{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,7]],"date-time":"2026-10-07T13:00:32Z","timestamp":1791378032771,"version":"4.3.2"},"reference-count":69,"publisher":"Royal Society of Chemistry (RSC)","license":[{"start":{"date-parts":[[2026,10,7]],"date-time":"2026-10-07T00:00:00Z","timestamp":1791331200000},"content-version":"vor","delay-in-days":279,"URL":"http:\/\/creativecommons.org\/licenses\/by-nc\/3.0\/"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["21772091"],"award-info":[{"award-number":["21772091"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100012246","name":"Priority Academic Program Development of Jiangsu Higher Education Institutions","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100012246","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["rsc.org"],"crossmark-restriction":true},"short-container-title":["RSC Adv."],"abstract":"<jats:p>Ambient-air benzylic C\u2013H electrochemical oxygenation is enabled by a cathode-loaded Fe\u2013N\u2013C electrocatalyst. The cathodic ORR-coupled anodic oxidation strategy is free from chemical oxidants, affording aldehydes and ketones in up to 96% yield.<\/jats:p>","DOI":"10.1039\/d6ra07068j","type":"journal-article","created":{"date-parts":[[2026,10,7]],"date-time":"2026-10-07T12:05:46Z","timestamp":1791374746000},"update-policy":"https:\/\/doi.org\/10.1039\/rsc_crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Selective benzylic C\u2013H electrochemical oxygenation under ambient air promoted by an Fe\u2013N\u2013C electrocatalyst"],"prefix":"10.1039","author":[{"given":"Zeyao","family":"Liang","sequence":"first","affiliation":[{"name":"Department of Applied Chemistry, College of Material Science and Technology, Nanjing University of Aeronautics and Astronautics, Nanjing 210016, PR China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jiahe","family":"Zhang","sequence":"additional","affiliation":[{"name":"Department of Applied Chemistry, College of Material Science and Technology, Nanjing University of Aeronautics and Astronautics, Nanjing 210016, PR China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zezhao","family":"Huang","sequence":"additional","affiliation":[{"name":"Department of Applied Chemistry, College of Material Science and Technology, Nanjing University of Aeronautics and Astronautics, Nanjing 210016, PR China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Li","family":"Zhu","sequence":"additional","affiliation":[{"name":"Department of Chemistry, School of Pharmacy, Nanjing Medical University, Nanjing 211166, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-3589-1475","authenticated-orcid":false,"given":"Xiaoquan","family":"Yao","sequence":"additional","affiliation":[{"name":"Department of Applied Chemistry, College of Material Science and Technology, Nanjing University of Aeronautics and Astronautics, Nanjing 210016, PR China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"292","published-online":{"date-parts":[[2026]]},"reference":[{"key":"D6RA07068J\/cit1\/1","doi-asserted-by":"crossref","first-page":"10542","DOI":"10.1021\/ja047297b","volume":"126","author":"Yang","year":"2004","journal-title":"J. Am. Chem. Soc."