{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,14]],"date-time":"2026-10-14T12:54:59Z","timestamp":1791982499569,"version":"4.4.0"},"reference-count":57,"publisher":"Royal Society of Chemistry (RSC)","issue":"39","license":[{"start":{"date-parts":[[2027,9,22]],"date-time":"2027-09-22T00:00:00Z","timestamp":1821571200000},"content-version":"am","delay-in-days":629,"URL":"http:\/\/rsc.li\/journals-terms-of-use"}],"funder":[{"DOI":"10.13039\/501100001871","name":"Funda\u00e7\u00e3o para a Ci\u00eancia e a Tecnologia","doi-asserted-by":"publisher","award":["UID\/PRR\/00313\/2025"],"award-info":[{"award-number":["UID\/PRR\/00313\/2025"]}],"id":[{"id":"10.13039\/501100001871","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001871","name":"Funda\u00e7\u00e3o para a Ci\u00eancia e a Tecnologia","doi-asserted-by":"publisher","award":["LA\/P\/0101\/2020"],"award-info":[{"award-number":["LA\/P\/0101\/2020"]}],"id":[{"id":"10.13039\/501100001871","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001871","name":"Funda\u00e7\u00e3o para a Ci\u00eancia e a Tecnologia","doi-asserted-by":"publisher","award":["UID\/00313\/2025"],"award-info":[{"award-number":["UID\/00313\/2025"]}],"id":[{"id":"10.13039\/501100001871","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001871","name":"Funda\u00e7\u00e3o para a Ci\u00eancia e a Tecnologia","doi-asserted-by":"publisher","award":["UIDB\/04326\/2020"],"award-info":[{"award-number":["UIDB\/04326\/2020"]}],"id":[{"id":"10.13039\/501100001871","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001871","name":"Funda\u00e7\u00e3o para a Ci\u00eancia e a Tecnologia","doi-asserted-by":"publisher","award":["UIDP\/04326\/2020"],"award-info":[{"award-number":["UIDP\/04326\/2020"]}],"id":[{"id":"10.13039\/501100001871","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100032383","name":"Comiss\u00e3o de Coordena\u00e7\u00e3o e Desenvolvimento Regional do Algarve","doi-asserted-by":"publisher","award":["ALG-01-0145-FEDER-022121"],"award-info":[{"award-number":["ALG-01-0145-FEDER-022121"]}],"id":[{"id":"10.13039\/100032383","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["rsc.org"],"crossmark-restriction":true},"short-container-title":["Phys. Chem. Chem. Phys."],"abstract":"<jats:p>\n                    The photophysical and photochemical behaviour of 2-methyl-5-((1-phenyl-1\n                    <jats:italic>H<\/jats:italic>\n                    -tetrazol-5-yl)thio)-1,3,4-thiadiazole (MeTDZ-PhTTZ) was investigated through a combined computational and experimental approach.\n                  <\/jats:p>","DOI":"10.1039\/d6cp01987k","type":"journal-article","created":{"date-parts":[[2026,9,22]],"date-time":"2026-09-22T13:08:51Z","timestamp":1790082531000},"page":"24132-24143","update-policy":"https:\/\/doi.org\/10.1039\/rsc_crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Solvent-controlled photodegradation pathways of a bioactive tetrazole\u2013thiadiazole conjugate revealed by TDDFT, UV-Vis spectroscopy and LC-MS"],"prefix":"10.1039","volume":"28","author":[{"ORCID":"https:\/\/orcid.org\/0009-0007-7660-0845","authenticated-orcid":false,"given":"Rodrigo C.","family":"Santos","sequence":"first","affiliation":[{"name":"CQC-IMS and Department of Chemistry, University of Coimbra, Rua Larga, 3004-545 