{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,8,26]],"date-time":"2026-08-26T14:21:13Z","timestamp":1787754073542,"version":"build-2784847793"},"reference-count":61,"publisher":"Royal Society of Chemistry (RSC)","license":[{"start":{"date-parts":[[2026,8,24]],"date-time":"2026-08-24T00:00:00Z","timestamp":1787529600000},"content-version":"vor","delay-in-days":235,"URL":"http:\/\/creativecommons.org\/licenses\/by\/3.0\/"}],"funder":[{"DOI":"10.13039\/501100003995","name":"Natural Science Foundation of Anhui Province","doi-asserted-by":"publisher","award":["2308085J14"],"award-info":[{"award-number":["2308085J14"]}],"id":[{"id":"10.13039\/501100003995","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22271002"],"award-info":[{"award-number":["22271002"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22478005"],"award-info":[{"award-number":["22478005"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22508006"],"award-info":[{"award-number":["22508006"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22578006"],"award-info":[{"award-number":["22578006"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["rsc.org"],"crossmark-restriction":true},"short-container-title":["Chem. Sci."],"abstract":"<jats:p>Pd-catalyzed quadruple C\u2013H activation enables the construction of NMI-fused BODIPYs with extended \u03c0-conjugation, low-lying LUMO energy levels, high reducibility to form stable anion radicals, and favorable n-type charge transport properties.<\/jats:p>","DOI":"10.1039\/d6sc04883h","type":"journal-article","created":{"date-parts":[[2026,8,24]],"date-time":"2026-08-24T07:23:59Z","timestamp":1787556239000},"update-policy":"https:\/\/doi.org\/10.1039\/rsc_crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Naphthalimide-fused BODIPYs\n                    <i>via<\/i>\n                    one-pot quadruple C\u2013H activation: ultra-low LUMO n-type semiconductors with efficient near-infrared emission"],"prefix":"10.1039","author":[{"given":"Heng","family":"Li","sequence":"first","affiliation":[{"name":"Key Laboratory of Functional Molecular Solids of Ministry of Education, College of Chemistry and Materials Science, School of Physics and Electronic Information, Anhui Normal University, Wuhu, 241002, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Qi","family":"Zhang","sequence":"additional","affiliation":[{"name":"Key Laboratory of Functional Molecular Solids of Ministry of Education, College of Chemistry and Materials Science, School of Physics and Electronic Information, Anhui Normal University, Wuhu, 241002, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Rui","family":"Gan","sequence":"additional","affiliation":[{"name":"Key Laboratory of Functional Molecular Solids of Ministry of Education, College of Chemistry and Materials Science, School of Physics and Electronic Information, Anhui Normal University, Wuhu, 241002, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-0467-1974","authenticated-orcid":false,"given":"Fan","family":"Ni","sequence":"additional","affiliation":[{"name":"School of Instrument Science and Optoelectronic Engineering, Hefei University of Technology, Hefei, Anhui 230009, P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Qinghua","family":"Wu","sequence":"additional","affiliation":[{"name":"School of Pharmacy, Anhui University of Chinese Medicine, Hefei 230012, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Huiquan","family":"Zuo","sequence":"additional","affiliation":[{"name":"Key