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Sci."],"abstract":"<jats:p>\n                    Pushing electrons uphill: Potassium and iridium react at high pressure to form K\n                    <jats:sub>5<\/jats:sub>\n                    Ir. Iridium in this phase extends the series of reduced 5d transition metals beyond the auride (Au\n                    <jats:sup>\u2013<\/jats:sup>\n                    ) and platinide (Pt\n                    <jats:sup>2\u2013<\/jats:sup>\n                    ) anions in semiconducting CsAu and Cs\n                    <jats:sub>2<\/jats:sub>\n                    Pt.\n                  <\/jats:p>","DOI":"10.1039\/d6sc03528k","type":"journal-article","created":{"date-parts":[[2026,9,25]],"date-time":"2026-09-25T10:41:08Z","timestamp":1790332868000},"update-policy":"https:\/\/doi.org\/10.1039\/rsc_crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["K\n                    <sub>5<\/sub>\n                    Ir: reduced iridium stabilized at high pressure"],"prefix":"10.1039","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-2391-1507","authenticated-orcid":false,"given":"Douglas H.","family":"Fabini","sequence":"first","affiliation":[{"name":"Department of Chemistry, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139, USA"},{"name":"PSI Center for Neutron and Muon Sciences, Paul Scherrer Institute, 5232 Villigen PSI, Switzerland"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2419-7090","authenticated-orcid":false,"given":"Romana-Iryna","family":"Martyniak","sequence":"additional","affiliation":[{"name":"Department of Chemistry, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139, USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Angelika D.","family":"Rosa","sequence":"additional","affiliation":[{"name":"European Synchrotron Radiation Facility, 38043 Grenoble Cedex 9, France"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Stella","family":"Chariton","sequence":"additional","affiliation":[{"name":"Center for Advanced Radiation Sources, University of Chicago, Argonne, Illinois 60439, USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Eric A.","family":"Riesel","sequence":"additional","affiliation":[{"name":"Department of Chemistry, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139, USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Emin","family":"Mijit","sequence":"additional","affiliation":[{"name":"European Synchrotron Radiation Facility, 38043 Grenoble Cedex 9, France"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-9270-2330","authenticated-orcid":false,"given":"Vitali B.","family":"Prakapenka","sequence":"additional","affiliation":[{"name":"Center for Advanced Radiation Sources, University of Chicago, Argonne, Illinois 60439, USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-2579-8835","authenticated-orcid":false,"given":"Danna E.","family":"Freedman","sequence":"additional","affiliation":[{"name":"Department of Chemistry, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139, USA"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"292","published-online":{"date-parts":[[2026]]},"reference":[{"key":"D6SC03528K\/cit1\/1","doi-asserted-by":"crossref","first-page":"1","DOI":"10.1103\/RevModPhys.18.1","volume":"18","author":"Bridgman","year":"1946","journal-title":"Rev. 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