{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,5]],"date-time":"2026-10-05T10:56:35Z","timestamp":1791197795115,"version":"4.1.0"},"reference-count":70,"publisher":"Royal Society of Chemistry (RSC)","license":[{"start":{"date-parts":[[2026,9,21]],"date-time":"2026-09-21T00:00:00Z","timestamp":1789948800000},"content-version":"vor","delay-in-days":263,"URL":"http:\/\/creativecommons.org\/licenses\/by\/3.0\/"}],"funder":[{"DOI":"10.13039\/501100001659","name":"Deutsche Forschungsgemeinschaft","doi-asserted-by":"publisher","award":["HA 3218\/12-1"],"award-info":[{"award-number":["HA 3218\/12-1"]}],"id":[{"id":"10.13039\/501100001659","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100003130","name":"Fonds Wetenschappelijk Onderzoek","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100003130","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["rsc.org"],"crossmark-restriction":true},"short-container-title":["Chem. Sci."],"abstract":"<jats:p>\n                    A complex featuring an unsupported 2c\u20132e Mg\u2013Yb bond and formal oxidation states Mg\n                    <jats:sup>0<\/jats:sup>\n                    \u2013Yb\n                    <jats:sup>II<\/jats:sup>\n                    was isolated. The properties and very high reactivity of the polarized Mg\n                    <jats:sup>\n                      <jats:italic>\u03b4<\/jats:italic>\n                      \u2212\n                    <\/jats:sup>\n                    \u2013Yb\n                    <jats:sup>\n                      <jats:italic>\u03b4<\/jats:italic>\n                      +\n                    <\/jats:sup>\n                    bond are compared with those of a related Mg\u2013Ca complex.\n                  <\/jats:p>","DOI":"10.1039\/d6sc05592c","type":"journal-article","created":{"date-parts":[[2026,9,21]],"date-time":"2026-09-21T08:43:02Z","timestamp":1789980182000},"update-policy":"https:\/\/doi.org\/10.1039\/rsc_crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Comparison of MgYb and Mg\u2013Ca bonding: structures, electronic analyses and reactivities"],"prefix":"10.1039","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-9103-780X","authenticated-orcid":false,"given":"Sandeep Kumar","family":"Thakur","sequence":"first","affiliation":[{"name":"Inorganic and Organometallic Chemistry, Universit\u00e4t Erlangen-N\u00fcrnberg, Egerlandstrasse 1, Erlangen 91058, Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-9768-125X","authenticated-orcid":false,"given":"Tanuja","family":"Tewari","sequence":"additional","affiliation":[{"name":"Inorganic and Organometallic Chemistry, Universit\u00e4t Erlangen-N\u00fcrnberg, Egerlandstrasse 1, Erlangen 91058, Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4688-4529","authenticated-orcid":false,"given":"Nil","family":"Roig","sequence":"additional","affiliation":[{"name":"Institut de Qu\u00edmica Computacional i Cat\u00e0lisi (IQCC) and Departament de Qu\u00edmica, Facultat de Ci\u00e8ncies, Universitat de Girona (UdG), C\/Maria Aur\u00e8lia Capmany 69, Girona 