{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,7]],"date-time":"2026-10-07T18:49:53Z","timestamp":1791398993179,"version":"4.3.3"},"reference-count":66,"publisher":"Royal Society of Chemistry (RSC)","issue":"38","license":[{"start":{"date-parts":[[2027,9,18]],"date-time":"2027-09-18T00:00:00Z","timestamp":1821225600000},"content-version":"am","delay-in-days":625,"URL":"http:\/\/rsc.li\/journals-terms-of-use"}],"funder":[{"DOI":"10.13039\/501100002858","name":"China Postdoctoral Science Foundation","doi-asserted-by":"publisher","award":["2024M764215"],"award-info":[{"award-number":["2024M764215"]}],"id":[{"id":"10.13039\/501100002858","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["52473236"],"award-info":[{"award-number":["52473236"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["62304109"],"award-info":[{"award-number":["62304109"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100012166","name":"National Key Research and Development Program of China","doi-asserted-by":"publisher","award":["2024YFA1210002"],"award-info":[{"award-number":["2024YFA1210002"]}],"id":[{"id":"10.13039\/501100012166","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["rsc.org"],"crossmark-restriction":true},"short-container-title":["Phys. Chem. Chem. Phys."],"abstract":"<jats:p>Ge-alloyed kesterites promote electron delocalization and stabilize band-edge fluctuations, while enhanced decoherence weakens electron-vibrational coupling and suppresses nonradiative loss.<\/jats:p>","DOI":"10.1039\/d6cp02887j","type":"journal-article","created":{"date-parts":[[2026,9,18]],"date-time":"2026-09-18T14:07:04Z","timestamp":1789740424000},"page":"23793-23801","update-policy":"https:\/\/doi.org\/10.1039\/rsc_crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Ge-alloying-regulated band-edge dynamics suppress nonradiative recombination in kesterite Cu\n                    <sub>2<\/sub>\n                    Zn(Ge\n                    <sub>\n                      <i>x<\/i>\n                    <\/sub>\n                    Sn\n                    <sub>\n                      1\u2212\n                      <i>x<\/i>\n                    <\/sub>\n                    )S\n                    <sub>4<\/sub>"],"prefix":"10.1039","volume":"28","author":[{"ORCID":"https:\/\/orcid.org\/0009-0002-9936-5511","authenticated-orcid":false,"given":"Xinwei","family":"Guo","sequence":"first","affiliation":[{"name":"MIIT Key Laboratory of Advanced Display Materials and Devices, Jiangsu Engineering Research Center for Quantum Dot Display, School of Materials Science and Engineering, Institute of Optoelectronics & Nanomaterials, Nanjing University of Science and Technology, Nanjing, Jiangsu 210094, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zuyun","family":"Chen","sequence":"additional","affiliation":[{"name":"School of Material Engineering, Jinling Institute of Technology, Nanjing 211169, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xuemin","family":"Hu","sequence":"additional","affiliation":[{"name":"MIIT Key Laboratory of Advanced Display Materials and Devices, Jiangsu Engineering Research Center for Quantum Dot Display, School of Materials Science and Engineering, Institute of Optoelectronics & Nanomaterials, Nanjing University of Science and Technology, Nanjing, Jiangsu 210094, China"},{"name":"School of Material Engineering, Jinling Institute of Technology, Nanjing 211169, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Chun","family":"Wang","sequence":"additional","affiliation":[{"name":"MIIT Key Laboratory of Advanced Display Materials and Devices, Jiangsu Engineering Research Center for Quantum Dot