},{"key":"D6RA07068J\/cit2\/1","doi-asserted-by":"crossref","first-page":"1132","DOI":"10.1038\/nature04190","volume":"437","author":"Hughes","year":"2005","journal-title":"Nature"},{"key":"D6RA07068J\/cit3\/1","doi-asserted-by":"crossref","first-page":"2943","DOI":"10.1021\/cr040679f","volume":"106","author":"Caron","year":"2006","journal-title":"Chem. Rev."},{"key":"D6RA07068J\/cit4\/1","doi-asserted-by":"crossref","first-page":"2745","DOI":"10.1002\/anie.201108540","volume":"51","author":"De Houwer","year":"2012","journal-title":"Angew. Chem., Int. Ed."},{"key":"D6RA07068J\/cit5\/1","doi-asserted-by":"crossref","first-page":"3381","DOI":"10.1039\/c2cs15224j","volume":"41","author":"Shi","year":"2012","journal-title":"Chem. Soc. Rev."},{"key":"D6RA07068J\/cit6\/1","doi-asserted-by":"crossref","first-page":"3116","DOI":"10.1039\/c3gc41459k","volume":"15","author":"Wertz","year":"2013","journal-title":"Green Chem."},{"key":"D6RA07068J\/cit7\/1","doi-asserted-by":"crossref","first-page":"7421","DOI":"10.1021\/cr300298j","volume":"113","author":"Tom\u00e1s","year":"2013","journal-title":"Chem. Rev."},{"key":"D6RA07068J\/cit8\/1","doi-asserted-by":"crossref","first-page":"2344","DOI":"10.1039\/c3gc42135j","volume":"16","author":"Chen","year":"2014","journal-title":"Green Chem."},{"key":"D6RA07068J\/cit9\/1","doi-asserted-by":"crossref","first-page":"5912","DOI":"10.1002\/anie.201702511","volume":"56","author":"Gaster","year":"2017","journal-title":"Angew. Chem., Int. Ed."},{"key":"D6RA07068J\/cit10\/1","doi-asserted-by":"crossref","first-page":"15197","DOI":"10.1016\/S0040-4020(96)00968-4","volume":"52","author":"Alcalde","year":"1996","journal-title":"Tetrahedron"},{"key":"D6RA07068J\/cit11\/1","doi-asserted-by":"crossref","first-page":"10205","DOI":"10.3390\/molecules200610205","volume":"20","author":"M\u0142ochowski","year":"2015","journal-title":"Molecules"},{"key":"D6RA07068J\/cit12\/1","doi-asserted-by":"crossref","first-page":"3183","DOI":"10.1021\/ja004218x","volume":"123","author":"Nicolaou","year":"2001","journal-title":"J. Am. Chem. Soc."},{"key":"D6RA07068J\/cit13\/1","doi-asserted-by":"crossref","first-page":"263","DOI":"10.1021\/ol047749p","volume":"7","author":"Yang","year":"2005","journal-title":"Org. Lett."},{"key":"D6RA07068J\/cit14\/1","doi-asserted-by":"crossref","first-page":"1500","DOI":"10.1039\/b403004d","volume":"13","author":"Nechab","year":"2004","journal-title":"Chem. Commun."},{"key":"D6RA07068J\/cit15\/1","doi-asserted-by":"crossref","first-page":"570","DOI":"10.1039\/b408974j","volume":"6","author":"Marwah","year":"2004","journal-title":"Green Chem."},{"key":"D6RA07068J\/cit16\/1","doi-asserted-by":"crossref","first-page":"7365","DOI":"10.1021\/jo8012435","volume":"73","author":"Dohi","year":"2008","journal-title":"J. Org. Chem."},{"key":"D6RA07068J\/cit17\/1","doi-asserted-by":"crossref","first-page":"1973","DOI":"10.1039\/b919346b","volume":"11","author":"Zhang","year":"2009","journal-title":"Green Chem."},{"key":"D6RA07068J\/cit18\/1","doi-asserted-by":"crossref","first-page":"77","DOI":"10.1038\/nature17431","volume":"533","author":"Horn","year":"2016","journal-title":"Nature"},{"key":"D6RA07068J\/cit19\/1","doi-asserted-by":"crossref","first-page":"1282","DOI":"10.1039\/C6SC03831J","volume":"8","author":"Hruszkewycz","year":"2017","journal-title":"Chem. Sci."