{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,6,30]],"date-time":"2026-06-30T21:52:47Z","timestamp":1782856367256,"version":"3.54.5"},"reference-count":38,"publisher":"Royal Society of Chemistry (RSC)","issue":"17","license":[{"start":{"date-parts":[[2026,3,25]],"date-time":"2026-03-25T00:00:00Z","timestamp":1774396800000},"content-version":"vor","delay-in-days":83,"URL":"http:\/\/creativecommons.org\/licenses\/by\/3.0\/"}],"funder":[{"DOI":"10.13039\/501100003407","name":"Ministero dell\u2019Istruzione, dell\u2019Universit\u00e0 e della Ricerca","doi-asserted-by":"publisher","award":["ECS00000041"],"award-info":[{"award-number":["ECS00000041"]}],"id":[{"id":"10.13039\/501100003407","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100004462","name":"Consiglio Nazionale delle Ricerche","doi-asserted-by":"publisher","award":["DFM.AD006.072"],"award-info":[{"award-number":["DFM.AD006.072"]}],"id":[{"id":"10.13039\/501100004462","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["rsc.org"],"crossmark-restriction":true},"short-container-title":["Nanoscale"],"abstract":"<jats:p>\n                    Mixed CoP and Co\n                    <jats:sub>2<\/jats:sub>\n                    P nanoclusters were grown on black phosphorus nanosheets. The corresponding noble-metal-free photocatalysts, TiO\n                    <jats:sub>2<\/jats:sub>\n                    \/BP@Co\n                    <jats:sub>\n                      <jats:italic>x<\/jats:italic>\n                    <\/jats:sub>\n                    P, gave 30-fold higher reaction rates in solar-driven H\n                    <jats:sub>2<\/jats:sub>\n                    evolution with respect to TiO\n                    <jats:sub>2<\/jats:sub>\n                    .\n                  <\/jats:p>","DOI":"10.1039\/d6nr00321d","type":"journal-article","created":{"date-parts":[[2026,3,25]],"date-time":"2026-03-25T09:00:57Z","timestamp":1774429257000},"page":"9167-9176","update-policy":"https:\/\/doi.org\/10.1039\/rsc_crossmark_policy","source":"Crossref","is-referenced-by-count":1,"title":["2D black phosphorus as a phosphide source for the formation of mixed cobalt phosphide clusters active in photocatalytic hydrogen evolution"],"prefix":"10.1039","volume":"18","author":[{"given":"Giacomo","family":"Provinciali","sequence":"first","affiliation":[{"name":"Institute of Chemistry of OrganoMetallic Compounds, National Council for Research, CNR-ICCOM, Via Madonna del Piano 10, I-50019 Sesto Fiorentino, Italy"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-6372-3586","authenticated-orcid":false,"given":"Manuel","family":"Serrano-Ruiz","sequence":"additional","affiliation":[{"name":"Institute of Chemistry of OrganoMetallic Compounds, National Council for Research, CNR-ICCOM, Via Madonna del Piano 10, I-50019 Sesto Fiorentino, Italy"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jonathan","family":"Filippi","sequence":"additional","affiliation":[{"name":"Institute of Chemistry of OrganoMetallic Compounds, National Council for Research, CNR-ICCOM, Via Madonna del Piano 10, I-50019 Sesto Fiorentino, Italy"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Beatrice","family":"Muzzi","sequence":"additional","affiliation":[{"name":"Institute of Chemistry of OrganoMetallic Compounds, National Council for Research, CNR-ICCOM, Via Madonna del Piano 10, I-50019 Sesto