Display, School of Materials Science and Engineering, Institute of Optoelectronics & Nanomaterials, Nanjing University of Science and Technology, Nanjing, Jiangsu 210094, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4981-231X","authenticated-orcid":false,"given":"Shengli","family":"Zhang","sequence":"additional","affiliation":[{"name":"MIIT Key Laboratory of Advanced Display Materials and Devices, Jiangsu Engineering Research Center for Quantum Dot Display, School of Materials Science and Engineering, Institute of Optoelectronics & Nanomaterials, Nanjing University of Science and Technology, Nanjing, Jiangsu 210094, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-8160-6394","authenticated-orcid":false,"given":"Wenhan","family":"Zhou","sequence":"additional","affiliation":[{"name":"MIIT Key Laboratory of Advanced Display Materials and Devices, Jiangsu Engineering Research Center for Quantum Dot Display, School of Materials Science and Engineering, Institute of Optoelectronics & Nanomaterials, Nanjing University of Science and Technology, Nanjing, Jiangsu 210094, China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"292","published-online":{"date-parts":[[2026]]},"reference":[{"key":"D6CP02887J\/cit1\/1","doi-asserted-by":"crossref","first-page":"aad4424","DOI":"10.1126\/science.aad4424","volume":"352","author":"Polman","year":"2016","journal-title":"Science"},{"key":"D6CP02887J\/cit2\/1","doi-asserted-by":"crossref","first-page":"227","DOI":"10.1038\/s41377-024-01461-x","volume":"13","author":"Yang","year":"2024","journal-title":"Light: Sci. Appl."},{"key":"D6CP02887J\/cit3\/1","doi-asserted-by":"crossref","first-page":"155933","DOI":"10.1016\/j.cej.2024.155933","volume":"499","author":"Yu","year":"2024","journal-title":"Chem. Eng. J."},{"key":"D6CP02887J\/cit4\/1","doi-asserted-by":"crossref","first-page":"2301871","DOI":"10.1002\/adma.202301871","volume":"35","author":"Guo","year":"2023","journal-title":"Adv. Mater."},{"key":"D6CP02887J\/cit5\/1","doi-asserted-by":"crossref","first-page":"2203046","DOI":"10.1002\/aenm.202203046","volume":"13","author":"Wang","year":"2023","journal-title":"Adv. Energy Mater."},{"key":"D6CP02887J\/cit6\/1","doi-asserted-by":"crossref","first-page":"2004313","DOI":"10.1002\/advs.202004313","volume":"8","author":"He","year":"2021","journal-title":"Adv. Sci."},{"key":"D6CP02887J\/cit7\/1","doi-asserted-by":"crossref","first-page":"190","DOI":"10.1039\/C3EE41437J","volume":"7","author":"Fan","year":"2014","journal-title":"Energy Environ. Sci."},{"key":"D6CP02887J\/cit8\/1","doi-asserted-by":"crossref","first-page":"511","DOI":"10.1021\/acs.accounts.5b00535","volume":"49","author":"Regulacio","year":"2016","journal-title":"Acc. Chem. Res."},{"key":"D6CP02887J\/cit9\/1","doi-asserted-by":"crossref","first-page":"16","DOI":"10.1038\/s41528-023-00250-7","volume":"7","author":"Li","year":"2023","journal-title":"npj Flex. Electron."},{"key":"D6CP02887J\/cit10\/1","doi-asserted-by":"crossref","first-page":"195203","DOI":"10.1103\/PhysRevB.82.195203","volume":"82","author":"Chen","year":"2010","journal-title":"Phys. Rev. B"},{"key":"D6CP02887J\/cit11\/1","doi-asserted-by":"crossref","first-page":"425","DOI":"10.1002\/pip.3831","volume":"32","author":"Green","year":"2024","journal-title":"Prog. Photovoltaics"},{"key":"D6CP02887J\/cit12\/1","doi-asserted-by":"crossref","first-page":"526","DOI":"10.1038\/s41560-023-01251-6","volume":"8","author":"Zhou","year":"2023","journal-title":"Nat. Energy"},{"key":"D6CP02887J\/cit13\/1","doi-asserted-by":"crossref","first-page":"754","DOI":"10.1038\/s41560-022-01078-7","volume":"7","author":"Li","year":"2022","journal-title":"Nat. Energy"},{"key":"D6CP02887J\/cit14\/1","doi-asserted-by":"crossref","first-page":"44","DOI":"10.1038\/s41578-019-0151-y","volume":"5","author":"Luo","year":"2020","journal-title":"Nat. Rev. Mater."