{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,16]],"date-time":"2026-10-16T11:54:05Z","timestamp":1792151645363,"version":"4.4.0"},"reference-count":46,"publisher":"Royal Society of Chemistry (RSC)","license":[{"start":{"date-parts":[[2026,10,13]],"date-time":"2026-10-13T00:00:00Z","timestamp":1791849600000},"content-version":"vor","delay-in-days":285,"URL":"http:\/\/creativecommons.org\/licenses\/by\/3.0\/"}],"funder":[{"DOI":"10.13039\/100000001","name":"National Science Foundation","doi-asserted-by":"publisher","award":["CHE-2102639"],"award-info":[{"award-number":["CHE-2102639"]}],"id":[{"id":"10.13039\/100000001","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100000001","name":"National Science Foundation","doi-asserted-by":"publisher","award":["CHE-2204206"],"award-info":[{"award-number":["CHE-2204206"]}],"id":[{"id":"10.13039\/100000001","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100000015","name":"U.S. Department of Energy","doi-asserted-by":"publisher","award":["DE-SC0018239"],"award-info":[{"award-number":["DE-SC0018239"]}],"id":[{"id":"10.13039\/100000015","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100000002","name":"National Institutes of Health","doi-asserted-by":"publisher","award":["P30-CA023168"],"award-info":[{"award-number":["P30-CA023168"]}],"id":[{"id":"10.13039\/100000002","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["rsc.org"],"crossmark-restriction":true},"short-container-title":["Dalton Trans."],"abstract":"<jats:p>\n                    The inductive effect of C\n                    <jats:sub>2<\/jats:sub>\n                    F\n                    <jats:sub>5<\/jats:sub>\n                    on the photoluminescence of copper\u2013pyrazolate tetramers results in dual emission at 450 and 520 nm. Blue emission is produced from high-lying excited states with hybrid\n                    <jats:sup>3<\/jats:sup>\n                    CC and\n                    <jats:sup>3<\/jats:sup>\n                    MLCT character.\n                  <\/jats:p>","DOI":"10.1039\/d6dt01868h","type":"journal-article","created":{"date-parts":[[2026,10,13]],"date-time":"2026-10-13T13:46:41Z","timestamp":1791899201000},"update-policy":"https:\/\/doi.org\/10.1039\/rsc_crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Electronic tuning of tetranuclear Cu(\n                    <scp>i<\/scp>\n                    )\u2013pyrazolate macrocycles: anti-Kasha emission through high-lying triplet states of a C\n                    <sub>2<\/sub>\n                    F\n                    <sub>5<\/sub>\n                    -substituted complex"],"prefix":"10.1039","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-6341-3641","authenticated-orcid":false,"given":"Shinaj K.","family":"Rajagopal","sequence":"first","affiliation":[{"name":"James and Margaret Tarpo Department of Chemistry, Purdue University, 560 Oval Drive, West Lafayette, IN, 47907, USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0006-6428-6871","authenticated-orcid":false,"given":"Christian M.","family":"Peterson","sequence":"additional","affiliation":[{"name":"James and Margaret Tarpo Department of Chemistry, Purdue University, 560 Oval Drive, West Lafayette, IN, 47907, USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Matthias","family":"Zeller","sequence":"additional","affiliation":[{"name":"James and Margaret Tarpo Department of Chemistry, Purdue University, 560 Oval Drive, West Lafayette, IN, 47907, USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Sergei","family":"Savikhin","sequence":"additional","affiliation":[{"name":"Department of Physics and Astronomy, Purdue University, 525 Northwestern Ave, West Lafayette, IN, 