{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,6]],"date-time":"2026-10-06T07:54:25Z","timestamp":1791273265589,"version":"4.1.0"},"reference-count":39,"publisher":"Royal Society of Chemistry (RSC)","license":[{"start":{"date-parts":[[2026,9,29]],"date-time":"2026-09-29T00:00:00Z","timestamp":1790640000000},"content-version":"vor","delay-in-days":271,"URL":"http:\/\/creativecommons.org\/licenses\/by-nc\/3.0\/"}],"funder":[{"DOI":"10.13039\/100000002","name":"National Institutes of Health","doi-asserted-by":"publisher","award":["GM136880"],"award-info":[{"award-number":["GM136880"]}],"id":[{"id":"10.13039\/100000002","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100023581","name":"National Science Foundation Graduate Research Fellowship Program","doi-asserted-by":"publisher","award":["1937971"],"award-info":[{"award-number":["1937971"]}],"id":[{"id":"10.13039\/100023581","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100000001","name":"National Science Foundation","doi-asserted-by":"publisher","award":["CHE-1521620"],"award-info":[{"award-number":["CHE-1521620"]}],"id":[{"id":"10.13039\/100000001","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["rsc.org"],"crossmark-restriction":true},"short-container-title":["Org. Chem. Front."],"abstract":"<jats:p>\n                    We report a C(sp\n                    <jats:sup>3<\/jats:sup>\n                    )-directed C\u2013H annulation using a one-carbon linchpin to form an alkyl boron substrate that undergoes Rh(\n                    <jats:sc>iii<\/jats:sc>\n                    )-catalyzed transmetallation, C\u2013H activation, and alkyne annulation, enabling access to diverse dihydroquinolines.\n                  <\/jats:p>","DOI":"10.1039\/d6qo01119e","type":"journal-article","created":{"date-parts":[[2026,9,29]],"date-time":"2026-09-29T21:03:27Z","timestamp":1790715807000},"update-policy":"https:\/\/doi.org\/10.1039\/rsc_crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["A one carbon linchpin for Rh(\n                    <scp>iii<\/scp>\n                    )-catalyzed, C(sp\n                    <sup>3<\/sup>\n                    )-directed C\u2013H annulation"],"prefix":"10.1039","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-8913-5571","authenticated-orcid":false,"given":"Michael R.","family":"Hollerbach","sequence":"first","affiliation":[{"name":"Department of Chemistry, Emory University, Atlanta, Georgia, 30322, USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Eleda V.","family":"Plouch","sequence":"additional","affiliation":[{"name":"Department of Chemistry, Emory University, Atlanta, Georgia, 30322, USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Samantha M.","family":"Velazquez","sequence":"additional","affiliation":[{"name":"Department of Chemistry, Emory University, Atlanta, Georgia, 30322, USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-4100-8610","authenticated-orcid":false,"given":"Simon B.","family":"Blakey","sequence":"additional","affiliation":[{"name":"Department of Chemistry, Emory University, Atlanta, Georgia, 30322, USA"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"292","published-online":{"date-parts":[[2026]]},"reference":[{"key":"D6QO01119E\/cit1\/1","doi-asserted-by":"crossref","first-page":"343","DOI":"10.1021\/acs.joc.5b02818","volume":"81","author":"Davies","year":"2016","journal-title":"J. Org. Chem."},{"key":"D6QO01119E\/cit2\/1","doi-asserted-by":"crossref","first-page":"522","DOI":"10.1038\/s41570-021-00300-6","volume":"5","author":"Guillemard","year":"2021","journal-title":"Nat. Rev. Chem."},{"key":"D6QO01119E\/cit3\/1","doi-asserted-by":"crossref","first-page":"1788","DOI":"10.1021\/acs.chemrev.9b00495","volume":"120","author":"Rej","year":"2020","journal-title":"Chem. Rev."},{"key":"D6QO01119E\/cit4\/1","doi-asserted-by":"crossref","first-page":"6603","DOI":"10.1039\/C8CS00201K","volume":"47","author":"Sambiagio","year":"2018","journal-title":"Chem. Soc. Rev."