},{"key":"D6RA07068J\/cit20\/1","doi-asserted-by":"crossref","first-page":"560","DOI":"10.1016\/j.electacta.2013.10.093","volume":"114","author":"Li","year":"2013","journal-title":"Electrochim. Acta"},{"key":"D6RA07068J\/cit21\/1","doi-asserted-by":"crossref","first-page":"525","DOI":"10.1023\/A:1024474620525","volume":"33","author":"Utley","year":"2003","journal-title":"J. Appl. Electrochem."},{"key":"D6RA07068J\/cit22\/1","doi-asserted-by":"crossref","first-page":"10770","DOI":"10.1021\/acscatal.3c02282","volume":"13","author":"Bryliakov","year":"2023","journal-title":"ACS Catal."},{"key":"D6RA07068J\/cit23\/1","doi-asserted-by":"crossref","first-page":"4549","DOI":"10.1021\/ol051765k","volume":"7","author":"Bonvin","year":"2005","journal-title":"Org. Lett."},{"key":"D6RA07068J\/cit24\/1","doi-asserted-by":"crossref","first-page":"3709","DOI":"10.1016\/j.tetlet.2008.04.044","volume":"49","author":"Callens","year":"2008","journal-title":"Tetrahedron Lett."},{"key":"D6RA07068J\/cit25\/1","first-page":"2475","volume":"14","author":"Kamijo","year":"2010","journal-title":"Synthesis"},{"key":"D6RA07068J\/cit26\/1","doi-asserted-by":"crossref","first-page":"2246","DOI":"10.1021\/ol1005938","volume":"12","author":"Vanover","year":"2010","journal-title":"Org. Lett."},{"key":"D6RA07068J\/cit27\/1","doi-asserted-by":"crossref","first-page":"1238","DOI":"10.1021\/ol300037p","volume":"14","author":"Xie","year":"2012","journal-title":"Org. Lett."},{"key":"D6RA07068J\/cit28\/1","doi-asserted-by":"crossref","first-page":"41","DOI":"10.1016\/j.catcom.2011.12.041","volume":"20","author":"Zhang","year":"2012","journal-title":"Catal. Commun."},{"key":"D6RA07068J\/cit29\/1","doi-asserted-by":"crossref","first-page":"1108","DOI":"10.1021\/ol4037083","volume":"16","author":"Shen","year":"2014","journal-title":"Org. Lett."},{"key":"D6RA07068J\/cit30\/1","doi-asserted-by":"crossref","first-page":"2759","DOI":"10.1039\/D1CS00895A","volume":"51","author":"He","year":"2022","journal-title":"Chem. Soc. Rev."},{"key":"D6RA07068J\/cit31\/1","doi-asserted-by":"crossref","first-page":"3480","DOI":"10.1039\/c3cs60282f","volume":"43","author":"Guo","year":"2014","journal-title":"Chem. Soc. Rev."},{"key":"D6RA07068J\/cit32\/1","doi-asserted-by":"crossref","first-page":"e202401266","DOI":"10.1002\/adsc.202401266","volume":"367","author":"Guo","year":"2025","journal-title":"Adv. Synth. Catal."},{"key":"D6RA07068J\/cit33\/1","doi-asserted-by":"crossref","first-page":"1314","DOI":"10.1021\/ol300195c","volume":"14","author":"Zeng","year":"2012","journal-title":"Org. Lett."},{"key":"D6RA07068J\/cit34\/1","doi-asserted-by":"crossref","first-page":"10260","DOI":"10.1002\/chem.201802588","volume":"24","author":"Mo","year":"2018","journal-title":"Chem. \u2013 Eur. J."},{"key":"D6RA07068J\/cit35\/1","doi-asserted-by":"crossref","first-page":"2134","DOI":"10.1007\/s11426-021-1061-x","volume":"64","author":"Li","year":"2021","journal-title":"Sci. China Chem."},{"key":"D6RA07068J\/cit36\/1","doi-asserted-by":"crossref","first-page":"2985","DOI":"10.1021\/acs.joc.2c02700","volume":"88","author":"Bai","year":"2023","journal-title":"J. Org. Chem."},{"key":"D6RA07068J\/cit37\/1","doi-asserted-by":"crossref","first-page":"36","DOI":"10.1021\/acselectrochem.4c00009","volume":"1","author":"Cheng","year":"2025","journal-title":"ACS Electrochem."