47907, USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Lyudmila V.","family":"Slipchenko","sequence":"additional","affiliation":[{"name":"James and Margaret Tarpo Department of Chemistry, Purdue University, 560 Oval Drive, West Lafayette, IN, 47907, USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-8587-1037","authenticated-orcid":false,"given":"Alexander","family":"Wei","sequence":"additional","affiliation":[{"name":"James and Margaret Tarpo Department of Chemistry, Purdue University, 560 Oval Drive, West Lafayette, IN, 47907, USA"},{"name":"Department of Materials Engineering, Purdue University, Neil Armstrong Hall of Engineering, 701 W Stadium Ave, West Lafayette, IN, 47907, USA"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"292","published-online":{"date-parts":[[2026]]},"reference":[{"key":"D6DT01868H\/cit1\/1","doi-asserted-by":"crossref","first-page":"9400","DOI":"10.1021\/jacs.5b04840","volume":"137","author":"Liu","year":"2015","journal-title":"J. Am. Chem. Soc."},{"key":"D6DT01868H\/cit2\/1","doi-asserted-by":"crossref","first-page":"18982","DOI":"10.1021\/acs.energyfuels.1c01956","volume":"35","author":"Au","year":"2021","journal-title":"Energy Fuels"},{"key":"D6DT01868H\/cit3\/1","doi-asserted-by":"crossref","first-page":"49","DOI":"10.1016\/j.ccr.2017.09.011","volume":"373","author":"Bizzarri","year":"2018","journal-title":"Coord. Chem. Rev."},{"key":"D6DT01868H\/cit4\/1","doi-asserted-by":"crossref","first-page":"e202400817","DOI":"10.1002\/chem.202400817","volume":"30","author":"Li","year":"2024","journal-title":"Chem. \u2013 Eur. J."},{"key":"D6DT01868H\/cit5\/1","doi-asserted-by":"crossref","first-page":"601","DOI":"10.1126\/science.aav2865","volume":"363","author":"Hamze","year":"2019","journal-title":"Science"},{"key":"D6DT01868H\/cit6\/1","doi-asserted-by":"crossref","first-page":"eaav9857","DOI":"10.1126\/sciadv.aav9857","volume":"5","author":"Xie","year":"2019","journal-title":"Sci. Adv."},{"key":"D6DT01868H\/cit7\/1","doi-asserted-by":"crossref","first-page":"10186","DOI":"10.1021\/jacs.1c13462","volume":"144","author":"Watanabe","year":"2022","journal-title":"J. Am. Chem. Soc."},{"key":"D6DT01868H\/cit8\/1","doi-asserted-by":"crossref","first-page":"11307","DOI":"10.1039\/D4CC04259J","volume":"60","author":"Rajagopal","year":"2024","journal-title":"Chem. Commun."},{"key":"D6DT01868H\/cit9\/1","author":"Washer","year":"2026","unstructured":"B. M.Washer ,  Y.Watanabe ,  S.Haghiri ,  K.Koshiba ,  M.Zeller ,  D. Y.Zemlyanov ,  L. V.Slipchenko  and  A.Wei ,  2026 , in revision"},{"key":"D6DT01868H\/cit10\/1","doi-asserted-by":"crossref","first-page":"9675","DOI":"10.1021\/acs.chemrev.0c00011","volume":"120","author":"Zheng","year":"2020","journal-title":"Chem. Rev."},{"key":"D6DT01868H\/cit11a\/1","doi-asserted-by":"crossref","first-page":"4425","DOI":"10.1039\/D0SC07058K","volume":"12","author":"Xie","year":"2021","journal-title":"Chem. Sci."},{"key":"D6DT01868H\/cit11b\/1","doi-asserted-by":"crossref","first-page":"1921","DOI":"10.1021\/acsmaterialslett.2c00661","volume":"4","author":"Yang","year":"2022","journal-title":"ACS Mater. Lett."},{"key":"D6DT01868H\/cit12\/1","doi-asserted-by":"crossref","first-page":"22","DOI":"10.1016\/j.ica.2017.07.015","volume":"470","author":"Titov","year":"2018","journal-title":"Inorg. Chim. Acta"},{"key":"D6DT01868H\/cit13\/1","doi-asserted-by":"crossref","first-page":"2977","DOI":"10.1016\/j.ica.2010.05.014","volume":"363","author":"Fujisawa","year":"2010","journal-title":"Inorg. Chim. Acta"},{"key":"D6DT01868H\/cit14\/1","doi-asserted-by":"crossref","first-page":"14979","DOI":"10.1039\/C9DT03402A","volume":"48","author":"Dias","year":"2019","journal-title":"Dalton Trans."