Laboratory of Functional Molecular Solids of Ministry of Education, College of Chemistry and Materials Science, School of Physics and Electronic Information, Anhui Normal University, Wuhu, 241002, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hua","family":"Wang","sequence":"additional","affiliation":[{"name":"Key Laboratory of Functional Molecular Solids of Ministry of Education, College of Chemistry and Materials Science, School of Physics and Electronic Information, Anhui Normal University, Wuhu, 241002, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-7234-4994","authenticated-orcid":false,"given":"Erhong","family":"Hao","sequence":"additional","affiliation":[{"name":"Key Laboratory of Functional Molecular Solids of Ministry of Education, College of Chemistry and Materials Science, School of Physics and Electronic Information, Anhui Normal University, Wuhu, 241002, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-3895-9642","authenticated-orcid":false,"given":"Lijuan","family":"Jiao","sequence":"additional","affiliation":[{"name":"Key Laboratory of Functional Molecular Solids of Ministry of Education, College of Chemistry and Materials Science, School of Physics and Electronic Information, Anhui Normal University, Wuhu, 241002, China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"292","published-online":{"date-parts":[[2026]]},"reference":[{"key":"D6SC04883H\/cit1\/1","doi-asserted-by":"crossref","first-page":"e202419318","DOI":"10.1002\/anie.202419318","volume":"64","author":"Wu","year":"2025","journal-title":"Angew. Chem., Int. Ed."},{"key":"D6SC04883H\/cit2\/1","doi-asserted-by":"crossref","first-page":"11663","DOI":"10.1021\/jacs.0c04096","volume":"142","author":"Hayakawa","year":"2020","journal-title":"J. Am. Chem. Soc."},{"key":"D6SC04883H\/cit3\/1","doi-asserted-by":"crossref","first-page":"16332","DOI":"10.1021\/jacs.4c05358","volume":"146","author":"Tanka","year":"2024","journal-title":"J. Am. Chem. Soc."},{"key":"D6SC04883H\/cit4\/1","doi-asserted-by":"crossref","first-page":"21705","DOI":"10.1039\/D5SC06197K","volume":"16","author":"Tan","year":"2025","journal-title":"Chem. Sci."},{"key":"D6SC04883H\/cit5\/1","doi-asserted-by":"crossref","first-page":"10277","DOI":"10.1021\/acs.chemmater.3c02106","volume":"35","author":"Chen","year":"2023","journal-title":"Chem. Mater."},{"key":"D6SC04883H\/cit6\/1","doi-asserted-by":"crossref","first-page":"2239","DOI":"10.1021\/jacs.4c11208","volume":"147","author":"Xie","year":"2025","journal-title":"J. Am. Chem. Soc."},{"key":"D6SC04883H\/cit7\/1","doi-asserted-by":"crossref","first-page":"1331","DOI":"10.1039\/D2CS00720G","volume":"52","author":"Zhang","year":"2023","journal-title":"Chem. Soc. Rev."},{"key":"D6SC04883H\/cit8\/1","doi-asserted-by":"crossref","first-page":"8099","DOI":"10.1039\/D1TC02048J","volume":"9","author":"Griggs","year":"2021","journal-title":"J. Mater. Chem. C"},{"key":"D6SC04883H\/cit9\/1","doi-asserted-by":"crossref","first-page":"3804","DOI":"10.1021\/acs.accounts.1c00381","volume":"54","author":"Feng","year":"2021","journal-title":"Acc. Chem. Res."},{"key":"D6SC04883H\/cit10\/1","doi-asserted-by":"crossref","first-page":"1600430","DOI":"10.1002\/aelm.201600430","volume":"3","author":"Li","year":"2017","journal-title":"Adv. Electron. Mater."},{"key":"D6SC04883H\/cit11\/1","doi-asserted-by":"crossref","first-page":"2395","DOI":"10.1039\/C8QO00423D","volume":"5","author":"Zhylitskaya","year":"2018","journal-title":"Org. Chem. Front."