Coimbra, Portugal"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-3106-7630","authenticated-orcid":false,"given":"Silvia","family":"Gramacho","sequence":"additional","affiliation":[{"name":"CQC-IMS and Department of Chemistry, University of Coimbra, Rua Larga, 3004-545 Coimbra, Portugal"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-7219-7939","authenticated-orcid":false,"given":"Bruno E. C.","family":"Guerreiro","sequence":"additional","affiliation":[{"name":"Center of Marine Sciences (CCMAR), and Department of Chemistry and Pharmacy (FCT), Gambelas Campus, University of Algarve, P-8005-039 Faro, Portugal"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9447-2855","authenticated-orcid":false,"given":"Maria L. S.","family":"Cristiano","sequence":"additional","affiliation":[{"name":"Center of Marine Sciences (CCMAR), and Department of Chemistry and Pharmacy (FCT), Gambelas Campus, University of Algarve, P-8005-039 Faro, Portugal"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-7004-0110","authenticated-orcid":false,"given":"Carlos","family":"Serpa","sequence":"additional","affiliation":[{"name":"CQC-IMS and Department of Chemistry, University of Coimbra, Rua Larga, 3004-545 Coimbra, Portugal"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0947-5750","authenticated-orcid":false,"given":"Pedro J. S. B.","family":"Caridade","sequence":"additional","affiliation":[{"name":"CQC-IMS and Department of Chemistry, University of Coimbra, Rua Larga, 3004-545 Coimbra, Portugal"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"292","published-online":{"date-parts":[[2026]]},"reference":[{"key":"D6CP01987K\/cit1\/1","doi-asserted-by":"crossref","first-page":"7945","DOI":"10.1021\/jo010635w","volume":"66","author":"Demko","year":"2001","journal-title":"J. Org. Chem."},{"key":"D6CP01987K\/cit2\/1","doi-asserted-by":"crossref","first-page":"2723","DOI":"10.1002\/ejoc.200600007","author":"Su","year":"2006","journal-title":"Eur. J. Org. Chem."},{"key":"D6CP01987K\/cit3\/1","doi-asserted-by":"crossref","first-page":"5528","DOI":"10.3390\/molecules20045528","volume":"20","author":"Wei","year":"2015","journal-title":"Molecules"},{"key":"D6CP01987K\/cit4\/1","doi-asserted-by":"crossref","first-page":"127762","DOI":"10.1016\/j.bmcl.2020.127762","volume":"34","author":"Li","year":"2021","journal-title":"Bioorg. Med. Chem. Lett."},{"key":"D6CP01987K\/cit5\/1","first-page":"3","volume":"27","author":"Hiskey","year":"2020","journal-title":"Proc. Int. Pyrotech. Semin."},{"key":"D6CP01987K\/cit6\/1","doi-asserted-by":"crossref","first-page":"1801","DOI":"10.1134\/S1070428022120090","volume":"58","author":"Uppadhayay","year":"2022","journal-title":"Russ. J. Org. Chem."},{"key":"D6CP01987K\/cit7\/1","doi-asserted-by":"crossref","first-page":"116870","DOI":"10.1016\/j.ejmech.2024.116870","volume":"279","author":"Yuan","year":"2024","journal-title":"Eur. J. Med. Chem."},{"key":"D6CP01987K\/cit8\/1","doi-asserted-by":"crossref","first-page":"D668","DOI":"10.1093\/nar\/gkj067","volume":"34","author":"Wishart","year":"2006","journal-title":"Nucleic Acids Res."},{"key":"D6CP01987K\/cit9\/1","doi-asserted-by":"crossref","first-page":"385","DOI":"10.1002\/cmdc.201200585","volume":"8","author":"Ballatore","year":"2013","journal-title":"ChemMedChem"},{"key":"D6CP01987K\/cit10\/1","doi-asserted-by":"crossref","first-page":"805","DOI":"10.1080\/14756366.2017.1326110","volume":"32","author":"Lamie","year":"2017","journal-title":"J. Enzyme Inhib. Med. Chem."