{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,5]],"date-time":"2026-10-05T11:02:38Z","timestamp":1791198158441,"version":"4.1.0"},"reference-count":37,"publisher":"Royal Society of Chemistry (RSC)","license":[{"start":{"date-parts":[[2027,9,28]],"date-time":"2027-09-28T00:00:00Z","timestamp":1822089600000},"content-version":"am","delay-in-days":635,"URL":"http:\/\/rsc.li\/journals-terms-of-use"}],"funder":[{"DOI":"10.13039\/501100020964","name":"Fusion Oriented REsearch for disruptive Science and Technology","doi-asserted-by":"publisher","award":["JPMJFR221K"],"award-info":[{"award-number":["JPMJFR221K"]}],"id":[{"id":"10.13039\/501100020964","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["rsc.org"],"crossmark-restriction":true},"short-container-title":["Dalton Trans."],"abstract":"<jats:p>\n                    We report a pentacoordinated As(v) dication, [Ph(ppy)\n                    <jats:sub>2<\/jats:sub>\n                    As]\n                    <jats:sup>2+<\/jats:sup>\n                    , balancing stability and reactivity. Oxidation strengthens As\u2013N chelation, forming a trigonal-bipyramidal geometry with Lewis acidity and base-triggered reactivity.\n                  <\/jats:p>","DOI":"10.1039\/d6dt01928e","type":"journal-article","created":{"date-parts":[[2026,9,28]],"date-time":"2026-09-28T06:23:01Z","timestamp":1790576581000},"update-policy":"https:\/\/doi.org\/10.1039\/rsc_crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["A pentacoordinated arsenic(\n                    <scp>v<\/scp>\n                    ) dication stabilized by intramolecular donor coordination"],"prefix":"10.1039","author":[{"given":"Taiki","family":"Adachi","sequence":"first","affiliation":[{"name":"Faculty of Molecular Chemistry and Engineering, Kyoto Institute of Technology, Goshokaido-cho, Matsugasaki, Sakyo-ku, Kyoto 606-0962, Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Tomoki","family":"Yasui","sequence":"additional","affiliation":[{"name":"Faculty of Molecular 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Biomolecular Engineering, Graduate School of Engineering, Tohoku University, 2-1-1 Katahira, Aoba-ku, Sendai-shi, Miyagi-ken 980-8577, Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-9399-0506","authenticated-orcid":false,"given":"Hitoshi","family":"Kasai","sequence":"additional","affiliation":[{"name":"Institute of Multidisciplinary Research for Advanced Materials, Tohoku University, 2-1-1 Katahira, Aoba-ku, Sendai-shi, Miyagi-ken 980-8577, Japan"},{"name":"Department of Biomolecular Engineering, Graduate School of Engineering, Tohoku University, 2-1-1 Katahira, Aoba-ku, Sendai-shi, Miyagi-ken 980-8577, Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-6806-2767","authenticated-orcid":false,"given":"Kouki","family":"Oka","sequence":"additional","affiliation":[{"name":"Institute of Multidisciplinary Research for Advanced Materials, Tohoku University, 2-1-1 Katahira, Aoba-ku, Sendai-shi, Miyagi-ken 980-8577, Japan"},{"name":"Department of Biomolecular Engineering, Graduate School of Engineering, Tohoku University, 2-1-1 Katahira, Aoba-ku, Sendai-shi, Miyagi-ken 980-8577, Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-2349-0714","authenticated-orcid":false,"given":"Takahiro","family":"Iwamoto","sequence":"additional","affiliation":[{"name":"Faculty of Molecular Chemistry and Engineering, Kyoto Institute of Technology, Goshokaido-cho, Matsugasaki, Sakyo-ku, Kyoto 606-0962, Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-4516-6296","authenticated-orcid":false,"given":"Kensuke","family":"Naka","sequence":"additional","affiliation":[{"name":"Faculty of Molecular Chemistry and Engineering, Kyoto Institute of Technology, Goshokaido-cho, Matsugasaki, Sakyo-ku, Kyoto 606-0962, Japan"},{"name":"Materials Innovation Lab, Kyoto Institute of Technology, 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