{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,1]],"date-time":"2026-09-01T21:40:57Z","timestamp":1788298857872,"version":"build-2803163510"},"reference-count":53,"publisher":"Royal Society of Chemistry (RSC)","issue":"26","license":[{"start":{"date-parts":[[2027,6,16]],"date-time":"2027-06-16T00:00:00Z","timestamp":1813104000000},"content-version":"am","delay-in-days":531,"URL":"http:\/\/rsc.li\/journals-terms-of-use"}],"funder":[{"DOI":"10.13039\/501100001501","name":"University Grants Commission","doi-asserted-by":"publisher","award":["NTA Reference Number: 211610022752"],"award-info":[{"award-number":["NTA Reference Number: 211610022752"]}],"id":[{"id":"10.13039\/501100001501","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["rsc.org"],"crossmark-restriction":true},"short-container-title":["Dalton Trans."],"abstract":"<jats:p>\n                    This study unveils nucleophilicity-dependent n \u2192 \u03c0* interactions in complexes of Be(CO)\n                    <jats:sub>3<\/jats:sub>\n                    and BH(CO)\n                    <jats:sub>2<\/jats:sub>\n                    with Lewis bases, providing a new perspective on donor-acceptor interactions in main-group chemistry.\n                  <\/jats:p>","DOI":"10.1039\/d6dt01195k","type":"journal-article","created":{"date-parts":[[2026,6,16]],"date-time":"2026-06-16T06:23:32Z","timestamp":1781591012000},"page":"9958-9968","update-policy":"https:\/\/doi.org\/10.1039\/rsc_crossmark_policy","source":"Crossref","is-referenced-by-count":1,"title":["Unveiling the n \u2192 \u03c0* interactions in main-group carbonyl complexes"],"prefix":"10.1039","volume":"55","author":[{"given":"Gautam","family":"Deo","sequence":"first","affiliation":[{"name":"Department of Chemistry, University of Delhi, Delhi-110007, India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-6303-8925","authenticated-orcid":false,"given":"Mrityunjay K.","family":"Tiwari","sequence":"additional","affiliation":[{"name":"Department of Chemistry, University of Delhi, Delhi-110007, India"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"292","published-online":{"date-parts":[[2026]]},"reference":[{"issue":"8","key":"D6DT01195K\/cit1\/1","doi-asserted-by":"crossref","first-page":"1838","DOI":"10.1021\/acs.accounts.7b00121","volume":"50","author":"Newberry","year":"2017","journal-title":"Acc. Chem. Res."},{"issue":"15","key":"D6DT01195K\/cit2\/1","doi-asserted-by":"crossref","first-page":"9596","DOI":"10.1039\/C4CP05536E","volume":"17","author":"Singh","year":"2015","journal-title":"Phys. Chem. Chem. Phys."},{"issue":"9","key":"D6DT01195K\/cit3\/1","doi-asserted-by":"crossref","first-page":"e202300288","DOI":"10.1002\/cplu.202300288","volume":"88","author":"Wang","year":"2023","journal-title":"ChemPlusChem"},{"issue":"11","key":"D6DT01195K\/cit4\/1","doi-asserted-by":"crossref","first-page":"2497","DOI":"10.1021\/ja0166904","volume":"124","author":"DeRider","year":"2002","journal-title":"J. Am. Chem. Soc."},{"issue":"8","key":"D6DT01195K\/cit5\/1","doi-asserted-by":"crossref","first-page":"615","DOI":"10.1038\/nchembio.406","volume":"6","author":"Bartlett","year":"2010","journal-title":"Nat. Chem. Biol."},{"issue":"7","key":"D6DT01195K\/cit6\/1","doi-asserted-by":"crossref","first-page":"991","DOI":"10.1016\/S0092-8674(05)80004-2","volume":"81","author":"Scott","year":"1995","journal-title":"Cell"},{"issue":"30","key":"D6DT01195K\/cit7\/1","doi-asserted-by":"crossref","first-page":"8998","DOI":"10.1021\/ja0357801","volume":"125","author":"Sarkhel","year":"2003","journal-title":"J. Am. Chem. Soc."