{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,4]],"date-time":"2026-10-04T04:46:36Z","timestamp":1791089196019,"version":"4.1.0"},"reference-count":64,"publisher":"Royal Society of Chemistry (RSC)","issue":"26","license":[{"start":{"date-parts":[[2026,5,15]],"date-time":"2026-05-15T00:00:00Z","timestamp":1778803200000},"content-version":"vor","delay-in-days":134,"URL":"http:\/\/creativecommons.org\/licenses\/by-nc\/3.0\/"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22293021"],"award-info":[{"award-number":["22293021"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22208337"],"award-info":[{"award-number":["22208337"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22288101"],"award-info":[{"award-number":["22288101"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22494712"],"award-info":[{"award-number":["22494712"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["rsc.org"],"crossmark-restriction":true},"short-container-title":["Chem. Sci."],"abstract":"<jats:p>Spatiotemporally-resolved spectroscopy was employed to probe the temperature of active clusters within individual zeolite, while simultaneously monitoring the spatial distribution of active-intermediates and coke species.<\/jats:p>","DOI":"10.1039\/d6sc01014h","type":"journal-article","created":{"date-parts":[[2026,5,15]],"date-time":"2026-05-15T09:20:55Z","timestamp":1778836855000},"page":"12925-12939","update-policy":"https:\/\/doi.org\/10.1039\/rsc_crossmark_policy","source":"Crossref","is-referenced-by-count":1,"title":["Unveiling the role of local temperature gradients in individual zeolites containing metal active sites"],"prefix":"10.1039","volume":"17","author":[{"given":"Bing","family":"Zhao","sequence":"first","affiliation":[{"name":"Department of Chemical Physics, University of Science and Technology of China, Hefei, Anhui, China, 230026"},{"name":"Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian, Liaoning, China, 116023"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhikang","family":"Xu","sequence":"additional","affiliation":[{"name":"Qingyuan Innovation Laboratory, Quanzhou, China, 362801"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Guida","family":"Li","sequence":"additional","affiliation":[{"name":"Department of Chemical Physics, University of Science and Technology of China, Hefei, Anhui, China, 230026"},{"name":"Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian, Liaoning, China, 116023"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Gang","family":"Meng","sequence":"additional","affiliation":[{"name":"Department of Chemical Physics, University of Science and Technology of China, Hefei, Anhui, China, 230026"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hang","family":"Chen","sequence":"additional","affiliation":[{"name":"Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian, Liaoning, China, 116023"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Tong","family":"Zhao","sequence":"additional","affiliation":[{"name":"Analytical Solution Plaza, HORIBA (China) Trading Co., Shanghai, China, 200335"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0536-6792","authenticated-orcid":false,"given":"Haibo","family":"Zhu","sequence":"additional","affiliation":[{"name":"National Engineering Research Center of Chemical Fertilizer Catalyst, School of Chemical Engineering, Fuzhou University, Fuzhou, Fujian, China, 350002"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Dan","family":"Zhao","sequence":"additional","affiliation":[{"name":"Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian, Liaoning, China, 