},{"key":"D6QO01119E\/cit5\/1","doi-asserted-by":"crossref","first-page":"5736","DOI":"10.1002\/anie.200352461","volume":"42","author":"Baudoin","year":"2003","journal-title":"Angew. Chem., Int. Ed."},{"key":"D6QO01119E\/cit6\/1","doi-asserted-by":"crossref","first-page":"792","DOI":"10.1002\/chem.200600811","volume":"13","author":"Hitce","year":"2007","journal-title":"Chem. \u2013 Eur. J."},{"key":"D6QO01119E\/cit7\/1","doi-asserted-by":"crossref","first-page":"15157","DOI":"10.1021\/ja805598s","volume":"130","author":"Chaumontet","year":"2008","journal-title":"J. Am. Chem. Soc."},{"key":"D6QO01119E\/cit8\/1","doi-asserted-by":"crossref","first-page":"1344","DOI":"10.1039\/C6SC04006C","volume":"8","author":"Yang","year":"2017","journal-title":"Chem. Sci."},{"key":"D6QO01119E\/cit9\/1","doi-asserted-by":"crossref","first-page":"4300","DOI":"10.1021\/acscatal.5b00898","volume":"5","author":"Holstein","year":"2015","journal-title":"ACS Catal."},{"key":"D6QO01119E\/cit10\/1","doi-asserted-by":"crossref","first-page":"3462","DOI":"10.1002\/anie.200600111","volume":"45","author":"Ren","year":"2006","journal-title":"Angew. Chem., Int. Ed."},{"key":"D6QO01119E\/cit11\/1","doi-asserted-by":"crossref","first-page":"14570","DOI":"10.1021\/ja076588s","volume":"129","author":"Lafrance","year":"2007","journal-title":"J. Am. Chem. Soc."},{"key":"D6QO01119E\/cit12\/1","doi-asserted-by":"crossref","first-page":"1759","DOI":"10.1021\/ol800425z","volume":"10","author":"Watanabe","year":"2008","journal-title":"Org. Lett."},{"key":"D6QO01119E\/cit13\/1","doi-asserted-by":"crossref","first-page":"1995","DOI":"10.1039\/c3sc00098b","volume":"4","author":"Larionov","year":"2013","journal-title":"Chem. Sci."},{"key":"D6QO01119E\/cit14\/1","doi-asserted-by":"crossref","first-page":"15021","DOI":"10.1002\/chem.201403985","volume":"20","author":"Katayev","year":"2014","journal-title":"Chem. \u2013 Eur. J."},{"key":"D6QO01119E\/cit15\/1","doi-asserted-by":"crossref","first-page":"7438","DOI":"10.1002\/anie.201102639","volume":"50","author":"Nakanishi","year":"2011","journal-title":"Angew. Chem., Int. Ed."},{"key":"D6QO01119E\/cit16\/1","doi-asserted-by":"crossref","first-page":"2238","DOI":"10.1002\/anie.201108511","volume":"51","author":"Saget","year":"2012","journal-title":"Angew. Chem., Int. Ed."},{"key":"D6QO01119E\/cit17\/1","doi-asserted-by":"crossref","first-page":"8040","DOI":"10.1021\/om3008772","volume":"31","author":"Donets","year":"2012","journal-title":"Organometallics"},{"key":"D6QO01119E\/cit18\/1","doi-asserted-by":"crossref","first-page":"11483","DOI":"10.1039\/c1cc14292e","volume":"47","author":"Anas","year":"2011","journal-title":"Chem. Commun."},{"key":"D6QO01119E\/cit19\/1","doi-asserted-by":"crossref","first-page":"6342","DOI":"10.1002\/anie.201901565","volume":"58","author":"Kong","year":"2019","journal-title":"Angew. Chem., Int. Ed."},{"key":"D6QO01119E\/cit20\/1","doi-asserted-by":"crossref","first-page":"5198","DOI":"10.1021\/ol9021172","volume":"11","author":"Fukutani","year":"2009","journal-title":"Org. Lett."},{"key":"D6QO01119E\/cit21\/1","doi-asserted-by":"crossref","first-page":"2867","DOI":"10.1021\/jo200339w","volume":"76","author":"Fukutani","year":"2011","journal-title":"J. Org. Chem."},{"key":"D6QO01119E\/cit22\/1","doi-asserted-by":"crossref","first-page":"9064","DOI":"10.1002\/anie.201405508","volume":"53","author":"Pedroni","year":"2014","journal-title":"Angew. Chem., Int. Ed."},{"key":"D6QO01119E\/cit23\/1","doi-asserted-by":"crossref","first-page":"11826","DOI":"10.1002\/anie.201505916","volume":"54","author":"Pedroni","year":"2015","journal-title":"Angew. Chem., Int. Ed."},{"key":"D6QO01119E\/cit24\/1","doi-asserted-by":"crossref","first-page":"5370","DOI":"10.1021\/jacs.8b02716","volume":"140","author":"Romanov-Michailidis","year":"2018","journal-title":"J. Am. Chem. Soc."