},{"key":"D6DT01868H\/cit15\/1","doi-asserted-by":"crossref","first-page":"9300","DOI":"10.1021\/acs.inorgchem.3c01667","volume":"62","author":"Smith","year":"2023","journal-title":"Inorg. Chem."},{"key":"D6DT01868H\/cit16a\/1","doi-asserted-by":"crossref","first-page":"12072","DOI":"10.1021\/ja036736o","volume":"125","author":"Dias","year":"2003","journal-title":"J. Am. Chem. Soc."},{"key":"D6DT01868H\/cit16b\/1","doi-asserted-by":"crossref","first-page":"16356","DOI":"10.1039\/D3DT03167E","volume":"52","author":"Vanga","year":"2023","journal-title":"Dalton Trans."},{"key":"D6DT01868H\/cit17\/1","doi-asserted-by":"crossref","first-page":"20755","DOI":"10.1039\/D5SC04685H","volume":"16","author":"Forni","year":"2025","journal-title":"Chem. Sci."},{"key":"D6DT01868H\/cit18\/1","doi-asserted-by":"crossref","first-page":"20463","DOI":"10.1021\/acsami.1c09189","volume":"14","author":"Monkman","year":"2022","journal-title":"ACS Appl. Mater. Interfaces"},{"key":"D6DT01868H\/cit19\/1","doi-asserted-by":"crossref","first-page":"2521","DOI":"10.3390\/nano13182521","volume":"13","author":"Siddiqui","year":"2023","journal-title":"Nanomaterials"},{"key":"D6DT01868H\/cit20\/1","doi-asserted-by":"crossref","first-page":"4105","DOI":"10.1021\/acs.organomet.8b00657","volume":"37","author":"Parasar","year":"2018","journal-title":"Organometallics"},{"key":"D6DT01868H\/cit21\/1","doi-asserted-by":"crossref","first-page":"2067","DOI":"10.1021\/acs.jpclett.9b03382","volume":"11","author":"Xing","year":"2020","journal-title":"J. Phys. Chem. Lett."},{"key":"D6DT01868H\/cit22\/1","doi-asserted-by":"crossref","first-page":"22624","DOI":"10.1002\/anie.202009789","volume":"60","author":"Behera","year":"2021","journal-title":"Angew. Chem., Int. Ed."},{"key":"D6DT01868H\/cit23\/1","doi-asserted-by":"crossref","first-page":"1987","DOI":"10.1038\/s41467-023-37662-y","volume":"14","author":"Li","year":"2023","journal-title":"Nat. Commun."},{"key":"D6DT01868H\/cit24\/1","doi-asserted-by":"crossref","first-page":"7829","DOI":"10.1039\/D5SC01471A","volume":"16","author":"Zhang","year":"2025","journal-title":"Chem. Sci."},{"key":"D6DT01868H\/cit25\/1","doi-asserted-by":"crossref","first-page":"15087","DOI":"10.1021\/acs.joc.9b02001","volume":"84","author":"Mestre","year":"2019","journal-title":"J. Org. Chem."},{"key":"D6DT01868H\/cit26\/1","doi-asserted-by":"crossref","first-page":"4933","DOI":"10.1021\/cr078200h","volume":"107","author":"Mezei","year":"2007","journal-title":"Chem. Rev."},{"key":"D6DT01868H\/cit27\/1","doi-asserted-by":"crossref","first-page":"441","DOI":"10.1021\/j100785a001","volume":"68","author":"Bondi","year":"1964","journal-title":"J. Phys. Chem."},{"key":"D6DT01868H\/cit28\/1","doi-asserted-by":"crossref","first-page":"12431","DOI":"10.1039\/D6DT01901C","volume":"55","author":"Koshiba","year":"2026","journal-title":"Dalton Trans."},{"key":"D6DT01868H\/cit29a\/1","doi-asserted-by":"crossref","first-page":"3625","DOI":"10.1021\/cr960109i","volume":"99","author":"Ford","year":"1999","journal-title":"Chem. Rev."},{"key":"D6DT01868H\/cit29b\/1","doi-asserted-by":"crossref","first-page":"566","DOI":"10.1016\/j.ccr.2015.03.004","volume":"306","author":"Cariati","year":"2016","journal-title":"Coord. Chem. Rev."},{"key":"D6DT01868H\/cit30\/1","doi-asserted-by":"crossref","first-page":"12057","DOI":"10.1039\/D0CC04788K","volume":"56","author":"Wu","year":"2020","journal-title":"Chem. Commun."},{"key":"D6DT01868H\/cit31\/1","doi-asserted-by":"crossref","first-page":"6415","DOI":"10.1021\/jacs.4c09907","volume":"147","author":"Huang","year":"2025","journal-title":"J. Am. Chem. Soc."