{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,12]],"date-time":"2026-10-12T08:47:11Z","timestamp":1791794831533,"version":"4.3.4"},"reference-count":40,"publisher":"Royal Society of Chemistry (RSC)","license":[{"start":{"date-parts":[[2026,10,7]],"date-time":"2026-10-07T00:00:00Z","timestamp":1791331200000},"content-version":"vor","delay-in-days":279,"URL":"http:\/\/creativecommons.org\/licenses\/by-nc\/3.0\/"}],"funder":[{"DOI":"10.13039\/501100001843","name":"Anusandhan National Research Foundation","doi-asserted-by":"publisher","award":["CRG\/2023\/004627"],"award-info":[{"award-number":["CRG\/2023\/004627"]}],"id":[{"id":"10.13039\/501100001843","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["rsc.org"],"crossmark-restriction":true},"short-container-title":["Chem. Sci."],"abstract":"<jats:p>\n                    A metal-free, boron-tethered N-heterocyclic nitrenium (NHN) catalyst enables synergistic CO\n                    <jats:sub>2<\/jats:sub>\n                    fixation into epoxides at 25 \u00b0C and 1 bar, efficiently yielding cyclic carbonates to advance sustainable main-group catalysis.\n                  <\/jats:p>","DOI":"10.1039\/d6sc05761f","type":"journal-article","created":{"date-parts":[[2026,10,7]],"date-time":"2026-10-07T14:46:01Z","timestamp":1791384361000},"update-policy":"https:\/\/doi.org\/10.1039\/rsc_crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Metal-free CO\n                    <sub>2<\/sub>\n                    fixation: conversion of epoxides to cyclic carbonates by a highly efficient bifunctional boron-tethered N-heterocyclic nitrenium catalyst"],"prefix":"10.1039","author":[{"given":"Rahul","family":"Mondal","sequence":"first","affiliation":[{"name":"Department of Inorganic and Physical Chemistry, Indian Institute of Science, Bangalore-560012, India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Reetu Rani","family":"Mondal","sequence":"additional","affiliation":[{"name":"Department of Inorganic and Physical Chemistry, Indian Institute of Science, Bangalore-560012, India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2064-1297","authenticated-orcid":false,"given":"K.","family":"Geetharani","sequence":"additional","affiliation":[{"name":"Department of Inorganic and Physical Chemistry, Indian Institute of Science, Bangalore-560012, India"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"292","published-online":{"date-parts":[[2026]]},"reference":[{"key":"D6SC05761F\/cit1\/1","doi-asserted-by":"crossref","first-page":"920","DOI":"10.1126\/science.aan5360","volume":"361","author":"Nolan","year":"2018","journal-title":"Science"},{"key":"D6SC05761F\/cit2\/1","doi-asserted-by":"crossref","first-page":"434","DOI":"10.1021\/acs.chemrev.7b00435","volume":"118","author":"Artz","year":"2018","journal-title":"Chem. Rev."},{"key":"D6SC05761F\/cit3\/1","doi-asserted-by":"crossref","first-page":"102239","DOI":"10.1016\/j.jcou.2022.102239","volume":"65","author":"Kim","year":"2022","journal-title":"J. CO2 Util."},{"key":"D6SC05761F\/cit4\/1","doi-asserted-by":"crossref","first-page":"5445","DOI":"10.1039\/D3SE00775H","volume":"7","author":"Detz","year":"2023","journal-title":"Sustainable Energy Fuels"},{"key":"D6SC05761F\/cit5\/1","doi-asserted-by":"crossref","first-page":"2892","DOI":"10.1021\/acs.accounts.9b00324","volume":"52","author":"Kar","year":"2019","journal-title":"Acc. Chem. Res."},{"key":"D6SC05761F\/cit6\/1","doi-asserted-by":"crossref","first-page":"10571","DOI":"10.1039\/D0SC03528A","volume":"11","author":"P","year":"2020","journal-title":"Chem. Sci."