/B817990E","volume":"2","author":"Zhang","year":"2009","journal-title":"Energy Environ. Sci."},{"key":"D6CP01426G\/cit62\/1","doi-asserted-by":"crossref","first-page":"9394","DOI":"10.1039\/c2ee23081j","volume":"5","author":"Wang","year":"2012","journal-title":"Energy Environ. Sci."},{"key":"D6CP01426G\/cit63\/1","doi-asserted-by":"crossref","first-page":"955","DOI":"10.1351\/pac198658070955","volume":"58","author":"Trasatti","year":"1986","journal-title":"Pure Appl. Chem."}],"container-title":["Physical Chemistry Chemical Physics"],"original-title":[],"language":"en","link":[{"URL":"http:\/\/pubs.rsc.org\/CP\/article-pdf\/doi\/10.1039\/D6CP01426G\/0\/D6CP01426G.pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,8,19]],"date-time":"2026-08-19T15:38:29Z","timestamp":1787153909000},"score":1,"resource":{"primary":{"URL":"http:\/\/pubs.rsc.org\/CP\/article-lookup\/doi\/10.1039\/D6CP01426G"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026]]},"references-count":62,"journal-issue":{"issue":"32","published-print":{"date-parts":[[2026,8,19]]}},"URL":"https:\/\/doi.org\/10.1039\/d6cp01426g","relation":{},"ISSN":["1463-9076","1463-9084"],"issn-type":[{"value":"1463-9076","type":"print"},{"value":"1463-9084","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026]]}}}