{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,1]],"date-time":"2026-10-01T09:59:54Z","timestamp":1790848794181,"version":"4.1.0"},"reference-count":40,"publisher":"Royal Society of Chemistry (RSC)","issue":"37","license":[{"start":{"date-parts":[[2027,9,11]],"date-time":"2027-09-11T00:00:00Z","timestamp":1820620800000},"content-version":"am","delay-in-days":618,"URL":"http:\/\/rsc.li\/journals-terms-of-use#chorus"}],"funder":[{"DOI":"10.13039\/501100003382","name":"Core Research for Evolutional Science and Technology","doi-asserted-by":"publisher","award":["JPMJCR20R4"],"award-info":[{"award-number":["JPMJCR20R4"]}],"id":[{"id":"10.13039\/501100003382","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["rsc.org"],"crossmark-restriction":true},"short-container-title":["Phys. Chem. Chem. Phys."],"abstract":"<jats:p>Cu steps and isolated Pd atoms decrease O\u2013H and C\u2013H scission barriers, and the Pd\/Cu(977) step surface enables dry and non-oxidative dehydrogenation of methanol to formaldehyde with nearly 100% selectivity.<\/jats:p>","DOI":"10.1039\/d6cp02570f","type":"journal-article","created":{"date-parts":[[2026,9,11]],"date-time":"2026-09-11T07:40:02Z","timestamp":1789112402000},"page":"23029-23038","update-policy":"https:\/\/doi.org\/10.1039\/rsc_crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Non-oxidative and selective methanol dehydrogenation to formaldehyde on Cu and Pd\/Cu model catalyst surfaces: roles of step sites and deposited Pd"],"prefix":"10.1039","volume":"28","author":[{"given":"Yoshiko","family":"Sakaguchi","sequence":"first","affiliation":[{"name":"The Institute for Solid State Physics, The University of Tokyo, 5-1-5 Kashiwanoha, Kashiwa, Chiba 277-8581, Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Wataru","family":"Osada","sequence":"additional","affiliation":[{"name":"National Metrology Institute of Japan, National Institute for Advanced Industrial Science and Technology, 1-1-1 Umezono, Tsukuba, Ibaraki 305-8563, Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-2033-9752","authenticated-orcid":false,"given":"Shunsuke","family":"Tanaka","sequence":"additional","affiliation":[{"name":"The Institute for Solid State Physics, The University of Tokyo, 5-1-5 Kashiwanoha, Kashiwa, Chiba 277-8581, Japan"},{"name":"Research Institute of Core Technology for Materials Innovation, National Institute of Advanced Industrial Science and Technology, 1-1-1 Higashi, Tsukuba, Ibaraki 305-8565, Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Kozo","family":"Mukai","sequence":"additional","affiliation":[{"name":"The Institute for Solid State Physics, The University of Tokyo, 5-1-5 Kashiwanoha, Kashiwa, Chiba 277-8581, Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-7774-8701","authenticated-orcid":false,"given":"Jun","family":"Yoshinobu","sequence":"additional","affiliation":[{"name":"The Institute for Solid State Physics, The University of Tokyo, 5-1-5 Kashiwanoha, Kashiwa, Chiba 277-8581, Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"292","published-online":{"date-parts":[[2026]]},"reference":[{"key":"D6CP02570F\/cit1\/1","doi-asserted-by":"crossref","first-page":"2636","DOI":"10.1002\/anie.200462121","volume":"44","author":"Olah","year":"2005","journal-title":"Angew. Chem., Int. Ed."},{"key":"D6CP02570F\/cit2\/1","doi-asserted-by":"crossref","first-page":"893","DOI":"10.3390\/catal11080893","volume":"11","author":"Malik","year":"2021","journal-title":"Catalysts"},{"key":"D6CP02570F\/cit3\/1","first-page":"379","volume":"44","author":"Usachev","year":"2004","journal-title":"Pet. Chem."},{"key":"D6CP02570F\/cit4\/1","doi-asserted-by":"crossref","first-page":"9247","DOI":"10.1021\/acs.iecr.7b02388","volume":"56","author":"Millar","year":"2017","journal-title":"Ind. Eng. Chem. Res."