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Sci."],"abstract":"<jats:p>\n                    Here, we report an iron-catalyzed aerobic transformation that activates N\/O\/S-\u03b1-C(sp\n                    <jats:sup>3<\/jats:sup>\n                    )\u2013H bonds under blue light irradiation, forming hemiacetal-like intermediates, amenable for trapping with diverse commercially available nucleophiles.\n                  <\/jats:p>","DOI":"10.1039\/d6sc05655e","type":"journal-article","created":{"date-parts":[[2026,9,18]],"date-time":"2026-09-18T11:03:02Z","timestamp":1789729382000},"update-policy":"https:\/\/doi.org\/10.1039\/rsc_crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Oxygen-enabled Fe-catalyzed heteroatom \u03b1-C(sp\n                    <sup>3<\/sup>\n                    )\u2013H functionalization with nucleophiles"],"prefix":"10.1039","author":[{"given":"Xinlong","family":"Zhou","sequence":"first","affiliation":[{"name":"College of Chemistry and Molecular Sciences, Henan University, Kaifeng 475004, P. 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