{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,14]],"date-time":"2026-10-14T07:46:52Z","timestamp":1791964012401,"version":"4.3.4"},"reference-count":36,"publisher":"Royal Society of Chemistry (RSC)","license":[{"start":{"date-parts":[[2027,10,14]],"date-time":"2027-10-14T00:00:00Z","timestamp":1823472000000},"content-version":"am","delay-in-days":651,"URL":"http:\/\/rsc.li\/journals-terms-of-use"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["92461313"],"award-info":[{"award-number":["92461313"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["rsc.org"],"crossmark-restriction":true},"short-container-title":["Phys. Chem. Chem. Phys."],"abstract":"<jats:p>\n                    A weak interaction barrier is found in the W(N\n                    <jats:sub>2<\/jats:sub>\n                    )\n                    <jats:sub>5<\/jats:sub>\n                    <jats:sup>\u2212<\/jats:sup>\n                    + N\n                    <jats:sub>2<\/jats:sub>\n                    reaction pathway, implying that the formation of octahedral W(N\n                    <jats:sub>2<\/jats:sub>\n                    )\n                    <jats:sub>6<\/jats:sub>\n                    <jats:sup>\u2212<\/jats:sup>\n                    is hindered by kinetics rather than by thermodynamics.\n                  <\/jats:p>","DOI":"10.1039\/d6cp03221d","type":"journal-article","created":{"date-parts":[[2026,10,14]],"date-time":"2026-10-14T07:10:04Z","timestamp":1791961804000},"update-policy":"https:\/\/doi.org\/10.1039\/rsc_crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["The reaction between W(N\n                    <sub>2<\/sub>\n                    )\n                    <sub>5<\/sub>\n                    <sup>\u2212<\/sup>\n                    and N\n                    <sub>2<\/sub>\n                    : the importance of the adsorption barrier"],"prefix":"10.1039","author":[{"ORCID":"https:\/\/orcid.org\/0009-0001-6232-7952","authenticated-orcid":false,"given":"Kai-Wen","family":"Liu","sequence":"first","affiliation":[{"name":"Ningbo Key Laboratory of Pharmaceutical Functional Materials, College of Basic Science, Zhejiang Pharmaceutical University, Ningbo 315500, China"},{"name":"Beijing National Laboratory for Molecular Sciences (BNLMS), State Key Laboratory of Molecular Reaction Dynamics, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China"},{"name":"University of Chinese Academy of Sciences, Beijing 100049, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Bin","family":"Yang","sequence":"additional","affiliation":[{"name":"Xi\u2019an Modern Chemistry Research Institute, Xi\u2019an 710065, China"},{"name":"State Key Laboratory of Fluorine & Nitrogen Chemical, Xi\u2019an 710065, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-6301-2362","authenticated-orcid":false,"given":"Ke-Wei","family":"Ding","sequence":"additional","affiliation":[{"name":"Xi\u2019an Modern Chemistry Research Institute, Xi\u2019an 710065, China"},{"name":"State Key Laboratory of Fluorine & Nitrogen Chemical, Xi\u2019an 710065, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-6992-2140","authenticated-orcid":false,"given":"Xi-Ling","family":"Xu","sequence":"additional","affiliation":[{"name":"Beijing National Laboratory for Molecular Sciences (BNLMS), State Key Laboratory of Molecular Reaction Dynamics, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China"},{"name":"University of Chinese Academy of Sciences, Beijing 100049, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-1406-0202","authenticated-orcid":false,"given":"Hong-Guang","family":"Xu","sequence":"additional","affiliation":[{"name":"Beijing National Laboratory for Molecular Sciences (BNLMS), State Key Laboratory of Molecular Reaction Dynamics, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China"},{"name":"University of Chinese Academy of Sciences, Beijing 100049, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9136-2693","authenticated-orcid":false,"given":"Wei-Jun","family":"Zheng","sequence":"additional","affiliation":[{"name":"Beijing National Laboratory for Molecular Sciences (BNLMS), State Key Laboratory of Molecular Reaction Dynamics, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China"},{"name":"University of Chinese Academy of Sciences, Beijing 100049, China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"292","published-online":{"date-parts":[[2026]]},"reference":[{"key":"D6CP03221D\/cit1\/1","doi-asserted-by":"crossref","first-page":"3992","DOI":"10.1039\/C6SC01066K","volume":"7","author":"Guo","year":"2016","journal-title":"Chem. 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