},{"key":"D6CP01987K\/cit11\/1","doi-asserted-by":"crossref","first-page":"232","DOI":"10.1128\/AAC.39.1.232","volume":"39","author":"De Sarro","year":"1995","journal-title":"Antimicrob. Agents Chemother."},{"key":"D6CP01987K\/cit12\/1","first-page":"12796","author":"Mohammed","year":"2016","journal-title":"Eur. J. Acad. Res."},{"key":"D6CP01987K\/cit13\/1","doi-asserted-by":"crossref","first-page":"2475","DOI":"10.1039\/a702458d","author":"Abell","year":"1997","journal-title":"J. Chem. Soc., Perkin Trans. 1"},{"key":"D6CP01987K\/cit14\/1","doi-asserted-by":"crossref","first-page":"1856","DOI":"10.2174\/1871520617666170327143148","volume":"17","author":"Popova","year":"2018","journal-title":"ACAMC"},{"key":"D6CP01987K\/cit15\/1","doi-asserted-by":"crossref","first-page":"25","DOI":"10.1007\/s41061-023-00435-8","volume":"381","author":"Chen","year":"2023","journal-title":"Top. Curr. Chem."},{"key":"D6CP01987K\/cit16\/1","doi-asserted-by":"crossref","first-page":"e3733","DOI":"10.1002\/poc.3733","volume":"31","author":"Shi","year":"2018","journal-title":"J. Phys. Org. Chem."},{"key":"D6CP01987K\/cit17\/1","doi-asserted-by":"crossref","first-page":"247","DOI":"10.1002\/prep.200400048","volume":"29","author":"Miyata","year":"2004","journal-title":"Propell. Explos. Pyrotech."},{"key":"D6CP01987K\/cit18\/1","doi-asserted-by":"crossref","first-page":"215604","DOI":"10.1016\/j.ccr.2023.215604","volume":"504","author":"Sajjadi","year":"2024","journal-title":"Coord. Chem. Rev."},{"key":"D6CP01987K\/cit19\/1","first-page":"111788","volume":"513","author":"Nasrollahzadeh","year":"2021","journal-title":"Mol Catal"},{"key":"D6CP01987K\/cit20\/1","doi-asserted-by":"crossref","first-page":"139342","DOI":"10.1016\/j.molstruc.2024.139342","volume":"1318","author":"Chen","year":"2024","journal-title":"J. Mol. Struct."},{"key":"D6CP01987K\/cit21\/1","doi-asserted-by":"crossref","first-page":"59","DOI":"10.1016\/0169-4332(95)00189-1","volume":"93","author":"Kertit","year":"1996","journal-title":"Appl. Surf. Sci."},{"key":"D6CP01987K\/cit22\/1","doi-asserted-by":"crossref","first-page":"557","DOI":"10.1111\/cbdd.12125","volume":"81","author":"Jain","year":"2013","journal-title":"Chem. Biol. Drug Des."},{"key":"D6CP01987K\/cit23\/1","doi-asserted-by":"crossref","first-page":"8616","DOI":"10.1021\/jm2011645","volume":"54","author":"Hasui","year":"2011","journal-title":"J. Med. Chem."},{"key":"D6CP01987K\/cit24\/1","doi-asserted-by":"crossref","first-page":"2782","DOI":"10.1016\/j.ejmech.2009.01.012","volume":"44","author":"Liu","year":"2009","journal-title":"Eur. J. Med. Chem."},{"key":"D6CP01987K\/cit25\/1","doi-asserted-by":"crossref","first-page":"1528","DOI":"10.1080\/00397911.2020.1745843","volume":"50","author":"Gowda","year":"2020","journal-title":"Synth. Commun."},{"key":"D6CP01987K\/cit26\/1","doi-asserted-by":"crossref","first-page":"S306","DOI":"10.1016\/j.jscs.2012.11.007","volume":"20","author":"Maddila","year":"2016","journal-title":"J. Saudi Chem. Soc."},{"key":"D6CP01987K\/cit27\/1","doi-asserted-by":"crossref","first-page":"351","DOI":"10.1007\/s00044-008-9132-1","volume":"18","author":"Pattanayak","year":"2009","journal-title":"Med. Chem. Res."