116023"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Mingbin","family":"Gao","sequence":"additional","affiliation":[{"name":"Department of Chemical and Biochemical Engineering, College of Chemistry and Chemical Engineering, State Key Laboratory of Physical Chemistry of Solid Surfaces, Xiamen University, Xiamen, Fujian, China, 361005"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-7078-2402","authenticated-orcid":false,"given":"Mao","family":"Ye","sequence":"additional","affiliation":[{"name":"Department of Chemical Physics, University of Science and Technology of China, Hefei, Anhui, China, 230026"},{"name":"Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian, Liaoning, China, 116023"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhongmin","family":"Liu","sequence":"additional","affiliation":[{"name":"Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian, Liaoning, China, 116023"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"292","published-online":{"date-parts":[[2026]]},"reference":[{"key":"D6SC01014H\/cit1\/1","doi-asserted-by":"crossref","first-page":"866","DOI":"10.1038\/s41563-019-0412-6","volume":"18","author":"Liu","year":"2019","journal-title":"Nat. Mater."},{"key":"D6SC01014H\/cit2\/1","doi-asserted-by":"crossref","first-page":"221","DOI":"10.1038\/s41586-020-2671-4","volume":"585","author":"Ryoo","year":"2020","journal-title":"Nature"},{"key":"D6SC01014H\/cit3\/1","doi-asserted-by":"crossref","first-page":"9920","DOI":"10.1021\/jacs.9b03361","volume":"141","author":"Chai","year":"2019","journal-title":"J. Am. Chem. Soc."},{"key":"D6SC01014H\/cit4\/1","doi-asserted-by":"crossref","first-page":"2412","DOI":"10.1039\/C8GC00768C","volume":"20","author":"Zhong","year":"2018","journal-title":"Green Chem."},{"key":"D6SC01014H\/cit5\/1","doi-asserted-by":"crossref","first-page":"90","DOI":"10.1016\/j.apcatb.2016.01.029","volume":"187","author":"Blanch-Raga","year":"2016","journal-title":"Appl. Catal., B"},{"key":"D6SC01014H\/cit6\/1","doi-asserted-by":"crossref","first-page":"193","DOI":"10.1126\/science.aaw1108","volume":"367","author":"Jin","year":"2020","journal-title":"Science"},{"key":"D6SC01014H\/cit7\/1","doi-asserted-by":"crossref","first-page":"76","DOI":"10.1126\/science.abe7935","volume":"372","author":"Zhou","year":"2021","journal-title":"Science"},{"key":"D6SC01014H\/cit8\/1","doi-asserted-by":"crossref","first-page":"6039","DOI":"10.1021\/acs.chemrev.2c00315","volume":"123","author":"Zhang","year":"2022","journal-title":"Chem. Rev."},{"key":"D6SC01014H\/cit9\/1","doi-asserted-by":"crossref","first-page":"771","DOI":"10.1126\/science.1240148","volume":"341","author":"Cargnello","year":"2013","journal-title":"Science"},{"key":"D6SC01014H\/cit10\/1","doi-asserted-by":"crossref","first-page":"423","DOI":"10.1126\/science.ads7290","volume":"388","author":"Rzepka","year":"2025","journal-title":"Science"},{"key":"D6SC01014H\/cit11\/1","doi-asserted-by":"crossref","first-page":"10618","DOI":"10.1021\/acscatal.9b01844","volume":"9","author":"Tang","year":"2019","journal-title":"ACS Catal."},{"key":"D6SC01014H\/cit12\/1","doi-asserted-by":"crossref","first-page":"204","DOI":"10.1126\/science.abn8289","volume":"377","author":"Cheng","year":"2022","journal-title":"Science"},{"key":"D6SC01014H\/cit13\/1","doi-asserted-by":"crossref","first-page":"20053","DOI":"10.1021\/acsnano.3c05622","volume":"17","author":"Jacobs","year":"2023","journal-title":"ACS Nano"},{"key":"D6SC01014H\/cit14\/1","doi-asserted-by":"crossref","first-page":"873","DOI":"10.1038\/nchem.1478","volume":"4","author":"Buurmans","year":"2012","journal-title":"Nat. Chem."