},{"key":"D6QO01119E\/cit25\/1","doi-asserted-by":"crossref","first-page":"1669","DOI":"10.1002\/adsc.202000112","volume":"362","author":"Moon","year":"2020","journal-title":"Adv. Synth. Catal."},{"key":"D6QO01119E\/cit26\/1","doi-asserted-by":"crossref","first-page":"7199","DOI":"10.1021\/acs.orglett.1c02597","volume":"23","author":"Liu","year":"2021","journal-title":"Org. Lett."},{"key":"D6QO01119E\/cit27\/1","doi-asserted-by":"crossref","first-page":"1744","DOI":"10.1002\/adsc.202301451","volume":"366","author":"Liu","year":"2024","journal-title":"Adv. Synth. Catal."},{"key":"D6QO01119E\/cit28\/1","doi-asserted-by":"crossref","first-page":"6452","DOI":"10.1021\/acs.orglett.6b03347","volume":"18","author":"Ming","year":"2016","journal-title":"Org. Lett."},{"key":"D6QO01119E\/cit29\/1","doi-asserted-by":"crossref","first-page":"4458","DOI":"10.1021\/ol301955s","volume":"14","author":"Molander","year":"2012","journal-title":"Org. Lett."},{"key":"D6QO01119E\/cit30\/1","doi-asserted-by":"crossref","first-page":"1315","DOI":"10.1021\/cr100412j","volume":"111","author":"Ackermann","year":"2011","journal-title":"Chem. Rev."},{"key":"D6QO01119E\/cit31\/1","doi-asserted-by":"crossref","first-page":"1118","DOI":"10.1246\/cl.2010.1118","volume":"39","author":"Lapointe","year":"2010","journal-title":"Chem. Lett."},{"key":"D6QO01119E\/cit32\/1","doi-asserted-by":"crossref","first-page":"3400","DOI":"10.1021\/acs.organomet.5b00369","volume":"34","author":"Walsh","year":"2015","journal-title":"Organometallics"},{"key":"D6QO01119E\/cit33\/1","doi-asserted-by":"crossref","first-page":"199","DOI":"10.1002\/9780470147108.ch4","volume":"1","author":"Allinger","year":"1967","journal-title":"Top. Stereochem."},{"key":"D6QO01119E\/cit34\/1","doi-asserted-by":"crossref","first-page":"4822","DOI":"10.1021\/acs.chemrev.3c00793","volume":"124","author":"Budiman","year":"2024","journal-title":"Chem. Rev."},{"key":"D6QO01119E\/cit35\/1","doi-asserted-by":"crossref","first-page":"7817","DOI":"10.1021\/ja901640m","volume":"131","author":"Clot","year":"2009","journal-title":"J. Am. Chem. Soc."},{"key":"D6QO01119E\/cit36\/1","doi-asserted-by":"crossref","first-page":"76","DOI":"10.1038\/s41586-020-2131-1","volume":"580","author":"MacKenzie","year":"2020","journal-title":"Nature"},{"key":"D6QO01119E\/cit37\/1","doi-asserted-by":"crossref","first-page":"3066","DOI":"10.1002\/anie.201107334","volume":"51","author":"Simmons","year":"2012","journal-title":"Angew. Chem., Int. Ed."},{"key":"D6QO01119E\/cit38\/1","doi-asserted-by":"crossref","first-page":"10610","DOI":"10.1002\/anie.201206191","volume":"51","author":"Pham","year":"2012","journal-title":"Angew. Chem., Int. Ed."},{"key":"D6QO01119E\/cit39\/1","doi-asserted-by":"crossref","first-page":"3484","DOI":"10.1002\/anie.201310723","volume":"53","author":"Pham","year":"2014","journal-title":"Angew. Chem., Int. Ed."}],"container-title":["Organic Chemistry Frontiers"],"original-title":[],"language":"en","link":[{"URL":"http:\/\/pubs.rsc.org\/QO\/article-pdf\/doi\/10.1039\/D6QO01119E\/0\/D6QO01119E.pdf","content-type":"application\/pdf","content-version":"vor","intended-application":"syndication"},{"URL":"http:\/\/pubs.rsc.org\/QO\/article-pdf\/doi\/10.1039\/D6QO01119E\/0\/D6QO01119E.pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,10,6]],"date-time":"2026-10-06T07:33:50Z","timestamp":1791272030000},"score":1,"resource":{"primary":{"URL":"http:\/\/pubs.rsc.org\/QO\/article-lookup\/doi\/10.1039\/D6QO01119E"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026]]},"references-count":39,"URL":"https:\/\/doi.org\/10.1039\/d6qo01119e","relation":{"has-preprint":[{"id-type":"doi","id":"10.26434\/chemrxiv-2024-m4kpm","asserted-by":"object"}]},"ISSN":["2052-4129"],"issn-type":[{"value":"2052-4129","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026]]}}}