},{"key":"D6CP01987K\/cit28\/1","doi-asserted-by":"crossref","first-page":"2893","DOI":"10.1016\/S0968-0896(02)00143-8","volume":"10","author":"Dogan","year":"2002","journal-title":"Bioorg. Med. Chem."},{"key":"D6CP01987K\/cit29\/1","doi-asserted-by":"crossref","first-page":"2822","DOI":"10.3390\/molecules25122822","volume":"25","author":"Kudelko","year":"2020","journal-title":"Molecules"},{"key":"D6CP01987K\/cit30\/1","doi-asserted-by":"crossref","first-page":"641","DOI":"10.1007\/s00604-019-3761-6","volume":"186","author":"Ghanbari","year":"2019","journal-title":"Mikrochim. Acta"},{"key":"D6CP01987K\/cit31\/1","doi-asserted-by":"crossref","first-page":"377","DOI":"10.1007\/s10800-010-0246-z","volume":"41","author":"Jin","year":"2011","journal-title":"J. Appl. Electrochem."},{"key":"D6CP01987K\/cit32\/1","doi-asserted-by":"crossref","first-page":"3074","DOI":"10.1021\/acsaem.4c03232","volume":"8","author":"Liao","year":"2025","journal-title":"ACS Appl. Energy Mater."},{"key":"D6CP01987K\/cit33\/1","doi-asserted-by":"crossref","first-page":"656","DOI":"10.1016\/j.snb.2011.08.044","volume":"160","author":"Yan","year":"2011","journal-title":"Sens. Actuators, B"},{"key":"D6CP01987K\/cit34\/1","doi-asserted-by":"crossref","first-page":"1929","DOI":"10.1039\/D1NJ05084B","volume":"46","author":"Selivanova","year":"2022","journal-title":"New J. Chem."},{"key":"D6CP01987K\/cit35\/1","doi-asserted-by":"crossref","first-page":"5623","DOI":"10.1021\/acscatal.9b05470","volume":"10","author":"Mondal","year":"2020","journal-title":"ACS Catal."},{"key":"D6CP01987K\/cit36\/1","doi-asserted-by":"crossref","first-page":"5572","DOI":"10.1021\/cr400131u","volume":"114","author":"Hu","year":"2014","journal-title":"Chem. Rev."},{"key":"D6CP01987K\/cit37\/1","volume-title":"Sittig's Handbook of Pesticides and Agricultural Vhemicals","author":"Pohanish","year":"2015","unstructured":"R. P.Pohanish ,  Sittig's Handbook of Pesticides and Agricultural Vhemicals ,  William Andrew Publishing ,  New York, USA ,  2015"},{"key":"D6CP01987K\/cit38\/1","doi-asserted-by":"crossref","first-page":"108510","DOI":"10.1016\/j.bioorg.2025.108510","volume":"161","author":"El-Saghier","year":"2025","journal-title":"Bioorg. Chem."},{"key":"D6CP01987K\/cit39\/1","doi-asserted-by":"crossref","first-page":"2644","DOI":"10.1080\/00397911.2021.1945106","volume":"51","author":"Ismail","year":"2021","journal-title":"Synth. Commun."},{"key":"D6CP01987K\/cit40\/1","doi-asserted-by":"crossref","first-page":"420","DOI":"10.37349\/eds.2023.00028","author":"Frija","year":"2023","journal-title":"Explor. Drug Sci."},{"key":"D6CP01987K\/cit41\/1","doi-asserted-by":"crossref","first-page":"3757","DOI":"10.3390\/molecules15053757","volume":"15","author":"Frija","year":"2010","journal-title":"Molecules"},{"key":"D6CP01987K\/cit42\/1","doi-asserted-by":"crossref","first-page":"71","DOI":"10.1016\/j.jphotochemrev.2013.09.001","volume":"18","author":"Frija","year":"2014","journal-title":"J. Photochem. Photobiol., C"},{"key":"D6CP01987K\/cit43\/1","doi-asserted-by":"crossref","first-page":"RCR5118","DOI":"10.59761\/RCR5118","volume":"93","author":"Ostrovskii","year":"2024","journal-title":"Russ. Chem. Rev."