{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,7,14]],"date-time":"2026-07-14T09:08:38Z","timestamp":1784020118678,"version":"3.55.0"},"reference-count":30,"publisher":"Royal Society of Chemistry (RSC)","issue":"27","license":[{"start":{"date-parts":[[2027,6,29]],"date-time":"2027-06-29T00:00:00Z","timestamp":1814227200000},"content-version":"am","delay-in-days":544,"URL":"http:\/\/rsc.li\/journals-terms-of-use"}],"funder":[{"DOI":"10.13039\/501100001412","name":"Council of Scientific and Industrial Research, India","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100001412","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001843","name":"Science and Engineering Research Board","doi-asserted-by":"publisher","award":["ECR\/2016\/000890"],"award-info":[{"award-number":["ECR\/2016\/000890"]}],"id":[{"id":"10.13039\/501100001843","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["rsc.org"],"crossmark-restriction":true},"short-container-title":["Dalton Trans."],"abstract":"<jats:p>\n                    Isolated Mn(\n                    <jats:sc>ii<\/jats:sc>\n                    ) complexes exhibiting the uncommon intermediate spin state (S = 3\/2).\n                  <\/jats:p>","DOI":"10.1039\/d6dt01052k","type":"journal-article","created":{"date-parts":[[2026,6,29]],"date-time":"2026-06-29T16:23:25Z","timestamp":1782750205000},"page":"10174-10179","update-policy":"https:\/\/doi.org\/10.1039\/rsc_crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Isolation of a trigonal bipyramidal Mn(\n                    <scp>ii<\/scp>\n                    ) diradical complex with an intermediate spin state (\n                    <i>S<\/i>\n                    = 3\/2)"],"prefix":"10.1039","volume":"55","author":[{"given":"Sujit","family":"Das","sequence":"first","affiliation":[{"name":"Department of Chemistry, Indian Institute of Technology Madras, Chennai, 600036, Tamil Nadu, India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9461-1448","authenticated-orcid":false,"given":"Bj\u00f6rn","family":"Schwarz","sequence":"additional","affiliation":[{"name":"Karlsruher Institut f\u00fcr Technologie, Hermann-von-Helmholtz-Platz 1, Eggenstein-Leopoldshafen, Baden-W\u00fcrttemberg, DE 76344, Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5830-3608","authenticated-orcid":false,"given":"Kartik Chandra","family":"Mondal","sequence":"additional","affiliation":[{"name":"Department of Chemistry, Indian Institute of Technology Madras, Chennai, 600036, Tamil Nadu, India"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"292","published-online":{"date-parts":[[2026]]},"reference":[{"key":"D6DT01052K\/cit1\/1","doi-asserted-by":"crossref","first-page":"3596","DOI":"10.1021\/ja00877a045","volume":"84","author":"Gray","year":"1962","journal-title":"J. Am. Chem. Soc."},{"key":"D6DT01052K\/cit2\/1","doi-asserted-by":"crossref","first-page":"93","DOI":"10.1016\/S0010-8545(01)00457-X","volume":"227","author":"Robertson","year":"2002","journal-title":"Coord. Chem. Rev."},{"key":"D6DT01052K\/cit3\/1","doi-asserted-by":"crossref","first-page":"10178","DOI":"10.1039\/D5TA08423G","volume":"14","author":"Das","year":"2026","journal-title":"J. Mater. Chem. A"},{"key":"D6DT01052K\/cit4\/1","doi-asserted-by":"crossref","first-page":"12869","DOI":"10.1021\/ja982914f","volume":"120","author":"Donahue","year":"1998","journal-title":"J. Am. Chem. Soc."},{"key":"D6DT01052K\/cit5\/1","doi-asserted-by":"crossref","first-page":"5829","DOI":"10.1021\/ic900154v","volume":"48","author":"Banerjee","year":"2009","journal-title":"Inorg. Chem."},{"key":"D6DT01052K\/cit6\/1","doi-asserted-by":"crossref","first-page":"3713","DOI":"10.1021\/ic00318a021","volume":"28","author":"Greiwe","year":"1989","journal-title":"Inorg. Chem."},{"key":"D6DT01052K\/cit7\/1","doi-asserted-by":"crossref","first-page":"5954","DOI":"10.3390\/molecules26195954","volume":"26","author":"Martini","year":"2021","journal-title":"Molecules"},{"key":"D6DT01052K\/cit8\/1","doi-asserted-by":"crossref","first-page":"4091","DOI":"10.1021\/ic00168a054","volume":"22","author":"Costa","year":"1983","journal-title":"Inorg. Chem."},{"key":"D6DT01052K\/cit9\/1","doi-asserted-by":"crossref","first-page":"51","DOI":"10.1016\/0020-1693(94)04357-2","volume":"232","author":"Tamura","year":"1995","journal-title":"Inorg. Chim. Acta"},{"key":"D6DT01052K\/cit10\/1","doi-asserted-by":"crossref","first-page":"11435","DOI":"10.1021\/ic801553s","volume":"47","author":"Lin","year":"2008","journal-title":"Inorg. Chem."