},{"key":"D6SC05761F\/cit7\/1","doi-asserted-by":"crossref","first-page":"15023","DOI":"10.1039\/D4SC02888K","volume":"15","author":"Desmons","year":"2024","journal-title":"Chem. Sci."},{"key":"D6SC05761F\/cit8\/1","doi-asserted-by":"crossref","first-page":"20397","DOI":"10.1021\/acscatal.5c06417","volume":"15","author":"Ghosh","year":"2025","journal-title":"ACS Catal."},{"key":"D6SC05761F\/cit9\/1","doi-asserted-by":"crossref","first-page":"2436","DOI":"10.1002\/cssc.201500161","volume":"8","author":"Cokoja","year":"2015","journal-title":"ChemSusChem"},{"key":"D6SC05761F\/cit10\/1","doi-asserted-by":"crossref","first-page":"82","DOI":"10.1016\/j.gce.2020.09.008","volume":"1","author":"Zhang","year":"2020","journal-title":"Green Chem. Eng."},{"key":"D6SC05761F\/cit11\/1","doi-asserted-by":"crossref","first-page":"100457","DOI":"10.1016\/j.cogsc.2021.100457","volume":"29","author":"Pescarmona","year":"2021","journal-title":"Curr. Opin. Green Sustainable Chem."},{"key":"D6SC05761F\/cit12\/1","doi-asserted-by":"crossref","first-page":"77","DOI":"10.1039\/D0GC03465G","volume":"23","author":"Guo","year":"2021","journal-title":"Green Chem."},{"key":"D6SC05761F\/cit13\/1","doi-asserted-by":"crossref","first-page":"4303","DOI":"10.1021\/cr030203g","volume":"104","author":"Xu","year":"2004","journal-title":"Chem. Rev."},{"key":"D6SC05761F\/cit14\/1","doi-asserted-by":"crossref","first-page":"4545","DOI":"10.1039\/c3py00343d","volume":"4","author":"Besse","year":"2013","journal-title":"Polym. Chem."},{"key":"D6SC05761F\/cit15\/1","doi-asserted-by":"crossref","first-page":"14194","DOI":"10.1021\/jacs.6b08841","volume":"138","author":"Cai","year":"2016","journal-title":"J. Am. Chem. Soc."},{"key":"D6SC05761F\/cit16\/1","doi-asserted-by":"crossref","first-page":"931","DOI":"10.1002\/anie.200803896","volume":"48","author":"Kember","year":"2009","journal-title":"Angew. Chem., Int. Ed."},{"key":"D6SC05761F\/cit17\/1","doi-asserted-by":"crossref","first-page":"1228","DOI":"10.1021\/ja311053h","volume":"135","author":"Whiteoak","year":"2013","journal-title":"J. Am. Chem. Soc."},{"key":"D6SC05761F\/cit18\/1","doi-asserted-by":"crossref","first-page":"15270","DOI":"10.1021\/ja507665a","volume":"136","author":"Ema","year":"2014","journal-title":"J. Am. Chem. Soc."},{"key":"D6SC05761F\/cit19\/1","doi-asserted-by":"crossref","first-page":"6882","DOI":"10.1021\/acscatal.8b01695","volume":"8","author":"Della Monica","year":"2018","journal-title":"ACS Catal."},{"key":"D6SC05761F\/cit20\/1","doi-asserted-by":"crossref","first-page":"6906","DOI":"10.1021\/acscatal.6b02265","volume":"6","author":"Toda","year":"2016","journal-title":"ACS Catal."},{"key":"D6SC05761F\/cit21\/1","doi-asserted-by":"crossref","first-page":"2589","DOI":"10.1021\/acscatal.7b04389","volume":"8","author":"Bobbink","year":"2018","journal-title":"ACS Catal."},{"key":"D6SC05761F\/cit22\/1","doi-asserted-by":"crossref","first-page":"100018","DOI":"10.1016\/j.scca.2023.100018","volume":"2","author":"Stiernet","year":"2023","journal-title":"Sustainable Chem. Clim. Action"},{"key":"D6SC05761F\/cit23\/1","doi-asserted-by":"crossref","first-page":"e202500002","DOI":"10.1002\/cctc.202500002","volume":"17","author":"Kilic","year":"2025","journal-title":"ChemCatChem"},{"key":"D6SC05761F\/cit24\/1","doi-asserted-by":"crossref","first-page":"1799","DOI":"10.1021\/acscatal.8b04282","volume":"9","author":"Andrea","year":"2019","journal-title":"ACS Catal."},{"key":"D6SC05761F\/cit25\/1","doi-asserted-by":"crossref","first-page":"172","DOI":"10.1016\/j.jcou.2018.12.006","volume":"29","author":"Zhao","year":"2019","journal-title":"J. CO2 Util."