},{"key":"D6SC04883H\/cit12\/1","doi-asserted-by":"crossref","first-page":"268","DOI":"10.1002\/adma.201001402","volume":"23","author":"Zhan","year":"2011","journal-title":"Adv. Mater."},{"key":"D6SC04883H\/cit13\/1","doi-asserted-by":"crossref","first-page":"15908","DOI":"10.1002\/anie.202005376","volume":"59","author":"Pigulski","year":"2020","journal-title":"Angew. Chem., Int. Ed."},{"key":"D6SC04883H\/cit14\/1","doi-asserted-by":"crossref","first-page":"e202418520","DOI":"10.1002\/anie.202418520","volume":"64","author":"Zhang","year":"2025","journal-title":"Angew. Chem., Int. Ed."},{"key":"D6SC04883H\/cit15\/1","doi-asserted-by":"crossref","first-page":"284","DOI":"10.1039\/D2SC05409D","volume":"14","author":"Tian","year":"2023","journal-title":"Chem. Sci."},{"key":"D6SC04883H\/cit16\/1","doi-asserted-by":"crossref","first-page":"543","DOI":"10.1021\/acsmaterialslett.2c01132","volume":"5","author":"Labella","year":"2023","journal-title":"ACS Mater. Lett."},{"key":"D6SC04883H\/cit17\/1","doi-asserted-by":"crossref","first-page":"7595","DOI":"10.1002\/anie.201702889","volume":"56","author":"Seifert","year":"2017","journal-title":"Angew. Chem., Int. Ed."},{"key":"D6SC04883H\/cit18\/1","doi-asserted-by":"crossref","first-page":"11390","DOI":"10.1021\/jacs.6b07826","volume":"138","author":"Zhylitskaya","year":"2016","journal-title":"J. Am. Chem. Soc."},{"key":"D6SC04883H\/cit19\/1","doi-asserted-by":"crossref","first-page":"1938","DOI":"10.1039\/C3TC32315C","volume":"2","author":"Chen","year":"2014","journal-title":"J. Mater. Chem. C"},{"key":"D6SC04883H\/cit20\/1","doi-asserted-by":"crossref","first-page":"18640","DOI":"10.1039\/D4SC05938G","volume":"15","author":"Kumar","year":"2024","journal-title":"Chem. Sci."},{"key":"D6SC04883H\/cit21\/1","doi-asserted-by":"crossref","first-page":"6390","DOI":"10.1002\/anie.201601433","volume":"55","author":"Seifert","year":"2016","journal-title":"Angew. Chem., Int. Ed."},{"key":"D6SC04883H\/cit22\/1","doi-asserted-by":"crossref","first-page":"5718","DOI":"10.1021\/jacs.2c00142","volume":"144","author":"Pigulski","year":"2022","journal-title":"J. Am. Chem. Soc."},{"key":"D6SC04883H\/cit23\/1","doi-asserted-by":"crossref","first-page":"457","DOI":"10.1038\/s41557-021-00861-5","volume":"14","author":"Mahl","year":"2022","journal-title":"Nat. Chem."},{"key":"D6SC04883H\/cit24\/1","doi-asserted-by":"crossref","first-page":"9886","DOI":"10.1021\/jacs.3c03441","volume":"145","author":"Tian","year":"2023","journal-title":"J. Am. Chem. Soc."},{"key":"D6SC04883H\/cit25\/1","doi-asserted-by":"crossref","first-page":"4891","DOI":"10.1021\/cr078381n","volume":"107","author":"Loudet","year":"2007","journal-title":"Chem. Rev."},{"key":"D6SC04883H\/cit26\/1","doi-asserted-by":"crossref","first-page":"1184","DOI":"10.1002\/anie.200702070","volume":"47","author":"Ulrich","year":"2008","journal-title":"Angew. Chem., Int. Ed."},{"key":"D6SC04883H\/cit27\/1","doi-asserted-by":"crossref","first-page":"213024","DOI":"10.1016\/j.ccr.2019.213024","volume":"399","author":"Boens","year":"2019","journal-title":"Coord. Chem. Rev."},{"key":"D6SC04883H\/cit28\/1","doi-asserted-by":"crossref","first-page":"218041","DOI":"10.1016\/j.ccr.2026.218041","volume":"562","author":"Wang","year":"2026","journal-title":"Coord. Chem. Rev."},{"key":"D6SC04883H\/cit29\/1","doi-asserted-by":"crossref","first-page":"202509416","DOI":"10.1002\/anie.202509416","volume":"64","author":"Teng","year":"2025","journal-title":"Angew. Chem., Int. Ed."