},{"issue":"1","key":"D6DT01195K\/cit8\/1","doi-asserted-by":"crossref","first-page":"180","DOI":"10.1073\/pnas.92.1.180","volume":"92","author":"Egli","year":"1995","journal-title":"Proc. Natl. Acad. Sci. U. S. A."},{"key":"D6DT01195K\/cit9\/1","doi-asserted-by":"crossref","DOI":"10.1007\/978-90-481-2582-1","volume-title":"Supramolecular chemistry: from biological inspiration to biomedical applications","author":"Cragg","year":"2010","unstructured":"P. J.Cragg ,  Supramolecular chemistry: from biological inspiration to biomedical applications ,  Springer Science & Business Media ,  2010"},{"issue":"11","key":"D6DT01195K\/cit10\/1","doi-asserted-by":"crossref","first-page":"1501","DOI":"10.1039\/b812026a","volume":"10","author":"Mooibroek","year":"2008","journal-title":"CrystEngComm"},{"issue":"10","key":"D6DT01195K\/cit11\/1","doi-asserted-by":"crossref","first-page":"2707","DOI":"10.1039\/C9SC05698J","volume":"11","author":"Chen","year":"2020","journal-title":"Chem. Sci."},{"issue":"15","key":"D6DT01195K\/cit12\/1","doi-asserted-by":"crossref","first-page":"5065","DOI":"10.1021\/ja00796a058","volume":"95","author":"Burgi","year":"1973","journal-title":"J. Am. Chem. Soc."},{"issue":"6","key":"D6DT01195K\/cit13\/1","first-page":"1517","volume":"30","author":"B\u00fcrgi","year":"1974","journal-title":"Struct. Sci."},{"issue":"12","key":"D6DT01195K\/cit14\/1","doi-asserted-by":"crossref","first-page":"1563","DOI":"10.1016\/S0040-4020(01)90678-7","volume":"30","author":"Dunitz","year":"1974","journal-title":"Tetrahedron"},{"issue":"27","key":"D6DT01195K\/cit15\/1","doi-asserted-by":"crossref","first-page":"7801","DOI":"10.1002\/anie.201511925","volume":"55","author":"Singh","year":"2016","journal-title":"Angew. Chem., Int. Ed."},{"issue":"76","key":"D6DT01195K\/cit16\/1","doi-asserted-by":"crossref","first-page":"10742","DOI":"10.1039\/C8CC06797J","volume":"54","author":"van der Werve","year":"2018","journal-title":"Chem. Commun."},{"issue":"48","key":"D6DT01195K\/cit17\/1","doi-asserted-by":"crossref","first-page":"14327","DOI":"10.1039\/D2SC05431K","volume":"13","author":"Dutta","year":"2022","journal-title":"Chem. Sci."},{"issue":"8","key":"D6DT01195K\/cit18\/1","doi-asserted-by":"crossref","first-page":"1491","DOI":"10.1039\/C4CC09132A","volume":"51","author":"Bauz\u00e1","year":"2015","journal-title":"Chem. Commun."},{"issue":"9","key":"D6DT01195K\/cit19\/1","doi-asserted-by":"crossref","first-page":"5520","DOI":"10.1021\/acs.cgd.6b00989","volume":"16","author":"Bauza","year":"2016","journal-title":"Cryst. Growth Des."},{"issue":"31","key":"D6DT01195K\/cit20\/1","doi-asserted-by":"crossref","first-page":"4485","DOI":"10.1039\/C7CE01266G","volume":"19","author":"Mooibroek","year":"2017","journal-title":"CrystEngComm"},{"issue":"1","key":"D6DT01195K\/cit21\/1","doi-asserted-by":"crossref","first-page":"14522","DOI":"10.1038\/ncomms14522","volume":"8","author":"Bauz\u00e1","year":"2017","journal-title":"Nat. Commun."},{"issue":"24","key":"D6DT01195K\/cit22\/1","doi-asserted-by":"crossref","first-page":"3061","DOI":"10.1039\/C8CC00763B","volume":"54","author":"Echeverr\u00eda","year":"2018","journal-title":"Chem. Commun."},{"issue":"9","key":"D6DT01195K\/cit23\/1","doi-asserted-by":"crossref","first-page":"5429","DOI":"10.1021\/acs.inorgchem.8b00392","volume":"57","author":"Echeverr\u00eda","year":"2018","journal-title":"Inorg. Chem."