},{"key":"D6SC05761F\/cit26\/1","doi-asserted-by":"crossref","first-page":"15717","DOI":"10.1021\/acs.joc.3c01702","volume":"88","author":"Luo","year":"2023","journal-title":"J. Org. Chem."},{"key":"D6SC05761F\/cit27\/1","doi-asserted-by":"crossref","first-page":"101873","DOI":"10.1016\/j.jcou.2021.101873","volume":"57","author":"Ge","year":"2022","journal-title":"J. CO2 Util."},{"key":"D6SC05761F\/cit28\/1","doi-asserted-by":"crossref","first-page":"4871","DOI":"10.1021\/acscatal.6b01422","volume":"6","author":"Wang","year":"2016","journal-title":"ACS Catal."},{"key":"D6SC05761F\/cit29\/1","doi-asserted-by":"crossref","first-page":"6692","DOI":"10.1039\/D4CY01052C","volume":"14","author":"Luo","year":"2024","journal-title":"Catal. Sci. Technol."},{"key":"D6SC05761F\/cit30\/1","doi-asserted-by":"crossref","first-page":"23291","DOI":"10.1002\/anie.202010651","volume":"59","author":"Zhang","year":"2020","journal-title":"Angew. Chem., Int. Ed."},{"key":"D6SC05761F\/cit31\/1","doi-asserted-by":"crossref","first-page":"525","DOI":"10.1038\/nchem.1068","volume":"3","author":"Tulchinsky","year":"2011","journal-title":"Nat. Chem."},{"key":"D6SC05761F\/cit32\/1","doi-asserted-by":"crossref","first-page":"7099","DOI":"10.1002\/chem.201405526","volume":"21","author":"Tulchinsky","year":"2015","journal-title":"Chem. \u2013 Eur. J."},{"key":"D6SC05761F\/cit33\/1","doi-asserted-by":"crossref","first-page":"4062","DOI":"10.1021\/jacs.6b12360","volume":"139","author":"Pogoreltsev","year":"2017","journal-title":"J. Am. Chem. Soc."},{"key":"D6SC05761F\/cit34\/1","doi-asserted-by":"crossref","first-page":"2715","DOI":"10.1002\/anie.201915547","volume":"59","author":"Mehta","year":"2020","journal-title":"Angew. Chem., Int. Ed."},{"key":"D6SC05761F\/cit35\/1","doi-asserted-by":"crossref","first-page":"6105","DOI":"10.1021\/acs.orglett.2c01697","volume":"24","author":"Danelzik","year":"2022","journal-title":"Org. Lett."},{"key":"D6SC05761F\/cit36\/1","doi-asserted-by":"crossref","first-page":"4598","DOI":"10.1021\/acs.orglett.2c01702","volume":"24","author":"Chen","year":"2022","journal-title":"Org. Lett."},{"key":"D6SC05761F\/cit37\/1","doi-asserted-by":"crossref","first-page":"e202500093","DOI":"10.1002\/ceur.202500093","volume":"3","author":"Mondal","year":"2025","journal-title":"ChemistryEurope"},{"key":"D6SC05761F\/cit38\/1","doi-asserted-by":"crossref","first-page":"1255","DOI":"10.1055\/s-0043-1775401","volume":"57","author":"Li","year":"2025","journal-title":"Synthesis"},{"key":"D6SC05761F\/cit39\/1","doi-asserted-by":"crossref","first-page":"5140","DOI":"10.1021\/acs.inorgchem.5c05901","volume":"65","author":"Bolch","year":"2026","journal-title":"Inorg. Chem."},{"key":"D6SC05761F\/cit40\/1","doi-asserted-by":"publisher","year":"2026","unstructured":"CCDC 2563179 (for Cat 1): Experimental Crystal Structure Determination ,  2026 ,  10.5517\/ccdc.csd.cc2s1668 .","DOI":"10.5517\/ccdc.csd.cc2s1668"}],"container-title":["Chemical Science"],"original-title":[],"language":"en","link":[{"URL":"http:\/\/pubs.rsc.org\/SC\/article-pdf\/doi\/10.1039\/D6SC05761F\/0\/D6SC05761F.pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,10,12]],"date-time":"2026-10-12T08:24:34Z","timestamp":1791793474000},"score":1,"resource":{"primary":{"URL":"http:\/\/pubs.rsc.org\/SC\/article-lookup\/doi\/10.1039\/D6SC05761F"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026]]},"references-count":40,"URL":"https:\/\/doi.org\/10.1039\/d6sc05761f","relation":{"has-preprint":[{"id-type":"doi","id":"10.26434\/chemrxiv.15004615\/v1","asserted-by":"object"}]},"ISSN":["2041-6520","2041-6539"],"issn-type":[{"value":"2041-6520","type":"print"},{"value":"2041-6539","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026]]}}}