17003, Catalonia, Spain"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-2895-4979","authenticated-orcid":false,"given":"Jens","family":"Langer","sequence":"additional","affiliation":[{"name":"Inorganic and Organometallic Chemistry, Universit\u00e4t Erlangen-N\u00fcrnberg, Egerlandstrasse 1, Erlangen 91058, Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-7076-2305","authenticated-orcid":false,"given":"Mercedes","family":"Alonso","sequence":"additional","affiliation":[{"name":"Eenheid Algemene Chemie (ALGC), Vrije Universiteit Brussel (VUB), Brussels 1050, Belgium"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-3997-1440","authenticated-orcid":false,"given":"Sjoerd","family":"Harder","sequence":"additional","affiliation":[{"name":"Inorganic and Organometallic Chemistry, Universit\u00e4t Erlangen-N\u00fcrnberg, Egerlandstrasse 1, Erlangen 91058, Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"292","published-online":{"date-parts":[[2026]]},"reference":[{"key":"D6SC05592C\/cit1\/1","volume-title":"Multiple Bonds Between Metal Atoms","year":"2005","unstructured":"Multiple Bonds Between Metal Atoms , ed.  F. A. Cotton ,  C. A. Murillo  and  R. A. Walton ,  Springer US ,  Boston, MA ,  2005"},{"key":"D6SC05592C\/cit2\/1","volume-title":"Molecular Metal-Metal Bonds: Compounds, Synthesis, Properties","year":"2015","unstructured":"Molecular Metal-Metal Bonds: Compounds, Synthesis, Properties , ed.  S. T. Liddle ,  Wiley , 1st edn,  2015"},{"key":"D6SC05592C\/cit3\/1","doi-asserted-by":"crossref","first-page":"2981","DOI":"10.1021\/acs.accounts.9b00373","volume":"52","author":"Liu","year":"2019","journal-title":"Acc. Chem. Res."},{"key":"D6SC05592C\/cit4\/1","doi-asserted-by":"crossref","first-page":"198","DOI":"10.1126\/science.abl5470","volume":"375","author":"Gould","year":"2022","journal-title":"Science"},{"key":"D6SC05592C\/cit5\/1","doi-asserted-by":"crossref","first-page":"18714","DOI":"10.1021\/jacs.4c06250","volume":"146","author":"Kwon","year":"2024","journal-title":"J. Am. Chem. Soc."},{"key":"D6SC05592C\/cit6\/1","doi-asserted-by":"crossref","first-page":"72","DOI":"10.1038\/s41586-021-03888-3","volume":"598","author":"Boronski","year":"2021","journal-title":"Nature"},{"key":"D6SC05592C\/cit7\/1","doi-asserted-by":"crossref","first-page":"223","DOI":"10.1146\/annurev.ms.23.080193.001255","volume":"23","author":"Wagner","year":"1993","journal-title":"Annu. Rev. Mater. Sci."},{"key":"D6SC05592C\/cit8\/1","doi-asserted-by":"crossref","first-page":"3934","DOI":"10.1021\/jacs.1c00115","volume":"143","author":"Riedel","year":"2021","journal-title":"J. Am. Chem. Soc."},{"key":"D6SC05592C\/cit9\/1","doi-asserted-by":"crossref","first-page":"1754","DOI":"10.1126\/science.1150856","volume":"318","author":"Green","year":"2007","journal-title":"Science"},{"key":"D6SC05592C\/cit10\/1","doi-asserted-by":"crossref","first-page":"1147","DOI":"10.1126\/science.adh4419","volume":"380","author":"Boronski","year":"2023","journal-title":"Science"},{"key":"D6SC05592C\/cit11\/1","doi-asserted-by":"crossref","first-page":"1125","DOI":"10.1126\/science.abf2374","volume":"371","author":"R\u00f6sch","year":"2021","journal-title":"Science"},{"key":"D6SC05592C\/cit12\/1","doi-asserted-by":"crossref","first-page":"12665","DOI":"10.1039\/D2CC04841H","volume":"58","author":"Mondal","year":"2022","journal-title":"Chem. Commun."