},{"key":"D6SC04883H\/cit30\/1","doi-asserted-by":"crossref","first-page":"21992","DOI":"10.1021\/jacs.2c08947","volume":"144","author":"Gong","year":"2022","journal-title":"J. Am. Chem. Soc."},{"key":"D6SC04883H\/cit31\/1","doi-asserted-by":"crossref","first-page":"3309","DOI":"10.1021\/acs.orglett.6c00416","volume":"28","author":"Zhang","year":"2026","journal-title":"Org. Lett."},{"key":"D6SC04883H\/cit32\/1","doi-asserted-by":"crossref","first-page":"68","DOI":"10.1021\/acs.orglett.4c03890","volume":"27","author":"Rottger","year":"2024","journal-title":"Org. Lett."},{"key":"D6SC04883H\/cit33\/1","doi-asserted-by":"crossref","first-page":"747","DOI":"10.1002\/anie.202012335","volume":"60","author":"Patra","year":"2021","journal-title":"Angew. Chem., Int. Ed."},{"key":"D6SC04883H\/cit34\/1","doi-asserted-by":"crossref","first-page":"e202519612","DOI":"10.1002\/anie.202519612","volume":"64","author":"Sugino","year":"2025","journal-title":"Angew. Chem., Int. Ed."},{"key":"D6SC04883H\/cit35\/1","doi-asserted-by":"crossref","first-page":"866","DOI":"10.1021\/ol2033916","volume":"14","author":"Hayashi","year":"2012","journal-title":"Org. Lett."},{"key":"D6SC04883H\/cit36\/1","doi-asserted-by":"crossref","first-page":"e26011","DOI":"10.1002\/anie.202526011","volume":"65","author":"Ceugniet","year":"2026","journal-title":"Angew. Chem., Int. Ed."},{"key":"D6SC04883H\/cit37\/1","doi-asserted-by":"crossref","first-page":"2893","DOI":"10.1021\/acs.orglett.7b01133","volume":"19","author":"Sheng","year":"2017","journal-title":"Org. Lett."},{"key":"D6SC04883H\/cit38\/1","doi-asserted-by":"crossref","first-page":"4853","DOI":"10.1002\/chem.200400173","volume":"10","author":"Shen","year":"2004","journal-title":"Chem.\u2013Eur. J."},{"key":"D6SC04883H\/cit39\/1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cclet.2026.112693","author":"He","year":"2026","journal-title":"Chin. Chem. Lett."},{"key":"D6SC04883H\/cit40\/1","doi-asserted-by":"crossref","first-page":"e202200130","DOI":"10.1002\/chem.202200130","volume":"28","author":"Ceugniet","year":"2022","journal-title":"Chem.\u2013Eur. J."},{"key":"D6SC04883H\/cit41\/1","doi-asserted-by":"crossref","first-page":"45441","DOI":"10.1021\/jacs.5c15893","volume":"147","author":"Wang","year":"2025","journal-title":"J. Am. Chem. Soc."},{"key":"D6SC04883H\/cit42\/1","doi-asserted-by":"crossref","first-page":"2203","DOI":"10.1021\/acs.orglett.5c00311","volume":"27","author":"Zuo","year":"2025","journal-title":"Org. Lett."},{"key":"D6SC04883H\/cit43\/1","doi-asserted-by":"crossref","first-page":"9925","DOI":"10.1039\/C8TC03138J","volume":"6","author":"Huaulme","year":"2018","journal-title":"J. Mater. Chem. C"},{"key":"D6SC04883H\/cit44\/1","doi-asserted-by":"crossref","first-page":"404","DOI":"10.1021\/acsmaterialslett.9b00221","volume":"1","author":"Huang","year":"2019","journal-title":"ACS Mater. Lett."},{"key":"D6SC04883H\/cit45\/1","doi-asserted-by":"crossref","first-page":"9693","DOI":"10.1021\/acs.joc.9b01425","volume":"84","author":"Miao","year":"2019","journal-title":"J. Org. Chem."},{"key":"D6SC04883H\/cit46\/1","doi-asserted-by":"crossref","first-page":"4135","DOI":"10.1039\/D0OB00790K","volume":"18","author":"Wang","year":"2020","journal-title":"Org. Biomol. Chem."},{"key":"D6SC04883H\/cit47\/1","doi-asserted-by":"crossref","first-page":"9129","DOI":"10.1039\/c2cc34549h","volume":"48","author":"Verbelen","year":"2012","journal-title":"Chem. Commun."