Fiorentino, Italy"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5348-0552","authenticated-orcid":false,"given":"Martina","family":"Banchelli","sequence":"additional","affiliation":[{"name":"Institute of Applied Physics \u201cNello Carrara\u201d, National Council for Research, CNR-IFAC, Via Madonna del Piano 10, I-50019 Sesto Fiorentino, Italy"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0001-3439-3629","authenticated-orcid":false,"given":"Carlo","family":"Calcatelli","sequence":"additional","affiliation":[{"name":"Department of Physics and Geology, University of Perugia, Via A. Pascoli, 06123 Perugia, Italy"},{"name":"CNR-IOM, Perugia Unit, c\/o Department of Physics and Geology, University of Perugia, Via A. Pascoli, 06123 Perugia, Italy"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-8880-2080","authenticated-orcid":false,"given":"Alberto","family":"Verdini","sequence":"additional","affiliation":[{"name":"CNR-IOM, Perugia Unit, c\/o Department of Physics and Geology, University of Perugia, Via A. Pascoli, 06123 Perugia, Italy"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Stefano","family":"Caporali","sequence":"additional","affiliation":[{"name":"Department of Industrial Engineering, University of Florence, Via di S. Marta 3, 50139 Firenze, Italy"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2207-6113","authenticated-orcid":false,"given":"Francesco","family":"D'Acapito","sequence":"additional","affiliation":[{"name":"CNR IOM-OGG, c\/o European Synchrotron Radiation Facility, 71 Avenue des Martyrs, CS 40220, 38043 Grenoble, Cedex 9, France"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Maurizio","family":"Peruzzini","sequence":"additional","affiliation":[{"name":"Institute of Chemistry of OrganoMetallic Compounds, National Council for Research, CNR-ICCOM, Via Madonna del Piano 10, I-50019 Sesto Fiorentino, Italy"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-6994-7313","authenticated-orcid":false,"given":"Maria","family":"Caporali","sequence":"additional","affiliation":[{"name":"Institute of Chemistry of OrganoMetallic Compounds, National Council for Research, CNR-ICCOM, Via Madonna del Piano 10, I-50019 Sesto Fiorentino, Italy"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"292","published-online":{"date-parts":[[2026]]},"reference":[{"key":"D6NR00321D\/cit1\/1","doi-asserted-by":"crossref","first-page":"2746","DOI":"10.1021\/jacsau.4c00527","volume":"4","author":"Beil","year":"2024","journal-title":"JACS Au"},{"key":"D6NR00321D\/cit2\/1","doi-asserted-by":"crossref","first-page":"e202416992","DOI":"10.1002\/anie.202416992","volume":"64","author":"Leng","year":"2025","journal-title":"Angew. Chem., Int. Ed."},{"key":"D6NR00321D\/cit3\/1","doi-asserted-by":"crossref","first-page":"263","DOI":"10.1016\/j.ijhydene.2023.12.084","volume":"53","author":"Zhao","year":"2024","journal-title":"Int. J. Hydrogen Energy"},{"key":"D6NR00321D\/cit4\/1","doi-asserted-by":"crossref","first-page":"2102155","DOI":"10.1002\/smll.202102155","volume":"17","author":"Zhao","year":"2021","journal-title":"Small"},{"key":"D6NR00321D\/cit5\/1","doi-asserted-by":"crossref","first-page":"116910","DOI":"10.1016\/j.envres.2023.116910","volume":"237","author":"Moradian","year":"2023","journal-title":"Environ. Res."},{"key":"D6NR00321D\/cit6\/1","doi-asserted-by":"crossref","first-page":"1472","DOI":"10.1021\/accountsmr.4c00144","volume":"5","author":"Tian","year":"2024","journal-title":"Acc. Mater. Res."