},{"key":"D6SC05592C\/cit13\/1","doi-asserted-by":"crossref","first-page":"e202506989","DOI":"10.1002\/anie.202506989","volume":"64","author":"Morasch","year":"2025","journal-title":"Angew. Chem., Int. Ed."},{"key":"D6SC05592C\/cit14\/1","doi-asserted-by":"crossref","first-page":"0059","DOI":"10.1038\/s41570-017-0059","volume":"1","author":"Jones","year":"2017","journal-title":"Nat. Rev. Chem."},{"key":"D6SC05592C\/cit15\/1","doi-asserted-by":"crossref","first-page":"9354","DOI":"10.1039\/D1CC04147A","volume":"57","author":"R\u00f6sch","year":"2021","journal-title":"Chem. Commun."},{"key":"D6SC05592C\/cit16\/1","doi-asserted-by":"crossref","first-page":"439","DOI":"10.1038\/s44160-022-00077-6","volume":"1","author":"Freeman","year":"2022","journal-title":"Nat. Synth."},{"key":"D6SC05592C\/cit17\/1","doi-asserted-by":"crossref","first-page":"66","DOI":"10.1016\/B978-0-12-409547-2.14705-5","volume-title":"Comprehensive Coordination Chemistry III","author":"Schulz","year":"2021","unstructured":"S.Schulz , in  Comprehensive Coordination Chemistry III ,  Elsevier ,  2021 ,  pp. 66\u2013105"},{"key":"D6SC05592C\/cit18\/1","doi-asserted-by":"crossref","first-page":"717","DOI":"10.1038\/s41586-021-03401-w","volume":"592","author":"R\u00f6sch","year":"2021","journal-title":"Nature"},{"key":"D6SC05592C\/cit19\/1","doi-asserted-by":"crossref","first-page":"10917","DOI":"10.1039\/D6SC01992G","volume":"17","author":"Jiang","year":"2026","journal-title":"Chem. Sci."},{"key":"D6SC05592C\/cit20\/1","doi-asserted-by":"crossref","first-page":"368","DOI":"10.1038\/s44160-023-00451-y","volume":"3","author":"Mai","year":"2023","journal-title":"Nat. Synth."},{"key":"D6SC05592C\/cit21\/1","doi-asserted-by":"crossref","first-page":"2714","DOI":"10.1002\/anie.200353557","volume":"43","author":"Harder","year":"2004","journal-title":"Angew. Chem., Int. Ed."},{"key":"D6SC05592C\/cit22\/1","doi-asserted-by":"crossref","first-page":"12555","DOI":"10.1021\/jacs.4c17853","volume":"147","author":"Thakur","year":"2025","journal-title":"J. Am. Chem. Soc."},{"key":"D6SC05592C\/cit23\/1","doi-asserted-by":"crossref","first-page":"127","DOI":"10.1016\/0022-328X(95)00508-N","volume":"500","author":"Green","year":"1995","journal-title":"J. Organomet. Chem."},{"key":"D6SC05592C\/cit24\/1","doi-asserted-by":"crossref","first-page":"807","DOI":"10.1021\/ed400504f","volume":"91","author":"Green","year":"2014","journal-title":"J. Chem. Educ."},{"key":"D6SC05592C\/cit25\/1","doi-asserted-by":"crossref","first-page":"927","DOI":"10.1039\/B614165J","author":"Wiecko","year":"2007","journal-title":"Chem. Commun."},{"key":"D6SC05592C\/cit26\/1","doi-asserted-by":"crossref","first-page":"1937","DOI":"10.1021\/cm0111130","volume":"14","author":"Ihanus","year":"2002","journal-title":"Chem. Mater."},{"key":"D6SC05592C\/cit27\/1","doi-asserted-by":"crossref","first-page":"e202201897","DOI":"10.1002\/chem.202201897","volume":"28","author":"Sch\u00fcler","year":"2022","journal-title":"Chem.\u2013Eur. J."