},{"key":"D6SC04883H\/cit48\/1","doi-asserted-by":"crossref","first-page":"e202300449","DOI":"10.1002\/chem.202300449","volume":"29","author":"Miao","year":"2023","journal-title":"Chem.\u2013Eur. J."},{"key":"D6SC04883H\/cit49\/1","doi-asserted-by":"crossref","first-page":"3267","DOI":"10.1039\/D5SC08201C","volume":"17","author":"Pan","year":"2026","journal-title":"Chem. Sci."},{"key":"D6SC04883H\/cit50\/1","doi-asserted-by":"crossref","first-page":"15104","DOI":"10.1021\/jacs.7b08176","volume":"139","author":"Patalag","year":"2017","journal-title":"J. Am. Chem. Soc."},{"key":"D6SC04883H\/cit51\/1","doi-asserted-by":"crossref","first-page":"4557","DOI":"10.1021\/acs.orglett.2c01659","volume":"24","author":"Yu","year":"2022","journal-title":"Org. Lett."},{"key":"D6SC04883H\/cit52\/1","doi-asserted-by":"crossref","first-page":"2028","DOI":"10.1039\/c3tc32207f","volume":"2","author":"Huang","year":"2014","journal-title":"J. Mater. Chem. C"},{"key":"D6SC04883H\/cit53\/1","doi-asserted-by":"crossref","first-page":"613","DOI":"10.1002\/adma.201104447","volume":"24","author":"Li","year":"2012","journal-title":"Adv. Mater."},{"key":"D6SC04883H\/cit54\/1","doi-asserted-by":"crossref","first-page":"e202207486","DOI":"10.1002\/anie.202207486","volume":"61","author":"Kumar","year":"2022","journal-title":"Angew. Chem., Int. Ed."},{"key":"D6SC04883H\/cit55\/1","doi-asserted-by":"crossref","first-page":"282","DOI":"10.1021\/acs.orglett.2c04173","volume":"25","author":"Odajima","year":"2023","journal-title":"Org. Lett."},{"key":"D6SC04883H\/cit56\/1","doi-asserted-by":"crossref","first-page":"877","DOI":"10.1021\/cr940053x","volume":"96","author":"Connelly","year":"1996","journal-title":"Chem. Rev."},{"key":"D6SC04883H\/cit57\/1","doi-asserted-by":"crossref","first-page":"4030","DOI":"10.1039\/C7TC05900K","volume":"6","author":"Squeo","year":"2018","journal-title":"J. Mater. Chem. C"},{"key":"D6SC04883H\/cit58\/1","doi-asserted-by":"crossref","first-page":"26199","DOI":"10.1021\/acs.jpcc.6b08225","volume":"120","author":"Singh","year":"2016","journal-title":"J. Phys. Chem. C"},{"key":"D6SC04883H\/cit59\/1","doi-asserted-by":"crossref","first-page":"4327","DOI":"10.1002\/adma.201300318","volume":"25","author":"Usta","year":"2013","journal-title":"Adv. Mater."},{"key":"D6SC04883H\/cit60\/1","doi-asserted-by":"crossref","first-page":"185","DOI":"10.1021\/acs.orglett.9b04142","volume":"22","author":"Sheng","year":"2020","journal-title":"Org. Lett."},{"key":"D6SC04883H\/cit61\/1","doi-asserted-by":"publisher","year":"2026","unstructured":"CCDC 2553505: Experimental Crystal Structure Determination ,  2026 ,  10.5517\/ccdc.csd.cc2rq44s","DOI":"10.5517\/ccdc.csd.cc2rq44s"}],"container-title":["Chemical Science"],"original-title":[],"language":"en","link":[{"URL":"http:\/\/pubs.rsc.org\/SC\/article-pdf\/doi\/10.1039\/D6SC04883H\/0\/D6SC04883H.pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,8,26]],"date-time":"2026-08-26T13:22:41Z","timestamp":1787750561000},"score":1,"resource":{"primary":{"URL":"http:\/\/pubs.rsc.org\/SC\/article-lookup\/doi\/10.1039\/D6SC04883H"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026]]},"references-count":61,"URL":"https:\/\/doi.org\/10.1039\/d6sc04883h","relation":{},"ISSN":["2041-6520","2041-6539"],"issn-type":[{"value":"2041-6520","type":"print"},{"value":"2041-6539","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026]]}}}