},{"key":"D6CP01987K\/cit44\/1","doi-asserted-by":"crossref","first-page":"3282","DOI":"10.3390\/molecules26113282","volume":"26","author":"Secrieru","year":"2021","journal-title":"Molecules"},{"key":"D6CP01987K\/cit45\/1","doi-asserted-by":"crossref","first-page":"392","DOI":"10.1021\/jo502419u","volume":"80","author":"Ismael","year":"2015","journal-title":"J. Org. Chem."},{"key":"D6CP01987K\/cit46\/1","doi-asserted-by":"crossref","first-page":"11656","DOI":"10.1021\/acs.joc.6b02023","volume":"81","author":"Ismael","year":"2016","journal-title":"J. Org. Chem."},{"key":"D6CP01987K\/cit47\/1","doi-asserted-by":"crossref","first-page":"3583","DOI":"10.1021\/jo060164j","volume":"71","author":"Frija","year":"2006","journal-title":"J. Org. Chem."},{"key":"D6CP01987K\/cit48\/1","doi-asserted-by":"crossref","first-page":"1046","DOI":"10.1039\/b718104c","volume":"6","author":"Frija","year":"2008","journal-title":"Org. Biomol. Chem."},{"key":"D6CP01987K\/cit49\/1","doi-asserted-by":"crossref","first-page":"131","DOI":"10.1016\/j.jksus.2010.09.001","volume":"24","author":"Yousif","year":"2012","journal-title":"J. King Saud. Univ. Sci."},{"key":"D6CP01987K\/cit50\/1","first-page":"e70019","volume":"15","author":"Neese","year":"2025","journal-title":"Wiley Interdiscip. Rev.: Comput. Mol. Sci."},{"key":"D6CP01987K\/cit51\/1","doi-asserted-by":"crossref","first-page":"6158","DOI":"10.1063\/1.478522","volume":"110","author":"Adamo","year":"1999","journal-title":"J. Chem. Phys."},{"key":"D6CP01987K\/cit52\/1","doi-asserted-by":"crossref","first-page":"131","DOI":"10.1016\/j.mencom.2024.01.040","volume":"34","author":"Samolyga","year":"2024","journal-title":"Mendeleev Commun."},{"key":"D6CP01987K\/cit53\/1","doi-asserted-by":"crossref","first-page":"4045","DOI":"10.3390\/app11094045","volume":"11","author":"Duque-Prata","year":"2021","journal-title":"Appl. Sci."},{"key":"D6CP01987K\/cit54\/1","doi-asserted-by":"crossref","first-page":"922","DOI":"10.1002\/jcc.26139","volume":"41","author":"Garcia-Rat\u00e9s","year":"2020","journal-title":"J. Comput. Chem."},{"key":"D6CP01987K\/cit55\/1","doi-asserted-by":"crossref","first-page":"1057","DOI":"10.1039\/b515623h","volume":"8","author":"Weigend","year":"2006","journal-title":"Phys. Chem. Chem. Phys."},{"key":"D6CP01987K\/cit56\/1","doi-asserted-by":"crossref","first-page":"104109","DOI":"10.1063\/5.0058766","volume":"155","author":"Helmich-Paris","year":"2021","journal-title":"J. Chem. Phys."},{"key":"D6CP01987K\/cit57\/1","doi-asserted-by":"crossref","first-page":"1995","DOI":"10.1021\/jp9716997","volume":"102","author":"Barone","year":"1998","journal-title":"J. Phys. Chem. A"}],"container-title":["Physical Chemistry Chemical Physics"],"original-title":[],"language":"en","link":[{"URL":"http:\/\/pubs.rsc.org\/CP\/article-pdf\/doi\/10.1039\/D6CP01987K\/0\/D6CP01987K.pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,10,14]],"date-time":"2026-10-14T12:43:44Z","timestamp":1791981824000},"score":1,"resource":{"primary":{"URL":"http:\/\/pubs.rsc.org\/CP\/article-lookup\/doi\/10.1039\/D6CP01987K"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026]]},"references-count":57,"journal-issue":{"issue":"39","published-print":{"date-parts":[[2026,10,14]]}},"URL":"https:\/\/doi.org\/10.1039\/d6cp01987k","relation":{},"ISSN":["1463-9076","1463-9084"],"issn-type":[{"value":"1463-9076","type":"print"},{"value":"1463-9084","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026]]}}}