},{"issue":"36","key":"D6DT01195K\/cit24\/1","doi-asserted-by":"crossref","first-page":"8590","DOI":"10.1002\/chem.201901187","volume":"25","author":"Katkova","year":"2019","journal-title":"Chem. \u2013 Eur. J."},{"issue":"7","key":"D6DT01195K\/cit25\/1","doi-asserted-by":"crossref","first-page":"1154","DOI":"10.1039\/C9CE01741K","volume":"22","author":"Mikherdov","year":"2020","journal-title":"CrystEngComm"},{"issue":"3","key":"D6DT01195K\/cit26\/1","doi-asserted-by":"crossref","first-page":"1636","DOI":"10.1021\/acs.cgd.0c01479","volume":"21","author":"Echeverr\u00eda","year":"2021","journal-title":"Cryst. Growth Des."},{"issue":"44","key":"D6DT01195K\/cit27\/1","doi-asserted-by":"crossref","first-page":"7532","DOI":"10.1039\/D0CE01063D","volume":"22","author":"Kia","year":"2020","journal-title":"CrystEngComm"},{"issue":"3","key":"D6DT01195K\/cit28\/1","doi-asserted-by":"crossref","first-page":"705","DOI":"10.1021\/acs.jpca.4c06738","volume":"129","author":"Purkayastha","year":"2025","journal-title":"J. Phys. Chem. A"},{"issue":"16","key":"D6DT01195K\/cit29\/1","doi-asserted-by":"crossref","first-page":"12573","DOI":"10.1039\/D4CP00908H","volume":"26","author":"Purkayastha","year":"2024","journal-title":"Phys. Chem. Chem. Phys."},{"issue":"9","key":"D6DT01195K\/cit30\/1","doi-asserted-by":"crossref","first-page":"890","DOI":"10.1038\/nchem.2542","volume":"8","author":"Arrowsmith","year":"2016","journal-title":"Nat. Chem."},{"issue":"26","key":"D6DT01195K\/cit31\/1","doi-asserted-by":"crossref","first-page":"10603","DOI":"10.1002\/anie.202002621","volume":"59","author":"Deng","year":"2020","journal-title":"Angew. Chem., Int. Ed."},{"issue":"11","key":"D6DT01195K\/cit32\/1","doi-asserted-by":"crossref","first-page":"2952","DOI":"10.1021\/ic00115a024","volume":"34","author":"Andrews","year":"1995","journal-title":"Inorg. Chem."},{"issue":"31","key":"D6DT01195K\/cit33\/1","doi-asserted-by":"crossref","first-page":"14656","DOI":"10.1021\/acs.inorgchem.4c02186","volume":"63","author":"Wang","year":"2024","journal-title":"Inorg. Chem."},{"issue":"47","key":"D6DT01195K\/cit34\/1","doi-asserted-by":"crossref","first-page":"10917","DOI":"10.1021\/acs.jpca.5c06468","volume":"129","author":"Jia","year":"2025","journal-title":"J. Phys. Chem. A"},{"issue":"21","key":"D6DT01195K\/cit35\/1","doi-asserted-by":"crossref","first-page":"e202400608","DOI":"10.1002\/cphc.202400608","volume":"25","author":"Mart\u00edn-Fern\u00e1ndez","year":"2024","journal-title":"ChemPhysChem"},{"issue":"9","key":"D6DT01195K\/cit36\/1","doi-asserted-by":"crossref","first-page":"1470","DOI":"10.1021\/acs.orglett.3c00205","volume":"25","author":"Yin","year":"2023","journal-title":"Org. Lett."},{"issue":"18","key":"D6DT01195K\/cit37\/1","doi-asserted-by":"crossref","first-page":"5676","DOI":"10.1002\/chem.201103965","volume":"18","author":"Celik","year":"2012","journal-title":"Chem. \u2013 Eur. J."},{"issue":"7556","key":"D6DT01195K\/cit38\/1","doi-asserted-by":"crossref","first-page":"327","DOI":"10.1038\/nature14489","volume":"522","author":"Braunschweig","year":"2015","journal-title":"Nature"},{"issue":"7","key":"D6DT01195K\/cit39\/1","doi-asserted-by":"crossref","first-page":"5648","DOI":"10.1063\/1.464913","volume":"98","author":"Becke","year":"1993","journal-title":"J. Chem. Phys."},{"issue":"7","key":"D6DT01195K\/cit40\/1","doi-asserted-by":"crossref","first-page":"1456","DOI":"10.1002\/jcc.21759","volume":"32","author":"Grimme","year":"2011","journal-title":"J. Comput. Chem."