},{"key":"D6CP02887J\/cit15\/1","doi-asserted-by":"crossref","first-page":"486","DOI":"10.1038\/s43588-022-00297-y","volume":"2","author":"Wang","year":"2022","journal-title":"Nat. Comput. Sci."},{"key":"D6CP02887J\/cit16\/1","doi-asserted-by":"crossref","first-page":"2705","DOI":"10.1039\/D3TC04431A","volume":"12","author":"Yang","year":"2024","journal-title":"J. Mater. Chem. C"},{"key":"D6CP02887J\/cit17\/1","doi-asserted-by":"crossref","first-page":"1522","DOI":"10.1002\/adma.201203146","volume":"25","author":"Chen","year":"2013","journal-title":"Adv. Mater."},{"key":"D6CP02887J\/cit18\/1","doi-asserted-by":"crossref","first-page":"1481","DOI":"10.1039\/D0EE00291G","volume":"13","author":"Kim","year":"2020","journal-title":"Energy Environ. Sci."},{"key":"D6CP02887J\/cit19\/1","doi-asserted-by":"crossref","first-page":"2371","DOI":"10.1007\/s40843-020-1385-0","volume":"63","author":"Duan","year":"2020","journal-title":"Sci. China Mater."},{"key":"D6CP02887J\/cit20\/1","doi-asserted-by":"crossref","first-page":"2405033","DOI":"10.1002\/aenm.202405033","volume":"15","author":"Ma","year":"2025","journal-title":"Adv. Energy Mater."},{"key":"D6CP02887J\/cit21\/1","doi-asserted-by":"crossref","first-page":"3567","DOI":"10.1039\/D1EE00260K","volume":"14","author":"Chen","year":"2021","journal-title":"Energy Environ. Sci."},{"key":"D6CP02887J\/cit22\/1","doi-asserted-by":"crossref","first-page":"84","DOI":"10.1007\/s40820-024-01574-3","volume":"17","author":"Zhao","year":"2025","journal-title":"Nano-Micro Lett."},{"key":"D6CP02887J\/cit23\/1","doi-asserted-by":"crossref","first-page":"32147","DOI":"10.1021\/jacs.4c14416","volume":"146","author":"Zhang","year":"2024","journal-title":"J. Am. Chem. Soc."},{"key":"D6CP02887J\/cit24\/1","first-page":"1095","volume":"9","author":"Shi","year":"2024","journal-title":"Nat. Energy"},{"key":"D6CP02887J\/cit25\/1","doi-asserted-by":"crossref","first-page":"2407075","DOI":"10.1002\/smll.202407075","volume":"21","author":"Xu","year":"2025","journal-title":"Small"},{"key":"D6CP02887J\/cit26\/1","doi-asserted-by":"crossref","first-page":"44","DOI":"10.1016\/j.solmat.2019.04.011","volume":"198","author":"Sanchez","year":"2019","journal-title":"Sol. Energy Mater. Sol. Cells"},{"key":"D6CP02887J\/cit27\/1","doi-asserted-by":"crossref","first-page":"166184","DOI":"10.1016\/j.jallcom.2022.166184","volume":"921","author":"Mora-Herrera","year":"2022","journal-title":"J. Alloys Compd."},{"key":"D6CP02887J\/cit28\/1","doi-asserted-by":"crossref","first-page":"2423251","DOI":"10.1002\/adfm.202423251","volume":"35","author":"Tao","year":"2025","journal-title":"Adv. Funct. Mater."},{"key":"D6CP02887J\/cit29\/1","doi-asserted-by":"crossref","first-page":"8940","DOI":"10.1021\/acs.nanolett.4c01809","volume":"24","author":"Lu","year":"2024","journal-title":"Nano Lett."},{"key":"D6CP02887J\/cit30\/1","doi-asserted-by":"crossref","first-page":"214","DOI":"10.1007\/s40843-023-2680-x","volume":"67","author":"Liu","year":"2024","journal-title":"Sci. China Mater."},{"key":"D6CP02887J\/cit31\/1","doi-asserted-by":"crossref","first-page":"3789","DOI":"10.1007\/s40843-025-3488-3","volume":"68","author":"Liu","year":"2025","journal-title":"Sci. China Mater."},{"key":"D6CP02887J\/cit32\/1","doi-asserted-by":"crossref","first-page":"882","DOI":"10.1021\/acs.nanolett.4c05701","volume":"25","author":"Wang","year":"2025","journal-title":"Nano Lett."