},{"key":"D6RA07068J\/cit38\/1","doi-asserted-by":"crossref","first-page":"7445","DOI":"10.1021\/acs.orglett.1c02651","volume":"23","author":"Li","year":"2021","journal-title":"Org. Lett."},{"key":"D6RA07068J\/cit39\/1","first-page":"113614","volume":"550","author":"Xu","year":"2023","journal-title":"Mol. Catal."},{"key":"D6RA07068J\/cit40\/1","doi-asserted-by":"crossref","first-page":"2706","DOI":"10.1038\/s41467-020-16519-8","volume":"11","author":"Xiong","year":"2020","journal-title":"Nat. Commun."},{"key":"D6RA07068J\/cit41\/1","doi-asserted-by":"crossref","first-page":"7806","DOI":"10.1021\/acs.joc.2c00455","volume":"87","author":"Hou","year":"2022","journal-title":"J. Org. Chem."},{"key":"D6RA07068J\/cit42\/1","doi-asserted-by":"crossref","first-page":"e202400033","DOI":"10.1002\/elsa.202400033","volume":"5","author":"Jannath","year":"2025","journal-title":"Electrochem. Sci. Adv."},{"key":"D6RA07068J\/cit43\/1","doi-asserted-by":"crossref","first-page":"e202500146","DOI":"10.1002\/celc.202500146","volume":"12","author":"Garc\u00e9s-Barr\u00eda","year":"2025","journal-title":"ChemElectroChem"},{"key":"D6RA07068J\/cit44\/1","doi-asserted-by":"crossref","first-page":"5542","DOI":"10.1002\/chem.201204207","volume":"19","author":"Meng","year":"2013","journal-title":"Chem. \u2013 Eur. J."},{"key":"D6RA07068J\/cit45\/1","doi-asserted-by":"crossref","first-page":"7543","DOI":"10.1039\/D0GC01871F","volume":"22","author":"Sun","year":"2020","journal-title":"Green\nChem."},{"key":"D6RA07068J\/cit46\/1","first-page":"112633","volume":"530","author":"Kong","year":"2022","journal-title":"Mol. Catal."},{"key":"D6RA07068J\/cit47\/1","doi-asserted-by":"crossref","first-page":"e202300570","DOI":"10.1002\/ejoc.202300570","volume":"26","author":"Sun","year":"2023","journal-title":"Eur. J. Org. Chem."},{"key":"D6RA07068J\/cit48\/1","doi-asserted-by":"crossref","first-page":"23905","DOI":"10.1021\/jacs.3c09907","volume":"145","author":"Peng","year":"2023","journal-title":"J. Am. Chem. Soc."},{"key":"D6RA07068J\/cit49\/1","doi-asserted-by":"crossref","first-page":"115792","DOI":"10.1016\/j.jcat.2024.115792","volume":"440","author":"Huang","year":"2024","journal-title":"J. Catal."},{"key":"D6RA07068J\/cit50\/1","doi-asserted-by":"crossref","first-page":"9106","DOI":"10.1021\/acscatal.5c01183","volume":"15","author":"Chuang","year":"2025","journal-title":"ACS Catal."},{"key":"D6RA07068J\/cit51\/1","doi-asserted-by":"crossref","first-page":"e9980873","DOI":"10.1002\/anie.9980873","volume":"65","author":"Liu","year":"2026","journal-title":"Angew. Chem., Int. Ed."},{"key":"D6RA07068J\/cit52\/1","doi-asserted-by":"crossref","first-page":"e202406588","DOI":"10.1002\/anie.202406588","volume":"63","author":"Zhang","year":"2024","journal-title":"Angew. Chem., Int. Ed."},{"key":"D6RA07068J\/cit53\/1","doi-asserted-by":"crossref","first-page":"14776","DOI":"10.1039\/D6CC02433E","volume":"62","author":"Fu","year":"2026","journal-title":"Chem. Commun."},{"key":"D6RA07068J\/cit54\/1","doi-asserted-by":"crossref","first-page":"13678","DOI":"10.1039\/D1TA03176G","volume":"9","author":"Wang","year":"2021","journal-title":"J. Mater. Chem. A"},{"key":"D6RA07068J\/cit55\/1","doi-asserted-by":"crossref","first-page":"10695","DOI":"10.1021\/acs.jpcc.9b02163","volume":"123","author":"Lazar","year":"2019","journal-title":"J. Phys. Chem. C"},{"key":"D6RA07068J\/cit56\/1","doi-asserted-by":"crossref","first-page":"34524","DOI":"10.1039\/D5RA05653E","volume":"15","author":"Shoaib","year":"2025","journal-title":"RSC Adv."