},{"key":"D6CP02570F\/cit5\/1","doi-asserted-by":"crossref","first-page":"e202101219","DOI":"10.1002\/cctc.202101219","volume":"14","author":"Oefner","year":"2022","journal-title":"ChemCatChem"},{"key":"D6CP02570F\/cit6\/1","doi-asserted-by":"crossref","first-page":"12800","DOI":"10.1021\/acs.jpcc.7b02957","volume":"121","author":"Wang","year":"2017","journal-title":"J. Phys. Chem. C"},{"key":"D6CP02570F\/cit7\/1","doi-asserted-by":"crossref","first-page":"516","DOI":"10.1016\/0039-6028(85)91077-5","volume":"163","author":"Russell Jr.","year":"1985","journal-title":"Surf. Sci."},{"key":"D6CP02570F\/cit8\/1","doi-asserted-by":"crossref","first-page":"6181","DOI":"10.1021\/nn402055k","volume":"7","author":"Boucher","year":"2013","journal-title":"ACS Nano"},{"key":"D6CP02570F\/cit9\/1","doi-asserted-by":"crossref","first-page":"121","DOI":"10.1016\/j.susc.2016.02.010","volume":"650","author":"Shan","year":"2016","journal-title":"Surf. Sci."},{"key":"D6CP02570F\/cit10\/1","doi-asserted-by":"crossref","first-page":"21952","DOI":"10.1021\/acs.jpcc.8b06730","volume":"122","author":"Hoyt","year":"2018","journal-title":"J. Phys. Chem. C"},{"key":"D6CP02570F\/cit11\/1","doi-asserted-by":"crossref","first-page":"17","DOI":"10.1016\/0039-6028(95)00649-4","volume":"343","author":"Chen","year":"1995","journal-title":"Surf. Sci."},{"key":"D6CP02570F\/cit12\/1","doi-asserted-by":"crossref","first-page":"248","DOI":"10.1021\/jp208448c","volume":"116","author":"Yang","year":"2012","journal-title":"J. Phys. Chem. C"},{"key":"D6CP02570F\/cit13\/1","doi-asserted-by":"crossref","first-page":"23322","DOI":"10.1039\/D5CP03538D","volume":"27","author":"Osada","year":"2025","journal-title":"Phys. Chem. Chem. Phys."},{"key":"D6CP02570F\/cit14\/1","doi-asserted-by":"crossref","first-page":"25402","DOI":"10.1021\/acs.jpcc.7b09598","volume":"121","author":"Koitaya","year":"2017","journal-title":"J. Phys. Chem. C"},{"key":"D6CP02570F\/cit15\/1","volume-title":"Doctoral thesis","author":"Shiozawa","year":"2016","unstructured":"Y.Shiozawa ,  Doctoral thesis ,  Graduate School of Frontier Sciences, The University of Tokyo ,  2016"},{"key":"D6CP02570F\/cit16\/1","first-page":"152019","volume":"425","author":"Toyoshima","year":"2013","journal-title":"J. Phys.: Conf. Ser."},{"key":"D6CP02570F\/cit17\/1","doi-asserted-by":"crossref","first-page":"523","DOI":"10.1038\/nmat3620","volume":"12","author":"Marcinkowski","year":"2013","journal-title":"Nat. Mater."},{"key":"D6CP02570F\/cit18\/1","doi-asserted-by":"crossref","first-page":"21705","DOI":"10.1039\/D2CP01652D","volume":"24","author":"Osada","year":"2022","journal-title":"Phys. Chem. Chem. Phys."},{"key":"D6CP02570F\/cit19\/1","doi-asserted-by":"crossref","first-page":"1978","DOI":"10.1039\/D4CP03942D","volume":"27","author":"Osada","year":"2025","journal-title":"Phys. Chem. Chem. Phys."},{"key":"D6CP02570F\/cit20\/1","doi-asserted-by":"crossref","first-page":"443","DOI":"10.1016\/0092-640X(79)90027-5","volume":"23","author":"Band","year":"1979","journal-title":"At. Data Nucl. Data Tables"},{"key":"D6CP02570F\/cit21\/1","doi-asserted-by":"crossref","first-page":"1","DOI":"10.1016\/0092-640X(85)90016-6","volume":"32","author":"Yeh","year":"1985","journal-title":"At. Data Nucl. Data Tables"},{"key":"D6CP02570F\/cit22\/1","doi-asserted-by":"crossref","first-page":"323","DOI":"10.1002\/sia.740150505","volume":"15","author":"Hemminger","year":"1990","journal-title":"Surf. Interface Anal."},{"key":"D6CP02570F\/cit23\/1","doi-asserted-by":"crossref","first-page":"044703","DOI":"10.1063\/1.5132979","volume":"152","author":"Shiozawa","year":"2020","journal-title":"J. Chem. Phys."},{"key":"D6CP02570F\/cit24\/1","unstructured":"National Institute of Standards and Technology (NIST), Formaldehyde: Mass spectrum (electron ionization),  https:\/\/webbook.nist.gov\/chemistry\/form-ser\/ , (accessed 22 June 2026)"},{"key":"D6CP02570F\/cit25\/1","doi-asserted-by":"crossref","first-page":"1209","DOI":"10.1126\/science.1215864","volume":"335","author":"Kyriakou","year":"2012","journal-title":"Science"},{"key":"D6CP02570F\/cit26\/1","doi-asserted-by":"crossref","first-page":"1","DOI":"10.1016\/0039-6028(89)90459-7","volume":"220","author":"Anger","year":"1989","journal-title":"Surf. Sci."