},{"key":"D6SC05592C\/cit28\/1","doi-asserted-by":"crossref","first-page":"e202408422","DOI":"10.1002\/anie.202408422","volume":"63","author":"Berthold","year":"2024","journal-title":"Angew. Chem., Int. Ed."},{"key":"D6SC05592C\/cit29\/1","doi-asserted-by":"crossref","first-page":"e202518538","DOI":"10.1002\/anie.202518538","volume":"64","author":"Stecher","year":"2025","journal-title":"Angew. Chem., Int. Ed."},{"key":"D6SC05592C\/cit30\/1","doi-asserted-by":"crossref","first-page":"e25777","DOI":"10.1002\/anie.202525777","volume":"65","author":"Thakur","year":"2026","journal-title":"Angew. Chem., Int. Ed."},{"key":"D6SC05592C\/cit31\/1","doi-asserted-by":"crossref","first-page":"5867","DOI":"10.1021\/jp000288e","volume":"104","author":"Murphy","year":"2000","journal-title":"J. Phys. Chem. A"},{"key":"D6SC05592C\/cit32\/1","doi-asserted-by":"crossref","first-page":"2832","DOI":"10.1039\/b801115j","author":"Cordero","year":"2008","journal-title":"Dalton Trans."},{"key":"D6SC05592C\/cit33\/1","doi-asserted-by":"crossref","first-page":"11402","DOI":"10.1039\/D0CC05200K","volume":"56","author":"R\u00f6sch","year":"2020","journal-title":"Chem. Commun."},{"key":"D6SC05592C\/cit34\/1","doi-asserted-by":"crossref","first-page":"3444","DOI":"10.1002\/anie.201108662","volume":"51","author":"Basalov","year":"2012","journal-title":"Angew. Chem., Int. Ed."},{"key":"D6SC05592C\/cit35\/1","doi-asserted-by":"crossref","first-page":"3350","DOI":"10.1021\/acs.organomet.6b00566","volume":"35","author":"Causero","year":"2016","journal-title":"Organometallics"},{"key":"D6SC05592C\/cit36\/1","doi-asserted-by":"crossref","first-page":"5320","DOI":"10.1021\/ic700403d","volume":"46","author":"Ruspic","year":"2007","journal-title":"Inorg. Chem."},{"key":"D6SC05592C\/cit37\/1","doi-asserted-by":"crossref","first-page":"3147","DOI":"10.1038\/s41467-021-23444-x","volume":"12","author":"Richardson","year":"2021","journal-title":"Nat. Commun."},{"key":"D6SC05592C\/cit38\/1","doi-asserted-by":"crossref","first-page":"16492","DOI":"10.1002\/anie.202103250","volume":"60","author":"Friedrich","year":"2021","journal-title":"Angew. Chem., Int. Ed."},{"key":"D6SC05592C\/cit39\/1","doi-asserted-by":"crossref","first-page":"e202405229","DOI":"10.1002\/anie.202405229","volume":"63","author":"Thakur","year":"2024","journal-title":"Angew. Chem., Int. Ed."},{"key":"D6SC05592C\/cit40\/1","doi-asserted-by":"crossref","first-page":"10525","DOI":"10.1002\/anie.201802745","volume":"57","author":"Postils","year":"2018","journal-title":"Angew. Chem., Int. Ed."},{"key":"D6SC05592C\/cit41\/1","doi-asserted-by":"crossref","first-page":"384","DOI":"10.1039\/D2SC05769G","volume":"14","author":"Gimferrer","year":"2023","journal-title":"Chem. Sci."},{"key":"D6SC05592C\/cit42\/1","doi-asserted-by":"crossref","first-page":"8764","DOI":"10.1021\/jacs.9b04085","volume":"141","author":"Yuvaraj","year":"2019","journal-title":"J. Am. Chem. Soc."},{"key":"D6SC05592C\/cit43\/1","doi-asserted-by":"crossref","first-page":"4383","DOI":"10.1039\/c3sc52242c","volume":"4","author":"Lalrempuia","year":"2013","journal-title":"Chem. Sci."