},{"issue":"2","key":"D6DT01195K\/cit41\/1","doi-asserted-by":"crossref","first-page":"1007","DOI":"10.1063\/1.456153","volume":"90","author":"Dunning Jr","year":"1989","journal-title":"J. Chem. Phys."},{"issue":"4","key":"D6DT01195K\/cit44\/1","doi-asserted-by":"crossref","first-page":"553","DOI":"10.1080\/00268977000101561","volume":"19","author":"Boys","year":"1970","journal-title":"Mol. Phys."},{"key":"D6DT01195K\/cit45\/1","first-page":"556","volume-title":"A quantum theory","author":"Bader","year":"1990","unstructured":"R. F.Bader ,  A quantum theory ,  Clarendon ,  Oxford, UK ,  1990 , pp.  556"},{"key":"D6DT01195K\/cit46\/1","volume-title":"Atoms in molecules","volume":"188","author":"Popelier","year":"2000","unstructured":"P. L. A.Popelier ,  F.Aicken  and  S.O'Brien ,  Atoms in molecules ,  Prentice Hall ,  Manchester ,  2000 , vol.  188"},{"issue":"18","key":"D6DT01195K\/cit47\/1","doi-asserted-by":"crossref","first-page":"6498","DOI":"10.1021\/ja100936w","volume":"132","author":"Johnson","year":"2010","journal-title":"J. Am. Chem. Soc."},{"issue":"3","key":"D6DT01195K\/cit48\/1","doi-asserted-by":"crossref","first-page":"625","DOI":"10.1021\/ct100641a","volume":"7","author":"Contreras-Garc\u00eda","year":"2011","journal-title":"J. Chem. Theory Comput."},{"issue":"8","key":"D6DT01195K\/cit49\/1","doi-asserted-by":"crossref","first-page":"082503","DOI":"10.1063\/5.0216272","volume":"161","author":"Lu","year":"2024","journal-title":"J. Chem. Phys."},{"issue":"1","key":"D6DT01195K\/cit50\/1","doi-asserted-by":"crossref","first-page":"33","DOI":"10.1016\/0263-7855(96)00018-5","volume":"14","author":"Humphrey","year":"1996","journal-title":"J. Mol. Graphics"},{"issue":"21","key":"D6DT01195K\/cit52\/1","doi-asserted-by":"crossref","first-page":"7843","DOI":"10.1021\/ja4033583","volume":"135","author":"Newberry","year":"2013","journal-title":"J. Am. Chem. Soc."},{"issue":"48","key":"D6DT01195K\/cit53\/1","doi-asserted-by":"crossref","first-page":"25958","DOI":"10.1039\/D5CP03535J","volume":"27","author":"Deo","year":"2025","journal-title":"Phys. Chem. Chem. Phys."},{"issue":"24","key":"D6DT01195K\/cit54\/1","doi-asserted-by":"crossref","first-page":"8617","DOI":"10.1039\/c3dt50599e","volume":"42","author":"Alvarez","year":"2013","journal-title":"Dalton Trans."},{"issue":"19","key":"D6DT01195K\/cit55\/1","doi-asserted-by":"crossref","first-page":"6651","DOI":"10.1021\/ja100931y","volume":"132","author":"Jakobsche","year":"2010","journal-title":"J. Am. Chem. Soc."},{"issue":"8","key":"D6DT01195K\/cit56\/1","doi-asserted-by":"crossref","first-page":"627","DOI":"10.1002\/anie.198406271","volume":"23","author":"Cremer","year":"1984","journal-title":"Angew. Chem., Int. Ed. Engl."}],"container-title":["Dalton Transactions"],"original-title":[],"language":"en","link":[{"URL":"http:\/\/pubs.rsc.org\/DT\/article-pdf\/doi\/10.1039\/D6DT01195K\/0\/D6DT01195K.pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,7,9]],"date-time":"2026-07-09T20:54:47Z","timestamp":1783630487000},"score":1,"resource":{"primary":{"URL":"http:\/\/pubs.rsc.org\/DT\/article-lookup\/doi\/10.1039\/D6DT01195K"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026]]},"references-count":53,"journal-issue":{"issue":"26","published-print":{"date-parts":[[2026,7,9]]}},"URL":"https:\/\/doi.org\/10.1039\/d6dt01195k","relation":{},"ISSN":["1477-9226","1477-9234"],"issn-type":[{"value":"1477-9226","type":"print"},{"value":"1477-9234","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026]]}}}