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Chem. Chem. Phys."],"abstract":"<jats:p>\n                    Gas phase spectroscopy of monocyclic carbon ring cations (C\n                    <jats:sub>4n<\/jats:sub>\n                    <jats:sup>+<\/jats:sup>\n                    ,\n                    <jats:italic>n<\/jats:italic>\n                    = 2\u20137) reveal intense infrared transitions due to Kekul\u00e9-type distortions. A breakdown in linear trends is observed for C\n                    <jats:sub>12<\/jats:sub>\n                    <jats:sup>+<\/jats:sup>\n                    and smaller rings, indicating a change of common structure.\n                  <\/jats:p>","DOI":"10.1039\/d6cp03280j","type":"journal-article","created":{"date-parts":[[2026,10,5]],"date-time":"2026-10-05T12:20:03Z","timestamp":1791202803000},"update-policy":"https:\/\/doi.org\/10.1039\/rsc_crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Unravelling the structure of monocyclic carbon ring cations using vibrational spectroscopy"],"prefix":"10.1039","author":[{"ORCID":"https:\/\/orcid.org\/0009-0006-8530-221X","authenticated-orcid":false,"given":"Thomas E.","family":"Douglas-Walker","sequence":"first","affiliation":[{"name":"School of Chemistry, The University of Edinburgh, Joseph Black Building, David Brewster Road, King's Buildings, Edinburgh, EH9 3FJ, Scotland, UK"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Amit","family":"Debnath","sequence":"additional","affiliation":[{"name":"School of Chemistry, The University of Edinburgh, Joseph Black Building, David Brewster Road, King's Buildings, Edinburgh, EH9 3FJ, Scotland, UK"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0007-3265-1675","authenticated-orcid":false,"given":"Olivia","family":"O'Neill","sequence":"additional","affiliation":[{"name":"School of Chemistry, The University of Edinburgh, Joseph Black Building, David Brewster Road, King's Buildings, Edinburgh, EH9 3FJ, Scotland, UK"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ewen K.","family":"Campbell","sequence":"additional","affiliation":[{"name":"School of Chemistry, The University of Edinburgh, Joseph Black Building, David Brewster Road, King's Buildings, Edinburgh, EH9 3FJ, Scotland, UK"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"292","published-online":{"date-parts":[[2026]]},"reference":[{"key":"D6CP03280J\/cit1\/1","doi-asserted-by":"crossref","first-page":"6511","DOI":"10.1063\/1.440991","volume":"74","author":"Dietz","year":"1981","journal-title":"J. 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