},{"key":"D6DT01052K\/cit11\/1","doi-asserted-by":"crossref","first-page":"15480","DOI":"10.1039\/C9DT02187F","volume":"48","author":"Hay","year":"2019","journal-title":"Dalton Trans."},{"key":"D6DT01052K\/cit12\/1","doi-asserted-by":"crossref","first-page":"3067","DOI":"10.1002\/anie.200454008","volume":"43","author":"Layfield","year":"2004","journal-title":"Angew. Chem., Int. Ed."},{"key":"D6DT01052K\/cit13\/1","doi-asserted-by":"crossref","first-page":"3570","DOI":"10.1021\/om060295a","volume":"25","author":"Layfield","year":"2006","journal-title":"Organometallics"},{"key":"D6DT01052K\/cit14\/1","doi-asserted-by":"crossref","first-page":"1098","DOI":"10.1039\/b708850g","volume":"37","author":"Layfield","year":"2008","journal-title":"Chem. Soc. Rev."},{"key":"D6DT01052K\/cit15\/1","doi-asserted-by":"crossref","first-page":"1956","DOI":"10.1039\/b106366a","author":"Bond","year":"2001","journal-title":"Chem. Commun."},{"key":"D6DT01052K\/cit16\/1","doi-asserted-by":"crossref","first-page":"3053","DOI":"10.1002\/chem.200501214","volume":"12","author":"Alvarez","year":"2006","journal-title":"Chem. \u2013 Eur. J."},{"key":"D6DT01052K\/cit17\/1","doi-asserted-by":"crossref","first-page":"6859","DOI":"10.1021\/jacs.7b03794","volume":"139","author":"Wang","year":"2017","journal-title":"J. Am. Chem. Soc."},{"key":"D6DT01052K\/cit18\/1","doi-asserted-by":"crossref","first-page":"16340","DOI":"10.1021\/jacs.4c05631","volume":"146","author":"Tran","year":"2024","journal-title":"J. Am. Chem. Soc."},{"key":"D6DT01052K\/cit19\/1","doi-asserted-by":"crossref","first-page":"5829","DOI":"10.1021\/ic900154v","volume":"48","author":"Banerjee","year":"2009","journal-title":"Inorg. Chem."},{"key":"D6DT01052K\/cit20\/1","doi-asserted-by":"crossref","first-page":"527","DOI":"10.1021\/acs.organomet.1c00607","volume":"41","author":"Wang","year":"2022","journal-title":"Organometallics"},{"key":"D6DT01052K\/cit21\/1","doi-asserted-by":"crossref","first-page":"317","DOI":"10.4236\/aces.2019.94023","volume":"9","author":"Matin","year":"2019","journal-title":"Adv. Chem. Eng. Sci."},{"key":"D6DT01052K\/cit22\/1","doi-asserted-by":"crossref","first-page":"2746","DOI":"10.1039\/D4CC03777D","volume":"61","author":"Das","year":"2025","journal-title":"Chem. Commun."},{"key":"D6DT01052K\/cit23\/1","doi-asserted-by":"crossref","first-page":"305","DOI":"10.2138\/am-1998-3-414","volume":"83","author":"Nesbitt","year":"1998","journal-title":"Am. Mineral."},{"key":"D6DT01052K\/cit24\/1","doi-asserted-by":"crossref","first-page":"13973","DOI":"10.1021\/acsnano.4c03964","volume":"18","author":"Lu","year":"2024","journal-title":"ACS Nano"},{"key":"D6DT01052K\/cit25\/1","doi-asserted-by":"crossref","first-page":"1427","DOI":"10.3390\/molecules21111427","volume":"21","author":"Buitendach","year":"2016","journal-title":"Molecules"},{"key":"D6DT01052K\/cit26\/1","doi-asserted-by":"crossref","first-page":"6131","DOI":"10.1021\/om300478v","volume":"31","author":"Engerer","year":"2012","journal-title":"Organometallics"},{"key":"D6DT01052K\/cit27\/1","doi-asserted-by":"crossref","first-page":"1467","DOI":"10.1021\/om500101m","volume":"33","author":"Chadha","year":"2014","journal-title":"Organometallics"},{"key":"D6DT01052K\/cit28\/1","doi-asserted-by":"crossref","first-page":"1941","DOI":"10.1021\/ic0401039","volume":"44","author":"Liao","year":"2005","journal-title":"Inorg. Chem."},{"key":"D6DT01052K\/cit29\/1","doi-asserted-by":"crossref","first-page":"3181","DOI":"10.1021\/ja710663n","volume":"130","author":"Lu","year":"2008","journal-title":"J. Am. Chem. Soc."},{"key":"D6DT01052K\/cit30\/1","doi-asserted-by":"publisher","year":"2026","unstructured":"CCDC 2430651: Experimental Crystal Structure Determination ,  2026 ,  10.5517\/ccdc.csd.cc2ml93n","DOI":"10.5517\/ccdc.csd.cc2ml93n"}],"container-title":["Dalton Transactions"],"original-title":[],"language":"en","link":[{"URL":"http:\/\/pubs.rsc.org\/DT\/article-pdf\/doi\/10.1039\/D6DT01052K\/0\/D6DT01052K.pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,7,14]],"date-time":"2026-07-14T08:51:03Z","timestamp":1784019063000},"score":1,"resource":{"primary":{"URL":"http:\/\/pubs.rsc.org\/DT\/article-lookup\/doi\/10.1039\/D6DT01052K"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026]]},"references-count":30,"journal-issue":{"issue":"27","published-print":{"date-parts":[[2026,7,14]]}},"URL":"https:\/\/doi.org\/10.1039\/d6dt01052k","relation":{},"ISSN":["1477-9226","1477-9234"],"issn-type":[{"value":"1477-9226","type":"print"},{"value":"1477-9234","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026]]}}}