},{"key":"D6NR00321D\/cit7\/1","doi-asserted-by":"crossref","first-page":"2005197","DOI":"10.1002\/adfm.202005197","volume":"31","author":"Gao","year":"2021","journal-title":"Adv. Funct. Mater."},{"key":"D6NR00321D\/cit8\/1","doi-asserted-by":"crossref","first-page":"7368","DOI":"10.1039\/C9TA13441G","volume":"8","author":"Ozawa","year":"2020","journal-title":"J. Mater. Chem. A"},{"key":"D6NR00321D\/cit9\/1","doi-asserted-by":"crossref","first-page":"3870","DOI":"10.1002\/cctc.202000546","volume":"12","author":"Ren","year":"2020","journal-title":"ChemCatChem"},{"key":"D6NR00321D\/cit10\/1","doi-asserted-by":"crossref","first-page":"5427","DOI":"10.1002\/anie.201402646","volume":"53","author":"Popczun","year":"2014","journal-title":"Angew. Chem., Int. Ed."},{"key":"D6NR00321D\/cit11\/1","doi-asserted-by":"crossref","first-page":"11717","DOI":"10.1021\/acssuschemeng.4c03443","volume":"12","author":"Wang","year":"2024","journal-title":"ACS Sustainable Chem. Eng."},{"key":"D6NR00321D\/cit12\/1","doi-asserted-by":"crossref","first-page":"2179","DOI":"10.1002\/cctc.201701907","volume":"10","author":"Liang","year":"2018","journal-title":"ChemCatChem"},{"key":"D6NR00321D\/cit13\/1","doi-asserted-by":"crossref","first-page":"7801","DOI":"10.1021\/acscatal.9b02274","volume":"9","author":"Yuan","year":"2019","journal-title":"ACS Catal."},{"key":"D6NR00321D\/cit14\/1","doi-asserted-by":"crossref","first-page":"e202300647","DOI":"10.1002\/cctc.202300647","volume":"15","author":"Provinciali","year":"2023","journal-title":"ChemCatChem"},{"key":"D6NR00321D\/cit15\/1","doi-asserted-by":"crossref","first-page":"6","DOI":"10.1016\/j.jcrysgro.2014.07.029","volume":"405","author":"K\u00f6pf","year":"2014","journal-title":"J. Cryst. Growth"},{"key":"D6NR00321D\/cit16\/1","doi-asserted-by":"crossref","first-page":"1500441","DOI":"10.1002\/admi.201500441","volume":"3","author":"Serrano-Ruiz","year":"2016","journal-title":"Adv. Mater. Interfaces"},{"key":"D6NR00321D\/cit17\/1","doi-asserted-by":"crossref","first-page":"641","DOI":"10.1016\/j.jcis.2022.01.185","volume":"616","author":"Xu","year":"2022","journal-title":"J. Colloid Interface Sci."},{"key":"D6NR00321D\/cit18\/1","doi-asserted-by":"crossref","first-page":"551","DOI":"10.1107\/S160057751801843X","volume":"26","author":"d'Acapito","year":"2019","journal-title":"J. Synchrotron Radiat."},{"key":"D6NR00321D\/cit19\/1","doi-asserted-by":"crossref","first-page":"537","DOI":"10.1107\/S0909049505012719","volume":"12","author":"Ravel","year":"2005","journal-title":"J. Synchrotron Radiat."},{"key":"D6NR00321D\/cit20\/1","doi-asserted-by":"crossref","first-page":"7565","DOI":"10.1103\/PhysRevB.58.7565","volume":"58","author":"Ankudinov","year":"1998","journal-title":"Phys. Rev. B: Condens. Matter Mater. Phys."},{"key":"D6NR00321D\/cit21\/1","doi-asserted-by":"crossref","first-page":"731","DOI":"10.3891\/acta.chem.scand.32a-0731","volume":"32","author":"Selte","year":"1978","journal-title":"Acta Chem. Scand., Ser. A"},{"key":"D6NR00321D\/cit22\/1","doi-asserted-by":"crossref","first-page":"31","DOI":"10.1002\/zaac.19472540102","volume":"254","author":"Nowotny","year":"1947","journal-title":"Z. Anorg. Allg. Chem."},{"key":"D6NR00321D\/cit23\/1","doi-asserted-by":"crossref","first-page":"L161407","DOI":"10.1103\/PhysRevB.111.L161407","volume":"111","author":"Kim","year":"2025","journal-title":"Phys. Rev. B"},{"key":"D6NR00321D\/cit24\/1","doi-asserted-by":"crossref","first-page":"8563","DOI":"10.1038\/ncomms9563","volume":"6","author":"Hanlon","year":"2015","journal-title":"Nat. Commun."