},{"key":"D6CP02887J\/cit33\/1","doi-asserted-by":"crossref","first-page":"2407991","DOI":"10.1002\/adfm.202407991","volume":"34","author":"Xiang","year":"2024","journal-title":"Adv. Funct. Mater."},{"key":"D6CP02887J\/cit34\/1","doi-asserted-by":"crossref","first-page":"A1133","DOI":"10.1103\/PhysRev.140.A1133","volume":"140","author":"Kohn","year":"1965","journal-title":"Phys. Rev."},{"key":"D6CP02887J\/cit35\/1","doi-asserted-by":"crossref","first-page":"B864","DOI":"10.1103\/PhysRev.136.B864","volume":"136","author":"Hohenberg","year":"1964","journal-title":"Phys. Rev."},{"key":"D6CP02887J\/cit36\/1","doi-asserted-by":"crossref","first-page":"15","DOI":"10.1016\/0927-0256(96)00008-0","volume":"6","author":"Kresse","year":"1996","journal-title":"Comput. Mater. Sci."},{"key":"D6CP02887J\/cit37\/1","doi-asserted-by":"crossref","first-page":"11169","DOI":"10.1103\/PhysRevB.54.11169","volume":"54","author":"Kresse","year":"1996","journal-title":"Phys. Rev. B"},{"key":"D6CP02887J\/cit38\/1","doi-asserted-by":"crossref","first-page":"3865","DOI":"10.1103\/PhysRevLett.77.3865","volume":"77","author":"Perdew","year":"1996","journal-title":"Phys. Rev. Lett."},{"key":"D6CP02887J\/cit39\/1","doi-asserted-by":"crossref","first-page":"8207","DOI":"10.1063\/1.1564060","volume":"118","author":"Heyd","year":"2003","journal-title":"J. Chem. Phys."},{"key":"D6CP02887J\/cit40\/1","doi-asserted-by":"crossref","first-page":"e1411","DOI":"10.1002\/wcms.1411","volume":"9","author":"Zheng","year":"2019","journal-title":"WIREs Comput. Mol. Sci."},{"key":"D6CP02887J\/cit41\/1","doi-asserted-by":"crossref","first-page":"7026","DOI":"10.1021\/acs.chemrev.7b00577","volume":"118","author":"Crespo-Otero","year":"2018","journal-title":"Chem. Rev."},{"key":"D6CP02887J\/cit42\/1","doi-asserted-by":"crossref","first-page":"22A545","DOI":"10.1063\/1.4757100","volume":"137","author":"Jaeger","year":"2012","journal-title":"J. Chem. Phys."},{"key":"D6CP02887J\/cit43\/1","doi-asserted-by":"crossref","first-page":"1502276","DOI":"10.1002\/aenm.201502276","volume":"6","author":"Bourdais","year":"2016","journal-title":"Adv. Energy Mater."},{"key":"D6CP02887J\/cit44\/1","doi-asserted-by":"crossref","first-page":"497","DOI":"10.1021\/acsenergylett.3c02653","volume":"9","author":"Zhu","year":"2024","journal-title":"ACS Energy Lett."},{"key":"D6CP02887J\/cit45\/1","doi-asserted-by":"crossref","first-page":"107","DOI":"10.1021\/acs.jpclett.2c03631","volume":"14","author":"Zhang","year":"2023","journal-title":"J. Phys. Chem. Lett."},{"key":"D6CP02887J\/cit46\/1","doi-asserted-by":"crossref","first-page":"165211","DOI":"10.1103\/PhysRevB.79.165211","volume":"79","author":"Chen","year":"2009","journal-title":"Phys. Rev. B"},{"key":"D6CP02887J\/cit47\/1","doi-asserted-by":"crossref","first-page":"10463","DOI":"10.1021\/acs.jpclett.0c03205","volume":"11","author":"Tong","year":"2020","journal-title":"J. Phys. Chem. Lett."},{"key":"D6CP02887J\/cit48\/1","doi-asserted-by":"crossref","first-page":"997","DOI":"10.1103\/PhysRevLett.52.997","volume":"52","author":"Runge","year":"1984","journal-title":"Phys. Rev. Lett."},{"key":"D6CP02887J\/cit49\/1","doi-asserted-by":"crossref","first-page":"2438","DOI":"10.1021\/acs.jpclett.5c00139","volume":"16","author":"Tian","year":"2025","journal-title":"J. Phys. Chem. Lett."},{"key":"D6CP02887J\/cit50\/1","doi-asserted-by":"crossref","first-page":"1547","DOI":"10.1021\/acsmaterialslett.5c00001","volume":"7","author":"Kamboj","year":"2025","journal-title":"ACS Mater. Lett."},{"key":"D6CP02887J\/cit51\/1","doi-asserted-by":"crossref","first-page":"16314","DOI":"10.1021\/jacs.4c05191","volume":"146","author":"Ma","year":"2024","journal-title":"J. Am. Chem. Soc."