},{"key":"D6SC05592C\/cit44\/1","doi-asserted-by":"crossref","first-page":"e202500080","DOI":"10.1002\/ceur.202500080","volume":"3","author":"Thum","year":"2025","journal-title":"ChemistryEurope"},{"key":"D6SC05592C\/cit45\/1","doi-asserted-by":"crossref","first-page":"5247","DOI":"10.1021\/jacs.4c16041","volume":"147","author":"Thompson","year":"2025","journal-title":"J. Am. Chem. Soc."},{"key":"D6SC05592C\/cit46\/1","doi-asserted-by":"crossref","first-page":"12127","DOI":"10.1039\/D5CC03340C","volume":"61","author":"Thum","year":"2025","journal-title":"Chem. Commun."},{"key":"D6SC05592C\/cit47\/1","doi-asserted-by":"crossref","first-page":"18190","DOI":"10.1021\/jacs.7b11368","volume":"139","author":"Boutland","year":"2017","journal-title":"J. Am. Chem. Soc."},{"key":"D6SC05592C\/cit48\/1","doi-asserted-by":"crossref","first-page":"3533","DOI":"10.1021\/ja00905a001","volume":"85","author":"Pearson","year":"1963","journal-title":"J. Am. Chem. Soc."},{"key":"D6SC05592C\/cit49\/1","doi-asserted-by":"crossref","first-page":"3208","DOI":"10.1039\/C9SC00200F","volume":"10","author":"Dange","year":"2019","journal-title":"Chem. Sci."},{"key":"D6SC05592C\/cit50\/1","doi-asserted-by":"crossref","first-page":"10386","DOI":"10.1039\/C7CC05792J","volume":"53","author":"Causero","year":"2017","journal-title":"Chem. Commun."},{"key":"D6SC05592C\/cit51\/1","doi-asserted-by":"crossref","first-page":"4724","DOI":"10.1039\/D3SC00909B","volume":"14","author":"Mai","year":"2023","journal-title":"Chem. Sci."},{"key":"D6SC05592C\/cit52\/1","doi-asserted-by":"crossref","first-page":"2677","DOI":"10.1002\/ejic.200601134","volume":"2007","author":"Hanna","year":"2007","journal-title":"Eur. J. Inorg. Chem."},{"key":"D6SC05592C\/cit53\/1","doi-asserted-by":"crossref","first-page":"10318","DOI":"10.1021\/ja0731571","volume":"129","author":"Fafard","year":"2007","journal-title":"J. Am. Chem. Soc."},{"key":"D6SC05592C\/cit54\/1","doi-asserted-by":"crossref","first-page":"1080","DOI":"10.1126\/science.1109389","volume":"307","author":"Zhao","year":"2005","journal-title":"Science"},{"key":"D6SC05592C\/cit55\/1","doi-asserted-by":"crossref","first-page":"486","DOI":"10.1002\/cctc.201501015","volume":"8","author":"Yadav","year":"2016","journal-title":"ChemCatChem"},{"key":"D6SC05592C\/cit56\/1","doi-asserted-by":"crossref","first-page":"e202502326","DOI":"10.1002\/anie.202502326","volume":"64","author":"Sarkar","year":"2025","journal-title":"Angew. Chem., Int. Ed."},{"key":"D6SC05592C\/cit57\/1","doi-asserted-by":"crossref","first-page":"10426","DOI":"10.1021\/ic701479r","volume":"46","author":"Ruspic","year":"2007","journal-title":"Inorg. Chem."},{"key":"D6SC05592C\/cit58\/1","doi-asserted-by":"crossref","first-page":"2912","DOI":"10.1039\/b902810m","author":"Kimura","year":"2009","journal-title":"Dalton Trans."},{"key":"D6SC05592C\/cit59\/1","doi-asserted-by":"crossref","first-page":"146","DOI":"10.1002\/9780470132586.ch27","volume-title":"Inorganic Syntheses","volume":"27","author":"Tilley","year":"1990","unstructured":"T. D.Tilley ,  J. M.Boncella ,  D. J.Berg ,  C. J.Burns ,  R. A.Andersen ,  G. A.Lawless ,  M. A.Edelman  and  M. F.Lappert , in  Inorganic Syntheses , ed.  