},{"key":"D6DT01868H\/cit32a\/1","doi-asserted-by":"crossref","first-page":"6999","DOI":"10.3390\/molecules26226999","volume":"26","author":"Malpicci","year":"2021","journal-title":"Molecules"},{"key":"D6DT01868H\/cit32b\/1","doi-asserted-by":"crossref","first-page":"33","DOI":"10.1039\/D0MH01316A","volume":"8","author":"Kukhta","year":"2021","journal-title":"Mater. Horiz."},{"key":"D6DT01868H\/cit33\/1","doi-asserted-by":"crossref","first-page":"4332","DOI":"10.1021\/acs.chemrev.3c00761","volume":"124","author":"Li","year":"2024","journal-title":"Chem. Rev."},{"key":"D6DT01868H\/cit34\/1","doi-asserted-by":"crossref","first-page":"2622","DOI":"10.1016\/j.ccr.2011.01.042","volume":"255","author":"Yersin","year":"2011","journal-title":"Coord. Chem. Rev."},{"key":"D6DT01868H\/cit35\/1","doi-asserted-by":"crossref","first-page":"27083","DOI":"10.1039\/D3CP03234E","volume":"25","author":"Mansour","year":"2023","journal-title":"Phys. Chem. Chem. Phys."},{"key":"D6DT01868H\/cit36\/1","doi-asserted-by":"crossref","first-page":"6121","DOI":"10.1039\/C7CP08703A","volume":"20","author":"Valiev","year":"2018","journal-title":"Phys. Chem. Chem. Phys."},{"key":"D6DT01868H\/cit37a\/1","doi-asserted-by":"crossref","first-page":"3964","DOI":"10.1039\/D2DT03725D","volume":"52","author":"Lu","year":"2023","journal-title":"Dalton Trans."},{"key":"D6DT01868H\/cit37b\/1","doi-asserted-by":"crossref","first-page":"16610","DOI":"10.1021\/acs.inorgchem.4c00751","volume":"63","author":"Baranova","year":"2024","journal-title":"Inorg. Chem."},{"key":"D6DT01868H\/cit38a\/1","doi-asserted-by":"crossref","first-page":"2781","DOI":"10.1021\/acs.inorgchem.9b03146","volume":"59","author":"Livshits","year":"2020","journal-title":"Inorg. Chem."},{"key":"D6DT01868H\/cit38b\/1","doi-asserted-by":"crossref","first-page":"3248","DOI":"10.1021\/acs.inorgchem.2c04315","volume":"62","author":"Rosko","year":"2023","journal-title":"Inorg. Chem."},{"key":"D6DT01868H\/cit39\/1","doi-asserted-by":"crossref","first-page":"1441","DOI":"10.1002\/chem.201704868","volume":"24","author":"San","year":"2018","journal-title":"Chem. \u2013 Eur. J."},{"key":"D6DT01868H\/cit40\/1","doi-asserted-by":"publisher","year":"2026","unstructured":"CCDC 2574785: Experimental Crystal Structure Determination ,  2026 ,  10.5517\/ccdc.csd.cc2sf8l3","DOI":"10.5517\/ccdc.csd.cc2sf8l3"}],"container-title":["Dalton Transactions"],"original-title":[],"language":"en","link":[{"URL":"http:\/\/pubs.rsc.org\/DT\/article-pdf\/doi\/10.1039\/D6DT01868H\/0\/D6DT01868H.pdf","content-type":"application\/pdf","content-version":"vor","intended-application":"syndication"},{"URL":"http:\/\/pubs.rsc.org\/DT\/article-pdf\/doi\/10.1039\/D6DT01868H\/0\/D6DT01868H.pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,10,16]],"date-time":"2026-10-16T11:20:44Z","timestamp":1792149644000},"score":1,"resource":{"primary":{"URL":"http:\/\/pubs.rsc.org\/DT\/article-lookup\/doi\/10.1039\/D6DT01868H"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026]]},"references-count":46,"URL":"https:\/\/doi.org\/10.1039\/d6dt01868h","relation":{"has-review":[{"id-type":"doi","id":"10.1039\/D6DT01868H\/v2\/review2","asserted-by":"object"},{"id-type":"doi","id":"10.1039\/D6DT01868H\/v1\/review2","asserted-by":"object"},{"id-type":"doi","id":"10.1039\/D6DT01868H\/v2\/decision1","asserted-by":"object"},{"id-type":"doi","id":"10.1039\/D6DT01868H\/v1\/review1","asserted-by":"object"},{"id-type":"doi","id":"10.1039\/D6DT01868H\/v2\/review1","asserted-by":"object"},{"id-type":"doi","id":"10.1039\/D6DT01868H\/v2\/response1","asserted-by":"object"},{"id-type":"doi","id":"10.1039\/D6DT01868H\/v1\/decision1","asserted-by":"object"}]},"ISSN":["1477-9226","1477-9234"],"issn-type":[{"value":"1477-9226","type":"print"},{"value":"1477-9234","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026]]}}}