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Sci."],"abstract":"<jats:p>Without a vanadium alkylidyne, and using a dianionic allene bound to vanadium, we demonstrate how vanadatetrahedranes and vanadacyclobutadienes can be accessed and how these species can interconvert.<\/jats:p>","DOI":"10.1039\/d6sc05321a","type":"journal-article","created":{"date-parts":[[2026,8,6]],"date-time":"2026-08-06T19:03:56Z","timestamp":1786043036000},"page":"19541-19562","update-policy":"https:\/\/doi.org\/10.1039\/rsc_crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["A dianionic allene bound to vanadium(\n                    <scp>iii<\/scp>\n                    ) enables interconversion between vanadatetrahedranes, vanadacyclobutadienes and deprotiovanadacyclobutadienes"],"prefix":"10.1039","volume":"17","author":[{"ORCID":"https:\/\/orcid.org\/0009-0004-3580-7610","authenticated-orcid":false,"given":"John B.","family":"Russell","sequence":"first","affiliation":[{"name":"Department of Chemistry, University of Pennsylvania, Philadelphia, Pennsylvania 19104, USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0001-3424-3401","authenticated-orcid":false,"given":"Dylan P.","family":"Grigas","sequence":"additional","affiliation":[{"name":"Department of Chemistry, University of Pennsylvania, Philadelphia, Pennsylvania 19104, USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-6889-9652","authenticated-orcid":false,"given":"Eva","family":"K\u00f6rber","sequence":"additional","affiliation":[{"name":"Department of Chemistry & Pharmacy, Inorganic Chemistry, Friedrich-Alexander-Universit\u00e4t Erlangen-N\u00fcrnberg (FAU), 91058 Erlangen, Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0009-7686-3850","authenticated-orcid":false,"given":"Alexandra M.","family":"Bacon","sequence":"additional","affiliation":[{"name":"Department of Chemistry, University of Pennsylvania, Philadelphia, Pennsylvania 19104, USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-4790-6980","authenticated-orcid":false,"given":"Michael R.","family":"Gau","sequence":"additional","affiliation":[{"name":"Department of Chemistry, University of Pennsylvania, Philadelphia, Pennsylvania 19104, USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-7844-2998","authenticated-orcid":false,"given":"Karsten","family":"Meyer","sequence":"additional","affiliation":[{"name":"Department of Chemistry & Pharmacy, Inorganic Chemistry, Friedrich-Alexander-Universit\u00e4t Erlangen-N\u00fcrnberg (FAU), 91058 Erlangen, Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-1119-0343","authenticated-orcid":false,"given":"Fabian","family":"Rei\u00df","sequence":"additional","affiliation":[{"name":"Leibniz Institute for Catalysis (LIKAT), Albert-Einstein-Str. 29a, 18059 Rostock, Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-2416-8874","authenticated-orcid":false,"given":"Torsten","family":"Beweries","sequence":"additional","affiliation":[{"name":"Leibniz Institute for Catalysis (LIKAT), Albert-Einstein-Str. 29a, 18059 Rostock, Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-8205-7868","authenticated-orcid":false,"given":"Daniel J.","family":"Mindiola","sequence":"additional","affiliation":[{"name":"Department of Chemistry, University of Pennsylvania, Philadelphia, Pennsylvania 19104, USA"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"292","published-online":{"date-parts":[[2026]]},"reference":[{"key":"D6SC05321A\/cit1\/1","doi-asserted-by":"crossref","first-page":"604","DOI":"10.1021\/ic50014a038","volume":"3","author":"Gowling","year":"1964","journal-title":"Inorg. 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