},{"key":"D6NR00321D\/cit25\/1","doi-asserted-by":"crossref","first-page":"111254","DOI":"10.1016\/j.optmat.2021.111254","volume":"118","author":"Bhandarkar","year":"2021","journal-title":"Opt. Mater."},{"key":"D6NR00321D\/cit26\/1","doi-asserted-by":"crossref","first-page":"2600","DOI":"10.1002\/anie.201710859","volume":"57","author":"Wang","year":"2018","journal-title":"Angew. Chem., Int. Ed."},{"key":"D6NR00321D\/cit27\/1","doi-asserted-by":"crossref","first-page":"6889","DOI":"10.1038\/s41467-023-42301-7","volume":"14","author":"Chen","year":"2023","journal-title":"Nat. Commun."},{"key":"D6NR00321D\/cit28\/1","doi-asserted-by":"crossref","first-page":"21","DOI":"10.1016\/j.jelechem.2015.11.003","volume":"761","author":"Jena","year":"2016","journal-title":"J. Electroanal. Chem."},{"key":"D6NR00321D\/cit29\/1","doi-asserted-by":"crossref","first-page":"275708","DOI":"10.1088\/1361-6528\/ab851e","volume":"31","author":"Caporali","year":"2020","journal-title":"Nanotechnology"},{"key":"D6NR00321D\/cit30\/1","doi-asserted-by":"crossref","first-page":"10088","DOI":"10.1021\/jacs.1c01754","volume":"143","author":"Vanni","year":"2021","journal-title":"J. Am. Chem. Soc."},{"key":"D6NR00321D\/cit31\/1","doi-asserted-by":"crossref","first-page":"2832","DOI":"10.1039\/b801115j","author":"Cordero","year":"2008","journal-title":"Dalton Trans."},{"key":"D6NR00321D\/cit32\/1","doi-asserted-by":"crossref","first-page":"362","DOI":"10.1107\/S0567740873002505","volume":"29","author":"Smith","year":"1973","journal-title":"Acta Crystallogr., Sect. B"},{"key":"D6NR00321D\/cit33\/1","doi-asserted-by":"crossref","first-page":"1800575","DOI":"10.1002\/advs.201800575","volume":"5","author":"Shi","year":"2018","journal-title":"Adv. Sci."},{"key":"D6NR00321D\/cit34\/1","doi-asserted-by":"crossref","first-page":"17459","DOI":"10.1021\/acsami.9b04078","volume":"11","author":"Shi","year":"2019","journal-title":"ACS Appl. Mater. Interfaces"},{"key":"D6NR00321D\/cit35\/1","doi-asserted-by":"crossref","first-page":"152071","DOI":"10.1016\/j.ijhydene.2025.152071","volume":"186","author":"Provinciali","year":"2025","journal-title":"Int. J. Hydrogen Energy"},{"key":"D6NR00321D\/cit36\/1","doi-asserted-by":"crossref","first-page":"8691","DOI":"10.1038\/srep08691","volume":"5","author":"Lee","year":"2015","journal-title":"Sci. Rep."},{"key":"D6NR00321D\/cit37\/1","doi-asserted-by":"crossref","first-page":"3321","DOI":"10.1021\/acs.langmuir.0c03362","volume":"37","author":"Liang","year":"2021","journal-title":"Langmuir"},{"key":"D6NR00321D\/cit38\/1","doi-asserted-by":"crossref","first-page":"e202200457","DOI":"10.1002\/cplu.202200457","volume":"88","author":"Vanni","year":"2023","journal-title":"ChemPlusChem"}],"container-title":["Nanoscale"],"original-title":[],"language":"en","link":[{"URL":"http:\/\/pubs.rsc.org\/en\/content\/articlepdf\/2026\/NR\/D6NR00321D","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,6,30]],"date-time":"2026-06-30T20:42:33Z","timestamp":1782852153000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.rsc.org\/nr\/article\/18\/17\/9167-9176\/1242008"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026]]},"references-count":38,"journal-issue":{"issue":"17","published-print":{"date-parts":[[2026,5,7]]}},"URL":"https:\/\/doi.org\/10.1039\/d6nr00321d","relation":{},"ISSN":["2040-3364","2040-3372"],"issn-type":[{"value":"2040-3364","type":"print"},{"value":"2040-3372","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026]]}}}