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Chem."],"abstract":"<jats:p>\n                    Natural indole\n                    <jats:italic>S<\/jats:italic>\n                    -glycosides (Types I\u2013III): discovery, structures, and bioactivities. Catalytic C\u2013S glycosylation (Cu, TMSOTf, I\n                    <jats:sub>2<\/jats:sub>\n                    , Ni, photoredox) enables the total synthesis of calanthoside, isatindigotindolosides I\u2013III, and isatigotindoledioside E.\n                  <\/jats:p>","DOI":"10.1039\/d6ob01137c","type":"journal-article","created":{"date-parts":[[2026,9,3]],"date-time":"2026-09-03T16:21:31Z","timestamp":1788452491000},"page":"7676-7689","update-policy":"https:\/\/doi.org\/10.1039\/rsc_crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Indole\n                    <i>S<\/i>\n                    -glycosides: from natural product discovery to chemical synthesis"],"prefix":"10.1039","volume":"24","author":[{"given":"Jie","family":"Huang","sequence":"first","affiliation":[{"name":"School of Pharmaceutical Sciences, South-Central Minzu University, Wuhan 430074, China"},{"name":"School of Pharmacology Science and Technology, Hangzhou Institute for Advanced Study, University of Chinese Academy of Sciences, Hangzhou 310024, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yang","family":"Zhang","sequence":"additional","affiliation":[{"name":"School of Pharmaceutical Sciences, South-Central Minzu University, Wuhan 430074, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-6048-4965","authenticated-orcid":false,"given":"Bin","family":"Wu","sequence":"additional","affiliation":[{"name":"School of Pharmaceutical Sciences, South-Central Minzu University, Wuhan 430074, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-3687-9988","authenticated-orcid":false,"given":"Wen-Wu","family":"Sun","sequence":"additional","affiliation":[{"name":"School of Pharmaceutical Sciences, South-Central Minzu University, Wuhan 430074, China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"292","published-online":{"date-parts":[[2026]]},"reference":[{"key":"D6OB01137C\/cit1\/1","first-page":"1","volume-title":"Progress in Heterocyclic Chemistry","volume":"14","author":"Bergman","year":"2002","unstructured":"J.Bergman  and  T.Janosik , in  Progress in Heterocyclic Chemistry , ed.  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