},{"key":"D6SC01014H\/cit15\/1","doi-asserted-by":"crossref","first-page":"42455","DOI":"10.1021\/acsami.9b11751","volume":"11","author":"Shang","year":"2019","journal-title":"ACS Appl. Mater. Interfaces"},{"key":"D6SC01014H\/cit16\/1","doi-asserted-by":"crossref","first-page":"2100139","DOI":"10.1002\/adpr.202100139","volume":"3","author":"Piotrowski","year":"2022","journal-title":"Adv. Photonics Res."},{"key":"D6SC01014H\/cit17\/1","doi-asserted-by":"crossref","first-page":"401","DOI":"10.1038\/nmat4510","volume":"15","author":"Saint Remi","year":"2016","journal-title":"Nat. Mater."},{"key":"D6SC01014H\/cit18\/1","doi-asserted-by":"crossref","first-page":"333","DOI":"10.1038\/nmat3917","volume":"13","author":"K\u00e4rger","year":"2014","journal-title":"Nat. Mater."},{"key":"D6SC01014H\/cit19\/1","doi-asserted-by":"crossref","first-page":"10429","DOI":"10.1021\/ja102566b","volume":"132","author":"Parvulescu","year":"2010","journal-title":"J. Am. Chem. Soc."},{"key":"D6SC01014H\/cit20\/1","doi-asserted-by":"crossref","first-page":"616","DOI":"10.1080\/00986440802484465","volume":"196","author":"Hwang","year":"2008","journal-title":"Chem. Eng. Commun."},{"key":"D6SC01014H\/cit21\/1","doi-asserted-by":"crossref","first-page":"992","DOI":"10.1021\/cs501345g","volume":"5","author":"Borodina","year":"2015","journal-title":"ACS Catal."},{"key":"D6SC01014H\/cit22\/1","doi-asserted-by":"crossref","first-page":"11156","DOI":"10.1039\/D1CS00395J","volume":"50","author":"Medeiros-Costa","year":"2021","journal-title":"Chem. Soc. Rev."},{"key":"D6SC01014H\/cit23\/1","doi-asserted-by":"publisher","DOI":"10.1002\/9783527610044.hetcat0001","volume-title":"Handbook of Heterogeneous Catalysis","author":"Dumesic","year":"1996","unstructured":"J. A.Dumesic ,  G. W.Huber  and  M.Boudart , in  Handbook of Heterogeneous Catalysis ,  1996 ,  10.1002\/9783527610044.hetcat0001"},{"key":"D6SC01014H\/cit24\/1","doi-asserted-by":"crossref","first-page":"2163","DOI":"10.1039\/b800260f","volume":"37","author":"N\u00f8rskov","year":"2008","journal-title":"Chem. Soc. Rev."},{"key":"D6SC01014H\/cit25\/1","doi-asserted-by":"publisher","first-page":"263","DOI":"10.1002\/9783527808397.ch9","volume-title":"Kinetics of Chemical Reactions","author":"Marin","year":"2019","unstructured":"G. B.Marin ,  G. S.Yablonsky  and  D.Constales , In  Kinetics of Chemical Reactions ,  2019 ,  pp. 263\u2013305 , DOI:  10.1002\/9783527808397.ch9"},{"key":"D6SC01014H\/cit26\/1","doi-asserted-by":"crossref","first-page":"9279","DOI":"10.1021\/acscatal.1c00331","volume":"11","author":"Lian","year":"2021","journal-title":"ACS Catal."},{"key":"D6SC01014H\/cit27\/1","doi-asserted-by":"crossref","first-page":"77","DOI":"10.1016\/j.jcat.2019.12.037","volume":"383","author":"Chen","year":"2020","journal-title":"J. Catal."},{"key":"D6SC01014H\/cit28\/1","doi-asserted-by":"crossref","first-page":"6078","DOI":"10.1021\/acscatal.5c00268","volume":"15","author":"Li","year":"2025","journal-title":"ACS Catal."},{"key":"D6SC01014H\/cit29\/1","doi-asserted-by":"crossref","first-page":"295","DOI":"10.1126\/science.adp7379","volume":"385","author":"Chen","year":"2024","journal-title":"Science"},{"key":"D6SC01014H\/cit30\/1","doi-asserted-by":"crossref","first-page":"2689","DOI":"10.1002\/aic.11565","volume":"54","author":"Simeone","year":"2008","journal-title":"AIChE J."},{"key":"D6SC01014H\/cit31\/1","doi-asserted-by":"crossref","first-page":"10452","DOI":"10.1021\/ja802075m","volume":"130","author":"Koptyug","year":"2008","journal-title":"J. Am. Chem. Soc."