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Sci."],"abstract":"<jats:p>\n                    Two new arsenides, CaM\n                    <jats:sub>3<\/jats:sub>\n                    Si\n                    <jats:sub>4<\/jats:sub>\n                    As\n                    <jats:sub>11<\/jats:sub>\n                    (M = Ga, In), featuring quasi-T\n                    <jats:sub>3<\/jats:sub>\n                    M\n                    <jats:sub>3<\/jats:sub>\n                    Si\n                    <jats:sub>4<\/jats:sub>\n                    As\n                    <jats:sub>11<\/jats:sub>\n                    [As\n                    <jats:sub>2<\/jats:sub>\n                    ]\n                    <jats:sub>6<\/jats:sub>\n                    supertetrahedra with [As\n                    <jats:sub>2<\/jats:sub>\n                    ] motifs, exhibit strong SHG responses, wide band gaps, broad IR transparency, and large birefringence.\n                  <\/jats:p>","DOI":"10.1039\/d6sc04910a","type":"journal-article","created":{"date-parts":[[2026,9,10]],"date-time":"2026-09-10T10:03:11Z","timestamp":1789034591000},"update-policy":"https:\/\/doi.org\/10.1039\/rsc_crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["CaM\n                    <sub>3<\/sub>\n                    Si\n                    <sub>4<\/sub>\n                    As\n                    <sub>11<\/sub>\n                    (M = Ga, In): arsenide infrared nonlinear optical crystals enforced by novel [As\n                    <sub>2<\/sub>\n                    ] linear motifs"],"prefix":"10.1039","author":[{"given":"Shusen","family":"Yang","sequence":"first","affiliation":[{"name":"State Key Laboratory of Crystal Materials, Tianjin Key Laboratory of Functional Crystal Materials, Institute of Functional Crystal, College of Materials Science and Engineering, Tianjin University of Technology, Tianjin 300384, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Qichao","family":"Zhao","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Crystal Materials, Tianjin Key Laboratory of Functional Crystal Materials, Institute of Functional Crystal, College of Materials Science and Engineering, Tianjin University of Technology, Tianjin 300384, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xuemei","family":"Shi","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Crystal Materials, Tianjin Key Laboratory of Functional Crystal Materials, Institute of Functional Crystal, College of Materials Science and Engineering, Tianjin University of Technology, Tianjin 300384, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-2092-8020","authenticated-orcid":false,"given":"Guang","family":"Peng","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Crystal Materials, Tianjin Key Laboratory of Functional Crystal Materials, Institute of Functional Crystal, College of Materials Science and Engineering, Tianjin University of Technology, Tianjin 300384, China"},{"name":"Tianjin Key Laboratory of Quantum Optics and Intelligent Photonics, School of Science, Tianjin University of Technology, Tianjin 300384, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-3679-4047","authenticated-orcid":false,"given":"Ning","family":"Ye","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Crystal Materials, Tianjin Key Laboratory of Functional Crystal Materials, Institute of Functional Crystal, College of Materials Science and Engineering, Tianjin University of Technology, Tianjin 300384, China"},{"name":"Tianjin Key Laboratory of Quantum Optics and Intelligent Photonics, School of Science, Tianjin University of Technology, Tianjin 300384, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-3940-9968","authenticated-orcid":false,"given":"Jindong","family":"Chen","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Crystal Materials, Tianjin Key Laboratory of Functional Crystal Materials, Institute of Functional Crystal, College of Materials Science and Engineering, Tianjin University of Technology, Tianjin 300384, China"},{"name":"Tianjin Key Laboratory of Quantum Optics and Intelligent Photonics, School of Science, Tianjin University of Technology, Tianjin 300384, China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"292","published-online":{"date-parts":[[2026]]},"reference":[{"issue":"6","key":"D6SC04910A\/cit1\/1","doi-asserted-by":"crossref","first-page":"702","DOI":"10.1364\/OPTICA.6.000702","volume":"6","author":"Junaid","year":"2019","journal-title":"Optica"},{"issue":"1","key":"D6SC04910A\/cit2\/1","doi-asserted-by":"crossref","first-page":"72","DOI":"10.1038\/s41377-025-02142-z","volume":"15","author":"Hong","year":"2026","journal-title":"Light:Sci. 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