A. P. Ginsberg ,  Wiley , 1st edn,  1990 , vol.  27 ,  pp. 146\u2013150"},{"key":"D6SC05592C\/cit60\/1","doi-asserted-by":"crossref","first-page":"1113","DOI":"10.1016\/j.jallcom.2004.12.126","volume":"408\u2013412","author":"Imamura","year":"2006","journal-title":"J. Alloys Compd."},{"key":"D6SC05592C\/cit61\/1","doi-asserted-by":"crossref","first-page":"6161","DOI":"10.1021\/acs.inorgchem.6b00736","volume":"55","author":"G\u00f6rne","year":"2016","journal-title":"Inorg. Chem."},{"key":"D6SC05592C\/cit62a\/1","doi-asserted-by":"publisher","year":"2026","unstructured":"CCDC 2566191: Experimental Crystal Structure Determination ,  2026 ,  10.5517\/ccdc.csd.cc2s4bcn .","DOI":"10.5517\/ccdc.csd.cc2s4bcn"},{"key":"D6SC05592C\/cit62b\/1","doi-asserted-by":"publisher","year":"2026","unstructured":"CCDC 2566192: Experimental Crystal Structure Determination ,  2026 ,  10.5517\/ccdc.csd.cc2s4bdp","DOI":"10.5517\/ccdc.csd.cc2s4bdp"},{"key":"D6SC05592C\/cit62c\/1","doi-asserted-by":"publisher","year":"2026","unstructured":"CCDC 2566193: Experimental Crystal Structure Determination ,  2026 ,  10.5517\/ccdc.csd.cc2s4bfq","DOI":"10.5517\/ccdc.csd.cc2s4bfq"},{"key":"D6SC05592C\/cit62d\/1","doi-asserted-by":"publisher","year":"2026","unstructured":"CCDC 2566194: Experimental Crystal Structure Determination ,  2026 ,  10.5517\/ccdc.csd.cc2s4bgr","DOI":"10.5517\/ccdc.csd.cc2s4bgr"},{"key":"D6SC05592C\/cit62e\/1","doi-asserted-by":"publisher","year":"2026","unstructured":"CCDC 2566195: Experimental Crystal Structure Determination ,  2026 ,  10.5517\/ccdc.csd.cc2s4bhs","DOI":"10.5517\/ccdc.csd.cc2s4bhs"},{"key":"D6SC05592C\/cit62f\/1","doi-asserted-by":"publisher","year":"2026","unstructured":"CCDC 2566196: Experimental Crystal Structure Determination ,  2026 ,  10.5517\/ccdc.csd.cc2s4bjt","DOI":"10.5517\/ccdc.csd.cc2s4bjt"},{"key":"D6SC05592C\/cit62g\/1","doi-asserted-by":"publisher","year":"2026","unstructured":"CCDC 2566197: Experimental Crystal Structure Determination ,  2026 ,  10.5517\/ccdc.csd.cc2s4bkv","DOI":"10.5517\/ccdc.csd.cc2s4bkv"},{"key":"D6SC05592C\/cit62h\/1","doi-asserted-by":"publisher","year":"2026","unstructured":"CCDC 2566198: Experimental Crystal Structure Determination ,  2026 ,  10.5517\/ccdc.csd.cc2s4blw","DOI":"10.5517\/ccdc.csd.cc2s4blw"},{"key":"D6SC05592C\/cit62i\/1","doi-asserted-by":"publisher","year":"2026","unstructured":"CCDC 2566199: Experimental Crystal Structure Determination ,  2026 ,  10.5517\/ccdc.csd.cc2s4bmx","DOI":"10.5517\/ccdc.csd.cc2s4bmx"}],"container-title":["Chemical Science"],"original-title":[],"language":"en","link":[{"URL":"http:\/\/pubs.rsc.org\/SC\/article-pdf\/doi\/10.1039\/D6SC05592C\/0\/D6SC05592C.pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,10,5]],"date-time":"2026-10-05T09:58:05Z","timestamp":1791194285000},"score":1,"resource":{"primary":{"URL":"http:\/\/pubs.rsc.org\/SC\/article-lookup\/doi\/10.1039\/D6SC05592C"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026]]},"references-count":70,"URL":"https:\/\/doi.org\/10.1039\/d6sc05592c","relation":{},"ISSN":["2041-6520","2041-6539"],"issn-type":[{"value":"2041-6520","type":"print"},{"value":"2041-6539","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026]]}}}