},{"key":"D6SC01014H\/cit32\/1","doi-asserted-by":"crossref","first-page":"1727","DOI":"10.1016\/j.joule.2022.06.019","volume":"6","author":"Mascaretti","year":"2022","journal-title":"Joule"},{"key":"D6SC01014H\/cit33\/1","doi-asserted-by":"crossref","first-page":"986","DOI":"10.1038\/s41929-019-0352-1","volume":"2","author":"Hartman","year":"2019","journal-title":"Nat. Catal."},{"key":"D6SC01014H\/cit34\/1","doi-asserted-by":"crossref","first-page":"3725","DOI":"10.1021\/acsnano.9b09834","volume":"14","author":"Hartman","year":"2020","journal-title":"ACS Nano"},{"key":"D6SC01014H\/cit35\/1","doi-asserted-by":"crossref","first-page":"4958","DOI":"10.1021\/jacs.3c14305","volume":"146","author":"Tian","year":"2024","journal-title":"J. Am. Chem. Soc."},{"key":"D6SC01014H\/cit36\/1","doi-asserted-by":"crossref","first-page":"187","DOI":"10.1038\/s41929-025-01295-9","volume":"8","author":"Filez","year":"2025","journal-title":"Nat. Catal."},{"key":"D6SC01014H\/cit37\/1","doi-asserted-by":"crossref","first-page":"21215","DOI":"10.1021\/acsami.5c00243","volume":"17","author":"Vogel","year":"2025","journal-title":"ACS Appl. Mater. Interfaces"},{"key":"D6SC01014H\/cit38\/1","doi-asserted-by":"crossref","first-page":"29656","DOI":"10.1021\/jacs.4c10395","volume":"146","author":"Elias","year":"2024","journal-title":"J. Am. Chem. Soc."},{"key":"D6SC01014H\/cit39\/1","doi-asserted-by":"crossref","first-page":"604","DOI":"10.1002\/tcr.201900090","volume":"20","author":"Wang","year":"2019","journal-title":"Chem. Rec."},{"key":"D6SC01014H\/cit40\/1","doi-asserted-by":"crossref","first-page":"10613","DOI":"10.1021\/cr5002436","volume":"114","author":"Sattler","year":"2014","journal-title":"Chem. Rev."},{"key":"D6SC01014H\/cit41\/1","doi-asserted-by":"crossref","first-page":"3315","DOI":"10.1039\/D0CS00814A","volume":"50","author":"Chen","year":"2021","journal-title":"Chem. Soc. Rev."},{"key":"D6SC01014H\/cit42\/1","doi-asserted-by":"crossref","first-page":"3095","DOI":"10.1039\/D2QI00653G","volume":"9","author":"Qu","year":"2022","journal-title":"Inorg. Chem. Front."},{"key":"D6SC01014H\/cit43\/1","doi-asserted-by":"crossref","first-page":"14737","DOI":"10.1021\/acscatal.3c04113","volume":"13","author":"Liu","year":"2023","journal-title":"ACS Catal."},{"key":"D6SC01014H\/cit44\/1","doi-asserted-by":"crossref","first-page":"1010","DOI":"10.1038\/nmat4941","volume":"16","author":"Grand","year":"2017","journal-title":"Nat. Mater."},{"key":"D6SC01014H\/cit45\/1","doi-asserted-by":"publisher","first-page":"e202504259","DOI":"10.1002\/anie.202504259","author":"Hou","year":"2025","journal-title":"Angew Chem. Int. Ed. Engl."},{"key":"D6SC01014H\/cit46\/1","doi-asserted-by":"crossref","first-page":"111537","DOI":"10.1016\/j.micromeso.2021.111537","volume":"329","author":"Yang","year":"2022","journal-title":"Microporous Mesoporous Mater."},{"key":"D6SC01014H\/cit47\/1","doi-asserted-by":"crossref","first-page":"133173","DOI":"10.1016\/j.cej.2021.133173","volume":"430","author":"Liu","year":"2022","journal-title":"Chem. Eng. J."},{"key":"D6SC01014H\/cit48\/1","doi-asserted-by":"crossref","first-page":"2298","DOI":"10.1016\/j.jssc.2008.05.010","volume":"181","author":"Jiang","year":"2008","journal-title":"J. Solid State Chem."},{"key":"D6SC01014H\/cit49\/1","doi-asserted-by":"crossref","first-page":"4619","DOI":"10.1021\/acs.energyfuels.6b00427","volume":"30","author":"Tang","year":"2016","journal-title":"Energy Fuels"},{"key":"D6SC01014H\/cit50\/1","doi-asserted-by":"crossref","first-page":"12127","DOI":"10.1021\/jacs.2c02636","volume":"144","author":"Hu","year":"2022","journal-title":"J. Am. Chem. Soc."