},{"key":"D6RA07068J\/cit57\/1","doi-asserted-by":"crossref","first-page":"1704282","DOI":"10.1002\/smll.201704282","volume":"14","author":"Wang","year":"2018","journal-title":"Small"},{"key":"D6RA07068J\/cit58\/1","doi-asserted-by":"crossref","first-page":"6937","DOI":"10.1002\/anie.201702473","volume":"56","author":"Chen","year":"2017","journal-title":"Angew. Chem., Int. Ed."},{"key":"D6RA07068J\/cit59\/1","doi-asserted-by":"crossref","first-page":"1801226","DOI":"10.1002\/aenm.201801226","volume":"8","author":"Miao","year":"2018","journal-title":"Adv. Energy Mater."},{"key":"D6RA07068J\/cit60\/1","doi-asserted-by":"crossref","first-page":"1706758","DOI":"10.1002\/adma.201706758","volume":"30","author":"Wang","year":"2018","journal-title":"Adv. Mater."},{"key":"D6RA07068J\/cit61\/1","doi-asserted-by":"crossref","first-page":"23297","DOI":"10.1021\/jacs.5c08109","volume":"147","author":"Zhang","year":"2025","journal-title":"J. Am. Chem. Soc."},{"key":"D6RA07068J\/cit62\/1","doi-asserted-by":"crossref","first-page":"779","DOI":"10.1039\/D4QO01724B","volume":"12","author":"Fu","year":"2025","journal-title":"Org. Chem. Front."},{"key":"D6RA07068J\/cit63\/1","doi-asserted-by":"crossref","first-page":"e202408186","DOI":"10.1002\/anie.202408186","volume":"63","author":"Tang","year":"2024","journal-title":"Angew. Chem., Int. Ed."},{"key":"D6RA07068J\/cit64\/1","doi-asserted-by":"crossref","first-page":"6768","DOI":"10.1021\/acs.joc.5c00495","volume":"90","author":"Zhang","year":"2025","journal-title":"J. Org. Chem."},{"key":"D6RA07068J\/cit65\/1","doi-asserted-by":"crossref","first-page":"2236","DOI":"10.1002\/chem.201504530","volume":"22","author":"Xu","year":"2016","journal-title":"Chem. \u2013 Eur. J."},{"key":"D6RA07068J\/cit66\/1","doi-asserted-by":"crossref","first-page":"7391","DOI":"10.1021\/acs.joc.3c00653","volume":"88","author":"Fan","year":"2023","journal-title":"J. Org. Chem."},{"key":"D6RA07068J\/cit67\/1","doi-asserted-by":"crossref","first-page":"1464","DOI":"10.1039\/B411031E","volume":"28","author":"Ren","year":"2004","journal-title":"New J. Chem."},{"key":"D6RA07068J\/cit68\/1","doi-asserted-by":"crossref","first-page":"16776","DOI":"10.1039\/D0NJ03907A","volume":"44","author":"Hosseini-Sarvari","year":"2020","journal-title":"New J. Chem."},{"key":"D6RA07068J\/cit69\/1","doi-asserted-by":"crossref","first-page":"5049","DOI":"10.1002\/cssc.202101762","volume":"14","author":"Wang","year":"2021","journal-title":"ChemSusChem"}],"container-title":["RSC Advances"],"original-title":[],"language":"en","link":[{"URL":"http:\/\/pubs.rsc.org\/RA\/article-pdf\/doi\/10.1039\/D6RA07068J\/0\/D6RA07068J.pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,10,7]],"date-time":"2026-10-07T12:05:56Z","timestamp":1791374756000},"score":1,"resource":{"primary":{"URL":"http:\/\/pubs.rsc.org\/RA\/article-lookup\/doi\/10.1039\/D6RA07068J"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026]]},"references-count":69,"URL":"https:\/\/doi.org\/10.1039\/d6ra07068j","relation":{},"ISSN":["2046-2069"],"issn-type":[{"value":"2046-2069","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026]]}}}