},{"key":"D6CP02887J\/cit52\/1","doi-asserted-by":"crossref","first-page":"28865","DOI":"10.1039\/D4CP01678E","volume":"26","author":"Lv","year":"2024","journal-title":"Phys. Chem. Chem. Phys."},{"key":"D6CP02887J\/cit53\/1","doi-asserted-by":"crossref","first-page":"655","DOI":"10.1021\/acs.chemmater.4c02530","volume":"37","author":"Shi","year":"2025","journal-title":"Chem. Mater."},{"key":"D6CP02887J\/cit54\/1","doi-asserted-by":"crossref","first-page":"29905","DOI":"10.1021\/jacs.4c12042","volume":"146","author":"Zhou","year":"2024","journal-title":"J. Am. Chem. Soc."},{"key":"D6CP02887J\/cit55\/1","doi-asserted-by":"crossref","first-page":"22481","DOI":"10.1039\/D6RA02305C","volume":"16","author":"Huang","year":"2026","journal-title":"RSC Adv."},{"key":"D6CP02887J\/cit56\/1","doi-asserted-by":"crossref","first-page":"6363","DOI":"10.1021\/acs.jpclett.4c01140","volume":"15","author":"Yang","year":"2024","journal-title":"J. Phys. Chem. Lett."},{"key":"D6CP02887J\/cit57\/1","doi-asserted-by":"crossref","first-page":"11543","DOI":"10.1021\/jacs.5c02139","volume":"147","author":"Liu","year":"2025","journal-title":"J. Am. Chem. Soc."},{"key":"D6CP02887J\/cit58\/1","doi-asserted-by":"crossref","first-page":"1267","DOI":"10.1103\/RevModPhys.76.1267","volume":"76","author":"Schlosshauer","year":"2005","journal-title":"Rev. Mod. Phys."},{"key":"D6CP02887J\/cit59\/1","doi-asserted-by":"crossref","first-page":"7274","DOI":"10.1021\/acs.jpclett.3c01831","volume":"14","author":"Gumber","year":"2023","journal-title":"J. Phys. Chem. Lett."},{"key":"D6CP02887J\/cit60\/1","doi-asserted-by":"crossref","first-page":"5294","DOI":"10.1103\/PhysRevLett.81.5294","volume":"81","author":"Prezhdo","year":"1998","journal-title":"Phys. Rev. Lett."},{"key":"D6CP02887J\/cit61\/1","doi-asserted-by":"crossref","first-page":"855","DOI":"10.1088\/0951-7715\/22\/4\/009","volume":"22","author":"Ruelle","year":"2009","journal-title":"Nonlinearity"},{"key":"D6CP02887J\/cit62\/1","doi-asserted-by":"crossref","first-page":"3857","DOI":"10.1021\/jz402035z","volume":"4","author":"Akimov","year":"2013","journal-title":"J. Phys. Chem. Lett."},{"key":"D6CP02887J\/cit63\/1","doi-asserted-by":"crossref","first-page":"6425","DOI":"10.1021\/acs.nanolett.4c01577","volume":"24","author":"Fu","year":"2024","journal-title":"Nano Lett."},{"key":"D6CP02887J\/cit64\/1","doi-asserted-by":"crossref","first-page":"16763","DOI":"10.1039\/D5TC01537E","volume":"13","author":"Sajid","year":"2025","journal-title":"J. Mater. Chem. C"},{"key":"D6CP02887J\/cit65\/1","doi-asserted-by":"crossref","first-page":"67756","DOI":"10.1039\/C6RA13608G","volume":"6","author":"Ya. Valakh","year":"2016","journal-title":"RSC Adv."},{"key":"D6CP02887J\/cit66\/1","doi-asserted-by":"crossref","first-page":"13278","DOI":"10.1039\/C5RA26844C","volume":"6","author":"Guc","year":"2016","journal-title":"RSC Adv."}],"container-title":["Physical Chemistry Chemical Physics"],"original-title":[],"language":"en","link":[{"URL":"http:\/\/pubs.rsc.org\/CP\/article-pdf\/doi\/10.1039\/D6CP02887J\/0\/D6CP02887J.pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,10,7]],"date-time":"2026-10-07T17:53:15Z","timestamp":1791395595000},"score":1,"resource":{"primary":{"URL":"http:\/\/pubs.rsc.org\/CP\/article-lookup\/doi\/10.1039\/D6CP02887J"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026]]},"references-count":66,"journal-issue":{"issue":"38","published-print":{"date-parts":[[2026,10,7]]}},"URL":"https:\/\/doi.org\/10.1039\/d6cp02887j","relation":{},"ISSN":["1463-9076","1463-9084"],"issn-type":[{"value":"1463-9076","type":"print"},{"value":"1463-9084","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026]]}}}