},{"key":"D6SC01014H\/cit51\/1","doi-asserted-by":"crossref","first-page":"691","DOI":"10.1038\/s41586-025-09168-8","volume":"643","author":"Xu","year":"2025","journal-title":"Nature"},{"key":"D6SC01014H\/cit52\/1","doi-asserted-by":"crossref","first-page":"3313","DOI":"10.1039\/C5CS00935A","volume":"45","author":"Hartmann","year":"2016","journal-title":"Chem. Soc. Rev."},{"key":"D6SC01014H\/cit53\/1","doi-asserted-by":"crossref","first-page":"123912","DOI":"10.1016\/j.apcatb.2024.123912","volume":"350","author":"Zang","year":"2024","journal-title":"Appl. Catal. B Environ. Energy"},{"key":"D6SC01014H\/cit54\/1","doi-asserted-by":"crossref","first-page":"1780","DOI":"10.1038\/s41467-024-46216-9","volume":"15","author":"Du","year":"2024","journal-title":"Nat. Commun."},{"key":"D6SC01014H\/cit55\/1","doi-asserted-by":"crossref","first-page":"637","DOI":"10.1016\/j.chempr.2022.10.026","volume":"9","author":"Liu","year":"2023","journal-title":"Chem"},{"key":"D6SC01014H\/cit56\/1","doi-asserted-by":"crossref","first-page":"1923","DOI":"10.1021\/acscatal.8b03230","volume":"9","author":"Yan","year":"2019","journal-title":"ACS Catal."},{"key":"D6SC01014H\/cit57\/1","doi-asserted-by":"crossref","first-page":"48","DOI":"10.1016\/j.cattod.2005.11.009","volume":"113","author":"Guerrero-P\u00e9rez","year":"2006","journal-title":"Catal. Today"},{"key":"D6SC01014H\/cit58\/1","doi-asserted-by":"crossref","first-page":"77","DOI":"10.1016\/j.apcata.2017.12.025","volume":"552","author":"Koirala","year":"2018","journal-title":"Appl. Catal., A"},{"key":"D6SC01014H\/cit59\/1","doi-asserted-by":"crossref","first-page":"1640","DOI":"10.1039\/C9CP06199A","volume":"22","author":"Martinelli","year":"2020","journal-title":"Phys. Chem. Chem. Phys."},{"key":"D6SC01014H\/cit60\/1","doi-asserted-by":"crossref","first-page":"298","DOI":"10.1002\/jrs.5036","volume":"48","author":"Wang","year":"2017","journal-title":"J. Raman Spectrosc."},{"key":"D6SC01014H\/cit61\/1","doi-asserted-by":"crossref","first-page":"3164","DOI":"10.1038\/s41467-024-47406-1","volume":"15","author":"Hong","year":"2024","journal-title":"Nat. Commun."},{"key":"D6SC01014H\/cit62\/1","doi-asserted-by":"crossref","first-page":"183","DOI":"10.1016\/j.jcat.2019.05.030","volume":"375","author":"Lee","year":"2019","journal-title":"J. Catal."},{"key":"D6SC01014H\/cit63\/1","doi-asserted-by":"crossref","first-page":"1079","DOI":"10.1038\/s41467-020-14493-9","volume":"11","author":"Wang","year":"2020","journal-title":"Nat. Commun."},{"key":"D6SC01014H\/cit64\/1","doi-asserted-by":"crossref","first-page":"42110","DOI":"10.1021\/jacs.5c16367","volume":"147","author":"Zhang","year":"2025","journal-title":"J. Am. Chem. Soc."}],"container-title":["Chemical Science"],"original-title":[],"language":"en","link":[{"URL":"http:\/\/pubs.rsc.org\/en\/content\/articlepdf\/2026\/SC\/D6SC01014H","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,7,8]],"date-time":"2026-07-08T10:52:51Z","timestamp":1783507971000},"score":1,"resource":{"primary":{"URL":"https:\/\/xlink.rsc.org\/?DOI=D6SC01014H"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026]]},"references-count":64,"journal-issue":{"issue":"26","published-print":{"date-parts":[[2026,7,8]]}},"URL":"https:\/\/doi.org\/10.1039\/d6sc01014h","relation":{},"ISSN":["2041-6520","2041-6539"],"issn-type":[{"value":"2041-6520","type":"print"},{"value":"2041-6539","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026]]}}}