},{"key":"D6CP02570F\/cit27\/1","doi-asserted-by":"crossref","first-page":"387","DOI":"10.1016\/S0039-6028(87)80064-X","volume":"187","author":"Davis","year":"1987","journal-title":"Surf. Sci."},{"key":"D6CP02570F\/cit28\/1","doi-asserted-by":"crossref","first-page":"1625","DOI":"10.1016\/S0584-8539(87)80059-4","volume":"43A","author":"Chesters","year":"1987","journal-title":"Spectrochim. Acta"},{"key":"D6CP02570F\/cit29\/1","author":"Moulder","year":"1992","unstructured":"J. F.Moulder ,  W. F.Stickle ,  P. E.Sobol ,  K. D.Bomben  and  J.Chastain ,  Handbook of X-ray Photoelectron Spectroscopy: a reference book of standard spectra for identification and interpretation of XPS data , Physical Electronics Division, PerkinElmer Corp.,  1992"},{"key":"D6CP02570F\/cit30\/1","doi-asserted-by":"crossref","first-page":"190","DOI":"10.1016\/0039-6028(80)90135-1","volume":"95","author":"Bowker","year":"1980","journal-title":"Surf. Sci."},{"key":"D6CP02570F\/cit31\/1","doi-asserted-by":"crossref","first-page":"114709","DOI":"10.1063\/1.2229198","volume":"125","author":"G\u00fcnther","year":"2006","journal-title":"J. Chem. Phys."},{"key":"D6CP02570F\/cit32\/1","doi-asserted-by":"crossref","first-page":"549","DOI":"10.1016\/0039-6028(82)90364-8","volume":"116","author":"Bowker","year":"1982","journal-title":"Surf. Sci."},{"key":"D6CP02570F\/cit33\/1","doi-asserted-by":"crossref","first-page":"328","DOI":"10.1007\/s11244-017-0856-3","volume":"61","author":"Wang","year":"2018","journal-title":"Top. Catal."},{"key":"D6CP02570F\/cit34\/1","doi-asserted-by":"crossref","first-page":"8354","DOI":"10.1021\/acs.jpcc.2c01948","volume":"126","author":"Osada","year":"2022","journal-title":"J. Phys. Chem. C"},{"key":"D6CP02570F\/cit35\/1","doi-asserted-by":"crossref","first-page":"10622","DOI":"10.1039\/D4CP00070F","volume":"26","author":"Ibrahim","year":"2024","journal-title":"Phys. Chem. Chem. Phys."},{"key":"D6CP02570F\/cit36\/1","doi-asserted-by":"crossref","first-page":"957","DOI":"10.1524\/zpch.218.8.957.35981","volume":"218","author":"P\u00f6llmann","year":"2004","journal-title":"Z. Phys. Chem."},{"key":"D6CP02570F\/cit37\/1","doi-asserted-by":"crossref","first-page":"8706","DOI":"10.1021\/acs.jpcc.6c01011","volume":"130","author":"Lal","year":"2026","journal-title":"J. Phys. Chem. C"},{"key":"D6CP02570F\/cit38\/1","doi-asserted-by":"crossref","first-page":"6099","DOI":"10.1021\/acs.jpcc.0c10278","volume":"125","author":"Ben David","year":"2021","journal-title":"J. Phys. Chem. C"},{"key":"D6CP02570F\/cit39\/1","doi-asserted-by":"crossref","first-page":"363","DOI":"10.1016\/0301-0104(93)80018-5","volume":"177","author":"Witko","year":"1993","journal-title":"Chem. Phys."},{"key":"D6CP02570F\/cit40\/1","doi-asserted-by":"crossref","first-page":"365","DOI":"10.1021\/cs200055d","volume":"1","author":"Grabow","year":"2011","journal-title":"ACS Catal."}],"container-title":["Physical Chemistry Chemical Physics"],"original-title":[],"language":"en","link":[{"URL":"http:\/\/pubs.rsc.org\/CP\/article-pdf\/doi\/10.1039\/D6CP02570F\/0\/D6CP02570F.pdf","content-type":"application\/pdf","content-version":"vor","intended-application":"syndication"},{"URL":"http:\/\/pubs.rsc.org\/CP\/article-pdf\/doi\/10.1039\/D6CP02570F\/0\/D6CP02570F.pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,10,1]],"date-time":"2026-10-01T09:25:06Z","timestamp":1790846706000},"score":1,"resource":{"primary":{"URL":"http:\/\/pubs.rsc.org\/CP\/article-lookup\/doi\/10.1039\/D6CP02570F"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026]]},"references-count":40,"journal-issue":{"issue":"37","published-print":{"date-parts":[[2026,9,30]]}},"URL":"https:\/\/doi.org\/10.1039\/d6cp02570f","relation":{},"ISSN":["1463-9076","1463-9084"],"issn-type":[{"value":"1463-9076","type":"print"},{"value":"1463-9084","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026]]}}}